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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 739 records · Page 41
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Salt Effects on Li-Ion Exchange Kinetics of Na 2 Mg 2 P 3 O 9 N: Systematic In Situ Synchrotron Diffraction Studies

The kinetics and thermodynamics of solid-state ion exchange of Li+ into Na2Mg2P3O9N were investigated using in situ synchrotron X-ray diffraction methods for a series of Li-containing salts, allowing systematic trends with general applicability to ion exchange reactions to be elucidated. The collection of data for a wide range of reaction conditions was enabled through the use of a novel multiwell sample environment which leverages the ability of the synchrotron beamline to rapidly (similar to 1 s) collect high-quality data suitable for monitoring reaction progress. From these data, it was possible to resolve the influence of salt choice and salt concentration on the ion exchange reaction kinetics. Furthermore, by carrying out experiments at different temperatures, initial estimates of activation energies were obtained. It was generally found that the ion exchange reaction kinetics strongly depended on the salt chosen as the ion source rather than being primarily determined by the ion mobility of the ceramic.

Cosby, Monty R.↗
NASA NTRS2011

The Cloud-Aerosol Transport System (CATS): a New Lidar for Aerosol and Cloud Profiling from the International Space Station

Spaceborne lidar profiling of aerosol and cloud layers has been successfully implemented during a number of prior missions, including LITE, ICESat, and CALIPSO. Each successive mission has added increased capability and further expanded the role of these unique measurements in wide variety of applications ranging from climate, to air quality, to special event monitoring (ie, volcanic plumes). Many researchers have come to rely on the availability of profile data from CALIPSO, especially data coincident with measurements from other A-Train sensors. The CALIOP lidar on CALIPSO continues to operate well as it enters its fifth year of operations. However, active instruments have more limited lifetimes than their passive counterparts, and we are faced with a potential gap in lidar profiling from space if the CALIOP lidar fails before a new mission is operational. The ATLID lidar on EarthCARE is not expected to launch until 2015 or later, and the lidar component of NASA's proposed Aerosols, Clouds, and Ecosystems (ACE) mission would not be until after 2020. Here we present a new aerosol and cloud lidar that was recently selected to provide profiling data from the International Space Station (ISS) starting in 2013. The Cloud-Aerosol Transport System (CATS) is a three wavelength (1064, 532, 355 nm) elastic backscatter lidar with HSRL capability at 532 nm. Depolarization measurements will be made at all wavelengths. The primary objective of CATS is to continue the CALIPSO aerosol and cloud profile data record, ideally with overlap between both missions and EarthCARE. In addition, the near real time data capability of the ISS will enable CATS to support operational applications such as air quality and special event monitoring. The HSRL channel will provide a demonstration of technology and a data testbed for direct extinction retrievals in support of ACE mission development. An overview of the instrument and mission will be provided, along with a summary of the science objectives and simulated data.

Welton, Ellsworth J.↗
DOE OSTI2018

Reuse Permit I-160-02Quality Assurance Project Plan (QAPP) for Required Environmental and Process MonitoringIdaho National Laboratory Materials and Fuels Complex Industrial Waste Ditch and Pond

The purpose of this quality assurance project plan (QAPP) is to describe the technical requirements and quality assurance (QA) activities of the environmental data collection/analyses operations to be performed under Reuse Permit I-160-02, Modification 1 (hereafter ‘permit’). It describes the scope of monitoring, the organization and persons involved, the data quality objectives, the monitoring procedures, and the specific quality control (QC) measures to be employed. All QAPP activities are implemented to determine whether the results of the sampling and monitoring performed are the right type, quantity, and quality to satisfy the requirements of the permit, Section 5.

99 GENERAL AND MISCELLANEOUS↗
NASA NTRS1992

Signal Quality Influence on Averaging Procedure for DIAL Pollution Monitoring

Presented here is an analysis of the relative effect of each stochastic phenomenon on the accuracy of LIDAR measurements. The preferred averaging procedure to be applied is noted. The analysis takes into account the temporal correlation of the transmitted power variations which are associated with laser modal noise, short term temporal correlation of atmospheric turbulence, and 'white' additive noise. A distinction is made between two types of systems, one that transmits a sequence of pulses tuned into two wavelengths, but with a relatively large time separation, and another that transmits pulses in two wavelengths almost coincidentally. This distinction is important because the effect of speckle noise can be minimized when the pulses at two wavelengths are sent within the correlation time of the atmospheric turbulence. The presented analysis compares the signal to noise ratio in the calculation of the ratio beta (sub 1)/beta (sub 2), as achieved by using two methods of calculations: first averaging the data related to each wavelength and then taking the ratio, and first taking the ratio and then averaging. For both methods, normalization with respect to the transmitted power is considered, either prior to or after the averaging of the signals in each wavelength.

