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At least 739 records · Page 41

Compressibility Effects on the Growth and Structure of Homogeneous Turbulent Shear Flow

Compressibility effects within decaying isotropic turbulence and homogeneous turbulent shear flow have been studied using direct numerical simulation. The objective of this work is to increase our understanding of compressible turbulence and to aid the development of turbulence models for compressible flows. The numerical simulations of compressible isotropic turbulence show that compressibility effects are highly dependent on the initial conditions. The shear flow simulations, on the other hand, show that measures of compressibility evolve to become independent of their initial values and are parameterized by the root mean square Mach number. The growth rate of the turbulence in compressible homogeneous shear flow is reduced compared to that in the incompressible case. The reduced growth rate is the result of an increase in the dissipation rate and energy transfer to internal energy by the pressure-dilatation correlation. Examination of the structure of compressible homogeneous shear flow reveals the presence of eddy shocklets, which are important for the increased dissipation rate of compressible turbulence.

Blaisdell, G. A.↗

Effects of core perturbations on the structure of the sun

The effects of perturbing the inner part of the solar core where the hydrogen abundance has been partially depleted by nuclear burning are investigated. Small regions are mixed within the core and the evolution of the resulting luminosity and radius perturbations is followed. The sensitivity of the solar luminosity and radius to mixing events of different sizes and at different locations in the core is determined and several relationships between the luminosity and radius perturbations are examined to see if the value of one of these perturbations can be inferred from a measurement of the other. It is found that any core perturbation which alters the hydrostatic structures will immediately affect the solar luminosity and radius. The behavior of these perturbations depends on the location of the mixing event within the core. Mixing events cannot produce the decrease in the solar radius without leading to a homogeneous evolution of the solar core and/or to a prohibitively large change in the solar luminosity.

Sweigart, A. V.↗

Ultrathin c-Si solar cells based on microcavity light trapping scheme

Ultrathin c-Si solar cells with a new light trapping scheme, which is a double-microcavity light trapping structure, are optimized and analyzed. The results show that by optimizing the geometric parameters of each light trapping unit, the light trapping structure can effectively improve the light absorption efficiencies of ultrathin crystalline silicon cells with different thicknesses. The thinner the active layer of a crystalline silicon solar cell, the more obvious the effect of the light trapping structure to enhance the light absorption. When the active layer thickness of a crystalline silicon cell is 3 μm, the battery efficiency can reach 16.3193%.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

β -Ga 2 O 3 MESFETs with insulating Mg-doped buffer grown by plasma-assisted molecular beam epitaxy

In this work, we develop in situ Mg doping techniques in plasma-assisted molecular beam epitaxy (PAMBE) of β -Ga 2 O 3 to compensate Si dopants at the substrate epilayer growth interface and eliminate parasitic leakage paths. Both abrupt and uniform Mg doping profiles over a wide range of concentrations were achieved in β -Ga 2 O 3 epilayers grown by PAMBE. Capacitance–voltage characteristics of Si and Mg co-doped samples confirmed the compensating effect of the Mg dopants. Mg delta-doping was then integrated into a β -Ga 2 O 3 metal-semiconductor field effect transistor structure and shown to be effective in eliminating source leakage. In conclusion, the results presented here show that Mg doping is a promising way to engineer insulating buffer layers for β -Ga 2 O 3 lateral devices grown by PAMBE.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Tuning the Néel Temperature of Hexagonal Ferrites by Structural Distortion

To tune the magnetic properties of hexagonal ferrites, a family of magnetoelectric multiferroic materials, by atomic-scale structural engineering, we studied the effect of structural distortion on the magnetic ordering temperature ( T N ) in these materials. Using the symmetry analysis, we show that unlike most antiferromagnetic rare-earth transition-metal perovskites, a larger structural distortion leads to a higher T N in hexagonal ferrites and manganites, because the K 3 structural distortion induces the three-dimensional magnetic ordering, which is forbidden in the undistorted structure by symmetry. We also revealed a near-linear relation between T N and the tolerance factor and a power-law relation between T N and the K 3 distortion amplitude. Following the analysis, a record-high T N (185 K) among hexagonal ferrites was predicted in hexagonal ScFeO 3 and experimentally verified in epitaxially stabilized films. Furthermore these results add to the paradigm of spin-lattice coupling in antiferromagnetic oxides and suggests further tunability of hexagonal ferrites if more lattice distortion can be achieved.

