SEARCH · Search NASA

Results for “pitting”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 739 records · Page 41

All sources NASA NTRS DOE OSTI

DOE OSTI2023

Critical Current Densities and n-Values of MgB 2 Conductors for SMES, MRI, and Low AC Loss Applications

Multifilamentary MgB 2 strands (filament numbers 36 to 114) prepared by the in-situ power-in-tube (PIT) route with carbon doping contents of 0, 2, and 3.2% were wound on barrels for transport J c and n -value measurement at 4.2 K in fields of up to 12 T. The strand and gauge lengths were 1 m and 0.5 m. Heat treatments at 675 °C and 650 °C centered around the melting point of Mg (650 °C) and both utilized the liquid-solid reaction. A pair of strands, with and without 2% C doping exhibited the J c (B) crossover effect. Here studied were the dependencies of J c on field strength, dopant concentration, and cabling and the dependence of n -value on field strength.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2018

Forensic Analysis of Faulted NSTX-U Inner Poloidal Field Coil

The failure of the NSTX-U PF1A upper coil suspended plasma operations during the project's first operational campaign after commissioning. Initial nondestructive testing and examination of the failed coil was followed by extensive nondestructive radiography. Destructive testing facilitated visual borescope/videoscope inspection through the cooling path, vacuum testing, and electrical testing of every conductor segment. One conductor cooling path visually evidenced a void through the sidewall of the cooling path in a layer-to-layer region. The identified void in the conductor cooling path was not proximal to a braze or joggle. Electrical testing indicated that the voided conductor segment was a member of a group of 14 conductor segments that evidenced low-resistance connectivity. Four braze joints and two lead segments were subjected to 400-lbf/in 2 hydrostatic pressure testing followed by helium leak testing and evidenced that there were no detectable leaks in the tested cooling path segments. The faulted region was proximal to the center of the coil pack and evidenced historical electrical pitting and molten conductor debris. Samples of the epoxy resin insulation system were extracted and analyzed with dynamic mechanical analysis and differential scanning calorimetry techniques. Epoxy resin insulation samples were subjected to immersion testing per ASTM D570. Metallurgical samples were extracted from the coil pack conductors and subjected to hardness testing and grain structure analysis. The base material testing results indicated no abnormalities. In conclusion, the coil incipient failure was determined to most likely have resulted from conductive material located between conductor and insulation layers.

25 ENERGY STORAGE↗

DOE OSTI2023

Detection efficiency of adult Pacific lamprey passage counts at Leaburg Dam and upstream distribution in the McKenzie River (Oregon, USA)

Abstract Adult Pacific lamprey ( Entosphenus tridentatus ) were counted using consistent methodology since 2005 with a video monitoring system as they passed Leaburg Dam (McKenzie River, Oregon, USA) en route to upstream spawning areas. In this study we evaluated the detection efficiency of the video system and upstream distribution of Pacific lamprey using the video counts of lamprey passage (herein, “dam counts”), passive integrated transponder (PIT) tags, and radio telemetry. In 2019–2020 we collected, tagged and tracked 32 adult lamprey (4 from the McKenzie River and 28 that were translocated from Willamette Falls). All fish were tagged and released into the tailrace of Leaburg Dam in June 2019. Oregon Department of Fish and Wildlife employees and volunteers from the local community conducted mobile radiotracking above and below the dam in drift boats (114 mainstem river kilometers) and on foot (several tributaries). The estimated detection efficiency for dam counts was 92% (95% confidence interval: 67%–99%). Fifty percent (16 of 32) of the tagged lamprey passed the dam, including 13 of 28 that were translocated. Thirty‐seven percent (6 of 16) of lamprey that passed Leaburg Dam were detected in a restored reach of the South Fork McKenzie, 32.6 river kilometers upstream of the dam.

