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At least 739 records · Page 41

Development of MOSCATO: A CFD-Level Electrochemistry and Corrosion Simulator for Molten Salt Systems

For both coolant and fueled variants of molten salt reactors (MSRs), the corrosion of structural materials is a significant challenge. The corrosion stems from chemical and electrochemical reactions initiated by fissile material, fission products, and impurities in the salt. Lower-fidelity models rely on empirical correlations for mass transfer, simplified lumped temperature profiles, and similar assumptions. They do not capture detailed spatial variations in complex geometries, creating the need for high-fidelity modeling to bridge this gap.As we approach the demonstration and possible deployment of MSRs in this decade, the development of a high-fidelity, high-performance simulator becomes imperative. To simulate the complex electrochemical environment and corrosion within molten salt systems, we have developed the Molten Salt Chemistry And TranspOrt (MOSCATO) code. This endeavor is comprised of three essential components. First, mass transfer equations are coupled with the Navier-Stokes equations in order to account for the transport of species in the salt. Second, the diffusion of alloy constituents, such as Cr, Fe, Ni, etc. is simulated within the structural metals. Third, the alloy and salt domains are coupled to account for the heterogeneous chemical and electrochemical reactions that occur at the salt-alloy interface.MOSCATO manages all three components within the framework of the highly scalable, open-source spectral element method computational fluid dynamics code Nek5000/NekRS. This integration enables MOSCATO to harness the immense computational power of modern high-performance computing resources, ensuring both high fidelity and computational speed.In addition to code development, we have initiated a comprehensive verification and validation campaign, utilizing data from diverse sources. First, MOSCATO's electrochemical solver was verified with reference numerical data. Then validation occurred against experiments: one of a thermal galvanic cell and the other for corrosion in flowing molten salt of FLiNaK (LiF-NaF-KF). This campaign verified and validated MOSCATO as a reliable tool for simulating electrochemical environments and corrosion in molten salt systems.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

An Investigation of the Effects of Nose and Lip Shapes for an Underslung Scoop Inlet at Mach Numbers from 0 to 1.9

An experimental investigation was conducted to determine the performance characteristics an underslung nose-scoop air-induction system for a supersonic airplane. Five different nose shapes, three lip shapes, and two internal diffusers were investigated. Tests were made at Mach numbers from 0 to 1.9, angles of attack from 0 deg to approximately l5 deg, and mass-flow ratios from 0 to maximum obtainable. It was found that the underslung nose-scoop inlet was able to operate at Mach numbers from 0.6 to 1.9 over a large positive angle-of-attack range without adverse effects on the pressure recovery. Although there was no one inlet configuration that was markedly superior over the entire range of operating variables, the arrangement having a nose designed to give increased supersonic compression at low angles of attack, and a sharp lip (configuration designated N3L3) showed the most favorable performance characteristics over the supersonic Mach number range. Inlets with sizable lip radii gave satisfactory performance up to a Mach number of 1.5; however, as a result of an increase in drag, the performance of such inlets was markedly inferior to the sharp-lip configuration above Mach numbers of 1.5. Throughout the range of test Mach numbers all inlet configurations evidenced stable air-flow characteristics over the mass-flow range for normal engine operation. Analysis of the inlet performance on the basis of a propulsive thrust parameter showed that a fixed inlet area could be used for Mach numbers up to 1.5 with only a small sacrifice in performance.

NOSE CONE↗

Measurement of the neutral composition of the lower thermosphere above Fort Churchill by rocket-borne mass spectrometer.

Measurement of the neutral atmospheric composition above Fort Churchill, Canada (59 N, 94 W), by mass spectrometers in two rocket flights at 0835 CST on Feb. 4 and 6, 1969. A quantitative measure for the extent of agreement with static diffusive equilibrium is introduced, and substantial agreement with profiles predicted when static diffusive equilibrium was assumed is found for all constituents including helium. A sensitive search for atomic nitrogen yielded upper limits of a few per cent for one flight and of 0.2% for the other.

Hickman, D. R.↗

Determination of the light ion abundances in the strong-helium star HR 3089

Using line blanketed model stellar atmospheres and a spectrum synthesis approach, a differential abundance study of the ultraviolet spectrum of HR 3089 relative to the normal star lambda Sco was performed. Both stars were found to have the same abundances of carbon and silicon, but the helium and nitrogen are significantly enhanced in HR 3089. The atmospheric parameters and the distribution of abundances found for HR 3089 agree well with the results of Osmer and Peterson on sharp-lined helium-rich stars. The rotational velocity of 160 km/sec found for HR 3089 places a constraint on the role of diffusion in producing the abundance anomalies. Examination of the resonance lines of C II, N II, Si III and Si IV shows no evidence for mass loss in either star.