Egert, S.↗
NASA NTRSDate not supplied

Hemispheric Airborne Measurements of Air Quality (HAMAQ)

Under NASA’s Earth Venture Suborbital program, Hemispheric Airborne Measurements of Air Quality (HAMAQ) will conduct a series of campaigns in 2028 under the Tropospheric Emissions: Monitoring of Pollution (TEMPO) geostationary satellite instrument. HAMAQ plans include two deployments, including the Mexico City megalopolis and another North American site yet to be selected. The effort will include two aircraft, NASA’s B777 for in situ sampling and G-III for remote sensing. These aircraft will be used to complete a system of integrated observations, combining satellite observations, ground-based monitoring and research observations with air quality modeling. HAMAQ field intensives will serve multiple objectives to include: improving the use of satellite observations in concert with traditional ground monitoring to inform air quality; assessing emissions to better understand their timing and source apportionment; advancing the development of satellite proxies for air quality; and assessing the factors controlling local air quality in each location sampled. Given the long lead time for this campaign, this poster welcomes discussion from the community on strategies and candidate sites for the second deployment. Given the broad applicability of the HAMAQ science objectives and observing strategy, possible partnerships to extend the pursuit of the larger vision of HAMAQ to also sample in Asia and Europe are of interest.

James H Crawford↗
DOE OSTI2020

Investigating relationship between surface topography and emissivity of metallic additively manufactured parts

Due to the direct relationship between thermal history and mechanical behavior, in situ thermal monitoring is key in gauging quality of parts produced with additive manufacturing (AM). Accurate monitoring of temperatures in an AM process requires knowledge of environment and object parameters including object emissivity. The emissivity is dependent on several variables, including: wavelength, material composition, temperature, and surface topography. Researchers have been concerned with the thermal emissivity dependence on temperature since large ranges are seen in metal powder bed processes, but there is also an extensive range of surfaces produced by AM. This work focused on discovering what roughness characteristics control thermal emissivity through investigation of prototypic 316 stainless steel AM samples produced with a range of build conditions on a laser powder bed fusion machine. Through experimental measurements of emissivity using hemispherical directional reflectance (HDR), guided by simulations using a finite-difference time-domain (FDTD) Maxwell solver, it was found that combinations of existing roughness parameters describing both height and slope of the surface correlate well with emissivity changes. Furthermore, these parameters work well due to their apt description of surface features encouraging internal reflection, which is the phenomenon that increases emissivity when a surface falls under the geometric optical region conditions.

36 MATERIALS SCIENCE↗
NASA NTRS1993

Measuring Weld Parameters By Spectroscopy

Optical-emission spectrometric apparatus used to monitor variable-polarity plasma arc welding of aluminum alloys. Spectrometer incorporated into control system to ensure quality of weld because in keyhole, arc fully penetrates weld joint and impurities flushed out. Apparatus helps ensure high quality of weld by monitoring such contaminants as oxygen and hydrogen in shield gas, detecting inadequate flow of shield gas, and sensing changes in temperature of arc with changes in arc current and voltage.

Nunes, Arthur↗
NASA NTRS2010

Global Estimates of Average Ground-Level Fine Particulate Matter Concentrations from Satellite-Based Aerosol Optical Depth

Exposure to airborne particles can cause acute or chronic respiratory disease and can exacerbate heart disease, some cancers, and other conditions in susceptible populations. Ground stations that monitor fine particulate matter in the air (smaller than 2.5 microns, called PM2.5) are positioned primarily to observe severe pollution events in areas of high population density; coverage is very limited, even in developed countries, and is not well designed to capture long-term, lower-level exposure that is increasingly linked to chronic health effects. In many parts of the developing world, air quality observation is absent entirely. Instruments aboard NASA Earth Observing System satellites, such as the MODerate resolution Imaging Spectroradiometer (MODIS) and the Multi-angle Imaging SpectroRadiometer (MISR), monitor aerosols from space, providing once daily and about once-weekly coverage, respectively. However, these data are only rarely used for health applications, in part because the can retrieve the amount of aerosols only summed over the entire atmospheric column, rather than focusing just on the near-surface component, in the airspace humans actually breathe. In addition, air quality monitoring often includes detailed analysis of particle chemical composition, impossible from space. In this paper, near-surface aerosol concentrations are derived globally from the total-column aerosol amounts retrieved by MODIS and MISR. Here a computer aerosol simulation is used to determine how much of the satellite-retrieved total column aerosol amount is near the surface. The five-year average (2001-2006) global near-surface aerosol concentration shows that World Health Organization Air Quality standards are exceeded over parts of central and eastern Asia for nearly half the year.