Romer, Jeremy D.↗

DOE OSTI2018

The challenge of acquiring a satisfactory EBSD result of CWSR Zircaloy-4 cladding tube

This article presents a methodology combining SEM, EDS, conventional EBSD, and transmission-EBSD to analyse a recrystallised Zircaloy-4 sheet and cold-worked stress-relieved (CWSR) Zircaloy-4 cladding in unprecedented detail. Second-phase precipitates (SPPs) in Zircaloy-4 specimens were revealed after chemical polishing using a solution containing hydrofluoric acid (HF). Pitting corrosion of Zircaloy-4 specimens was revealed after electropolishing using an electrolyte containing HClO4. A zirconium coupon without SPPs was used to confirm the chemical response of SPPs on surface morphology. Intrinsic features of cold-worked Zircaloy-4 such as relatively small grain sizes, high dislocation density, and complex microstructure make it significantly more difficult to collect excellent EBSD results compared to recrystallised Zircaloy-4. The fine hydride structure of as-hydrided CWSR Zircaloy-4 cladding further increases the level of challenge on EBSD analysis.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2013

Gunnar uranium mine environmental remediation - Northern Saskatchewan

The Gunnar Mine and mill site was the largest of some 38 now-abandoned uranium mines that were developed and operated in Northern Saskatchewan, Canada, during the Cold War years. During their operating lifetimes these mines produced large quantities of ore and tailings. The Gunnar mine (open pit and underground) produced over 5 million tonnes of uranium ore and nearly 4.4 million tonnes of mine tailings during its operations from 1955 through 1963. An estimated 2.2 to 2.7 million m{sup 3} of waste rock that was generated during the processing of the ore abuts the shores of Lake Athabasca, the 22. largest lake in the world. After closure in the 1960's, the Gunnar site was abandoned with little to no decommissioning being done. The Saskatchewan Research Council has been contracted to manage the clean-up of these abandoned northern uranium mine and mill sites. The Gunnar Mine, because of the magnitude of tailings and waste rock, is subject to an environmental site assessment process regulated by both provincial and federal governments. This process requires a detailed study of the environmental impacts that have resulted from the mining activities and an analysis of projected impacts from remediation efforts. The environmental assessment process, specific site studies, and public involvement initiatives are all now well underway. Due to the many uncertainties associated with an abandoned site, an adaptive remediation approach, utilizing a decision tree, presented within the environmental assessment documents will be used as part of the site regulatory licensing. A critical early task was dealing with major public safety hazards on the site. The site originally included many buildings that were remnants of a community of approximately 800 people who once occupied the site. These buildings, many of which contained high levels of asbestos, had to be appropriately abated and demolished. Similarly, the original mine head frame and mill site buildings, many of which still contained the original machinery and equipment, also had to be dismantled. Remediation options for the accumulated demolition debris have been assessed, as have remediation options for the waste rock and tailings, all of which form part of the environmental assessment. The regulatory requirements include the environmental assessment processes, a complex public involvement strategy, and licensing from the Canadian Nuclear Safety Commission (CNSC) with the long-term goal of releasing the property in a remediated and stable state to the Province of Saskatchewan. Prescribed environmental and land use endpoints will be determined based on the environmental assessment studies and remediation options analyzed and implemented. Ultimately, the site will be released into an institutional controls program that will allow long-term government management and monitoring. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2022

THERMAL MODELING OF HANFORD LEAD CANISTER’S HEATER BENCH TESTS

A computational fluid dynamics (CFD) model was built to simulate planned testing of heater assemblies for the Hanford Lead Canister (HLC) project. The HLC is a canister storage system that will contain heaters to simulate the decay heat of nuclear material and provide the canister storage system with environmental conditions equivalent to the operating conditions on a dry storage pad. The HLC will be equipped with long-term data collection and monitoring systems to provide an early warning of corrosion, pitting, cracking, or other signs of canister degradation that might threaten the integrity of the containment boundary over the potentially long term of dry storage. An important part of the HLC development is to confirm the function and ability of the electric heater assemblies that were specially designed to provide heating similar to the decay heat of nuclear material contained within the canister storage system. Heater bench testing is planned for early 2022 in a test configuration that does not include the canister. The goal of the bench testing is to verify that the heaters can replicate the decay heat of a canister with nuclear material and to validate the thermal models, which are critical to understanding the HLC’s thermal environment, including the local air flow within the canister storage system. Testing of the heater assemblies inside the canister system are planned in the future to validate canister level thermal models, and rigorous pre-deployment testing of the complete HLC cask and canister system is intended to be completed before the HLC is deployed in the 2025-2026 timeframe. This study presents the pre-test temperature predictions of the bench testing. A description of the heater assemblies and planned bench testing is presented. The model was developed with the commercial CFD code STAR-CCM+. An uncertainty analysis was run with the CFD model to determine the uncertainty in the temperature predictions and provide a range over which the predicted temperatures are expected to vary. The uncertainty analysis was performed by coupling STAR-CCM+ with the software Dakota, which provides advanced parametric analyses, including quantification of margins and uncertainty with computational models. This work is expected to provide insight into SNF canister behavior.