Lester, J. B.↗

Comment on the paper 'On the influx of small comets into the earth's upper atmosphere. II - Interpretation' by L. A. Frank, J. B. Sigwarth and J. D. Craven

The proposal by Frank et al. (1986) that clouds of small comets periodically inject large amounts of H2O into the upper atmospheres of the earth, Venus, and Mars is examined critically, with a focus on transport and disposal mechanisms invoked to account for the large H2O masses involved. It is argued that observed parameter values (such as mixing ratios, vertical wind velocities, and H escape flows) prohibit transport by eddy, molecular diffusion, vertical avection, or coherent movement. In a reply by Frank et al., these objections are discussed in terms of an overall description of the decelerataion and penetration of a cometary water cloud, and H2O concentrations and mixing mechanisms consistent with observed values for the earth are proposed. It is suggested that an increase in cometary H2O influx could lead to concentrations attaining the frost point and to formation of a global mesospheric cloud with significant climate effects. A lower H2O influx rate for Venus (consistent with observed H loss and atmospheric H2O concentration) and relatively rapid loading of the Mars surface and atmosphere with H2O ice and vapor (followed by brief warming periods with increased exospheric H2O outflow and surface flow of liquid H2O) are considered.

Donahue, T. M.↗

Radial transport of storm time ring current ions

Radial transport of energetic ions for the development of the main phase of geomagnetic storms is investigated with data from the medium energy particle analyzer (MEPA) on the Charge Composition Explorer spacecraft, which monitored protons, helium ions, and the carbon-nitrogen-oxygen group, which is mostly dominated by oxygen ions. From a study of four geomagnetic storms, we show that the flux increase of these ions in the inner ring current region can be accounted for by an inward displacement of the ring current population by 0.5 to 3.5 R(E). There is a general trend that a larger inward displacement occurs at higher L shells than at lower ones. These results are in agreement with previous findings. The radially injected population consists of the prestorm population modified by substorm injections which occur on a much shorter time scale than that for a storm main phase. It is also found that the inward displacement is relatively independent of ion mass and energy, suggesting that the radial transport of these energetic ions is effected primarily by convective motion from a large electric field or by diffusion resulting from magnetic field fluctuations.

Lui, A. T. Y.↗

ROSAT observations of compact groups of galaxies

We have systematically analyzed a sample of 13 new and archival ROSAT Position Sensitive Proportional Counter (PSPC) observations of compact groups of galaxies: 12 Hickson compact groups plus the NCG 2300 group. We find that approximately two-thirds of the groups have extended X-ray emission and, in four of these, the emission is resolved into diffuse emission from gas at a temperature of kT approximately 1 keV in the group potential. All but one of the groups with extended emission have a spiral fraction of less than 50%. The baryon fraction of groups with diffuse emission is 5%-19%, similar to the values in clusters of galaxies. However, with a single exception (HCG 62), the gas-to-stellar mass ratio in our groups has a median value near 5%, somewhat greater than the values for individual early-type galaxies and two orders of magnitude than in clusters of galaxies. The X-ray luminosities of individual group galaxies are comparable to those of similar field galaxies, although the L(sub X)-L(sub B) relation for early-type galaxies may be flatter in compact groups than in the field.

Pildis, Rachel A.↗

Ultraviolet and X-ray properties of Coma’s ultra-diffuse galaxies

Many ultra-diffuse galaxies (UDGs) have been discovered in the Coma cluster, and there is evidence that some, notably Dragonfly 44, have Milky Way-like dynamical masses despite dwarf-like stellar masses. We used X-ray, ultraviolet (UV), and optical data to investigate the star formation and nuclear activity in the Coma UDGs, and we obtained deep UV and X-ray data (Swift and XMM–Newton) for Dragonfly 44 to search for low-level star formation, hot circumgalactic gas, and the integrated emission from X-ray binaries. Among the Coma UDGs, we find UV luminosities consistent with quiescence but NUV−r colours indicating star formation in the past Gyr. This indicates that the UDGs were recently quenched. The r-band luminosity declines with projected distance from the Coma core. The Dragonfly 44 UV luminosity is also consistent with quiescence, with SFR<6×10^−4M(ʘ)/yr,and no X-rays are detected down to a sensitivity of 10^38erg/s. This rules out a hot corona with a M>10^8M(ʘ) within the virial radius, which would normally be expected for a dynamically massive galaxy. The absence of bright, low-mass X-ray binaries is consistent with the expectation from the Galaxy total stellar mass, but it is unlikely if most low-mass X-ray binaries form in globular clusters, as Dragonfly 44 has a very large population. Based on the UV and X-ray analysis, the Coma UDGs are consistent with quenched dwarf galaxies, although we cannot rule out a dynamically massive population.

