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At least 739 records · Page 41

Effects of cation compositions on the electronic properties and optical dispersion of indium zinc tin oxide thin films by electron spectroscopy

Highlights: • REELS analysis can provide optical dispersion and electronic properties of oxide materials. • The band gap varied with In/Zn/Sn compositions and increased after annealing. • The optical properties were examined using REELS in conjunction with the Tougaard–Yubero model. • The dispersion parameters were determined by a single-oscillator Wemple–DiDomenico model. • The Zn and Sn contents play a crucial role in determining the single-oscillator constant and dispersion energy of IZTO thin films. - Abstract: The electronic properties and optical dispersion of indium zinc tin oxide (IZTO) films with different cation compositions were investigated by reflection electron energy loss spectroscopy (REELS). The REELS spectra of IZTO films revealed that the band gap varied with different Sn/Zn ratios and In content. The optical properties were examined with REELS data using Tougaard–Yubero model and the results were compared with the envelope of the transmission spectra obtained using a UV-spectrometer. The dispersion behavior of the refractive index from REELS results was studied in terms of the single-oscillator Wemple–DiDomenico model. The results showed that the different compositions of In/Zn/Sn caused a change in the dispersion parameters of IZTO thin films in contrast to the static values of refractive indices and dielectric constant which remained the same. Our work demonstrated that REELS is an efficient tool to study the optical properties of a material by obtaining the optical parameters.

36 MATERIALS SCIENCE↗

POPULATION III GAMMA-RAY BURSTS AND BREAKOUT CRITERIA FOR ACCRETION-POWERED JETS

We investigate the propagation of accretion-powered jets in various types of massive stars such as Wolf-Rayet stars, light Population III (Pop III) stars, and massive Pop III stars, all of which are the progenitor candidates of gamma-ray bursts (GRBs). We perform two-dimensional axisymmetric simulations of relativistic hydrodynamics, taking into account both the envelope collapse and the jet propagation (i.e., the negative feedback of the jet on the accretion). Based on our hydrodynamic simulations, we show for the first time that the accretion-powered jet can potentially break out relativistically from the outer layers of Pop III progenitors. In our simulations, the accretion rate is estimated by the mass flux going through the inner boundary, and the jet is injected with a fixed accretion-to-jet conversion efficiency {eta}. By varying the efficiency {eta} and opening angle {theta}{sub op} for more than 40 models, we find that the jet can make a relativistic breakout from all types of progenitors for GRBs if a simple condition {eta} {approx}> 10{sup -4}({theta}{sub op}/8 Degree-Sign ){sup 2} is satisfied, which is consistent with analytical estimates. Otherwise no explosion or some failed spherical explosions occur.

79 ASTRONOMY AND ASTROPHYSICS↗

THE MAGNETIC FIELD IN THE CLASS 0 PROTOSTELLAR DISK OF L1527

We present subarcsecond (∼0.''35) resolved observations of the 1.3 mm dust polarization from the edge-on circumstellar disk around the Class 0 protostar L1527. The inferred magnetic field is consistent with a dominantly toroidal morphology; there is no significantly detected vertical poloidal component to which observations of an edge-on disk are most sensitive. This suggests that angular momentum transport in Class 0 protostars (when large amounts of material are fed down to the disk from the envelope and accreted onto the protostar) is driven mainly by magnetorotational instability rather than magnetocentrifugal winds at 50 AU scales. In addition, with the data to date there is an early, tentative trend that R > 30 AU disks have so far been found in Class 0 systems with average magnetic fields on the 1000 AU scale strongly misaligned with the rotation axis. The absence of such a disk in the aligned case could be due to efficient magnetic braking that disrupts disk formation. If this is the case, this implies that candidate Class 0 disk systems could be identified by the average magnetic field direction at ∼1000 AU spatial scales.