Suffield, Sarah R.↗

DOE OSTI2024

THERMAL MODELING OF HANFORD CESIUM AND STRONTIUM CANISTERS DURING SIMULATED LOADING

A computational fluid dynamics (CFD) model was built to simulate planned testing of heater assemblies within a canister and overpack for the Hanford Lead Canister (HLC) project. The HLC is a canister storage system that will contain heaters to simulate the decay heat of nuclear material and provide the canister storage system with environmental conditions equivalent to the operating conditions on a dry storage pad. The HLC will be equipped with long-term data collection and monitoring systems to provide an early warning of corrosion, pitting, cracking, or other signs of canister degradation that might threaten the integrity of the containment boundary over the potentially long term of dry storage. An important part of the HLC development is to make pretest numerical predictions for the behavior of the heated canister during the simulated radiolytic decay heat testing, which simulates the dry storage system during loading operations. The simulated radiolytic decay heat test is planned for mid-2024 in a configuration that includes the heater assembly, overpack, and canister, but with the lids removed to allow loading cesium and strontium capsules into the canister. One of the goals of the test is to evaluate the thermal behavior of the canister and overpack assembly in the ambient air of the test facility, which will provide data critical to validating the thermal models and understanding how the HLC will perform as a system once deployed. To best approximate real-world conditions, the CFD model includes the full air volume of the mock-up truck bay the heated canister test will be performed in, enabling detailed investigation of how the heated canister affects airflow around it. Rigorous pre-deployment testing of the complete HLC cask and canister system is intended to be completed before the HLC is deployed in the 2028 timeframe. This study presents the pre-test temperature predictions of the simulated radiolytic decay heat test. A description of the heater assembly, canister, and overpack system is presented. The model was developed with the commercial CFD software STAR-CCM+. An uncertainty analysis was run with the CFD model to determine the uncertainty in the temperature predictions and provide a range over which the predicted temperatures are expected to vary. The uncertainty analysis was preformed by coupling STAR-CCM+ with the software Dakota, which provides advanced parametric analyses, including quantification of margins and uncertainty with computational models. This work is expected to provide insight into SNF canister behavior.

Carpenter-Graffy, Dina E.↗

DOE OSTI2021

Feasibility of Lead Fast Reactor Heat Exchanger Tube Online Monitoring

Within virtually all reactor systems with heat exchangers, the thinnest barriers between primary and secondary fluids are the heat exchanger tubes. Consistent with light water reactor experience, the advanced reactor heat exchangers are the most susceptible regions for corrosion and leakage (NRC, 2019). Moreover, traditional inspections and repairs using robotics will be expensive or impractical. On-line structural health corrosion monitoring (OLSHM) is therefore desirable to detect tube degradation prior to leaks that may allow mixing of heat exchanger fluids. Rhetorically many molten salt reactor (MSR) designers plan for on-line monitoring of critical reactor components including heat exchangers but there are no proven OLSHM sensors or systems for MSR heat exchangers. Guided wave ultrasound from the tube-end or ID using conventional low-temperature piezoelectric sensors has been shown to be sensitive to pits and cracks less than 50% through-wall in long pipes and tubes (Narayanan M.M., 2019) . Mode and frequency selection are important for practical sensor design decisions and ultimate performance. The L-0 wave-mode is easily excited by L-mode transducers but they have surface normal wave motion that will be sensitive to and more attenuative because of fluid interaction with the tube surface (Rose J.L., 1994). Shear Horizontal (SH) wave modes have material motion parallel to the tube surface therefore are virtually unaffected by fluid interaction. For SH-0 to be nondispersive in steel, the frequency-thickness product (MHz-mm) must be less than approximately 1.5. SH mode transducers must be coupled by a material that can support shear stress; a thin layer of honey works well for temporary sensors and an adhesive or a brazed metallurgical bond for permanent sensors. If sensors are incorporated into the fabrication process, the same kinds of SH-0 waves can be generated from the stagnant flow area of the tube OD without compromising the heat-exchange tube function. Piezoelectric materials are also available that can withstand harsh temperatures of molten salt heat exchangers (Stevenson T., 2015) (Machura et al., 2008). Though they may not have as high-performance characteristics, their performance only needs to be good enough to detect flaws of interest. This project attempts to demonstrate feasibility to develop a sensor that can be sensitive to flaws of interest and perform long-term monitoring of a molten salt reactor heat exchanger. Benefits to the advanced reactor system include: • Minimizing the expense of a reactor shut down for periodic inspection—only shutdown for cause. • Reduce risk of unexpected tube rupture by detecting flaws before they grow to through-wall leaks. • Cost reduction by minimizing need to design for manual/robotic inspectability. Transducer design, characterization of the beam profile, wedges vs. direct application of piezoelectric sensors, and ultrasonic pulse-echo responses from a representative heat exchange tube with fabricated flaw types are discussed.