Chris H. Lee↗

Mass dependence of overshooting beneath convective envelopes

State of the art stellar evolution codes [Paxton et al., 2010, Demarque et al., 2004, Weiss and Schlattl, 2008, Siess et al., 2013, Christensen-Dalsgaard, 2008] evoke a diffusive process to model convective overshooting. The diffusion coefficient [Freytag et al., 1996, Pratt et al., 2017] used in the model can be set to change with the classification of the convective zone as non-burning, H-burning, He-burning, or metal-burning. It can also be set to change at defined evolutionary points, such as the bottom of the asymptotic giant branch, or during the third dredge up [Herwig, 2000, Lugaro et al., 2003]. Aside from these abrupt changes, the diffusion coefficient is typically locked to a percentage of the pressure scale height measured at the convective boundary. However, there is no theoretical reason for convective overshooting, or indeed other convective properties, to change in the same way that the pressure scale height changes as a star evolves.

79 ASTRONOMY AND ASTROPHYSICS↗

Development of a New Membrane Casting Apparatus for Studying Macrovoid Defects in Low-G

A new membrane-casting apparatus is developed for studying macrovoid defects in polymeric membranes made by the wet- and dry-casting process in low-gravity. Macrovoids are large (10-50 micron), open cavities interspersed among the smaller pores in the substructure under the gelled skin surface layer of the cast membrane. Although their occurrence is considered endemic to the wet- and dry-casting process since they can lead to compaction or skin rupture in the membrane process, recent studies suggest several useful applications such as transdermal and osmotic drug delivery systems, miniature bioreactors, etc. However, lack of knowledge about the macrovoid formation mechanism is an obstacle to further development of applications using them. An on-going debate is the role of the surface-tension-driven solutocapillary convection during macrovoid formation. The rapid growth of macrovoids within 1-5 seconds and the high polymer concentration in and near macrovoids make it difficult to explain the mechanism of macrovoid growth by diffusion alone, which is the widely accepted hypothesis proposed by Reuvers et al. The hypothesis advanced by our research group can explain this rapid growth via a mechanism that involves diffusion from the casting solution in the meta-stable region to the macrovoid enhanced by solutocapillary convection induced by the steep nonsolvent concentration gradient in the vicinity of the macrovoid. Since macrovoid growth is hypothesized to be the interplay of a solutocapillary-induced driving force counteracted by viscous drag and buoyancy, eliminate the latter provides a means for testing this hypothesis. Moreover, free convection mass transfer in the nonsolvent immersion bath used to cause phase-separation in membrane casting complicates developing a model for both the wet-casting process and macrovoid growth. The low-g environment minimizes gravitationally induced free convection thereby permitting a tractable solution to the ternary diffusion equations that characterize membrane formation. NASA's Parabolic Flight Research Aircraft provides a small window of low-g (approximately 25 s) that can be used to study macrovoid development in both wet- and dry-cast membranes if an appropriate casting apparatus is used. This casting apparatus should be able to cast the membrane in both low- and high-g in a manner so that essential one-dimensional mass transfer conditions are achieved to insure lateral uniformity in the membrane. The apparatus used in previous research on membrane casting in low-gravity was operated with the plunger driven mechanism. The spring-loaded plunger pushes the bottom block containing the polymer casting solution well directly under the absorbent chamber located in the upper stationary block. However, membranes made via this casting apparatus often displayed lateral nonuniformities that precluded obtaining quantitative information on the macrovoid growth process. Thus, it was necessary to determine the reason for these structural irregularities observed in the low-g casting apparatus. Both experimental as well as computer simulation studies of the low-g casting apparatus established that the impulsive action of the plunger caused the undesired structural nonuniformities. The simulation results showed that the width-to-depth aspect ratio of the shallow well that contains the casting solution in this apparatus was not an important factor in minimizing this problem. Even for a 40:1 (width : depth) aspect ratio, any convection induced by the horizontal motion of the interface of the casting solution will be damped out within 6.25x10(exp 4) seconds. However, the experimental studies revealed that the impulsive motion of the plunger caused a 'sloshing' of the casting solution that had to be eliminated. Therefore, the plungerdriven mechanism was changed to a cam-driven mechanism that did not cause any impulsive motion of the casting solution. Other refinements to this new membrane-casting apparatus include provision for removing the membranes from the casting wells in a less destructive manner. This was accomplished by using a slit geometry for the casting well that permitted disassembly for removal of the cast membrane. The materials used in the construction of this casting apparatus were chosen to insure wetting at the side walls and to maintain precise control of the thickness of the polymer solution in the casting well. An additional provision in this new casting apparatus is the ability to carry out both wet- as well as dry-casting. As such, this apparatus permitted the first studies of the wet-casting of polymeric membranes in low-g. Both wet- and dry-casting experiments on NASA's KC-135 research aircraft employing this new membrane-casting apparatus are scheduled in July 2002. The morphology of the resulting membranes will be characterized using an environmental scanning electron microscope (ESEM). The results of these low-g studies will be reported later.