79 ASTRONOMY AND ASTROPHYSICS↗

Novel perspective on a conventional technique: Impact of ultra-low temperature on bacterial viability and protein extraction

Ultra-low temperature (ULT) storage of microbial biomass is routinely practiced in biological laboratories. However, there is very little insight regarding the effects of biomass storage at ULT and the structure of the cell envelope, on cell viability. Eventually, these aspects influence bacterial cell lysis which is one of the critical steps for biomolecular extraction, especially protein extraction. Therefore, we studied the effects of ULT-storage (-80°C) on three different bacterial platforms: Escherichia coli , Bacillus subtilis and the cyanobacterium Synechocystis sp. PCC 6803. By using a propidium iodide assay and a modified MTT assay we determined the impact of ULT storage on cellular viability. Subsequently, the protein extraction efficiency was determined by analyzing the amount of protein released following the storage. The results successfully established that longer the ULT-storage time lower is the cell viability and larger is the protein extraction efficiency. Interestingly, E . coli and B . subtilis exhibited significant reduction in cell viability over Synechocystis 6803. This indicates that the cell membrane structure and composition may play a major role on cell viability in ULT storage. Interestingly, E . coli exhibited concomitant increase in cell lysis efficiency resulting in a 4.5-fold increase (from 109 μg/ml of protein on day 0 to 464 μg/ml of protein on day 2) in the extracted protein titer following ULT storage. Furthermore, our investigations confirmed that the protein function, tested through the extraction of fluorescent proteins from cells stored at ULT, remained unaltered. These results established the plausibility of using ULT storage to improve protein extraction efficiency. Towards this, the impact of shorter ULT storage time was investigated to make the strategy more time efficient to be adopted into protocols. Interestingly, E . coli transformants expressing mCherry yielded 2.7-fold increase (93 μg/mL to 254 μg/mL) after 10 mins, while 4-fold increase (380 μg/mL) after 120 mins of ULT storage in the extracted soluble protein. We thereby substantiate that: (1) the storage time of bacterial cells in -80°C affect cell viability and can alter protein extraction efficiency; and (2) exercising a simple ULT-storage prior to bacterial cell lysis can improve the desired protein yield without impacting its function.

59 BASIC BIOLOGICAL SCIENCES↗

Flight evaluation of a digital electronic engine control system in an F-15 airplane

Benefits provided by a full-authority digital engine control are related to improvements in engine efficiency, performance, and operations. An additional benefit is the capability of detecting and accommodating failures in real time and providing engine-health diagnostics. The digital electronic engine control (DEEC), is a full-authority digital engine control developed for the F100-PW-100 turbofan engine. The DEEC has been flight tested on an F-15 aircraft. The flight tests had the objective to evaluate the DEEC hardware and software over the F-15 flight envelope. A description is presented of the results of the flight tests, which consisted of nonaugmented and augmented throttle transients, airstarts, and backup control operations. The aircraft, engine, DEEC system, and data acquisition and reduction system are discussed.

Myers, L. P.↗

Comparison of Computational Approaches for Rapid Aerodynamic Assessment of Small UAVs

Computational Fluid Dynamic (CFD) methods were used to determine the basic aerodynamic, performance, and stability and control characteristics of the unmanned air vehicle (UAV), Kahu. Accurate and timely prediction of the aerodynamic characteristics of small UAVs is an essential part of military system acquisition and air-worthiness evaluations. The forces and moments of the UAV were predicted using a variety of analytical methods for a range of configurations and conditions. The methods included Navier Stokes (N-S) flow solvers (USM3D, Kestrel and Cobalt) that take days to set up and hours to converge on a single solution; potential flow methods (PMARC, LSAERO, and XFLR5) that take hours to set up and minutes to compute; empirical methods (Datcom) that involve table lookups and produce a solution quickly; and handbook calculations. A preliminary aerodynamic database can be developed very efficiently by using a combination of computational tools. The database can be generated with low-order and empirical methods in linear regions, then replacing or adjusting the data as predictions from higher order methods are obtained. A comparison of results from all the data sources as well as experimental data obtained from a wind-tunnel test will be shown and the methods will be evaluated on their utility during each portion of the flight envelope.

