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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 739 records · Page 41

Wave Dark Matter

Here we review the physics and phenomenology of wave dark matter: a bosonic dark matter candidate lighter than about 30 eV. Such particles have a de Broglie wavelength exceeding the average interparticle separation in a galaxy like the Milky Way and are, thus, well described as a set of classical waves. We outline the particle physics motivations for such particles, including the quantum chromodynamics axion as well as ultralight axion-like particles such as fuzzy dark matter. The wave nature of the dark matter implies a rich phenomenology: Wave interference gives rise to order unity density fluctuations on de Broglie scale in halos. One manifestation is vortices where the density vanishes and around which the velocity circulates. There is one vortex ring per de Broglie volume on average. For sufficiently low masses, soliton condensation occurs at centers of halos. The soliton oscillates and undergoes random walks, which is another manifestation of wave interference. The halo and subhalo abundance is expected to be suppressed at small masses, but the precise prediction from numerical wave simulations remains to be determined. For ultralight ∼10 −22 eV dark matter, the wave interference substructures can be probed by tidal streams or gravitational lensing. The signal can be distinguished from that due to subhalos by the dependence on stream orbital radius or image separation. Axion detection experiments are sensitive to interference substructures for wave dark matter that is moderately light. The stochastic nature of the waves affects the interpretation of experimental constraints and motivates the measurement of correlation functions. Current constraints and open questions, covering detection experiments and cosmological, galactic, and black hole observations, are discussed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Ultrafast Dynamics of Photosynthetic Light Harvesting: Strategies for Acclimation Across Organisms

Photosynthetic light harvesting exhibits near-unity quantum efficiency. The high efficiency is achieved through a series of energy and charge transfer steps within a network of pigment-containing proteins. Remarkably, high efficiency is conserved across many organisms despite differences in the protein structures and organization that allow each organism to respond to its own biological niche and the stressors within. In this review, we highlight recent progress toward understanding how organisms maintain optimal light-harvesting ability by acclimating to their environment. First, we review the building blocks of photosynthetic light harvesting, energy transfer, and time-resolved spectroscopic techniques. Then, we explore how three classes of photosynthetic organisms—purple bacteria, cyanobacteria, and green plants—optimize their light-harvesting apparatuses to their particular environment. Overall, research has shown that photosynthetic energy transfer is robust to changing environmental conditions, with each organism utilizing its own strategies to optimize photon capture in its particular biological niche.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Status and Targets for Polymer-Based Solid-State Batteries for Electric Vehicle Applications

There is growing interest in the development of Li-metal-based solid state batteries, driven by their promise in improving the energy density to satisfy electric vehicle requirements. In this work, we examine the status of Solid polymer electrolytes (SPEs) based solid state batteries for electric vehicle applications using a continuum scale mathematical model. We examine LiFePO4(LFP) cathode/lithium metal anode batteries containing three different electrolytes, namely (1) a liquid electrolyte, (2) the polystyrene-b-poly(ethylene oxide) (SEO) block copolymer electrolyte, and (3) a single-ion conducting (SIC) block copolymer electrolyte, with the liquid electrolyte serving as the baseline for the comparison. By using an optimization procedure, we assemble "virtual" batteries to identify the optimal design that maximizes energy density while allowing the power requirements of electric vehicles (EVs) to be satisfied. Results show the present status of different SPEs are still below what is considered acceptable and further improvements are needed to achieve electric vehicle targets. The optimization studies conducted here show that for low transference number electrolytes (similar to 0.2) the conductivity target is 5 x 10(-3)S cm(-1), while for a unity transference number electrolyte this target decreases to 4 x 10(-4)S cm(-1). These targets provide guidance for polymer synthesis researchers to develop better polymers for use in EVs.

25 ENERGY STORAGE↗

Review—Polymer/Ceramic Interface Barriers: The Fundamental Challenge for Advancing Composite Solid Electrolytes for Li-Ion Batteries

Composite-solid electrolytes, in which ion-conducting polymers are combined with superionic ceramics, could revolutionize electrochemical-energy-storage devices enabling higher energy density, providing greater stability during operation and enhanced safety. However, the interfacial resistance between the ceramic and polymer phases strongly suppresses the ionic conductivity and presents the main obstacle to the use of these materials. Here, we emphasize the need for a distinct focus on reducing energy barriers to interfacial ion transport and improving the cation transference number. To achieve this goal, it is essential to develop a fundamental understanding of the parameters that influence the interfacial barriers to ion transport in composite electrolytes, and to understand the effect of the type of ceramic ("active" and "inert") and its content on ion-transport phenomena. We suggest that adapting the polymer chemistry, mainly directed on polymerized ionic liquids, (PolyILs), and combined with functionalization of the surface of ceramic nanoparticles is a promising route for overcoming the high-energy-barrier challenge. Owing to high content of ion-conducting ceramics and high t+ of PolyILs, the fractional contribution of the migrating cationic species to the total ionic conductivity of polymer-in-ceramic electrolytes via an interfacial percolation path, will be close to unity, thus eliminating complications that might arise from emerging concentration gradients during the operation of solid-state batteries.