Lee, Hanyong↗

Theory of Influence of a Low-Volatility, Soluble Impurity on Spherically-Symmetric Combustion of Fuel Droplets

Analyses are given for the evolution of liquid-phase mass fraction profiles and temperature during combustion of fuel droplets composed of binary miscible mixtures of low-volatility and high-volatility constituents, with small initial mass fractions of the low-volatility material, or slow introduction of low-volatility material into the liquid phase by absorption from the gas phase. The gas phase is assumed to remain quasi-steady and the liquid temperature spatially uniform. The ratio of the liquid-phase diffusion coefficient to the initial burning-rate constant is treated as a small parameter. Asymptotic analyses in this parameter are developed, and the conservation equations are integrated numerically in obtaining descriptions of the combustion history. It is shown that at the surface of the droplet a boundary layer arises in which the mass fraction of the low-volatility component increases with time. The results are used to explain qualitatively some observed conditions of flame contraction and liquid disruption in droplet combustion.

Shaw, B. D.↗

Radiation Temperature and Extinction of Transient Gaseous Diffusion Flames in Microgravity

The absence of buoyancy-induced flows in micro-g and the resulting increase in the reactant residence time significantly alters the fundamentals of many combustion processes. Substantial differences between 1-g and micro-g flames have been reported in experiments on candle flames, flame spread over solids, droplet combustion and others. These differences are more basic than just in the visible flame shape. Longer residence times and higher concentration of combustion products in the flame zone create a thermochemical environment which changes the flame chemistry and the heat and mass transfer processes. Processes such as flame radiation (and its interaction with flame chemistry), that are often ignored under normal gravity, become very important and sometimes even controlling. This is particularly true for conditions at extinction of a micro-g diffusion flame.

Arvind Atreya↗

EGRET observations of gamma-ray emission from the interstellar gas in Orion

The high-energy diffuse gamma-ray emission from the interstellar gas in Orion was studied using observations from the Energetic Gamma-Ray Experiment Telescope (EGRET) on the Compton Gamma-Ray Observatory (CGRO) and radio surveys of the H I and CO emission. The good correlation of the gamma-ray emission with the atomic and molecular gas permits determination of the gamma-ray emissivity per nucleon in the interstellar medium and the molecular mass calibrating ratio N(H2)/W(sub co) in Orion. The integral gamma-ray emissivity is (1.7 +/- 0.1) x 10(exp -26)/s/sr for E greater than 100 MeV, in good agreement with expectations from studies of the diffuse emission on larger scales. The N(H2)/W(sub co) ratio is (1.06 +/- 0.14) x 10(exp 20)/sq cm/(K km/s), approximately 40% less than the commonly adopted Galactic average. We find no evidence for variations of the cosmic-ray density or N(H2)/W(sub co) ratio in Orion at the sensitivity and resolution of EGRET.

Digel, S. W.↗

Simulation of the Solar Energetic Particle Event on 2020 May 29 Observed by Parker Solar Probe

This paper presents a stochastic three-dimensional focused transport simulation of solar energetic particles (SEPs) produced by a data-driven coronal mass ejection (CME) shock propagating through a data-driven model of coronal and heliospheric magnetic fields. The injection of SEPs at the CME shock is treated using diffusive shock acceleration of post-shock suprathermal solar wind ions. A time-backward stochastic simulation is employed to solve the transport equation to obtain the SEP time–intensity profile at any location, energy, and pitch angle. The model is applied to a SEP event on 2020 May 29, observed by STEREO-A close to ∼1 au and by Parker Solar Probe (PSP) when it was about 0.33 au away from the Sun. The SEP event was associated with a very slow CME with a plane-of-sky speed of 337 km s −1 at a height below 6 RS as reported in the SOHO/LASCO CME catalog. We compute the time profiles of particle flux at PSP and STEREO-A locations, and estimate both the spectral index of the proton energy spectrum for energies between ∼2 and 16 MeV and the equivalent path length of the magnetic field lines experienced by the first arriving SEPs. We find that the simulation results are well correlated with observations. The SEP event could be explained by the acceleration of particles by a weak CME shock in the low solar corona that is not magnetically connected to the observers.

