Search NASA⌕ Search

SEARCH · Search NASA

Results for “atom trapping”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 739 records · Page 41
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Radiation protection design considerations for man in geosynchronous orbits

A description is presented of preliminary studies which have been carried out to identify design requirements and mission constraints imposed by the geosynchronous radiation environment. The radiation species of dominant impact are the trapped electrons and solar flare particles. The criterion used in the conducted shielding design analysis has been to limit the skin dose to 100 rems for 3 months. The analysis included the optimization of an electron/bremsstrahlung shield for residence within the vehicle, the minimization of the dose received in extravehicular activity, and the calculation of special shield requirements for solar flares. An investigation was conducted of the potential benefits accruing from a three-layered composite shield with part of the aluminum layer replaced with a lower atomic number material. The materials considered were polyethylene, carbon, beryllium, and lithium hydride.

Rossi, M. L.↗
NASA NTRS1981

Energetic heavy ions with nuclear charge Z greater than or equal to 4 in the equatorial radiation belts of the earth - Magnetic storms

Direct in situ observations of trapped energetic heavy ions with nuclear charge Z greater than or equal to 4 at energies in the lower MeV range made with Explorer 45 during the period June-December 1972 are presented. It is noted that all measurements were carried out in the vicinity of the geomagnetic equatorial plane and that the data show the varying effects of four major magnetic storm periods. Orders of magnitude increases in the trapped heavy ion population are seen deep within the radiation belts following the August 1972 solar flare and magnetic storm events. Fluxes of the Z greater than or equal to 4 ions are found to decay faster than those of helium ions of comparable energies; typical decay times for these ions are found to be 24-40 days at L less than or equal to 4 and shorter at higher L shells. The observations are compared with the expected post-injection long-term behavior of atomic oxygen ions deduced from charge exhange, radial diffusive transport, and Coulomb collisions. Good agreement is found between theory and observations.

Spjeldvik, W. N.↗
DOE OSTI2021

Precision mass measurement of lightweight self-conjugate nucleus 80 Zr

Protons and neutrons in the atomic nucleus move in shells analogous to the electronic shell structures of atoms. The nuclear shell structure varies due to changes of the nuclear mean field with the number of neutrons N and protons Z, and these variations can be probed by measuring mass differences between nuclei. The N=Z=40 self-conjugate nucleus 80 Zr is of particular interest as its proton and neutron shell structures are expected to be very similar, and its ground state is highly deformed. Here, we provide evidence for the existence of a deformed double shell closure in 80Zr through high precision Penning trap mass measurements of 80-83 Zr. Our mass values show that 80Zr is significantly lighter, and thus more strongly bound than predicted. This can be attributed to the deformed shell closure at N=Z=40 and the large Wigner energy. A statistical Bayesian model mixing analysis employing several global nuclear mass models demonstrates difficulties with reproducing the observed mass anomaly using current theory.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1975

Solar-wind interactions - Nature and composition of lunar atmosphere

The nature and composition of the lunar atmosphere are examined on the basis of solar-wind interactions, and the nature of the species in the trapped-gas layer is discussed using results of theoretical and experimental investigations. It is shown that the moon has a highly tenuous atmosphere consisting of various species derived from five sources: solar-wind interaction products, cosmic-ray interaction products, effects of meteoritic impacts, planetary degassing, and radioactive-decay products. Atmospheric concentrations are determined for those species derived from solar-wind protons, alpha particles, and oxygen ions. Carbon chemistry is briefly discussed, and difficulties encountered in attempts to determine quantitatively the concentrations of molecular oxygen, atomic oxygen, carbon monoxide, carbon dioxide, and methane are noted. The calculated concentrations are shown to be in good agreement with observations by the Apollo 17 lunar-surface mass spectrometer and orbital UV spectrometer.