36 MATERIALS SCIENCE↗

Analytical ultrasonics for structural materials

The application of ultrasonic velocity and attenuation measurements to characterize the microstructure of structural materials is discussed. Velocity measurements in cast stainless steel are correlated with microstructural variations ranging from equiaxed (elastically isotropic) to columnar (elastically anisotropic) grain structure. The effect of the anisotropic grain structure on the deviation of ultrasonic waves in cast stainless steel is also reported. Field-implementable techniques for distinguishing equiaxed from columnar grain structures in cast strainless steel structural members are presented. The application of ultrasonic velocity measurements to characterize structural ceramics in the green state is also discussed.

Kupperman, D. S.↗

Some effects of tip fins on wing flutter characteristics

A wind tunnel investigation has been conducted over the Mach number range from about 0.6 to 1.2 to determine the effects of large tip fins on the flutter characteristics of a swept wing. The basic wing configuration had an aspect ratio of 0.95, leading-edge sweep of 40 deg 0, and trailing-edge sweep of 21 deg. Two of these configurations were modified with tip fins of 60 deg dihedral and had effective aspect ratios of 1.5 and 2.2. In general, the results indicate that the addition of tip fins reduces the flutter speed, with the larger fin having the greater effect. Comparison of the experimental flutter speeds at Mach numbers between 0.60 and 0.90 with calculated values obtained by using doublet-lattice unsteady aerodynamic theory was good. Analytical results where structural and aerodynamic effects of the tip fins were isolated indicated that the reduction in flutter speed produced by the addition of the fins was caused by both effects, with the structural effect being the more pronounced.

Goetz, R. C.↗

Self-shadowing effects on the thermal-structural response of orbiting trusses

An investigation of self-shadowing effects on the thermal-structural response of orbiting trusses is described. The shadowing, heating, thermal and structural analyses are summarized. The significance of shadowing on the thermal-structural behavior of a single member and a beam constructed from truss members is described. For the trusses considered, the study shows that member self-shadowing effects significantly alter the behavior and must be included to predict the thermal-structural response correctly.

Thornton, E. A.↗

Joint nonlinearity effects in the design of a flexible truss structure control system

Nonlinear effects are introduced in the dynamics of large space truss structures by the connecting joints which are designed with rather important tolerances to facilitate the assembly of the structures in space. The purpose was to develop means to investigate the nonlinear dynamics of the structures, particularly the limit cycles that might occur when active control is applied to the structures. An analytical method was sought and derived to predict the occurrence of limit cycles and to determine their stability. This method is mainly based on the quasi-linearization of every joint using describing functions. This approach was proven successful when simple dynamical systems were tested. Its applicability to larger systems depends on the amount of computations it requires, and estimates of the computational task tend to indicate that the number of individual sources of nonlinearity should be limited. Alternate analytical approaches, which do not account for every single nonlinearity, or the simulation of a simplified model of the dynamical system should, therefore, be investigated to determine a more effective way to predict limit cycles in large dynamical systems with an important number of distributed nonlinearities.

Mercadal, Mathieu↗

Pressure effect on the electronic, structural, and vibrational properties of layered 2 H - MoTe 2

Layered molybdenum dichalchogenides differ from the classic example of bilayer graphene with their unique electronic properties: the application of pressure can continuously tune electronic structure since the band gap is controlled by delicate interlayer interaction. In this work, we have performed measurements of Raman scattering, synchrotron x-ray diffraction, electrical conductivity, and Hall coefficient combined with density functional theory calculations to synthetically study the pressure effect on $2H$-MoTe 2 . Both the experiments and calculations consistently demonstrate that MoTe2 undergoes a semiconductor-to-metallic (S-M) transition above 10 GPa. Unlike MoS 2 , the S-M transition is driven by the gradual tunability of electric structure and band gap without structural transition. The applied pressure also effectively enhances conductivity and carrier concentration while reducing the mobility, which makes MoTe 2 more suitable for applications than most other transition-metal dichalchogenides and allows it to be applied in strain-modulated optoelectronic devices.

36 MATERIALS SCIENCE↗

The effects of weighting function errors on spatial filters for structural control

Distributed-effect sensors, which respond to spatially distributed inputs over a significant gauge length, encompass piezoelectric laminate films, modal-domain optical fiber sensors, and holographic sensors; they can be fabricated with spatially varying sensitivity to a distributed measurand for spatial filtering. Such spatial filters are configurable to extract various structural parameters from distributed measurements that cannot be directly measured by sensors. A modeling is presently conducted for distributed-effect sensors' integration into state-space structural models, noting the effects of fabrication errors on sensor operation.

