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At least 721 records · Page 40

Classification of Simple Vegetation Types Using POLSAR Image Data

Mapping basic vegetation or land cover types is a fairly common problem in remote sensing. Knowledge of the land cover type is a key input to algorithms which estimate geophysical parameters, such as soil moisture, surface roughness, leaf area index or biomass from remotely sensed data. In an earlier paper, an algorithm for fitting a simple three-component scattering model to POLSAR data was presented. The algorithm yielded estimates for surface scatter, double-bounce scatter and volume scatter for each pixel in a POLSAR image data set. In this paper, we show how the relative levels of each of the three components can be used as inputs to a simple classifier for vegetation type.

Freeman, A.↗

Albedo maps of Pluto and Charon - Initial mutual event results

By applying the technique of maximum entropy image reconstruction to invert observed lightcurves, surface maps of single-scattering albedo are obtained for the surfaces of Pluto and Charon from 1954 to 1986. The albedo features of the surface of Pluto are similar to those of the Buie and Tholen (1989) spot model maps; a south polar cap is evident. The map of Charon is somewhat darker, with single-scattering albedos as low as 0.03.

Buie, Marc W.↗

Surface Height and Sea Ice Freeboard of the Arctic Ocean from ICESat-2: Characteristics and Early Results

We present the first winter season of surface height and sea ice freeboards of the Arctic Ocean from the new ICESat-2 (IS-2) mission. The Advanced Topographic Laser Altimeter System (ATLAS) onboard has six photon-counting beams for surface profiling with a 10-kHz pulse-rate (inter-pulse distance ~0.7m) and footprints of ~17m. Geolocated heights assigned to individual photons scattered from the surface allow significant flexibility in the construction of height distributions used in surface finding. For IS-2 sea ice products, a fixed 150-photon aggregate is used to control height precision and obtain better along-track resolution over high reflectance surfaces. Quasi-specular returns in openings as narrow as ~27m, crucial for freeboard calculations, are resolved. The fixed photon aggregate results in unique variable along-track resolutions and non-uniform sampling (17m x 27m to 17m x 200m for the strong beams) of the surface. The six profiling beams – three pairs separated by 3.3 km with a strong and weak beam in each pair – provide correlated statistics at regional length scales for assessment of beam-to-beam retrieval consistency and accuracy. Analysis shows along-track height precisions of ~2cm, and agreement in the monthly freeboard distributions across the strong beams to 1-2cm. In this paper, we describe briefly the approaches used in surface height and freeboard retrievals from ATLAS photon clouds, and detail the key features of these along-track sea ice products, focusing on the first release of data collected over the Arctic Ocean, which spans the period between October 14, 2018 – the start of data collection – and the end of March 2019.

R Kwok↗

Direct dioxygen evolution in collisions of carbon dioxide with surfaces

The intramolecular conversion of CO 2 to molecular oxygen is an exotic reaction, rarely observed even with extreme optical or electronic excitation means. Here we show that this reaction occurs readily when CO 2 ions scatter from solid surfaces in a two-step sequential collision process at hyperthermal incidence energies. The produced O 2 is preferentially ionized by charge transfer from the surface over the predominant atomic oxygen product, leading to direct detection of both O 2 + and O 2 - . First-principles simulations of the collisional dynamics reveal that O 2 production proceeds via strongly-bent CO 2 configurations, without visiting other intermediates. Bent CO 2 provides dynamic access to the symmetric dissociation of CO2 to C+O2 with a calculated yield of 1 to 2% depending on molecular orientation. This unexpected collision-induced transformation of individual CO 2 molecules provides an accessible pathway for generating O 2 in astrophysical environments and may inspire plasmadriven electro- and photo-catalytic strategies for terrestrial CO 2 reduction.