Mukherjee, N. R.↗
DOE OSTI2020

Effects of excess Te on flux inclusion formation in the growth of cadmium zinc telluride when forced melt convection is applied

The presence of second phase defects, particularly flux inclusions of tellurium rich composition, are of great concern for charge collection efficiency in cadmium zinc telluride (CZT) and cadmium telluride (CT) material intended for applications such as radiation detection. These inclusions can distort applied electric field lines within the detector as well as act as trapping centers for charge carriers. Reduction and/or elimination of these inclusions is required to achieve appropriate charge collection efficiencies, especially in detectors of thicknesses greater than 5 mm. These so-called flux inclusions are understood to form as a consequence of constitutional undercooling at the crystal growth interface. In this study, a forced melt convection technique was applied in Vertical Bridgman (VB) melt growth of CZT without reducing imposed growth rates of ~2 mm/hr. Several rotation profiles were tested while adjusting the melt composition from 51.62 to 61.75 atomic percent (at%) Te where the Te concentration was initially increased to improve overall material purity. With forced melt convection, the best inclusion distributions were achieved with highly Te rich melt compositions, far beyond the stoichiometric composition range for the CZT system. Average inclusion diameters were reduced to 2 µm while inclusions greater than 5 µm were essentially eliminated. Composition analyses of these ingots revealed near equilibrium concentrations of Te, even with ingots grown from Te concentrations as high as 61.75 at% Te. In this paper, a recipe for the reduction of inclusions in CZT melt growth is put forward and the implications of this method on our understanding of inclusion formation are discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Neutron Irradiation Induced Changes in Isotopic Abundance of 6Li and 3D Nanoscale Distribution of Tritium in LiAlO2 Pellets Analyzed by Atom Probe Tomography

Tritium, a radioactive isotope of hydrogen is produced by neutron irradiation of 6Li enriched LiAlO2 pellets in Tritium producing burnable absorber rods (TPBARs). Three-dimensional nanoscale mapping of Tritium in irradiated pellets is critical to understand its spatial variation and its association with various microstructural features in the pellets. Spatially resolved analysis of 6Li isotopic enrichment in such ceramic pellets before and after irradiation can provide insights to heterogeneities in Li isotopic distribution. However, Li being a light isotope, its spatially resolved compositional or isotopic analysis is a challenging task to most analytical methods. Here we used atom probe tomography, to evaluate the Li isotopic enrichment in both the LiAlO¬2 matrix and the Li deficient secondary phase LiAl5O8 before irradiation. These results were then compared with 6Li isotopic ratio measured by APT analysis of neutron irradiated pellets to clearly demonstrate the unique capability of APT to quantitatively analyze the isotopic enrichment of 6Li as well as for other light elements present in these materials. Evidence for heterogenous nanoscale distribution of 3H and O3H within irradiated pellet microstructure is also provided, which is attributed to 3H trapping in irradiation induced vacancy clusters or voids within the LiAlO2 matrix. The characterization results given here, now prove the feasibility for using APT for analyzing nanoscale spatially resolved isotopic enrichment of Li as well as other light elements such as Tritium in TPBARs. This work also paves way to adopt APT for analyzing light elements such as Li and tritium in materials used for nuclear fusion reactor applications, geochemistry, astrophysics as well as for energy storage applications.

Devaraj, Arun↗
NASA NTRS1996

Helium and Neon in Comets

Two comets were observed with EUVE in late 1994. Both comet Mueller and comet Borrelly are short-period comets having well established orbital elements and accurate ephemerides. Spectra of 40 ksec were taken of each. No evidence for emission lines from either Helium or Neon was detected. We calculated limits on the production rates of these atoms (relative to solar) assuming a standard isotropic outflow model, with a gas streaming speed of 1 km/s. The 3-sigma (99.7% confidence) limits (1/100,000 for He, 0.8 for Ne) are based on a conservative estimate of the noise in the EUVE spectra. They are also weakly dependent on the precise pointing and tracking of the EUVE field of view relative to the comet during the integrations. These limits are consistent with ice formation temperatures T greater than or equal to 30 K, as judged from the gas trapping experiments of Bar-Nun. For comparison, the solar abundances of these elements are He/O = 110, Ne/O = 1/16. Neither limit was as constraining as we had initially hoped, mainly because comets Mueller and Borrelly were intrinsically less active than anticipated.