On-Line Tube Monitor, Guided Wave Ultrasound, SH-0↗

DOE OSTI2013

Stability and etching of titanium oxynitride films in hydrogen microwave plasma

Epitaxial titanium oxynitride (TiNO) films deposited on MgO by pulsed laser deposition were treated in hydrogen microwave plasma. Scanning electron microscopy and x-ray photoelectron spectroscopy were used to examine the stability and etching of TiNO which strongly depended on hydrogen gas pressure. TiNO was very chemically stable and remained with good crystallinity under hydrogen pressure below 5300 Pa. With increase of pressure, it may lead to the formation of etch pits in inverse pyramid shape. The etch mechanism as well as the effects of gas pressure and etching time are also presented.

36 MATERIALS SCIENCE↗

DOE OSTI2016

Optimization of a chlorine-based deep vertical etch of GaN demonstrating low damage and low roughness

The dry etching of GaN to form deep vertical structures is a critical step in many power device processes. To accomplish this, a chlorine and argon etch is investigated in detail to satisfy several criteria simultaneously such as surface roughness, crystal damage, and etch angle. Etch depths from 2 to 3.4 μm are shown in this paper. The authors investigate the formation of etch pits and its contributing factors. In addition, a nickel hard mask process is presented, with an investigation into the causes of micromasking and a pre-etch to prevent it. The authors show the results of optimized etch conditions resulting in a 2 μm deep, 0.831 nm rms roughness etch, with a 7.6° angle from vertical and low surface damage as measured by photoluminescence.

Tahhan, Maher↗

DOE OSTI2021

Impact of carrier wafer on etch rate, selectivity, morphology, and passivation during GaN plasma etching

The choice of carrier wafer was found to significantly influence etch rates, selectivity, and morphology in GaN micropillar etching in a Cl 2 -Ar high-density inductively coupled plasma. 7 × 7 mm 2 GaN on sapphire chips with a plasma-enhanced chemical vapor deposition SiO 2 hard mask was etched on top of 4-in. fused silica, silicon carbide, silicon, sapphire, aluminum nitride, and high purity aluminum carriers. Silicon and silicon carbide carriers reduced GaN:SiO 2 selectivity because incidental SiCl x and CCl x etch products from the carriers attack the SiO 2 mask. Aluminum nitride and high-purity aluminum carriers yielded the highest GaN:SiO 2 selectivities due to the deposition of Al-based etched by-products, while the highest GaN etch rate was achieved using the sapphire carrier since it was the most inert carrier and did not sink any Cl 2 . Overall, results indicate that SiO 2 and Al may be used as passivation materials during GaN etching, as vertical profiles were achieved when SiO 2 or Al is redeposited from the fused silica and aluminum carriers, respectively. Floor pitting, trenching, sidewall roughness, and faceting were all influenced by carrier wafer type and will be discussed.

36 MATERIALS SCIENCE↗

DOE OSTI2014

SU-E-T-26: A Study On the Influence of Photonuclear Reactions On the Biological Effectiveness of Therapeutic High Energy X-Ray Beam