Shafer, Theresa C.↗

Palmitoylation of the feline immunodeficiency virus envelope glycoprotein and its effect on fusion activity and envelope incorporation into virions

The feline immunodeficiency virus (FIV) envelope glycoprotein (Env) possesses a short cytoplasmic domain of 53 amino acids containing four highly conserved cysteines at Env positions 804, 811, 815 and 848. Since palmitoylation of transmembrane proteins occurs at or near the membrane anchor, we investigated whether cysteines 804, 811 and 815 are acylated and analyzed the relevance of these residues for Env functions. Replacement of cysteines 804, 811 and 815 individually or in combination by serine residues resulted in Env glycoproteins that were efficiently expressed and processed. However, mutations C804S and C811S reduced Env fusogenicity by 93% and 84%, respectively, compared with wild-type Env. By contrast, mutant C815S exhibited a fusogenic capacity representing 50% of the wild-type value. Remarkably, the double mutation C804S/C811S abrogated both Env fusion activity and Env incorporation into virions. Finally, by means of Click chemistry assays we demonstrated that the four FIV Env cytoplasmic cysteines are palmitoylated.

60 APPLIED LIFE SCIENCES↗

Enhanced LAW Glass Formulation Testing (Final Report)

The principal objective of this work was to extend the glass formulation methodology developed in the earlier work for Envelope A, B and C waste compositions for development of compliant glass compositions targeting five high sodium-sulfur waste loading regions. This was accomplished through a combination of crucible-scale tests, and tests on the DM10 melter system. The DM10 was used for several previous tests on LAW compositions to determine the maximum feed sulfur concentrations that can be processed without forming secondary sulfate phases on the surface of the melt pool. This melter is the most efficient melter platform for screening glass compositions over a wide range of sulfate concentrations and therefore was selected for the present tests. The tests were conducted to provide information on melter processing characteristics and off-gas data, including sulfur incorporation and partitioning. As described above, the main objective was to identify the limits of waste loading in compliant glass formulations spanning the range of expected Na 2 O and SO 3 concentrations in the LAW glasses.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Experimental Study of an Axisymmetric Dual Throat Fluidic Thrust Vectoring Nozzle for Supersonic Aircraft Application

An axisymmetric version of the Dual Throat Nozzle concept with a variable expansion ratio has been studied to determine the impacts on thrust vectoring and nozzle performance. The nozzle design, applicable to a supersonic aircraft, was guided using the unsteady Reynolds-averaged Navier-Stokes computational fluid dynamics code, PAB3D. The axisymmetric Dual Throat Nozzle concept was tested statically in the Jet Exit Test Facility at the NASA Langley Research Center. The nozzle geometric design variables included circumferential span of injection, cavity length, cavity convergence angle, and nozzle expansion ratio for conditions corresponding to take-off and landing, mid climb and cruise. Internal nozzle performance and thrust vectoring performance was determined for nozzle pressure ratios up to 10 with secondary injection rates up to 10 percent of the primary flow rate. The 60 degree span of injection generally performed better than the 90 degree span of injection using an equivalent injection area and number of holes, in agreement with computational results. For injection rates less than 7 percent, thrust vector angle for the 60 degree span of injection was 1.5 to 2 degrees higher than the 90 degree span of injection. Decreasing cavity length improved thrust ratio and discharge coefficient, but decreased thrust vector angle and thrust vectoring efficiency. Increasing cavity convergence angle from 20 to 30 degrees increased thrust vector angle by 1 degree over the range of injection rates tested, but adversely affected system thrust ratio and discharge coefficient. The dual throat nozzle concept generated the best thrust vectoring performance with an expansion ratio of 1.0 (a cavity in between two equal minimum areas). The variable expansion ratio geometry did not provide the expected improvements in discharge coefficient and system thrust ratio throughout the flight envelope of typical a supersonic aircraft. At mid-climb and cruise conditions, the variable geometry design compromised thrust vector angle achieved, but some thrust vector control would be available, potentially for aircraft trim. The fixed area, expansion ratio of 1.0, Dual Throat Nozzle provided the best overall compromise for thrust vectoring and nozzle internal performance over the range of NPR tested compared to the variable geometry Dual Throat Nozzle.