Jewitt, David↗
DOE OSTI2022

ANS Winter 2022: ATF-2C Physics Safety and Scoping Analysis

ATF-2C comprises four tiers with six rodlets each. The experiment test train (TT) is situated in Loop 2A in the center flux trap (CFT) of the ATR, in which typical pressurized water reactor (PWR) conditions shall be approximated. Tier 1 (bottom) of the TT tests Framatome silicon carbide (SiC) cladding, containing molybdenum heater rods. Low-enriched uranium (LEU) Framatome rodlets with chrome-coated M5 cladding have been modeled in their place for the physics safety analysis to allow the substitution of this tier with fuel if needed. Tier 2 tests LEU Framatome rodlets with M5 cladding, which had irradiated in ATR in prior ATF experiments. Tier 3 tests General Atomics SiC composite cladding, also containing molybdenum heater rods. Tier 4/5/6 (top) tests the Japan Atomic Energy Agency (JAEA)/Mitsubishi Heavy Industries (MHI) fueled rodlets. This upper tier tests LEU rodlets with chrome-coated MDA cladding—several with temperature or pressure instrumentation. To flatten the axial power profile, lower portion of Tier 4/5/6 is surrounded by a hafnium (Hf) shroud, and the bottom two UO2 pellets are of natural enrichment. The ATF-2C TT is to be irradiated in the CFT of ATR (Fig. 1) for three or four 60-day cycles.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

Inorganometallic Catalyst Design Center (ICDC) EFRC Accomplishments

The ICDC focused largely on heterogeneous catalysis of oxidative chemical transformations, especially those that came to prominence as natural gas (wet shale gas) supplanted crude oil as the primary feedstock in North America for carbon-based manufacturing of commodity chemicals. Driven by fracking-enabled access to enormous stores of shale-trapped wet gas, the feedstock change from oil to gas enabled a shift away from high-temperature catalytic breakdown of large hydrocarbons to catalytic build-up of C4, C3, C2, and C1 into desired intermediates, but now at much more modest temperatures. In turn, the much lower thermal force accompanying these kinds of reactions facilitates catalyst stabilization and characterization, including operando characterization, while slowing on-stream catalyst evolution (i.e., preserving catalyst structure), accommodating catalyst complexity, and enabling creation of uniform arrays of heterogeneous catalysts with single-atom or near-single-atom precision—at least for model systems. Together these features have proven to be a boon to hypothesis-driven catalysis science and to experimentally testable computation-based design advances and mechanism explication. The ICDC has greatly facilitated the integration of catalyst synthesis, advanced characterization, performance assessment, and computational elucidation—with advances in each of these realms spurring achievements in catalysis science and complementary realms.

03 NATURAL GAS↗
DOE OSTI2020

Plasma and trap-based techniques for science with antimatter

Positrons (i.e., antielectrons) find use in a wide variety of applications, and antiprotons are required for the formation and study of antihydrogen. Available sources of these antiparticles are relatively weak. To optimize their use, most applications require that the antiparticles be accumulated into carefully prepared plasmas. We present an overview of the techniques that have been developed to efficiently accumulate low energy antiparticles and create, in particular, tailored antiparticle plasmas. Techniques are also described to create tailored antiparticle beams. Many of these techniques are based on methods first developed by the nonneutral plasma community using electron plasmas for increased data rate. They have enabled the creation and trapping of antihydrogen, have been critical to studies of positron and positronium interactions with matter, including advanced techniques to characterize materials and material surfaces, and have led to the creation and study of the positronium molecule. Rather than attempting to be comprehensive, we focus on techniques that have proven most useful, applications where there has been significant, recent progress, and areas that hold promise for future advances. Examples of the latter include the ever more precise comparisons of the properties of antihydrogen and hydrogen, tests of gravity using antihydrogen and positronium atoms, and efforts to create and study phases of the many-electron, many-positron system.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Collapse of Jahn-Teller phonons in La 1−x Sr x MnO 3 with weak magnetoresistance