Van Donkelaar, A.↗
DOE OSTI2022

Pacific Northwest National Laboratory Annual Site Environmental Report for Calendar Year 2021 (Final Report)

The U.S. Department of Energy requires that all its site facilities develop an annual site environmental report to comply with DOE Order 231.1B Chg 1 and DOE Order 458.1 Admin Chg 4. This report provides a synopsis of calendar year 2021 information related to environmental management performance and compliance efforts at the Pacific Northwest National Laboratory. It summarizes site compliance with federal, state, and local environmental laws, regulations, policies, directives, permits, and Orders, and provides environmental management performance benchmarks and their status to the public, regulatory agencies, community officials, Native American tribes, and public interest groups.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2012

The Cloud-Aerosol Transport System (CATS): A New Lidar for Aerosol and Cloud Profiling from the International Space Station

Spaceborne lidar profiling of aerosol and cloud layers has been successfully implemented during a number of prior missions, including LITE, ICESat, and CALIPSO. Each successive mission has added increased capability and further expanded the role of these unique measurements in wide variety of applications ranging from climate, to air quality, to special event monitoring (ie, volcanic plumes). Many researchers have come to rely on the availability of profile data from CALIPSO, especially data coincident with measurements from other A-Train sensors. The CALIOP lidar on CALIPSO continues to operate well as it enters its fifth year of operations. However, active instruments have more limited lifetimes than their passive counterparts, and we are faced with a potential gap in lidar profiling from space if the CALIOP lidar fails before a new mission is operational. The ATLID lidar on EarthCARE is not expected to launch until 2015 or later, and the lidar component of NASA's proposed Aerosols, Clouds, and Ecosystems (ACE) mission would not be until after 2020. Here we present a new aerosol and cloud lidar that was recently selected to provide profiling data from the International Space Station (ISS) starting in 2013. The Cloud-Aerosol Transport System (CATS) is a three wavelength (1064,532,355 nm) elastic backscatter lidar with HSRL capability at 532 nm. Depolarization measurements will be made at all wavelengths. The primary objective of CATS is to continue the CALIPSO aerosol and cloud profile data record, ideally with overlap between both missions and EarthCARE. In addition, the near real time (NRT) data capability ofthe ISS will enable CATS to support operational applications such as aerosol and air quality forecasting and special event monitoring. The HSRL channel will provide a demonstration of technology and a data testbed for direct extinction retrievals in support of ACE mission development. An overview of the instrument and mission will be provided, along with a summary of the science objectives and simulated data. Input from the ICAP community is desired to help plan our NRT mission goals and interactions with ICAP forecasters.

Welton, Ellsworth J.↗
DOE OSTI2016

Performance Monitoring using Pecos (V.0.1)

Advances in sensor technology have rapidly increased our ability to monitor natural and human-made physical systems. In many cases, it is critical to process the resulting large volumes of data on a regular schedule and alert system operators when the system has changed. Automated quality control and performance monitoring can allow system operators to quickly detect performance issues. Pecos is an open source python package designed to address this need. Pecos includes built-in functionality to monitor performance of time series data. The software can be used to automatically run a series of quality control tests and generate customized reports which include performance metrics, test results, and graphics. The software was developed specifically for solar photovoltaic system monitoring, and is intended to be used by industry and the research community. The software can easily be customized for other applications. The following Pecos documentation includes installation instructions and examples, description of software features, and software license. It is assumed that the reader is familiar with the Python Programming Language. References are included for additional background on software components.

47 OTHER INSTRUMENTATION↗
DOE OSTI2026

On the formation of swelling and related flaws in laser powder bed fusion

Process monitoring in laser powder bed fusion additive manufacturing can provide insights into stochastic anomalies, melt pool and plume dynamics, and part quality. Swelling, a build anomaly where overbuilt material protrudes through the powder layer after recoating, is readily detectable in post-recoat visible light images of the powder bed. Here, this work identifies several of the underlying mechanisms driving swelling formation by analyzing the influence of processing parameters, laser scan paths, and build plate locations on the presence of swelling detected in situ. Swelling near the edge of the part and swelling in the internal region of the part are shown to correlate with different process conditions. Edge and internal swelling may be driven by different phenomena, with edge swelling predominately occurring on the edge of a part facing the laser module and correlated to clusters of near-surface voids (detected with X-ray computed tomography). A larger spot size, higher laser power, and lower scan velocity also increased the presence of edge swelling. Laser spot size and scan path influenced internal swelling, which occurred preferentially with a larger spot size and in regions with large melt pools, caused by localized heat accumulation due to non-optimal processing parameters or scan path strategies. For coupons processed with a slicer-defined maximum scan vector length, swelling seldom occurred at internal vector-stripe boundaries. These results provide a mechanistic understanding of how swelling can be linked to material flaws, insight into how some instances of swelling can be avoided, and evidence supporting the use of swelling as an in situ indicator for quality assurance and part qualification.

