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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Video detection and analysis techniques of transient astronomical phenomena

Low-light-level television systems have been utilized to gain information on meteors, aurorae, and other faint, transient astronomical phenomena. Such phenomena change not only their position as a function of time, but also their photometric and spectral characteristics in as little as 1/60 second, thus requiring unique methods of analysis. Data observed with television systems and recorded on video tape have been analyzed with a system utilizing both analog and digital techniques. Both off-the-shelf equipment and inhouse developments are used to isolate sequences of moving images and to store them in a form suitable for photometric and spectral reduction. Current emphasis of the analysis effort is directed at the measurement of the first-order emission lines of meteor spectra, the results of which will yield important compositional information concerning the nature of the impinging meteoroid.

Clifton, K. S.↗
DOE OSTI2015

THE ROLE OF ERUPTING SIGMOID IN TRIGGERING A FLARE WITH PARALLEL AND LARGE-SCALE QUASI-CIRCULAR RIBBONS

In this paper, we present observations and analysis of an interesting sigmoid formation, eruption, and the associated flare that occurred on 2014 April 18 using multi-wavelength data sets. We discuss the possible role of the sigmoid eruption in triggering the flare, which consists of two different sets of ribbons: parallel ribbons and a large-scale quasi-circular ribbon. Several observational evidence and nonlinear force-free field extrapolation results show the existence of a large-scale fan-spine type magnetic configuration with a sigmoid lying under a section of the fan dome. The event can be explained with the following two phases. During the preflare phase, we observed the formation and appearance of the sigmoid via tether-cutting reconnection between the two sets of sheared fields under the fan dome. The second, main flare phase features the eruption of the sigmoid, the subsequent flare with parallel ribbons, and a quasi-circular ribbon. We propose the following multi-stage successive reconnection scenario for the main flare. First, tether-cutting reconnection is responsible for the formation and the eruption of the sigmoid structure. Second, the reconnection occurring in the wake of the erupting sigmoid produces the parallel flare ribbons on the both sides of the circular polarity inversion line. Third, the null-type reconnection higher in the corona, possibly triggered by the erupting sigmoid, leads to the formation of a large quasi-circular ribbon. For the first time, we suggest a mechanism for this type of flare consisting of a double set of ribbons triggered by an erupting sigmoid in a large-scale fan-spine-type magnetic configuration.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1982

Outer satellite atmospheres: Their nature and planetary interactions

Significant progress is reported in early modeling analysis of observed sodium cloud images with our new model which includes the oscillating Io plasma torus ionization sink. Both the general w-D morphology of the region B cloud as well as the large spatial gradient seen between the region A and B clouds are found to be consistent with an isotropic flux of sodium atoms from Io. Model analysis of the spatially extended high velocity directional features provided substantial evidence for a magnetospheric wind driven gas escape mechanism from Io. In our efforts to define the source(s) of hydrogen atoms in the Saturn system, major steps were taken in order to understand the role of Titan. We have completed the comparison of the Voyager UVS data with previous Titan model results, as well as the update of the old model computer code to handle the spatially varying ionization sink for H atoms.

Smyth, W. H.↗
DOE OSTI2024

Quantification of Swelling in Hematite Pellets Reduced Using Hydrogen–Nitrogen Gas Mixture

Iron ore pellets are reduced in a 50%H 2 –50%N 2 1 atm gas mixture at 750, 800, 850, 900, and 950 °C while simultaneously documenting swelling (change in pellet radius) and weight change. Swelling increases with increasing temperature, with catastrophic swelling (>20% of reduction swelling index) observed at 850, 900, and 950 °C. As the pellet is reduced, the pellet radius increases until 40–50% reduction is achieved, followed by a decrease in diameter beyond 40–50% reduction at 750 and 850 °C. At 950 °C, the pellet radius continues to increase with additional pellet reduction without any subsequent decrease in diameter. Scanning electron microscopy (SEM) analysis shows that the neighboring grains inside the pellet sinter together at 750 and 850 °C, whereas the individual grains sinter internally at 950 °C. SEM analysis and observations suggest that the reduction process at 750 and 850 °C can be approximated as a topochemical reaction process, while the reduction process at 950 °C can no longer be approximated as a topochemical reaction process. In conclusion, an empirical equation for the radius of the pellet is derived with fitting parameters dependent on temperature and the degree of reduction of the pellet undergoing reduction based on the experimental data.