25 ENERGY STORAGE↗

The Influence of Fe Substitution in Lanthanum Calcium Cobalt Oxide on the Oxygen Evolution Reaction in Alkaline Media

The effect due to systematic substitution of cobalt by iron in La 0.6 Ca 0.4 Co 1-x Fe x O 3 towards the oxygen evolution reaction(OER) in alkaline media has been investigated. We synthesized these compounds by a facile glycine-nitrate synthesis and the phase formation was confirmed by X-ray diffraction and Neutron Diffraction elemental analysis. The apparent OER activity was evaluated by quasi steady state current measurements in alkaline media using a traditional three-electrode cell. X-ray photoelectron spectroscopy shows iron substitution causes an increase in the surface concentration of various cobalt oxidation states. Tafel slope in the vicinity of 60 mV/decade and electrochemical reaction order towards OH- near unity were achieved for the unsubstituted La 0.6 Ca 0.4 CoO 3 . Moreover, a decrease in the Tafel slope to 49 mV/decade was observed when iron is substituted in high amounts in the perovskite structure. The area specific current density showed dependence on the Fe fraction, however the relationship of specific current density with Fe fraction is not linear. High Fe substitutions, La 0.6 Ca 0.4 Co 0.2 Fe 0.8 O 3 and La 0.6 Ca 0.4 Co 0.1 Fe 0.9 O 3 showed higher area specific activity towards OER than La 0.6 Ca 0.4 CoO 3 or La 0.6 Ca 0.4 FeO 3 . Finally, we believe iron inclusion in the cobalt sites of the perovskite helps decrease the electron transfer barrier and facilitates the formation of cobalt-hydroxide at the surface. Possible OER mechanisms based on the observed kinetic parameters will be discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Fusion Nuclear Science Facilities and Pilot Plants Based on the Spherical Tokamak

A Fusion Nuclear Science Facility (FNSF) could play an important role in the development of fusion energy by providing the nuclear environment needed to develop fusion materials and components. The spherical torus/tokamak (ST) is a leading candidate for an FNSF due to its potentially high neutron wall loading and modular configuration. A key consideration for the choice of FNSF configuration is the range of achievable missions as a function of device size. Possible missions include: providing high neutron wall loading and fluence, demonstrating tritium self-sufficiency, and demonstrating electrical self-sufficiency. All of these missions must also be compatible with a viable divertor, first-wall, and blanket solution. ST-FNSF configurations have been developed simultaneously incorporating for the first time: (1) a blanket system capable of tritium breeding ratio TBR approximately 1, (2) a poloidal field coil set supporting high elongation and triangularity for a range of internal inductance and normalized beta values consistent with NSTX/NSTX-U previous/planned operation, (3) a long-legged divertor analogous to the MAST-U divertor which substantially reduces projected peak divertor heat-flux and has all outboard poloidal field coils outside the vacuum chamber and superconducting to reduce power consumption, and (4) a vertical maintenance scheme in which blanket structures and the centerstack can be removed independently. Progress in these ST-FNSF missions vs. configuration studies including dependence on plasma major radius R0 for a range 1m to 2.2m are described. In particular, it is found the threshold major radius for TBR = 1 is R0 greater than or equal to 1.7m, and a smaller R0=1m ST device has TBR approximately 0.9 which is below unity but substantially reduces T consumption relative to not breeding. Calculations of neutral beam heating and current drive for non-inductive ramp-up and sustainment are described. An A=2, R0=3m device incorporating high-temperature superconductor toroidal field coil magnets capable of high neutron fluence and both tritium and electrical self-sufficiency is also presented following systematic aspect ratio studies.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