Solar energetic particles↗

Far-infrared properties of NGC 6822

IRAS FIR maps of NGC 6822, one of the few noninteracting Magellanic irregular galaxies resolved in the FIR by IRAS, are examined and compared to optical and H I data. The diffuse FIR emission at large radii from the center of the galaxy is found to be due to Galactic cirrus. There is a general correspondence between H-alpha and FIR emission in that FIR peaks are associated with major H II complexes, but the ratio of the FIR to the H-alpha emission varies between these complexes by about a factor of five. H I mass-to-FIR luminosity ratios cover a similar range for the three major H I cloud complexes in NGC 6822. More than about half of the FIR flux is produced in regions near H II region complexes. The remaining flux comes from diffuse FIR emission that extends over the entire optically visible galaxy. A model for the galaxy is discussed in which the galaxy is fairly transparent and the FIR is strongest where there is a strong UV source and higher optical depth due to dust in gas clouds.

Gallagher, John S., III↗

Kinetically Dormant Ni‐Rich Layered Cathode During High‐Voltage Operation

Abstract The degradation of Ni‐rich cathodes during long‐term operation at high voltage has garnered significant attention from both academia and industry. Despite many post‐mortem qualitative structural analyses, precise quantification of their individual and coupling contributions to the overall capacity degradation remains challenging. Here, by leveraging multiscale synchrotron X‐ray probes, electron microscopy, and post‐galvanostatic intermittent titration technique, the thermodynamically irreversible and kinetically reversible capacity loss is successfully deconvoluted in a polycrystalline LiNi 0.83 Mn 0.1 Co 0.07 O 2 cathode during long‐term charge/discharge cycling in full cell configuration. Contradicting the dramatic capacity loss, the layered structure remains highly alive even after 1000 cycles at 4.6 V while undergoing a three‐order of magnitude reduction in the mass transfer kinetics, leading to almost fully recoverable capacity under kinetic‐free conditions. Such kinetic dormant behavior after cycling is not simply ascribed to poor chemical diffusion by reconstructed cathode surface but highly synchronizes with the lattice strain evolution stemming from the structural heterogeneity between deeply delithiated layered and degraded rock‐salt phases at high voltage. These findings deepen the degradation mechanism of high‐voltage cathodes to achieve long‐cycling and fast‐charging performance.

36 MATERIALS SCIENCE↗

The neutral-atmosphere temperature instrument.

The determination of the temperature of the neutral gas at the location of the satellite is based on measurement of the velocity distribution of the molecular nitrogen. Measurement of the thermal-velocity component in the presence of the free-stream velocity will be obtained through application of the velocity-scan technique and, independently, through use of a baffle technique. A 3-cm diameter spherical sampling chamber with a 0.5-cm diameter precisely knife-edged orifice is located at the satellite equator to permit free diffusion of atmosphere gases between the chamber interior and the atmosphere. The spherical chamber is connected through a high-conductance tube to a quadrupole mass-spectrometer sensor to permit accurate quantitative evaluation of the density of the gas.

Spencer, N. W.↗

Diurnal variations in the thermosphere. I - Theoretical formulation

A nonlinear perturbation theory is formulated for the solution of the multicomponent equations of energy, mass, and momentum conservation in the atmosphere. The theory is three-dimensional and includes the effects of heat conduction and advection, viscosity, ion drag, and diffusion. The theory is described as a superposition of mathematical modes obtained by expanding the physical quantities into vector and spherical harmonics. The coupling between the various modes, both linear and nonlinear, is included. The theory provides a basis for the treatment of the thermosphere and its interaction with the lower atmosphere, where 'mode coupling' is most important. As an example, a comparison is presented between one-dimensional and three-dimensional calculations of the fundamental mode of the diurnal component in the thermosphere. Coupling between the lowest modes is considered to describe the physical conditions of the lower thermosphere where inertia and Coriolis forces become dominant over the ion-drag and viscous forces. In this region, the latitude structures of the temperature, wind field, and diffusively controlled oxygen are shown to change significantly.

Harris, I.↗