Flamm, Jeffrey D.↗

Fluorescent lighting with aluminum nitride phosphors

A fluorescent lamp includes a glass envelope; at least two electrodes connected to the glass envelope; mercury vapor and an inert gas within the glass envelope; and a phosphor within the glass envelope, wherein the phosphor blend includes aluminum nitride. The phosphor may be a wurtzite (hexagonal) crystalline structure Al.sub.(1-x)M.sub.xN phosphor, where M may be drawn from beryllium, magnesium, calcium, strontium, barium, zinc, scandium, yttrium, lanthanum, cerium, praseodymium, europium, gadolinium, terbium, ytterbium, bismuth, manganese, silicon, germanium, tin, boron, or gallium is synthesized to include dopants to control its luminescence under ultraviolet excitation. The disclosed Al.sub.(1-x)M.sub.xN:Mn phosphor provides bright orange-red emission, comparable in efficiency and spectrum to that of the standard orange-red phosphor used in fluorescent lighting, Y.sub.2O.sub.3:Eu. Furthermore, it offers excellent lumen maintenance in a fluorescent lamp, and does not utilize "critical rare earths," minimizing sensitivity to fluctuating market prices for the rare earth elements.

36 MATERIALS SCIENCE↗

Low-energy high-brightness electron beam dynamics based on slice beam matrix method

Preserving the phase space quality has been of crucial importance to high-brightness electron beam transport. Any driving source of beam performance limitations in such a transport system must be carefully examined in order to preserve the beam phase space quality. It is found that in the low beam energy, high bunch charge regime, space charge effect on the charged particle beam evolution can be complicated. It may be insufficient to analyze the beam properties through the envelope or lower order moments for the mere bulk of the beam. In this work we will study the space-charge-dominated, low-energy, high-brightness electron beam dynamics based on the slice beam matrix method. The slice beam matrix method, extended from the existing bulk beam analysis, is applicable to an arbitrary longitudinal bunch distribution and can thus take the nonlinear RF curvature into account. The semi-analytical sliced beam space charge model is constructed and assumes an axisymmetric beam in the presence of perfect conducting cylindrical pipe with circular cross section. We present in this paper the theoretical formulation, starting from single-particle dynamics, space charge field calculation, followed by the moment description of a collection of particles, based on beam sigma matrix and longitudinal slice decomposition. We prove the equivalence between the beam matrix method and the envelope formalism in the presence of space charge effect, in both the transverse and longitudinal dimensions. Two examples are then demonstrated, one for a unit cell of superconducting radio-frequency (RF) cavity and the other for a 1.5-cell RF gun system. The semi-analytical results from beam matrix calculation are discussed and compared with particle tracking simulation using ASTRA. In conclusion, we expect that the analysis based on the slice beam matrix method shall serve as an efficient and advanced tool to further investigate the low-energy high-brightness electron beam dynamics.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Globular Cluster Formation at High Density: A Model for Elemental Enrichment with Fast Recycling of Massive-star Debris