Lindner, Douglas K.↗

Actinide arene-metalates: ion pairing effects on the electronic structure of unsupported uranium–arenide sandwich complexes

Addition of [UI 2 (THF) 3 (μ-OMe)] 2 ·THF (2·THF) to THF solutions containing 6 equiv. of K[C 14 H 10 ] generates the heteroleptic dimeric complexes [K(18-crown-6)(THF) 2 ] 2 [U(η 6 -C 14 H 10 )(η 4 -C 14 H 10 )(μ-OMe)] 2 ·4THF (1 18C6 ·4THF) and {[K(THF) 3 ][U(η 6 -C 14 H 10 )(η 4 -C 14 H 10 )(μ-OMe)]} 2 (1 THF ) upon crystallization of the products in THF in the presence or absence of 18-crown-6, respectively. Both 1 18C6 ·4THF and 1 THF are thermally stable in the solid-state at room temperature; however, after crystallization, they become insoluble in THF or DME solutions and instead gradually decompose upon standing. X-ray diffraction analysis reveals 1 18C6 ·4THF and 1 THF to be structurally similar, possessing uranium centres sandwiched between bent anthracenide ligands of mixed tetrahapto and hexahapto ligation modes. Yet, the two complexes are distinguished by the close contact potassium-arenide ion pairing that is seen in 1 THF but absent in 1 18C6 ·4THF, which is observed to have a significant effect on the electronic characteristics of the two complexes. Structural analysis, SQUID magnetometry data, XANES spectral characterization, and computational analyses are generally consistent with U(IV) formal assignments for the metal centres in both 1 18C6 ·4THF and 1 THF , though noticeable differences are detected between the two species. For instance, the effective magnetic moment of 1 THF (3.74 μ B ) is significantly lower than that of 1 18C6 ·4THF (4.40 μ B ) at 300 K. Furthermore, the XANES data shows the U L III -edge absorption energy for 1 THF to be 0.9 eV higher than that of 1 18C6 ·4THF, suggestive of more oxidized metal centres in the former. Of note, CASSCF calculations on the model complex {[U(η 6 -C 14 H 10 )(η 4 -C 14 H 10 )(μ-OMe)] 2 } 2– (1*) shows highly polarized uranium–arenide interactions defined by π-type bonds where the metal contributions are primarily comprised by the 6d-orbitals (7.3 ± 0.6%) with minor participation from the 5f-orbitals (1.5 ± 0.5%). These unique complexes provide new insights into actinide–arenide bonding interactions and show the sensitivity of the electronic structures of the uranium atoms to coordination sphere effects.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Flutter Sensitivity to Boundary Layer Thickness, Structural Damping, and Static Pressure Differential for a Shuttle Tile Overlay Repair Concept

This paper examines the aeroelastic stability of an on-orbit installable Space Shuttle patch panel. CFD flutter solutions were obtained for thick and thin boundary layers at a free stream Mach number of 2.0 and several Mach numbers near sonic speed. The effect of structural damping on these flutter solutions was also examined, and the effect of structural nonlinearities associated with in-plane forces in the panel was considered on the worst case linear flutter solution. The results of the study indicated that adequate flutter margins exist for the panel at the Mach numbers examined. The addition of structural damping improved flutter margins as did the inclusion of nonlinear effects associated with a static pressure difference across the panel.

Scott, Robert C.↗

Effect of the composition and structure of carbofunctional oligodimethylsiloxanes on their colloidal-chemical properties

The effect of the composition and structure of oligodimethylsiloxanes containing carboxy- and amino-functional substituents at the silicon atom on their colloidal-chemical properties was studied. It was established that their colloidal-chemical properties are affected not only by the nature and concentration of functional groups, but also by the molecular weight of the organosilicon compound.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Passive Microwave Remote Sensing of Soil Moisture: the Effect of Tilled Row Structure

The tilled rowstructure is known to be one of the important factors affecting the observations of the microwave emission from a natural surface. Measurements of this effect were carried out with both I and X band radiometers mounted on a mobile truck on a bare 40 m x 45 m row tilled field. The soil moisture content during the measurements ranged from approximately 10 percent to approximately 30 percent by dry weight. The results of these measurements showed that the variations of the antenna temperatures with incident angle theta changed with the azimuthal angle a measured from the row direction. A numerical calculation based on a composite surface roughness was made and found to predict the observed features within the model's limit of accuracy. It was concluded that the difference between the horizontally and vertically polarized temperatures was due to the change in the local angle of field emission within the antenna field of view caused by the large scale row structure.

Wang, J. R.↗