Purpose: Photons from a modern high-energy therapeutic linear accelerator used in X-ray radiotherapy causes photonuclear reactions in an accelerator or patient's body. The aim of this study is to evaluate the biological effectiveness including these particles by Microdosimetric Kinetic Model (MKM) based on microdosimetry. Methods: A linear accelerator operating at 15 MV was used. CR-39 was used to obtain LET spectra of secondary ions selectively, as CR-39 is regarded insensitive to photons. CR-39 was put on the central axis of the X-ray beam at depths of 0, 5 and 10 cm in plastic phantom at a source to detector distance of 100 cm. Pits formed by the traversal of ions were etched then analyzed to obtain restricted LET distribution. Frequency-mean and dose-mean lineal energy was evaluated from the relationship between the restricted LET and the lineal energy required to evaluate the biological effectiveness by MKM. The relationship was calculated by Monte Carlo simulations with GEANT4. Results: Restricted LET distributions of secondary particles showed broad distributions that decreases exponentially with increasing LET. Frequency-mean and dose-mean lineal energy were determined uniquely within the scope of the energies of secondary particles generated from photons of 15 MeV. The frequency-mean lineal energies at the depth of 0, 5 and 10 cm were 15.1, 16.0 and 19.7 keV/μm respectively, and the dose-mean lineal energies were 18.6, 20.5 and 19.6 keV/μm, respectively. RBE of secondary particles for HSG cell evaluated by MKM was about 2.0 at all depths, and RBE of all particles including photons was evaluated 1.0. Conclusion: We investigated the biological effectiveness of secondary particles by photonuclear reactions. The method to evaluate RBE by MKM was established with measurements and simulations. However, the influence of these secondary ions on RBE was found negligible in the entire biological effectiveness of the high-energy X-ray. This study has been supported by JSPS KAKENHI Grant Number 25861144.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2015

SU-E-J-231: Comparison of Delineation Variability of Soft Tissue Volume and Position in Head-And-Neck Between Two T1-Weighted Pulse Sequences Using An MR-Simulator with Immobilization

Purpose: There is growing interests in applying MR-simulator(MR-sim) in radiotherapy but MR images subject to hardware, patient and pulse sequence dependent geometric distortion that may potentially influence target definition. This study aimed to evaluate the influence on head-and-neck tissue delineation, in terms of positional and volumetric variability, of two T1-weighted(T1w) MR sequences on a 1.5T MR-sim Methods: Four healthy volunteers were scanned (4 scans for each on different days) using both spin-echo (3DCUBE, TR/TE=500/14ms, TA=183s) and gradient-echo sequences (3DFSPGR, TE/TR=7/4ms, TA=173s) with identical coverage, voxel-size(0.8×0.8×1.0mm3), receiver-bandwidth(62.5kHz/pix) and geometric correction on a 1.5T MR-sim immobilized with personalized thermoplastic cast and head-rest. Under this setting, similar T1w contrast and signal-to-noise ratio were obtained, and factors other than sequence that might bias image distortion and tissue delineation were minimized. VOIs of parotid gland(PGR, PGL), pituitary gland(PIT) and eyeballs(EyeL, EyeR) were carefully drawn, and inter-scan coefficient-of-variation(CV) of VOI centroid position and volume were calculated for each subject. Mean and standard deviation(SD) of the CVs for four subjects were compared between sequences using Wilcoxon ranksum test. Results: The mean positional(<4%) and volumetric(<7%) CVs varied between tissues, majorly dependent on tissue inherent properties like volume, location, mobility and deformability. Smaller mean volumetric CV was found in 3DCUBE, probably due to its less proneness to tissue susceptibility, but only PGL showed significant difference(P<0.05). Positional CVs had no significant differences for all VOIs(P>0.05) between sequences, suggesting volumetric variation might be more sensitive to sequence-dependent delineation difference. Conclusion: Although 3DCUBE is considered less prone to tissue susceptibility-induced artifact and distortion, our preliminary data showed that both sequences had insignificant differences on positional and volumetric CV in most head-and-neck tissues except for PGL. This study is majorly limited in its small sample size. Influences of image contrasts(T1w v.s. T2w) and inter-observer difference have to be further investigated.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2022

Molecular beam homoepitaxy of N-polar AlN: Enabling role of aluminum-assisted surface cleaning

N-polar aluminum nitride (AlN) is an important building block for next-generation high-power radio frequency electronics. We report successful homoepitaxial growth of N-polar AlN by molecular beam epitaxy (MBE) on large-area, cost-effective N-polar AlN templates. Direct growth without any in situ surface cleaning leads to films with inverted Al polarity. It is found that Al-assisted cleaning before growth enables the epitaxial film to maintain N-polarity. The grown N-polar AlN epilayer with its smooth, pit-free surface duplicates the structural quality of the substrate, as evidenced by a clean and smooth growth interface with no noticeable extended defects generation. Near band-edge photoluminescence peaks are observed at room temperature on samples with MBE-grown layers but not on the bare AlN templates, implying the suppression of nonradiative recombination centers in the epitaxial N-polar AlN.