08 HYDROGEN↗
NASA NTRS1983

Energetics analysis of the global circulation during the special observation periods of FGGE

A global energetics analysis is presented for the FGGE SOP-1 and SOP-2 with ECMWF and GFDL data sets. Both global integral properties and spectral characteristics are examined. There is a large discrepancy between the present FGGE analysis and previously available estimates concerning the level of available potential energy and kinetic energy. This discrepancy is attributable to an earlier restriction of data coverage. There is a significant seasonal difference in the energy reservoir of the Northern Hemisphere, whereas the diference is minor in the Southern Hemisphere. This leads to a seasonal contrast of the globally integrated energy budget which comes mostly from the Northern Hemisphere. Both the global energy level and the intensity of the general circulation are more pronounced during SOP-1 than during SOP-2. One major focus of attention in this study is an energetics comparison of ECMWF and GFDL data sets. There is a twofold difference in the intensity of the general circulation as measured with these two data sets. The energetics diagnosis indicates that the operational modes of the general circulation as described by these two data sets also differ considerably. The contrasts between SOP-1 and SOP-2 and between the ECMWF and GFDL versions of the data sets are apparent in the pattern of energy flow in the wavenumber domain.

Kung, E. C.↗
DOE OSTI2020

The potential role of organics in new particle formation and initial growth in the remote tropical upper troposphere

Abstract. Global observations and model studies indicate that new particle formation (NPF) in the upper troposphere (UT) and subsequent particles supply 40 %–60 % of cloud condensation nuclei (CCN) in the lower troposphere, thus affecting the Earth's radiative budget. There are several plausible nucleation mechanisms and precursor species in this atmospheric region, which, in the absence of observational constraints, lead to uncertainties in modeled aerosols. In particular, the type of nucleation mechanism and concentrations of nucleation precursors, in part, determine the spatial distribution of new particles and resulting spatial distribution of CCN from this source. Although substantial advances in understanding NPF have been made in recent years, NPF processes in the UT in pristine marine regions are still poorly understood and are inadequately represented in global models. Here, we evaluate commonly used and state-of-the-art NPF schemes in a Lagrangian box model to assess which schemes and precursor concentrations best reproduce detailed in situ observations. Using measurements of aerosol size distributions (0.003 < Dp < 4.8 µm) in the remote marine troposphere between ∼0.18 and 13 km altitude obtained during the NASA Atmospheric Tomography (ATom) mission, we show that high concentrations of newly formed particles in the tropical UT over both the Atlantic and Pacific oceans are associated with outflow regions of deep convective clouds. We focus analysis on observations over the remote Pacific Ocean, which is a region less perturbed by continental emissions than the Atlantic. Comparing aerosol size distribution measurements over the remote Pacific with box model simulations for 32 cases shows that none of the NPF schemes most commonly used in global models, including binary nucleation of sulfuric acid and water (neutral and ion-assisted) and ternary involving sulfuric acid, water, and ammonia, are consistent with observations, regardless of precursor concentrations. Through sensitivity studies, we find that the nucleation scheme among those tested that is able to explain most consistently (21 of 32 cases) the observed size distributions is that of Riccobono et al. (2014), which involves both organic species and sulfuric acid. The method of Dunne et al. (2016), involving charged sulfuric acid–water–ammonia nucleation, when coupled with organic growth of the nucleated particles, was most consistent with the observations for 5 of 32 cases. Similarly, the neutral sulfuric acid–water–ammonia method of Napari (2002), when scaled with a tuning factor and with organic growth added, was most consistent for 6 of 32 cases. We find that to best reproduce both nucleation and growth rates, the mixing ratios of gas-phase organic precursors generally need to be at least twice that of SO2, a proxy for dimethyl sulfide (DMS). Unfortunately, we have no information on the nature of oxidized organic species that participated in NPF in this region. Global models rarely include organic-driven nucleation and growth pathways in UT conditions where globally significant NPF takes place, which may result in poor estimates of NPF and CCN abundance and contribute to uncertainties in aerosol–cloud–radiation effects. Furthermore, our results indicate that the organic aerosol precursor vapors may be important in the tropical UT above marine regions, a finding that should guide future observational efforts.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1984