Anomaly↗
NASA NTRS2018

TPSAS-NF1676L-30290-DND

The Summer 2017 Ozone Water Land Environmental Transition Study (OWLETS) mission set out to compare the differences in ozone concentrations between inland measurements of air quality, specifically at Langley Research Center (LaRC), and measurements taken over water, specifically on the Chesapeake Bay Bridge Tunnel (CBBT), as well as the vertical profiles above each location. Current weather models often predict a gradient in ozone concentration between land and ocean and this campaign attempted to capture this difference using hand-held Personal Ozone Monitors (POMs) in correspondence to ozonesondes and LIDAR measurements. The Tropospheric Emissions: Monitoring of Pollution (TEMPO) is the first geostationary satellite that will take hourly measurements to monitor air pollutants across North America using solar backscatter. The small footprint allows for higher spatial resolution readings of many parameters including O3, NO2 , and aerosol. TEMPO’s higher resolution readings would benefit from validation techniques on the ground. Validation methods usually include comparison to air quality monitoring stations, but they could also incorporate other forms of validation such as comparison to small sensors. In cooperation with TEMPO, OWLETS aims to provide the user community high resolution temporal and spatial, both horizontal and vertical, variability of O3 simultaneously over the land and water during various air quality events to improve forecast models and air quality satellite retrievals. Together, these missions will improve spatial resolution and capture temporal variability of air quality over North America.

Emily Gargulinski↗
NASA NTRS2021

From Low-Cost Sensors to High-Quality Data: A Review of Challenges and Summary of Best Practices for Effectively Using Low-Cost Particulate Matter Mass Sensors

Low-cost sensors for particulate matter mass (PM) enable spatially dense, high temporal resolution measurements of air quality that traditional reference monitoring cannot. Low-cost PM sensors are especially beneficial in low and middle-income countries where few, if any, reference grade measurements exist and in areas where the concentration fields of air pollutants have significant spatial gradients. Unfortunately, low-cost PM sensors also come with a number of challenges that must be addressed if their data products are to be used for anything more than a qualitative characterization of air quality. The various PM sensors used in low-cost monitors are all subject to biases and calibration dependencies, corrections for which range from relatively straightforward(e.g. meteorology, age of sensor) to complex (e.g. aerosol source, composition, refractive index). The methods for correcting and calibrating these biases and dependencies that have been used in the literature likewise range from simple linear and quadratic models to complex machine learning algorithms. Here we review the needs and challenges when trying to get high-quality data from low-cost sensors. We also present a set of best practices to follow to obtain high-quality data from these low-cost sensors.

low-cost sensors↗
DOE OSTI2017

An approach to online network monitoring using clustered patterns

Network traffic monitoring is a core element in network operations and management for various purposes such as anomaly detection, change detection, and fault/failure detection. In this study, we introduce a new approach to online monitoring using a pattern-based representation of the network traffic. Unlike the past online techniques limited to a single variable to summarize (e.g., sketch), the focus of this study is on capturing the network state from the multivariate attributes under consideration. To this end, we employ clustering with its benefit of the aggregation of multidimensional variables. The clustered result represents the state of the network with regard to the monitored variables, which can also be compared with the previously observed patterns visually and quantitatively. Finally, we demonstrate the proposed method with two popular use cases, one for estimating state changes and the other for identifying anomalous states, to confirm its feasibility.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2021

Pacific Northwest National Laboratory Annual Site Environmental Report for Calendar Year 2020. Final Report

The U.S. Department of Energy requires that all its site facilities develop an annual site environmental report to comply with DOE Order 231.1B, Chg 1, and DOE Order 458.1, Admin Chg 4. This report provides a synopsis of calendar year 2020 information related to environmental management performance and compliance efforts at Pacific Northwest National Laboratory. It summarizes site compliance with federal, state, and local environmental laws, regulations, policies, directives, permits, and Orders, and provides environmental management performance benchmarks and their status to the public, regulatory agencies, community officials, Native American tribes, and public interest groups.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1986

Monitoring Prepregs As They Cure

Quality IR spectra obtained in dynamic heating environment. New technique obtains quality infrared spectra on graphite-fiber-reinforced, polymeric-matrix-resin prepregs as they cure. Technique resulted from modification of diffuse reflectance/Fourier transform infrared (DR/FTIR) technique previously used to analyze environmentally exposed cured graphite composites. Technique contribute to better understanding of prepreg chemistry/temperature relationships and development of more efficient processing cycles for advanced materials.

Young, P. R.↗