59 BASIC BIOLOGICAL SCIENCES↗

Poly(N-isopropylacrylamide)-grafted gold nanoparticles at the vapor/water interface

Hypothesis: Grafting nanoparticles surfaces with water-soluble polymers modify interparticle interactions that are pivotal for assembling them into ordered phases. By manipulating salt concentrations of gold nanoparticles (AuNPs) that are grafted with poly(N-isopropylacrylamide) (PNIPAM-AuNPs), we hypothesize that various aggregated phases form at the suspension/vapor interface or in the bulk that depend on the molecular weight (MW) of PNIPAM and on salt concentrations. Experiments: AuNPs are grafted with thiolated PNIPAM of molecular weights of 3 or 6 kDa, and grafting is confirmed by dynamic light scattering. Liquid-surfaces X-ray reflectivity and grazing incidence small-angle X-ray scattering are used to determine the density profiles of the suspension/vapor interface and their inplane structure as salt is added to the suspensions. Findings: We observe that surface enrichment is induced by adding NaCl to the suspensions, and that at low salt concentrations, the monoparticle layer formed is dispersed, and above a threshold salt concentration, depending on MW of PNIPAM, the PNIPAM-AuNPs order in a hexagonal structure. We show that the lattice constant of the two-dimensional hexagonal structure varies with salt concentration, and more significantly with MW of PNIPAM.

36 MATERIALS SCIENCE↗

The photometric functions of Phobos and Deimos. III - Surface photometry of Phobos

Mariner 9 television pictures of Phobos are used to study the uniformity of a certain photometric scattering parameter over the surface of the satellite, assuming that the scattering law for Phobos can be represented by the Hapke-Irvine equation. Ways of avoiding topographically irregular areas are discussed, phase functions for Phobos are obtained from scans along the photometric equator, and the photometric behavior of selected areas not along this equator is examined. Searches are conducted for anomalously bright areas and evidence of solid rock on the surface. The results indicate that: (1) at least three large regions on the surface of Phobos are covered by a dark material of complex texture which scatters light according to the Hapke-Irvine law; (2) the average intrinsic phase coefficient of this material is 0.020 mag/deg over the phase-angle range from 20 to 80 deg; (3) even the topographically irregular areas have photometric properties similar to those of the three smooth regions; (4) the surface of Phobos is rougher than that of Deimos on the largest scale; and (5) apparent bright patches are most likely caused by local tilts of the surface.

Noland, M.↗

Seasonal Dependent Impact of Ice Cloud Longwave Scattering on the Polar Climate

Most climate models neglect cloud longwave (LW) scattering because scattering is considered negligible compared to strong LW absorption by clouds and greenhouse gases. While this rationale is valid for simulating extrapolar regions, it is questionable for the polar regions, where the atmosphere is dry and hence has weak absorption, and ice clouds that have strong scattering capability frequently occur. Using the slab-ocean Community Earth System Model, we show that ice cloud LW scattering can warm winter surface air temperature by 0.8–1.8 K in the Arctic and 1.3–1.9 K in the Antarctic, while this warming becomes much weaker in polar summer. Such scattering effect cannot be correctly assessed when sea surface temperature and sea ice are prescribed as this effect is manifested through a surface-atmosphere coupling. Furthermore, cloud LW scattering is a necessity for the correct simulation of polar climate and surface radiation budget, especially in the winter.

54 ENVIRONMENTAL SCIENCES↗

Aging gracefully? Investigating iridium oxide ink's impact on microstructure, catalyst/ionomer interface, and PEMWE performance

Here, in this study, we conducted a thorough investigation of the impact of aging iridium oxide (IrO 2 ) perfluorosulfonic acid ionomer ink for up to 14 days on the properties of the ink and the resulting catalyst layers. We examined ink properties, such as zeta potential, dynamic light scattering (DLS), density, surface tension, and rheology, as functions of ink aging time. To evaluate the microstructure and catalyst/ionomer interface, we employed transmission electron microscopy (TEM), X-ray scattering, and X-ray photoelectron spectroscopy (XPS) techniques. Furthermore, we assessed the effect of ink aging on the performance of proton exchange membrane water electrolyzers (PEMWEs). Our findings reveal that most ink properties remain stable for 14 days. The variations in PEMWE cell performance are minimal, and no clear trend is observed in relation to ink aging time. This study demonstrates that the effects of aging the inks for 14 days on ink properties, catalyst layer structure, catalyst/ionomer interface, and PEMWE performance are negligible, indicating a substantial time window after ink preparation without any significant changes in its properties. These insights provide crucial guidance for the commercial production and coating processes of ink, which is necessary for scaling up PEM technologies to meet future demand.