MenuFramework

The Menu Framework is a reusable Extended Reality multi-level menu system for the Unity Development Platform. The menu structure is architected for reusability to suit whatever need the developer may have for a multi-level, reusable menu framework. Menu Framework's architecture, GUI, and functionality are based on the paper "Extended Reality for Enhanced Training and Knowledge Capture" (SAND2020-2361C). This tool uses the Microsoft Mixed Reality ToolKit (MRTK) built in functionality to provide a suite of functionalities including bounding box, follow me, minimize, maximize, settings, and help commands. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525. SAND2021-1507 O

Klein, BrandonThorin↗

Pxl

The code consists of several scripts. The image is fetched from a predefined URL, downloaded, and is displayed in the virtual environment at a predefined location. The image is also dynamically scaled to fit in the virtual environment depending on its size. The image is sent to have each pixel's value written to a CSV file. While the CSV is being written, a dictionary is populated with values that map each pixel to a temperature reading. The image's height, width, position and references to its corners are sent to make a button that is the same size as the image and placed right behind the image in the virtual scene. The button defines behavior that should be triggered when the user pushes the image. Unity provides visual cues that alert the user when they are about to touch something in the virtual environment. The code holds references to the cues for the left and right hands. The button queries the cue tracker and receives the position of the active cue in the form of a 3D vector. The 3D vector is compared to the bottom left corner of the image to transform the world space coordinates of the cue to the pixel space of the image. The specific pixel is approximated relative to how far left and up the user touched from the bottom left corner of the image. The approximated pixel value, which is represented as a coordinate in 2D space, is used to retrieve the temperature value associated with the approximated pixel. A window of text is then updated to display the temperature reading.

. Otis, KrystianeS [Idaho National Laboratory (INL↗

Comments on “A Unified Representation of Deep Moist Convection in Numerical Modeling of the Atmosphere. Part I”

Arakawa and Wu (2013, hereafter referred to as AW13) recently developed a formal approach to a unified parameterization of atmospheric convection for high-resolution numerical models. The work is based on ideas formulated by Arakawa et al. (2011). It lays the foundation for a new parameterization pathway in the era of high-resolution numerical modeling of the atmosphere. The key parameter in this approach is convective cloud fraction. In conventional parameterization, it is assumed that <<1. This assumption is no longer valid when horizontal resolution of numerical models approaches a few to a few tens kilometers, since in such situations convective cloud fraction can be comparable to unity. Therefore, they argue that the conventional approach to parameterizing convective transport must include a factor 1 - in order to unify the parameterization for the full range of model resolutions so that it is scale-aware and valid for large convective cloud fractions. While AW13’s approach provides important guidance for future convective parameterization development, in this note we intend to show that the conventional approach already has this scale awareness factor 1 - built in, although not recognized for the last forty years. Therefore, it should work well even in situations of large convective cloud fractions in high-resolution numerical models.

atmospheric↗

Improved Representation of Surface Spectral Emissivity in a Global Climate Model and Its Impact on Simulated Climate

Surface longwave emissivity can be less than unity and vary significantly with frequency. However, most climate models still assume a blackbody surface in the longwave (LW) radiation scheme of their atmosphere models. This study incorporates realistic surface spectral emissivity into the atmospheric component of the Community Earth System Model (CESM), version 1.1.1, and evaluates its impact on simulated climate. By ensuring consistency of the broadband surface longwave flux across different components of the CESM, the top-of-the-atmosphere (TOA) energy balance in the modified model can be attained without retuning the model. Inclusion of surface spectral emissivity, however, leads to a decrease of net upward longwave flux at the surface and a comparable increase of latent heat flux. Global-mean surface temperature difference between the modified and standard CESM simulation is 0.20 K for the fully coupled run and 0.45 K for the slab-ocean run. Noticeable surface temperature differences between the modified and standard CESM simulations are seen over the Sahara Desert and polar regions. Accordingly, the climatological mean sea ice fraction in the modified CESM simulation can be less than that in the standard CESM simulation by as much as 0.1 in some regions. When spectral emissivities of sea ice and open ocean surfaces are considered, the broadband LW sea ice emissivity feedback is estimated to be −0.003 W m −2 K −1 , assuming flat ice emissivity as sea ice emissivity, and 0.002 W m −2 K −1 , assuming coarse snow emissivity as sea ice emissivity, which are two orders of magnitude smaller than the surface albedo feedback.

