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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 739 records · Page 41

Data-Driven Mapping of the Cesium Cadmium Bromide Phase Space Utilizing a Soft-Chemistry Approach

Soft-chemistry techniques provide a versatile approach to synthesizing inorganic materials under mild conditions, enabling access to compositions and structures that are challenging to achieve through traditional thermodynamically driven solid-state methods. However, these solution-based routes often result in phase competition, requiring precise control over reaction conditions to achieve selective product formation. While one-variable-at-a-time (OVAT) approaches have traditionally been used for phase selection, data-driven strategies are emerging as more efficient methods for navigating complex synthetic spaces. Ternary metal halides, such as cesium cadmium bromides (Cs–Cd–Br), are of growing interest due to their potential in wide and ultrawide band gap applications. Unlike the well-studied cesium lead halide phases, the compositional diversity and solution-based synthesis of ternary Cs–Cd–Br phases remain largely unexplored. This study systematically investigates the synthetic phase space of the Cs–Cd–Br system by constructing a data-driven phase map. Using a common set of precursors and a standardized experimental procedure, we successfully synthesize all four known Cs–Cd–Br phases—CsCdBr 3 , Cs 2 CdBr 4 , Cs 3 CdBr 5 , and Cs 7 Cd 3 Br 13 —each exhibiting distinct structures, morphologies, and optical properties. Our findings highlight the potential of soft-chemistry methods for expanding the library of ternary metal halides and provide key insights into the thermodynamic and kinetic factors governing phase formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Economical space power systems

A commercial approach to design and fabrication of an economical space power system is investigated. Cost projections are based on a 2 kW space power system conceptual design taking into consideration the capability for serviceability, constraints of operation in space, and commercial production engineering approaches. A breakdown of the system design, documentation, fabrication, and reliability and quality assurance estimated costs are detailed.

Burkholder, J. H.↗

Historical and projected power requirements

Policy planning for projected space power requirements is discussed. Topics of discussion cover: (1) historical space power trends (prime power requirements and power system costs); and (2) two approaches to future space power requirements (mission/traffic model approach and advanced system scenario approach). Graphs, tables, and flow charts are presented.

Wolfe, M. G.↗

Energy impact assessment of NASA's past, present, and future space launch vehicles

An approach to analyze the total energy required for overall support of space launch vehicles is outlined along with some of the basic data required for such analyses. Selected results obtained by using this approach are presented for various past (some are already phased out), present, and future NASA launch vehicles, including an estimate of the total annual energy required to support one projected NASA launch vehicle traffic model. The material presented is expected to give a better insight into the details of an energy impact analysis. Major conclusions are that: (1) for expendable launch vehicle systems, the energy required to manufacture hardware and support launch operations is most significant; (2) for totally reusable systems, the energy required to process/manufacture propellants and fluids is by far the most significant contributor; and (3) up to 1991, the projected highest annual energy requirement for the NASA launch vehicles does not constitute a significant energy impact relative to the nation's total energy needs.

Rice, E. E.↗

Rocket Ejector Studies for Application to RBCC Engines: An Integrated Experimental/CFD Approach

Recent interest in low cost, reliable access to space has generated increased interest in advanced technology approaches to space transportation systems. A key to the success of such programs lies in the development of advanced propulsion systems capable of achieving the performance and operations goals required for the next generation of space vehicles. One extremely promising approach involves the combination of rocket and air- breathing engines into a rocket-based combined-cycle engine (RBCC). A key element of that engine is the rocket ejector which is utilized in the zero to Mach two operating regime. Studies of RBCC engine concepts are not new and studies dating back thirty years are well documented in the literature. However, studies focused on the rocket ejector mode of the RBCC cycle are lacking. The present investigation utilizes an integrated experimental and computation fluid dynamics (CFD) approach to examine critical rocket ejector performance issues. In particular, the development of a predictive methodology capable of performance prediction is a key objective in order to analyze thermal choking and its control, primary/secondary pressure matching considerations, and effects of nozzle expansion ratio. To achieve this objective, the present study emphasizes obtaining new data using advanced optical diagnostics such as Raman spectroscopy and CFD techniques to investigate mixing in the rocket ejector mode. A new research facility for the study of the rocket ejector mode is described along with the diagnostic approaches to be used. The CFD modeling approach is also described along with preliminary CFD predictions obtained to date.