30 DIRECT ENERGY CONVERSION↗

Combined High-Resolution Active and Passive Imaging of Ocean Surface Winds from Aircraft

A unique complement of passive and active microwave imaging and sensing instruments for observing ocean surface emission and scattering signatures were integrated onto the NASA Wallops Flight Facility's Orion P-3B aircraft (N426NA) for the purpose of studying the signature of ocean surface winds. The complement included: (1) a, four-band (X, K, Ka, and W) tri-polarimetric scanning radiometer (PSR), (2) a C-band ocean surface scatterometer (CSCAT), (3) a Ka-band conical-scanning polarimetric radiometer (KASPR), (4) a nadir-viewing Ka-band polarimetric radiometer, (KAPOL), (5) a 21- and 31-GHz zenith-viewing cloud and water vapor radiometer (CWVR), and (6) a radar ocean wave spectrometer (ROWS). The above Ocean Winds Imaging (OWI) complement was flown during January-March, 1997 over the Labrador Sea. Conically-scanned brightness temperature and backscatter imagery were observed over open ocean for a variety of wind speeds and cloud conditions. Presented herein are the results of a preliminary intercomparison of data from several of the OWI instruments.

Gasiewski, A. J.↗

APC: A New Code for Atmospheric Polarization Computations

A new polarized radiative transfer code Atmospheric Polarization Computations (APC) is described. The code is based on separation of the diffuse light field into anisotropic and smooth (regular) parts. The anisotropic part is computed analytically. The smooth regular part is computed numerically using the discrete ordinates method. Vertical stratification of the atmosphere, common types of bidirectional surface reflection and scattering by spherical particles or spheroids are included. A particular consideration is given to computation of the bidirectional polarization distribution function (BPDF) of the waved ocean surface.

surface reflection↗

Electronic structure, and magnetic and superconducting pairing tendencies of the alternating single layer–bilayer stacking nickelate La 5 ⁢Ni 3 ⁢O 11 under pressure

Nickelates have continued to surprise since their unconventional superconductivity was discovered. Recently, the layered nickelate La 5 ⁢Ni 3 ⁢O 11 with hybrid single-layer and bilayer stacking showed superconductivity under high pressure. This compound combines features of single-layer La 2 ⁢NiO 4 and bilayer La 3 ⁢Ni 2 ⁢O 7 , but its pairing mechanism remains to be understood. Motivated by this finding, here we report a comprehensive theoretical study of this system. Our density functional theory calculations reveal that the undistorted P4/mmm phase without pressure is unstable due to three distortion modes. As pressure increases, these modes are suppressed, leading to the high-symmetry P4/mmm phase without NiO 6 octahedron tilting. Moreover, the “charge transfer” between the single-layer and bilayer sublattices was observed, leading to hole doping in the single-layer blocks. Our random-phase approximation calculations indicate a leading 𝑑 𝑥 2 −𝑦 2 -wave pairing state that arises from spin-fluctuation scattering between Fermi surface states mainly originating from the single-layer blocks and additional weaker contributions from the bilayer blocks. These spin fluctuations could be detected by inelastic neutron scattering as a strong peak at 𝐪 = (𝜋,𝜋). Our findings distinguish La 5 ⁢Ni 3 ⁢O 11 from other nickelate superconductors discovered so far and the high-𝑇 𝑐 cuprates. We also discuss both similarities and differences between La 5⁢ Ni 3 ⁢O 11 and other hybrid stacking nickelates.

Zhang, Yang [Univ. of Tennessee, Knoxville, TN (Un↗

A combined finite element-boundary element formulation for solution of axially symmetric bodies

A new method is presented for the computation of electromagnetic scattering from axially symmetric bodies. To allow the simulation of inhomogeneous cross sections, the method combines the finite element and boundary element techniques. Interior to a fictitious surface enclosing the scattering body, the finite element method is used which results in a sparce submatrix, whereas along the enclosure the Stratton-Chu integral equation is enforced. By choosing the fictitious enclosure to be a right circular cylinder, most of the resulting boundary integrals are convolutional and may therefore be evaluated via the FFT with which the system is iteratively solved. In view of the sparce matrix associated with the interior fields, this reduces the storage requirement of the entire system to O(N) making the method attractive for large scale computations. The details of the corresponding formulation and its numerical implementation are described.