Cometary nucleus and active regions

On the basis of the icy conglomerate model of cometary nuclei, various observations demonstrate the spotted nature of many or most nuclei, i.e., regions of unusual activity, either high or low. Rotation periods, spin axes and even precession of the axes are determined. The observational evidence for variations in activity over the surfaces of cometary nuclei are listed and discussed. On June 11 the comet IRAS-ARAKI-ALCOCK approached the Earth to a distance of 0.031 AU, the nearest since C/Lexell, 1770 I, providing a unique opportunity for near-nucleus observations. Preliminary analysis of these images establishes the spin axis of the nucleus, with an oblioquity to the orbit plane of approximately 50 deg, and a lag angle of sublimation approximately 35 deg from the solar meridian on the nucleus. Asymmetries of the inner coma suggests a crazy-quilt distribution of ices with differing volatility over the surface of the nucleus. The observations of Comet P/Homes 1892 III, exhibiting two 8-10 magnitude bursts, are carefully analyzed. The grazing encounter produced, besides the first great burst, an active area on the nucleus, which was rotating retrograde with a period of 16.3hr and inclination nearly 180 deg. After the first burst the total magnitude fell less than two magnitudes from November 7 to November 30 (barely naked eye) while the nuclear region remained diffuse or complex, rarely if ever showing a stellar appearance. The fading was much more rapid after the second burst. The grazing encounter distributed a volume of large chunks in the neighborhood of the nucleus, maintaining activity for weeks.

Whipple, F. L.↗
NASA NTRS2003

The [C II] 158 Micron Line in Ultraluminous Infrared Galaxies Revisited

We present a study of the [C II] 157.74 micron fine-structure line in a sample of 15 ultraluminous infrared (IR) galaxies (IR luminosity L(sub IR greater than or equal to 10(exp 12)L.; ULIRGs) using the Long Wavelength Spectrometer (LWS) on the Infrared Space Observatory (ISO). We confirm the observed order of magnitude deficit (compared to normal and starburst galaxies) in the strength of the [C II] line relative to the far-infrared (FIR) dust continuum emission found in our initial report, but here with a sample that is twice as large. This result suggests that the deficit is a general phenomenon affecting 4 out of 5 ULIRGs. We present an analysis using observations of generally acknowledged photodissociation region (PDR) tracers ([C II], [OI] 63 and 145 micron, and FIR continuum emission), which suggests that a high ultraviolet flux G(sub 0) incident on a moderate density n PDR could explain the deficit. However, comparisons with other ULIRG observations, including CO (1-0), [C I] (1-0), and 6.2 micron polycyclic aromatic hydrocarbon (PAH) emission, suggest that high G(sub 0)/n PDRs alone cannot produce a self-consistent solution that is compatible with all of the observations. We propose that non-PDR contributions to the FIR continuum can explain the apparent [C II] deficiency. Here, unusually high G(sub 0) and/ or n physical conditions in ULIRGs as compared to those in normal and starburst galaxies are not required to explain the [C II] deficit. Dust-bounded photoionization regions, which generate much of the FIR emission but do not contribute significant [C II] emission, offer one possible physical origin for this additional non-PDR component. Such environments may also contribute to the observed suppression of FIR fine-structure emission from ionized gas and PAHs, as well as the warmer FIR colors found in ULIRGs. The implications for observations at higher redshifts are also revisited.