Pal, S.↗

Transition-Metal-Related Quantum Emitters in Wurtzite AlN and GaN

Transition-metal centers exhibit a paramagnetic ground state in wide-bandgap semiconductors and are promising for nanophotonics and quantum information processing. Specifically, there is a growing interest in discovering prominent paramagnetic spin defects that can be manipulated using optical methods. Here, we investigate the electronic structure and magneto-optical properties of Cr and Mn substitutional centers in wurtzite AlN and GaN. We use state-of-the-art hybrid density functional theory calculations to determine level structure, stability, optical signatures, and magnetic properties of these centers. The excitation energies are calculated using the constrained occupation approach and rigorously verified with the complete active space configuration interaction approach. Our simulations of the photoluminescence spectra indicate that $Cr$$^{1+}_{Al}$ in AlN and $Cr$$^{1+}_{Ga}$ in GaN are responsible for the observed narrow quantum emission near 1.2 eV. We compute the zero-field splitting (ZFS) parameters and outline an optical spin polarization protocol for $Cr$$^{1+}_{Al}$ and $Cr$$^{1+}_{Ga}$. Our results demonstrate that these centers are promising candidates for spin qubits.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Fundamental studies of heat load and thermal-structure analysis of large space structures

Investigation of the basic requirements for modeling slender member shadowing effects on thermally induced deformation continues. The theoretical formulation is complete and computer programming is underway. The basic requirements for thermal finite elements to model heat transfer in orbiting structures were also studied. The need for planar isothermal elements to model large space structures' antenna meshes was established. Finite Element approaches for modeling space structure cable and membrane components with thermal effects is underway. Three levels of structural modeling and analysis were identified: (1) a linear-elastic small deflection analysis that does not permit cable slackening; (2) a linear-elastic analysis that includes stress stiffening (the ANSYS program), but not large deflections; and (3) full nonlinear large deflection analysis with stress stiffening. Methods of determining cable initial tensions are currently being evaluated.

Thornton, E. A.↗

Iterative refinement scheduling

We present a heuristics-based approach to deep space mission scheduling which is modeled on the approach used by expert human schedulers in producing schedules for planetary encounters. New chronological evaluation techniques are used to focus the search by using information gained during the scheduling process to locate, classify, and resolve regions of conflict. Our approach is based on the assumption that during the construction of a schedule there exist several disjunct temporal regions where the demand for one resource type or a single temporal constraint dominates (bottleneck regions). If the scheduler can identify these regions and classify them based on their dominant constraint, then the scheduler can select the scheduling heuristic.

Biefeld, Eric↗

We Must Take the Next Steps Towards Safe, Routine Space Travel

This paper presents, in viewgraph form, six in a half generations of airplanes in a century. Some of the topics include: 1) Enterprise goals; 2) Generations of Reusable Launch Vehicles; 3) Space Transportation Across NASA; 4) Three Tiered Implementation Approach for Future Space Transportation Technology; 5) Develop a Comprehensive, Agency Level Space Transportation Plan That Will Enable NASA's Strategic Plan; 6) Timeline for Addressing NASA's Needs; 7) Significant 2nd Generation Technology Drivers; 8) Example Large Scale Ground Demonstrations; and 9) Example Pathfinder Demonstrations. The paper also includes various aircraft designs and propulsion system technology.

Lyles, G. M.↗

Prevention of Spacecraft Anomalies: The Role of Space Climate and Space Weather Models

Space-based systems are developing into critical infrastructure to support the quality of life on Earth. Mission requirements along with rapidly evolving technologies have outpaced efforts to accommodate detrimental space environment impacts on systems. This chapter describes approaches to accommodate space climate and space weather impacts on systems and notes areas where gaps in model development limit our ability to prevent spacecraft anomalies.

Barth, Janet L.↗

Design Considerations for Spacecraft Operations During Uncrewed Dormant Phases of Human Exploration Missions

NASA is transforming human spaceflight. The Agency is shifting from an exploration-based program with human activities in low Earth orbit (LEO) and targeted robotic missions in deep space to a more sustainable and integrated pioneering approach. However, pioneering space involves daunting technical challenges of transportation, maintaining health, and enabling crew productivity for long durations in remote, hostile, and alien environments. Subject matter experts from NASA's Human Exploration and Operations Mission Directorate (HEOMD) are currently studying a human exploration campaign that involves deployment of assets for planetary exploration. This study, called the Evolvable Mars Campaign (EMC) study, explores options with solar electric propulsion as a central component of the transportation architecture. This particular in-space transportation option often results in long duration transit to destinations. The EMC study is also investigating deployed human rated systems like landers, habitats, rovers, power systems and ISRU system to the surface of Mars, which also will involve long dormant periods when these systems are staged on the surface. In order to enable the EMC architecture, campaign and element design leads along with system and capability development experts from HEOMD's System Maturation Team (SMT) have identified additional capabilities, systems and operation modes that will sustain these systems especially during these dormant phases of the mission. Dormancy is defined by the absence of crew and relative inactivity of the systems. For EMC missions, dormant periods could range from several months to several years. Two aspects of uncrewed dormant operations are considered herein: (1) the vehicle systems that are placed in a dormant state and (2) the autonomous vehicle systems and robotic capabilities that monitor, maintain, and repair the vehicle and systems. This paper describes the mission stages of dormancy operations, phases of dormant operations, and critical system capabilities that are needed for dormant operations. This paper will compare dormancy operations of past robotic missions to identify lessons that can be applied to planned human exploration missions. Finally, this paper will also identify future work and analysis planned to assess system performance metrics and integrated system operations.