54 ENVIRONMENTAL SCIENCES↗

The Effects of Surface Longwave Spectral Emissivity on Atmospheric Circulation and Convection over the Sahara and Sahel

This study quantifies the impact of the inclusion of realistic surface spectral emissivity in the Sahara and Sahel on the simulated local climate and beyond. The surface emissivity in these regions can be as low as 0.6–0.7 over the infrared window band while close to unity in other spectral bands, but such spectral dependence has been ignored in current climate models. Realistic surface spectral emissivities over the Sahara and Sahel are incorporated into the Community Earth System Model (CESM) version 1.1.1, while treatments of surface emissivity for the rest of the globe remain unchanged. Both the modified and standard CESM are then forced with prescribed climatological SSTs and fixed present-day forcings for 35-yr simulations. The outputs from the last 30 years are analyzed. Compared to the standard CESM, the modified CESM has warmer surface air temperature, as well as a warmer and wetter planetary boundary layer over the Sahara and Sahel. The modified CESM thus favors more convection in these regions and has more convective rainfall, especially in the Sahara. The moisture convergence induced by such inclusion of surface spectral emissivity also contributes to the differences in simulated precipitation in the Sahel and the region south to it. Compared to observations, inclusion of surface spectral emissivity reduces surface temperature biases in the Sahara and precipitation biases in the Gulf of Guinea but exacerbates the wet biases in the Sahara. Such realistic representation of surface spectral emissivity can help unmask other factors contributing to regional biases in the original CESM.

54 ENVIRONMENTAL SCIENCES↗

Simulated Polarimetric Fields of Ice Vapor Growth Using the Adaptive Habit Model. Part I: Large-Eddy Simulations

Abstract The bulk adaptive habit model (AHM) explicitly predicts ice particle aspect ratio, improving the representation of microphysical processes and properties, including ice–liquid-phase partitioning. With the unique ability to predict ice particle shape and density, the AHM is combined with an offline forward operator to produce fields of simulated polarimetric variables. An evaluation of AHM-forward-simulated dual-polarization radar signatures in an idealized Arctic mixed-phase cloud is presented. Interpretations of those signatures are provided through microphysical model output using the large-eddy simulation mode of the Weather Research and Forecasting Model. Vapor-grown ice properties are associated with distinct observable signatures in polarimetric radar variables, with clear sensitivities to the simulated ice particle properties, including ice number, size, and distribution shape. In contrast, the liquid droplet number has little influence on both polarimetric and microphysical variables in the case presented herein. Polarimetric quantities are sensitive to the dominating crystal habit type in a volume, with enhancements for aspect ratios much lower or higher than unity. This synthesis of a microphysical model and a polarimetric forward simulator is a first step in the evaluation of detailed AHM microphysics.

54 ENVIRONMENTAL SCIENCES↗

Semi-Automatic Geographic Information System Framework for Creating Photo-Realistic Digital Twin Cities to Support Autonomous Driving Research

Digital twin cities are frequently used in vehicle and traffic simulations to render realistic on-road driving scenarios under various traffic and environmental conditions. These digital twins provide a high-fidelity replica of the physical world (e.g., buildings, roads, infrastructures, traffic) to create three-dimensional (3D) virtual-physical environments to support various emerging vehicle and transportation technologies such as connected and automated vehicles. These virtual environments provide a cost-effective digital proving ground to evaluate, validate, and test emerging technologies that include control algorithms, localization, perception, and sensors. Replicating a real-world traffic scenario in a digital twin using a traditional 3D modeling approach is a time-consuming and labor-intensive effort. Here this paper presents a semi-automated spatial framework to construct realistic 3D digital twin cities to support autonomous driving research using readily available geographic information system (GIS) data and 3D prefabricated (prefab) models. We start with a comprehensive review of geospatial data sources of essential digital entities required in a 3D digital twin city and present an integrated GIS-3D modeling pipeline using customized QGIS/GDAL and Blender scripting in Python. The pipeline outputs are realistic 3D digital twin cities compatible with common vehicle simulation software, such as CARLA and IPG CarMaker. The paper closes with a showcase to demonstrate the quality and usability of a digital twin city created to replicate the Shallowford Road corridor in Chattanooga in both Unity and Unreal engine-based virtual environment. The generated digital twin city can be applied to a hardware-in-the-loop simulation environment with an actual testing vehicle to facilitate autonomous driving research.