Luhman, M. L.↗
DOE OSTI2017

A Dynamical and Statistical Characterization of U.S. Extreme Precipitation Events and Their Associated Large-Scale Meteorological Patterns

Abstract Regional patterns of extreme precipitation events occurring over the continental United States are identified via hierarchical cluster analysis of observed daily precipitation for the period 1950–2005. Six canonical extreme precipitation patterns (EPPs) are isolated for the boreal warm season and five for the cool season. The large-scale meteorological pattern (LMP) inducing each EPP is identified and used to create a “base function” for evaluating a climate model’s potential for accurately representing the different patterns of precipitation extremes. A parallel analysis of the Community Climate System Model, version 4 (CCSM4), reveals that the CCSM4 successfully captures the main U.S. EPPs for both the warm and cool seasons, albeit with varying degrees of accuracy. The model’s skill in simulating each EPP tends to be positively correlated with its capability in representing the associated LMP. Model bias in the occurrence frequency of a governing LMP is directly related to the frequency bias in the corresponding EPP. In addition, however, discrepancies are found between the CCSM4’s representation of LMPs and EPPs over regions such as the western United States and Midwest, where topographic precipitation influences and organized convection are prominent, respectively. In these cases, the model representation of finer-scale physical processes appears to be at least equally important compared to the LMPs in driving the occurrence of extreme precipitation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Harnessing Satellite Data Alone for Mapping Global Thermal Anisotropy

Mapping thermal anisotropy across global lands is critical for advancing a wide range of Earth science studies. However, a comprehensive understanding of global thermal anisotropy intensity (TAI) and its governing factors remains missing. We introduce a novel data-driven methodology to quantify global TAI exclusively using multi-angle MODIS land surface temperature time series observations. Our analysis reveals distinct seasonal and diurnal TAI patterns, with global mean summertime TAI exceeding 2.9°C. Furthermore, we identify strong associations between TAI and key surface and atmospheric parameters, such as leaf area index and downward shortwave radiation. Our findings advocate for a paradigm shift from model-based to data-driven approaches in correcting thermal anisotropy, thereby addressing a critical bottleneck in Earth observation.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2012