Perovskite manganites are quantum materials exhibiting competing interactions inducing colossal magnetoresistance (CMR). The prevailing theory of CMR highlights the essential role of electron-phonon coupling (EPC), but mounting evidence suggests the underlying mechanism is more complicated. Here, we investigate phonons and spin-phonon coupling in ferromagnetic CMR manganites La 1−x Sr x MnO 3 (x=0.2,0.3) with relatively small CMR associated with melting of the magnetic order above room temperature. High-resolution neutron scattering experiments combined with density functional theory (DFT) show that the low-temperature ferromagnetic phase is conventional: neutron scattering from phonons agrees with DFT predictions and magnons follow sinusoidal dispersions. Fluctuating magnetic moments and low-energy phonons remain conventional in the high-temperature paramagnetic phase, indicating the Mn and La/Sr sublattices are not strongly perturbed by melting of ferromagnetism. In contrast, the Jahn–Teller-active optical oxygen vibrations collapse entirely above the Curie temperature, despite low CMR in these compositions, with some of the lost spectral weight reappearing as quasielastic scattering. We attribute this highly anomalous behavior to giant EPC in the charge and/or orbital channel. It drives cooperative diffusive motion of quasistatic carrier-trapping oxygen sublattice distortions once ferromagnetism disappears. We hypothesize the magnitude of magnetoresistance correlates with the rate of diffusion rather than with the strength of Jahn–Teller EPC.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Helium partitioning to the core-shelled Ta nanoclusters in nanocrystalline Cu-Ta alloy

In this work, a nanocrystalline (NC) Cu-10at.%Ta alloy is irradiated with helium at different temperatures to assess the stability and effectiveness of Ta nanoclusters in trapping helium and suppressing swelling. Advanced microstructural characterization of the room-temperature irradiated specimens indicated the presence of small He-bubbles (∼1-2 nm) at the peak damage depth mainly at the core and along the interface of Ta nanoclusters with Cu matrix. Few bubbles were found along grain boundaries, with much smaller bubbles homogenously distributed within the copper lattice. High-temperature irradiation exhibited bubbles of ∼3-5 nm, which were primarily associated with nanoclusters as compared to other locations, with no observed faceting of the bubbles. In conclusion, atom probe analysis confirmed helium partitioning to the Ta nanoclusters indicating the effective entrapment of these He atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Effect of niobium doping on excitonic dynamics in MoSe 2

Abstract Transition metal dichalcogenides (TMDs) have emerged as attractive two-dimensional semiconductors for future electronic and optoelectronic applications. Their charge transport properties, such as conductivity and the type of charge carriers, can be effectively controlled by substitutional doping of the transition metal atoms. However, the effects of doping on the excitonic properties, particularly their dynamical properties, have been less studied. Using Nb-doped MoSe 2 as a case study, we experimentally investigate the effect of doping on excitonic dynamics in TMDs. Transient absorption measurements are used to directly compare the dynamical properties of excitons in Nb-doped MoSe 2 across monolayer, bilayer, and bulk flakes with their undoped counterparts. The exciton lifetimes in Nb-doped flakes are significantly shorter than those in their undoped counterparts. This effect is attributed to the trapping of excitons in defect states introduced by Nb impurities. These results reveal an important consequence of Nb doping on excitonic dynamics in TMDs.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2023

Transition Metal Dichalcogenides: Making Atomic‐Level Magnetism Tunable with Light at Room Temperature

Abstract The capacity to manipulate magnetization in 2D dilute magnetic semiconductors (2D‐DMSs) using light, specifically in magnetically doped transition metal dichalcogenide (TMD) monolayers ( M ‐doped TX 2 , where M = V, Fe, and Cr; T = W, Mo; X = S, Se, and Te), may lead to innovative applications in spintronics, spin‐caloritronics, valleytronics, and quantum computation. This Perspective paper explores the mediation of magnetization by light under ambient conditions in 2D‐TMD DMSs and heterostructures. By combining magneto‐LC resonance (MLCR) experiments with density functional theory (DFT) calculations, we show that the magnetization can be enhanced using light in V‐doped TMD monolayers (e.g., V‐WS 2 , V‐WSe 2 ). This phenomenon is attributed to excess holes in the conduction and valence bands, and carriers trapped in magnetic doping states, mediating the magnetization of the semiconducting layer. In 2D‐TMD heterostructures (VSe 2 /WS 2 , VSe 2 /MoS 2 ), the significance of proximity, charge‐transfer, and confinement effects in amplifying light‐mediated magnetism is demonstrated. We attributed this to photon absorption at the TMD layer that generates electron–hole pairs mediating the magnetization of the heterostructure. These findings will encourage further research in the field of 2D magnetism and establish a novel design of 2D‐TMDs and heterostructures with optically tunable magnetic functionalities, paving the way for next‐generation magneto‐optic nanodevices.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Characterization of light-induced potentials in the strong-field dissociation of O 2 +