Collins, Jeffrey D.↗

The photometric functions of Phobos and Deimos. II - Surface photometry of Deimos

Mariner 9 television pictures of Deimos are used to study the uniformity of a certain photometric scattering parameter over the surface of the satellite. It is shown that the photometric data considered satisfy the reciprocity principle and that the Hapke-Irvine scattering law is adequate for describing the surface. Phase functions for Deimos are obtained from scans along the photometric equator, and the photometric behavior of the brightest and darkest areas on the satellite's disk is examined. The results indicate that the surface of Deimos is covered uniformly by a dark and texturally complex material whose photometric behavior is well-represented by the Hapke-Irvine law, that the intrinsic phase coefficient of this material is about 0.017 mag/deg over the phase-angle range from 20 to 80 deg, and that slightly brighter material is present near some craters. Since enhanced brightening was not observed at the specular point of the photometric equator in any of the pictures studied, it is concluded that large exposures of solid rock are absent from the Mars-facing side of Deimos.

Noland, M.↗

Modeling Spectral Degradation of MODIS and VIIRS Solar Diffusers

Solar diffusers (SDs) onboard the Moderate Resolution Imaging Spectroradiometer (MODIS) on Terra and Aqua spacecraft and the Visible Infrared Imaging Radiometer Suite (VIIRS) on SNPP and NOAA-20 spacecraft have been used as the primary onboard radiometric calibrator for reflective solar bands and their spectral reflectance is known to degrade on-orbit. All of the solar diffusers on these instrument show faster degradation of reflectance in the 0.4 to 0.6 µm channels than the longer wavelength channels. The spectral degradation of these SDs is due to the surface roughness growth under the exposure to solar UV and energetic particle radiation in space. In this paper, the origin of SD degradation is modeled by the physics-based Surface Roughness-induced Rayleigh Scattering (SRRS) model. The longterm growths of surface roughness of the SD on these instruments are characterized to show the consistency of SD roughness growth rates between Terra/Aqua MODIS and SNPP/NOAA-20 VIIRS. There was coincidental flattening or reverse in the growth trend of the surface roughness for the Terra/Aqua MODIS and SNPP VIIRS SDs, which can be due to the space weather variation. The applicability of the SRRS model is demonstrated with the long term spectral reflectance data from independent spaceborne SDs.

Calibration↗

Stationary and non-stationary nonlinear optical spectroscopy on surface polaritons

A phenomenological theory is given for non-stationary electromagnetic surface waves propagating along the boundary plane between two homogeneous isotropic media. The description of nonlinear optical effects using shortened wave equations is demonstrated for spontaneous and simulated Raman scattering processes on surface polaritons.

Ponath, H. E.↗

Multipath induced errors in meteorological Doppler/interferometer location systems

One application of an RF interferometer aboard a low-orbiting spacecraft to determine the location of ground-based transmitters is in tracking high-altitude balloons for meteorological studies. A source of error in this application is reflection of the signal from the sea surface. Through propagating and signal analysis, the magnitude of the reflection-induced error in both Doppler frequency measurements and interferometer phase measurements was estimated. The theory of diffuse scattering from random surfaces was applied to obtain the power spectral density of the reflected signal. The processing of the combined direct and reflected signals was then analyzed to find the statistics of the measurement error. It was found that the error varies greatly during the satellite overpass and attains its maximum value at closest approach. The maximum values of interferometer phase error and Doppler frequency error found for the system configuration considered were comparable to thermal noise-induced error.

Wallace, R. G.↗

Interferometric SAR for observation of glacier motion and firn penetration

A digital elevation model (DEM) for a swath in west Greenland above Jakobshavn Isbrae derived from a number ERS-1 interferograms combined so as to reduce phase errors and other problems is presented. The DEM shows a wealth of kilometer-scale, dynamically supported topography, which arises from ice sheet flow over the rough bed. A correlation is shown between topography and interferometric phase due solely to ice sheet motion, which clearly shows the translations of scatterers in the surface up and downslope in the topography. Finally, the low correlation in interferograms of ice sheet dry snow zones motivates investigation on the depth-locus of backscattering. A scattering model is presented, including realistic firn grain size distributions and layering, which shows that layering helps to localize backscattering from dry firn to shallower depths than would otherwise be expected.

Winebrenner, Dale P.↗