33 ADVANCED PROPULSION SYSTEMS↗

Plasma power recycling at the divertor surface

With a divertor made of solid materials like carbon and tungsten, plasma ions are expected to be recycled at the divertor surface with a time-averaged particle recycling coefficient very close to unity in steady-state operation. This means that almost every plasma ion (hydrogen and helium) will be returned to the plasma, mostly as neutrals. The power flux deposited by the plasma on the divertor surface, on the other hand, can have varying recycling characteristics depending on the material choice of the divertor; the run-time atomic composition of the surface, which can be modified by material mix due to impurity migration in the chamber; and the surface morphology change over time. In general, a high-Z–material (such as tungsten) surface tends to reflect light ions and produce stronger power recycling, while a low-Z–material (such as carbon) surface tends to have a larger sticking coefficient for light ions and hence lower power recycling. Here, an explicit constraint on target plasma density and temperature is derived from the truncated bi-Maxwellian sheath model, in relation to the absorbed power load and power recycling coefficient at the divertor surface. Lastly, it is shown that because of the surface recombination energy flux, the attached plasma has a sharper response to power recycling in comparison to a detached plasma.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

VADER: A Tool for Criticality Safety Validation

The purpose of criticality safety is to prevent any inadvertent criticality from occurring during the handling or storage of fissile material. Calculations are frequently used to demonstrate that a sufficient subcritical margin exists. Validation is a key aspect of the evaluation process, establishing the suitability, accuracy, and associated uncertainty of the computational method and data to be used for the intended application. The validation process is performed by comparing the results of critical experiments with the calculated results from models of the experiments using the computational method to be validated. Laboratory critical experiments are controlled systems that achieve a k eff of approximately 1 in order to investigate the parameters at which such a critical condition is achieved. The validation parameters that are traditionally applied to safety analysis calculations are the bias and the bias uncertainty . The bias is the deviation of the average k eff of the validation suite from unity. The bias uncertainty accounts for the statistical uncertainty in the bias based on the standard deviation, sample size, and distribution of k eff values of the validation suite. The values of bias and bias uncertainty ensure that the systems predicted to be subcritical by the computational method will indeed be subcritical. The bias and bias uncertainty are often combined to determine an upper subcritical limit (USL) or computational margin that can then be applied to safety analysis calculations. Many methods have been developed by different organizations to calculate the bias and bias uncertainty for various types of criticality analyses. Each of these methods typically requires that the validity of various underpinning statistical assumptions be confirmed to demonstrate that the method is appropriate for the analysis of a given validation suite. An example of the validation decision making flow is shown in Fig.1. As shown in Fig. 1, the analyst performing the validation fits a trend line to the data and performs a test to determine if the trend was a statistically better representation of the data than if it were treated as an uncorrelated sample. If the trend line is a better representation of the data, then the analyst uses any one of a number of trending techniques to determine the bias and bias uncertainty. If a trend is not an appropriate representation of the data, then the analyst proceeds to perform a normality assessment for the data. If the normal assumption can be shown to be acceptable, then the analyst calculates the bias and bias uncertainty with the parametric technique. If the assumption of normality cannot be justified, then the nonparametric technique is used. Once the decision flow has been followed and the appropriate technique has been selected, the bias and bias uncertainty is typically combined with an administrative margin to determine a USL below which calculated values of k eff for safety analysis models can be considered subcritical. The calculations used in each decision are often performed with spreadsheets or with small programs available at various sites performing criticality analyses. Expertise in understanding and interpreting the results must be maintained to perform these calculations. This can often be an error-prone process. Oak Ridge National Laboratory (ORNL) is currently developing the Validation and Data Evaluation Resource (VADER) to simplify and automate the criticality safety validation process and to provide a software quality assurance pedigree to the calculational methods used. This paper discusses the use of the Fulcrum user interface with VADER, the anticipated initial capabilities of VADER to perform validation analyses, and the output from the code.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Computational expressions for signals in frequency-modulation spectroscopy

In this study, general expressions for the signals in frequency-modulation spectroscopy (FMS) appear in the literature but are often reduced to simple analytical equations following the assumption of a weak modulation index. This is little help to the experimentalist who wants to predict signals for modulation depths of the order of unity or greater, where strong FMS signals reside. Here, we develop general formulas for FMS signals in the case of an absorber with a Voigt line shape and then link these expressions to an example and existing numerical code for the line shape. The resulting computational recipe is easy to implement and exercised here to show where the larger FMS signals are found over the coordinates of modulation index and modulation frequency. One can also estimate from provided curves the in-phase FMS signal over a wide range of modulation parameters at either the Lorentzian-broadening or Doppler-broadening limit, or anywhere in between by interpolation.

74 ATOMIC AND MOLECULAR PHYSICS↗