Williams-Byrd, Julie↗

Reuse and Interoperability of Avionics for Space Systems

The space environment presents unique challenges for avionics. Launch survivability, thermal management, radiation protection, and other factors are important for successful space designs. Many existing avionics designs use custom hardware and software to meet the requirements of space systems. Although some space vendors have moved more towards a standard product line approach to avionics, the space industry still lacks similar standards and common practices for avionics development. This lack of commonality manifests itself in limited reuse and a lack of interoperability. To address NASA s need for interoperable avionics that facilitate reuse, several hardware and software approaches are discussed. Experiences with existing space boards and the application of terrestrial standards is outlined. Enhancements and extensions to these standards are considered. A modular stack-based approach to space avionics is presented. Software and reconfigurable logic cores are considered for extending interoperability and reuse. Finally, some of the issues associated with the design of reusable interoperable avionics are discussed.

Hodson, Robert F.↗

A Principled Approach to the Specification of System Architectures for Space Missions

Modern space systems are increasing in complexity and scale at an unprecedented pace. Consequently, innovative methods, processes, and tools are needed to cope with the increasing complexity of architecting these systems. A key systems challenge in practice is the ability to scale processes, methods, and tools used to architect complex space systems. Traditionally, the process for specifying space system architectures has largely relied on capturing the system architecture in informal descriptions that are often embedded within loosely coupled design documents and domain expertise. Such informal descriptions often lead to misunderstandings between design teams, ambiguous specifications, difficulty in maintaining consistency as the architecture evolves throughout the system development life cycle, and costly design iterations. Therefore, traditional methods are becoming increasingly inefficient to cope with ever-increasing system complexity. We apply the principles of component-based design and platform-based design to the development of the system architecture for a practical space system to demonstrate feasibility of our approach using SysML. Our results show that we are able to apply a systematic design method to manage system complexity, thus enabling effective data management, semantic coherence and traceability across different levels of abstraction in the design chain. Just as important, our approach enables interoperability among heterogeneous tools in a concurrent engineering model based design environment.

platform-based design↗

Modifications to the NASA Ames Space Station Proximity Operations (PROX OPS) Simulator

As the United States is approaching an operational space station era, flight simulators are required to investigate human design and performance aspects associated with orbital operations. Among these are proximity operations (PROX OPS), those activities occurring within a 1-km sphere of Space Station including rendezvous, docking, rescue, and repair. The Space Station Proximity Operations Simulator at NASA Ames Research Center was modified to provide the capability for investigations into human performance aspects of proximity operations. Accurate flight equations of motion were installed to provide the appropriate visual scene to test subjects performing simulated missions. Also, the flight control system was enhanced by enabling pilot control over thruster acceleration values. Currently, research is under way to examine human performance in a variety of mission scenarios.

Brody, Adam↗

Phase behavior of continuous-space systems: A supervised machine learning approach

The phase behavior of complex fluids is a challenging problem for molecular simulations. Supervised machine learning (ML) methods have shown potential for identifying the phase boundaries of lattice models. In this work, we extend these ML methods to continuous-space systems. We propose a convolutional neural network model that utilizes grid-interpolated coordinates of molecules as input data of ML and optimizes the search for phase transitions with different filter sizes. We test the method for the phase diagram of two off-lattice models, namely, the Widom–Rowlinson model and a symmetric freely jointed polymer blend, for which results are available from standard molecular simulations techniques. The ML results show good agreement with results of previous simulation studies with the added advantage that there is no critical slowing down. We find that understanding intermediate structures near a phase transition and including them in the training set is important to obtain the phase boundary near the critical point. The method is quite general and easy to implement and could find wide application to study the phase behavior of complex fluids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Space shuttle GN and C equation document no. 22: Approach guidance

The approach guidance routine for taking the space shuttle orbiter vehicle from the end of the entry phase altitude of approximately 100,000 feet to the start of the terminal guidance phase is presented. The guidance routine consists of six modes: (1) acquisition, (2) energy dissipation, (3) turn in, (4) initial approach, (5) heading alignment, and (6) final approach. Diagrams of the flight path for the various modes are included. Equations of motion governing the performance of the vehicle during each mode are developed.

Tao, Y.↗

Engineering micromotion in Floquet prethermalization via space-time symmetries

We present a systematic framework for Floquet prethermalization under strong resonant driving, emphasizing the pivotal role of dynamical space-time symmetries. Our approach demonstrates how dynamical space-time symmetries map onto the projective static symmetry group of the prethermal Hamiltonian governing the prethermal regime. We introduce techniques for detecting dynamical symmetries through the time evolution of local observables, facilitating a detailed analysis of micromotion within each period and surpassing the limitations of conventional stroboscopic Floquet prethermal dynamics. To implement this framework, we present a prethermal protocol that preserves order-2 dynamical symmetry in a spin-ladder model, confirming the predicted relationships between the expectation values of local observables at distinct temporal points in the Floquet cycle, linked by this symmetry.

floquet systems↗