In this work, we investigate theoretically the imprints of light-induced potentials (LIPs) on the dissociation dynamics of O 2 + molecular ions, as observable in angle-resolved fragment kinetic-energy-release (KER) spectra. Following the vibrational and rotational dynamics of the initial pump-laser-excited cationic nuclear wave packet, while accounting for the dipole coupling between the O 2 + ( a 4 Π u ) and O 2 + ( f 4 Π g ) electronic states in 800-nm 40-fs probe-laser pulses with peak intensities between 10 13 and 10 14 W / cm 2 , we calculate angle-resolved KER spectra which reveal characteristic energy- and angle-dependent fringe structures. These fringes shift downward in energy as the molecular alignment angle θ relative to the probe-pulse polarization direction increases from 0 to π / 2 . The angle-dependent shifts in the KER fringes increase for larger probe-pulse peak intensities and follow the angle and light-wave-intensity dependence of the vibrational spectrum in the associated Floquet bond-hardening well, which is a manifestation of transient O 2 + nuclear-probability trapping in the LIP during dissociation. By examining the rovibrational dynamics of the dissociating molecular cation near the light-induced conical intersection (LICI) in the cationic LIP surface at θ = π / 2 , we identify related angle-dependent structures in the KER spectra, suggesting a means for assessing the significance of LICIs in molecular dissociation pathways.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS2006

Miniaturized Mercury Ion Clock for Ultrastable Deep Space Applications

We have recently completed a prototype ion-clock physics package based on Hg ions shuttled between a quadrupole and a 16-pole rf trap. With this architecture we have demonstrated short-term stability ~2-3x10-13 at 1 second, averaging to 10-15 at 1 day. This development shows that H-maser quality stabilities can be produced in a small clock package, comparable in size to an ultra-stable quartz oscillator required for holding 1-2x10-13 at 1 second. This performance was obtained in a sealed vacuum configuration where only a getter pump was used to maintain vacuum. The vacuum tube containing the traps has now been under sealed vacuum conditions for nearly 1.5 years with no measurable degradation of ion trapping lifetimes or clock short-term performance. Because the tube is sealed, the Hg source and Neon buffer gas are held indefinitely, for the life of the tube. There is no consumption of Hg in this system unlike in a Cs beam tube where lifetime is often limited by Cs depletion.

mercury ion clocks↗
NASA NTRS2003

Stabilized Fiber-Optic Distribution of Reference Frequency

An optoelectronic system distributes a reference signal of low noise and highly stabilized phase and frequency (100 MHz) from an atomic frequency standard to a remote facility at a distance up to tens of kilometers. The reference signal is transmitted to the remote station as amplitude modulation of an optical carrier signal propagating in an optical fiber. The stabilization scheme implemented in this system is intended particularly to suppress phase and frequency fluctuations caused by vibrations and by expansion and contraction of the optical fiber and other components in diurnal and seasonal heating and cooling cycles. The system (see figure) comprises several subsystems, the main one being (1) a hydrogen-maser or linear-ion-trap frequency standard in an environmentally controlled room in a signal-processing center (SPC), (2) a stabilized fiber-optic distribution assembly (SFODA), (3) a compensated sapphire oscillator (CSO) in an environmentally controlled room in the remote facility, (4) thermally stabilized distribution amplifiers and cabling from the environmentally controlled room to end users, and (5) performance- measuring equipment.

Calhoun, Malcolm↗