The self-enrichment of massive star clusters by p -processed elements is shown to increase significantly with increasing gas density as a result of enhanced star formation rates and stellar scatterings compared to the lifetime of a massive star. Considering the type of cloud core where a globular cluster (GC) might have formed, we follow the evolution and enrichment of the gas and the time dependence of stellar mass. A key assumption is that interactions between massive stars are important at high density, including interactions between massive stars and massive-star binaries that can shred stellar envelopes. Massive-star interactions should also scatter low-mass stars out of the cluster. Reasonable agreement with the observations is obtained for a cloud-core mass of ∼4 × 10{sup 6} M {sub ⊙} and a density of ∼2 × 10{sup 6} cm{sup −3}. The results depend primarily on a few dimensionless parameters, including, most importantly, the ratio of the gas consumption time to the lifetime of a massive star, which has to be low, ∼10%, and the efficiency of scattering low-mass stars per unit dynamical time, which has to be relatively large, such as a few percent. Also for these conditions, the velocity dispersions of embedded GCs should be comparable to the high gas dispersions of galaxies at that time, so that stellar ejection by multistar interactions could cause low-mass stars to leave a dwarf galaxy host altogether. This could solve the problem of missing first-generation stars in the halos of Fornax and WLM.

79 ASTRONOMY AND ASTROPHYSICS↗

An extremely carbon-poor planetary nebula in the Small Magellanic Cloud

An optical and ultraviolet study is presented of object 28 of Sanduleak et al. (1978) in the SMC. This object is an extreme type of I PN which apparently has undergone all three stages of nuclear dredge-up together with an appreciable amount of convective envelope burning. Optical and UV data are well-represented by a model in which the central star has a temperature of 180,000 K and a radius of 0.09 solar radius. A nebular mass of 0.71 solar mass and a central star mass of 0.65-0.71 solar mass are inferred. The object apparently evolved from a massive progenitor with main-sequence mass greater than five solar masses, which underwent both second and third nuclear dredge-up and very efficient hot bottom burning.

Meatheringham, Stephen J.↗

Spitzer view of massive star formation in the tidally stripped Magellanic Bridge

The Magellanic Bridge is the nearest low-metallicity, tidally stripped environment, offering a unique high-resolution view of physical conditions in merging and forming galaxies. In this paper, we present an analysis of candidate massive young stellar objects (YSOs), i.e., in situ, current massive star formation (MSF) in the Bridge using Spitzer mid-IR and complementary optical and near-IR photometry. While we definitely find YSOs in the Bridge, the most massive are ∼10 M {sub ☉}, <<45 M {sub ☉} found in the LMC. The intensity of MSF in the Bridge also appears to be decreasing, as the most massive YSOs are less massive than those formed in the past. To investigate environmental effects on MSF, we have compared properties of massive YSOs in the Bridge to those in the LMC. First, YSOs in the Bridge are apparently less embedded than in the LMC: 81% of Bridge YSOs show optical counterparts, compared to only 56% of LMC sources with the same range of mass, circumstellar dust mass, and line-of-sight extinction. Circumstellar envelopes are evidently more porous or clumpy in the Bridge's low-metallicity environment. Second, we have used whole samples of YSOs in the LMC and the Bridge to estimate the probability of finding YSOs at a given H I column density, N(H I). We found that the LMC has ∼3 × higher probability than the Bridge for N(H I) >12 × 10{sup 20} cm{sup –2}, but the trend reverses at lower N(H I). Investigating whether this lower efficiency relative to H I is due to less efficient molecular cloud formation or to less efficient cloud collapse, or to both, will require sensitive molecular gas observations.

79 ASTRONOMY AND ASTROPHYSICS↗

The design and performance of the electromagnetic calorimeters in Hall C at Jefferson Lab