42 ENGINEERING↗

DOE OSTI2017

SEM, Chemical Etching and THz Wave Generation of 4-Dimethylamino-N-methyl-4-stilbazolium Tosylate (DAST) Single Crystals

The 4-dimethylamino-N-methyl-4-stilbazolium tosylate (DAST) crystal which was candidate for generating and detecting terahertz (THz) wave was grown by slope nucleation method (SNM). The functional groups of DAST were identified by Fourier Transform Infrared (FTIR) studies. Macroscopic steps and streaks on the (001) face were found by scanning electron microscope (SEM). Different patterns of etch pits under different chemical etchants were studied by optical microscope. Widely tunable THz waves ranging from 0.38 to 18.10 THz were generated from 0.5 mm-thick DAST crystal. The maximum output energy was 345.4 nJ/pulse at 3.39 THz and the conversion efficiency was 8.44 × 10{sup –5}.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2018

CeSOX: Short-Distance Neutrino Oscillations with BoreXino

Several experimental anomalies in neutrino physics may point to the possible existence of one or more additional neutrino species that do not interact weakly, the so-called sterile neutrinos. The third phase of the Borexino experiment (SOX) is devoted to verification of this hypothesis. Within the first stage (CeSOX) the count rate of antineutrino events in the liquid scintillation detector from the artificial source {sup 1}44Ce–{sup 1}44Pr placed in the special pit beneath the setup will be measured. The smaller antineutrino flux, as compared to the original one, would indicate the presence of oscillations into sterile states. This paper gives a survey of the CeSOX experiment, including the general description, the characterization of the radioactive source and the specific features of its use, the description of the method for data analysis, and the expected results. Depending on the significance of the obtained scientific information, the decision on carrying out the second stage of the SOX experiment with the {sup 51}Cr source of electron neutrinos will be made.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2017

High-temperature annealing of macroporous silicon in an inert-gas flow

Interest in the sintering of macroporous silicon is due to the possibility of purposefully modifying its structure. The annealing of macroporous structures in an atmosphere of Ar, instead of H{sub 2}, simplifies the requirements to equipment and safety engineering. The sintering of macroporous silicon as result of annealing at T = 1000–1280°C in a horizontal tube purged with high-purity gases: Ar or Ar + 3%H{sub 2} is examined. Experiments were conducted with layers having deep cylindrical macropores produced by the electrochemical etching of samples with seed pits on their surface (ordered pores) and without seeds (random pores). The morphology of the porous structure and the changes in this structure upon annealing are studied with electron and optical microscopes. It is shown that, depending on the pore diameter and treatment temperature, the following transformation occurs: the pore surface is smoothed, pores are closed and a surface crust is formed, cylindrical pores are spheroidized and decompose into isolated hollow spheres, and a fine structure and faceting are formed. It is shown that the (111) planes have the minimal surface energy. It is found that the annealing of macroporous silicon in an inert gas leads to strong thermal etching, which is manifested in the fact that the porosity increases or even the porous layer at the sample edge fully disappears. Moreover, an oxide layer appears as a film, beads, or long filaments forming a glass wool upon annealing, especially at low temperatures. These features can be attributed to the presence of trace amounts of an oxidizing agent in the inert gas, which causes the formation of highly volatile SiO and products formed in the reaction involving this compound.

36 MATERIALS SCIENCE↗

DOE OSTI2019

Evolution of Micropits on Large Terraces of the Si(111) Surface during High-Temperature Annealing

The transformation of micropits on large terraces of the Si(111) surface containing no vicinal atomic steps has been investigated by in situ ultrahigh-vacuum reflection electron microscopy upon thermal annealing of the substrate in the range of 1200–1400°C. A procedure for the formation of micropits on large terraces of the Si(111) surface with the application of focused-ion-beam (Ga{sup +}) technology has been proposed. It has been found that the micropit decay kinetics varies upon reaching the critical radius R{sub crit}, which is caused by the activation of nucleation of two-dimensional vacancy islands on the micropit bottom. A theoretical model describing variations in the lateral sizes of the micropit both before and after reaching R{sub crit} has been proposed. Based on analysis of the found temperature dependence of the nucleation frequencies of two-dimensional vacancy pits on the micropit bottom, the effective energy of nucleation of a vacancy island has been determined to be 4.1 ± 0.1 eV.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