The Re-Analysis of Ozone Profile Data from a 41-Year Series of SBUV Instruments

In this study we present the validation of ozone profiles from a number of Solar Back Scattered Ultra Violet (SBUV) and SBUV/2 instruments that were recently reprocessed using an updated (Version 8.6) algorithm. The SBUV dataset provides the longest available record of global ozone profiles, spanning a 41-year period from 1970 to 2011 (except a 5-year gap in the 1970s) and includes ozone profile records obtained from the Nimbus-4 BUV and Nimbus-7 SBUV instruments, and a series of SBUV(/2) instruments launched on NOAA operational satellites (NOAA 09, 11, 14, 16, 17, 18, 19). Although modifications in instrument design were made in the evolution from the BUV instrument to the modern SBUV(/2) model, the basic principles of the measurement technique and retrieval algorithm remain the same. The long term SBUV data record allows us to create a consistent, calibrated dataset of ozone profiles that can be used for climate studies and trend analyses. In particular, we focus on estimating the various sources of error in the SBUV profile ozone retrievals using independent observations and analysis of the algorithm itself. For the first time we include in the metadata a quantitative estimate of the smoothing error, defined as the error due to profile variability that the SBUV observing system cannot inherently measure. The magnitude of the smoothing error varies with altitude, latitude, season and solar zenith angle. Between 10 and 1 hPa the smoothing errors for the SBUV monthly zonal mean retrievals are of the order of 1 %, but start to increase above and below this layer. The largest smoothing errors, as large as 15-20%, were detected in in the troposphere. The SBUV averaging kernels, provided with the ozone profiles in version 8.6, help to eliminate the smoothing effect when comparing the SBUV profiles with high vertical resolution measurements, and make it convenient to use the SBUV ozone profiles for data assimilation and model validation purposes. The smoothing error can also be minimized by combining layers of data, and we will discuss recommendations for this approach as well. The SBUV ozone profiles have been intensively validated against satellite profile measurements obtained from the Microwave Limb Sounders (MLS) (on board the UARS and AURA satellites), Stratospheric Aerosol and Gas Experiment (SAGE) and Michelson Interferometer for Passive Atmospheric Sounding (MIPAS). Also, we compare coincident and collocated SBUV ozone retrievals with observations made by ground-based instruments, such as microwave spectrometers, lidars, Umkehr instruments and balloon-borne ozonosondes. Finally, we compare the SBUV ozone profiles with output from the NASA GSFC GEOS-CCM model. In the stratosphere between 25 and 1 hPa the mean biases and standard deviations are within 5% for monthly mean ozone profiles. Above and below this layer the vertical resolution of the SBUV algorithm decreases and the effects of vertical smoothing should be taken into account. Though the SBUV algorithm has a coarser vertical resolution in the lower stratosphere and troposphere, it is capable of precisely estimating the integrated ozone column between the surface and 25 hPa. The time series of the tropospheric - lower stratospheric ozone column derived from SBUV agrees within 5% with the corresponding values observed by an ensemble of ozone sonde stations in North Hemisphere. Drift of the ozone time series obtained from each SBUV(/2) instrument relative to ground based and satellite measurements are evaluated and some features of individual SBUV(l2) instruments are discussed. In addition to evaluating individual instruments against independent observations, we also focus on the instrument to instrument consistency in the series. Overall, Version 8.6 ozone profiles obtained from two different SBUV(l2) instruments compare within a couple of percent during overlap periods and are consistently varying in time, with some exceptions. Some of the noted discrepancies might bssociated with ozone diurnal variations, since the difference in the local time of the observations for a pair of SBUV(l2) instruments could be several hours. Other issues include the potential short-term drift in measurements as the instrument orbit drifts, and measurements are obtained at high solar zenith angles (>85 ). Based on the results of the validation, a consistent, calibrated dataset of SBUV ozone profiles has been created based on internal calibration only.

Kramarova, Natalya↗
NASA NTRS2006

Impact of Three-Dimensional Radiative Effects on Satellite Retrievals of Cloud Droplet Sizes

There are several dozen papers that study the effects of cloud horizontal inhomogeneity on the retrievals of cloud optical thickness, but only a few of them deal with cloud droplet sizes. This paper is one of the first comprehensive attempts to fill this gap: It takes a close theoretical look at the radiative effects of cloud 3-D structure in retrievals of droplet effective radii. Under some general assumptions, it was found that ignoring subpixel (unresolved) variability produces a negative bias in the retrieved effective radius, while ignoring cloud inhomogeneity at scales larger than a pixel scale (resolved variability), on the contrary, leads to overestimation of the domain average droplet size. The theoretical results are illustrated with examples from Large Eddy Simulations (LES) of cumulus (Cu) and stratocumulus (Sc) cloud fields. The analysis of cloud drop size distributions retrieved from both LES fields confirms that ignoring shadowing in 1-D retrievals results in substantial overestimation of effective radii which is more pronounced for broken Cu than for Sc clouds. Collocated measurements of broken Cu clouds by Moderate Resolution Imaging Spectrometer (MODIS) and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) are used to check simulations and theory with observations. The analysis of ASTER and MODIS data and associated derived products recommends against blindly using retrieved effective radii for broken cloud fields, especially if one wants to relate aerosol amounts to cloud droplet sizes.