The design and performance of the electromagnetic calorimeters in the magnetic spectrometers in Hall C at Jefferson Lab are presented. For the existing HMS and SOS spectrometers, construction information and comparisons of simulated and experimental results are presented. The design and simulated performance for a new calorimeter to be used in the new SHMS spectrometer is also presented. We have developed and constructed electromagnetic calorimeters from TF-1 type lead-glass blocks for the HMS and SOS magnetic spectrometers at JLab Hall C. The HMS/SOS calorimeters are of identical design and construction except for their total size. Blocks of dimension 10 cm × 10 cm × 70 cm are arranged in four planes and stacked 13 and 11 blocks high in the HMS and SOS respectively. The energy resolution of these calorimeters is better than 6%/√E, and pion/electron (π/e) separation of about 100:1 has been achieved in energy range 1–5 GeV. Good agreement has been observed between the experimental and GEANT4 simulated energy resolutions. The HMS/SOS calorimeters have been used nearly in all Hall C experiments, providing good energy resolution and a high pion suppression factor. No significant deterioration in their performance has been observed in the course of use since 1994. For the SHMS spectrometer, presently under construction, details on the calorimeter design and accompanying GEANT4 simulation efforts are given. A Preshower+Shower design was selected as the most cost-effective among several design choices. The preshower will consist of a layer of 28 modules with TF-1 type lead glass radiators, stacked in two columns. The shower part will consist of 224 modules with F-101 type lead glass radiators, stacked in a “fly&#x27;s eye” configuration of 14 columns and 16 rows. The active area of 120 × 130 cm(2) will encompass the beam envelope at the calorimeter. The anticipated performance of the new calorimeter is simulated over the full momentum range of the SHMS, predicting resolution and yields similar to the HMS calorimeter. Good electron/hadron separation can be achieved by using energy deposition in the Preshower along with total energy deposition in the calorimeter. In this case the PID capability is similar to or better than that attainable with HMS calorimeter, with a pion suppression factor of a few hundreds predicted for 99% electron detection efficiency.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Analysis of Energy Savings and CO2 Emission Reduction Contribution for Industrial Facilities in USA

Abstract Energy audits can identify energy consumptions, energy costs of the facility and evolve to develop measures to maximize efficiency, optimize supply energy, and eliminate waste. This paper investigates the potential energy savings at 20 different industrial sectors with 152 assessments for various facilities in Wisconsin, USA. On average, eight energy recommendations were suggested and applied in each facility. This paper provides a detailed guideline for each industry in terms of eight different energy categories: heating, ventilation, and air conditioning (HVAC) systems, heat recovery systems, electrical demand management, and utility bills, motors, compressors, waste management, and productivity enhancement, lighting, besides building envelope. In total, the energy savings were as follows: 98 million kWh in the shape of electricity, 561 billion British thermal units (BTUs) gas savings, 44 million gallons water savings, and 2-million-pound solid waste savings. Based on these savings, a 100-thousand-ton reduction in carbon dioxide emissions was obtained.

Energy & Fuels↗

Wing design with attainable thrust considerations

A CAD process that includes leading-edge thrust considerations for wings with high aerodynamic efficiencies is outlined. Rectangular grids are used for evaluation of both subsonic and supersonic pressure loadings. Account is taken of the Mach number, Re, the wing planform, the presence of camber, the airfoil geometry and the locations and forces induced by shed vortices. Optimization techniques are applied to the candidate surfaces in order to consider the attainable thrust. Inclusion of the optimization techniques permits analyses of mission-adaptive wings and various flap systems and the elimination of singularities in the flight envelope.

Carlson, H. W.↗

Some Recent Developments in Numerical Modelling at ECMWF

A new atmospheric model was introduced into operational forecasting at the European Center for Medium Range Weather Forecasts, on 21 April 1983. The principal differences between this model and the Center's first operational model were in the adiabatic formulation, which, in the new model, includes use of a spectral representation in the horizontal, a more general vertical coordinate, and a modified, more-efficient, time-stepping scheme. In addition, new programming techniques and standards were adopted to facilitate both the model's use as a research tool and its adaptation to make full use of the features of the recently-acquired CRAY X-MP computer. A number of revisions were also made in detailed aspects of the formulation of the parameterization schemes. The operational change to this new model was accompanied by a second important change, namely the use of a higher envelope orography in the lower boundary conditions of the model. Problems in the operational performance of the model and development preparatory to the future operational implementation of a high resolution version of the model on the CRAY X-MP are discussed.

Simmons, A. J.↗