Marshak, Alexander↗
NASA NTRS1998

Design, Evaluation and GCM-Performance of a New Parameterization for Microphysics of Clouds with Relaxed Arakawa-Schubert Scheme (McRas)

A prognostic cloud scheme named McRAS (Microphysics of clouds with Relaxed Arakawa-Schubert Scheme) was developed with the aim of improving cloud-microphysics, and cloud-radiation interactions in GCMs. McRAS distinguishes convective, stratiform, and boundary-layer clouds. The convective clouds merge into stratiform clouds on an hourly time-scale, while the boundary-layer clouds do so instantly. The cloud condensate transforms into precipitation following the auto-conversion relations of Sundqvist that contain a parametric adaptation for the Bergeron-Findeisen process of ice crystal growth and collection of cloud condensate by precipitation. All clouds convect, advect, and diffuse both horizontally and vertically with a fully active cloud-microphysics throughout its life-cycle, while the optical properties of clouds are derived from the statistical distribution of hydrometeors and idealized cloud geometry. An evaluation of McRAS in a single column model (SCM) with the GATE Phase III data has shown that McRAS can simulate the observed temperature, humidity, and precipitation without discernible systematic errors. An evaluation with the ARM-CART SCM data in a cloud model intercomparison exercise shows reasonable but not an outstanding accurate simulation. Such a discrepancy is common to almost all models and is related, in part, to the input data quality. McRAS was implemented in the GEOS II GCM. A 50 month integration that was initialized with the ECMWF analysis of observations for January 1, 1987 and forced with the observed sea-surface temperatures and sea-ice distribution and vegetation properties (biomes, and soils), with prognostic soil moisture, snow-cover, and hydrology showed a very realistic simulation of cloud process, incloud water and ice, and cloud-radiative forcing (CRF). The simulated ITCZ showed a realistic time-mean structure and seasonal cycle, while the simulated CRF showed sensitivity to vertical distribution of cloud water which can be easily altered by the choice of time constant and incloud critical cloud water amount regulators for auto-conversion. The CRF and its feedbacks also have a profound effect on the ITCZ. Even though somewhat weaker than observed, the McRAS-GCM simulation produces robust 30-60 day oscillations in the 200 hPa velocity potential. Two ensembles of 4-summer (July, August, September) simulations, one each for 1987 and 1988 show that the McRAS-GCM simulates realistic and statistically significant precipitation differences over India, Central America, and tropical Africa. Several seasonal simulations were performed with McRAS-GEOS II GCM for the summer (June-July- August) and winter (December-January-February) periods to determine how the simulated clouds and CRFs would be affected by: i) advection of clouds; ii) cloud top entrainment instability, iii) cloud water inhomogeneity correction, and (iv) cloud production and dissipation in different cloud-processes. The results show that each of these processes contributes to the simulated cloud-fraction and CRF.

Sud, Y. C.↗
DOE OSTI2022

Unveiling User Behavior on Summit Login Nodes as a User

We observe and analyze usage of the login nodes of the leadership class Summit supercomputer from the perspective of an ordinary user—not a system administrator—by periodically sampling user activities (job queues, running processes, etc.) for two full years (2020–2021). Our findings unveil key usage patterns that evidence misuse of the system, including gaming the policies, impairing I/O performance, and using login nodes as a sole computing resource. Our analysis highlights observed patterns for the execution of complex computations (workflows), which are key for processing large-scale applications.

Wilkinson, Sean↗
NASA NTRS1979

Synchronization of clocks by very-long-baseline interferometry

Two hydrogen-maser clocks, one at Haystack Observatory and one at the National Radio Astronomy Observatory, were synchronized by means of observations of several extragalactic radio sources on March 28, and again on September 23, 1977. Observations were made sequentially in eight 360-kHz bands distributed between about 8.4 and 8.5 GHz with spacings designed to enable the group-delay difference between the signals received at the two observatories from a given source to be estimated unambiguously, within an uncertainty of less than 1 ns set by receiver noise. The epoch and the rate differences between the observatories' clocks for each experiment were estimated by analysis of observations that spanned several hours. The application of corrections for the contributions to the delays of the antennas, feeds, receiver systems, and recorders yielded absolute determinations of the clock epoch differences. During each experiment, portable cesium clocks were flown from the U.S. Naval Observatory to the observatories and back. The traveling-clock data, analyzed in each case after the VLBI synchronization had been completed, confirmed the VLBI results to within 18 and 14 ns for the first and second experiments, respectively.

Clark, T. A.↗
NASA NTRS2012

From Radio with Love: An Overview of the Role of Radio Observations in Understanding High-Energy Emission from Active Galaxies

The gamma-ray satellite Fermi and the ground based TeV facilities MAGIC, VERITAS and HESS have ushered in a new era in the observation of high-energy emission from active galaxies. The energy budgets of these objects have a major contribution from gamma-rays and it is simply not possible to understand their physics without high-energy observations. Though the exact mechanisms for high-energy production in galaxies remains an open question, gamma-rays typically result from interactions between high-energy particles. Via different interactions these same particles can produce radio emission. Thus the non-thermal nature of gamma-ray emission practically guarantees that high-energy emitters are also radio loud. Aside from their obvious role as a component of multiwavelength analysis, radio observations provide two crucial elements essential to understanding the source structure and physical processes of high-energy emitters: very high timing resolution and very high spatial resolution. A brief overview of the unique role played by radio observations in unraveling the mysteries of the high energy Universe as presented here.

Ojha, Roopesh↗
NASA NTRS2002

Theoretical Study of Infrared and Raman Spectra of Hydrated Magnesium Sulfate Salts

Harmonic and anharmonic vibrational frequencies, as well as infrared and Raman intensities, are calculated for MgSO4.nH20 (n=1-3). Electronic structure theory at the second order Moller-Plesset perturbation theory (MP2) level with a triple-zeta + polarization (TZP) basis set is used to determine the geometry, properties, and vibrational spectra of pure and hydrated MgSO4 salts. The direct vibrational self-consistent field (VSCF) method and its correlation corrected (CC-VSCF) extension are used to determine anharmonic corrections to vibrational frequencies and intensities for the pure MgSO4 and its complex with one water molecule. Very significant differences are found between vibrational of water molecules in complexes with MgSO4 and pure water. Some of the O-H stretching frequencies are shifted to the red very significantly (by up to 1500-2000/cm) upon complexation with magnesium sulfate. They should be observed between 1700 and 3000/cm in a region very different from the corresponding O-H stretch frequency region of pure water (3700-3800/cm). In addition, the SO2 stretching vibrations are found at lower frequency regions than the water vibrations. They can serve as unique identifiers for the presence of sulfate salts. The predicted infrared and Raman spectra should be of valuable help in the design of future missions and analysis of observed data from the ice surface of Jupiter's moon Europa that possibly contains hydrated MgSO4 salts.

Chaban, Galina M.↗
DOE OSTI2026

21 cm Power Spectrum Analysis of North Celestial Pole Observations with the Tianlai Dish Pathfinder Array

The Tianlai Dish Pathfinder Array (TDPA) is a radio interferometer designed to test techniques for 21 cm intensity mapping in the post-reionization Universe as a means of measuring large-scale cosmic structure. Using nine nights of observations targeting the North Celestial Pole field, totaling approximately 107 hr of integration time, we analyze data in the frequency range 700–800 MHz (corresponding to redshift z ∼ 0.9). We do the data format conversion, radio frequency interference flagging, calibration, imaging and point source subtraction, and foreground removal via Singular Value Decomposition. The spherically averaged power spectrum Δ 2 (k) is obtained. Furthermore, this work successfully establishes and validates a comprehensive data analysis framework for the TDPA. We identify key improvements including sky model refinement, increased integration time, and pipeline optimization that will enable future detection of the 21 cm signal through auto-correlation and cross-correlation with optical galaxy surveys.

cosmology: large-scale structure of universe↗