Spin canting across core/shell Fe[subscript 3]O[subscript 4]/Mn[subscript x]Fe[subscript 3;#8722;x]O[subscript 4] nanoparticles
Abstract not provided
Oberdick, Samuel D.↗
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Soil Moisture and Snow Cover: Active or Passive Elements of Climate?
A key question in the study of the hydrologic cycle is the extent to which surface effects such as soil moisture and snow cover are simply passive elements or whether they can affect the evolution of climate on seasonal and longer time scales. We have constructed ensembles of predictability studies using the NCAR CCM3 in which we compared the relative roles of initial surface and atmospheric conditions over the central and western U.S. in determining the subsequent evolution of soil moisture and of snow cover. We have also made sensitivity studies with exaggerated soil moisture and snow cover anomalies in order to determine the physical processes that may be important. Results from simulations with realistic soil moisture anomalies indicate that internal climate variability may be the strongest factor, with some indication that the initial atmospheric state is also important. The initial state of soil moisture does not appear important, a result that held whether simulations were started in late winter or late spring. Model runs with exaggerated soil moisture reductions (near-desert conditions) showed a much larger effect, with warmer surface temperatures, reduced precipitation, and lower surface pressures; the latter indicating a response of the atmospheric circulation. These results suggest the possibility of a threshold effect in soil moisture, whereby an anomaly must be of a sufficient size before it can have a significant impact on the atmospheric circulation and hence climate. Results from simulations with realistic snow cover anomalies indicate that the time of year can be crucial. When introduced in late winter, these anomalies strongly affected the subsequent evolution of snow cover. When introduced in early winter, however, little or no effect is seen on the subsequent snow cover. Runs with greatly exaggerated initial snow cover indicate that the high reflectively of snow is the most important process by which snow cover cart impact climate, through lower surface temperatures and increased surface pressures. In early winter, the amount of solar radiation is very small and so this albedo effect is inconsequential while in late winter, with the sun higher in the sky and period of daylight longer, the effect is much stronger.
Oglesby, Robert J.↗
Soil Moisture and Snow Cover: Active or Passive Elements of Climate?
A key question in the study of the hydrologic cycle is the extent to which surface effects such as soil moisture and snow cover are simply passive elements or whether they can affect the evolution of climate on seasonal and longer time scales. We have constructed ensembles of predictability studies using the NCAR CCM3 in which we compared the relative roles of initial surface and atmospheric conditions over the central and western U.S. GAPP region in determining the subsequent evolution of soil moisture and of snow cover. We have also made sensitivity studies with exaggerated soil moisture and snow cover anomalies in order to determine the physical processes that may be important. Results from simulations with realistic soil moisture anomalies indicate that internal climate variability may be the strongest factor, with some indication that the initial atmospheric state is also important. The initial state of soil moisture does not appear important, a result that held whether simulations were started in late winter or late spring. Model runs with exaggerated soil moisture reductions (near-desert conditions) showed a much larger effect, with warmer surface temperatures, reduced precipitation, and lower surface pressures; the latter indicating a response of the atmospheric circulation. These results suggest the possibility of a threshold effect in soil moisture, whereby an anomaly must be of a sufficient size before it can have a significant impact on the atmospheric circulation and hence climate. Results from simulations with realistic snow cover anomalies indicate that the time of year can be crucial. When introduced in late winter, these anomalies strongly affected the subsequent evolution of snow cover. When introduced in early winter, however, little or no effect is seen on the subsequent snow cover. Runs with greatly exaggerated initial snow cover indicate that the high reflectivity of snow is the most important process by which snow cover can impact climate, through lower surface temperatures and increased surface pressures. In early winter, the amount of solar radiation is very small and so this albedo, effect is inconsequential while in late winter, with the sun higher in the sky and period of daylight longer, the effect is much stronger. The results to date were obtained for model runs with present-day conditions. We are currently analyzing runs made with projected forcings for the 21st century to see if these results are modified in any way under likely scenarios of future climate change.
Oglesby, Robert J.↗
On the role of spatial position of bridged oxygen atoms as surface passivants on the ground-state gap and photo-absorption spectrum of silicon nano-crystals
Silicon nano-crystals (NCs) are potential candidates for enhancing and tuning optical properties of silicon for optoelectronic and photo-voltaic applications. Due to the high surface-to-volume ratio, however, optical properties of NC result from the interplay of quantum confinement and surface effects. In this work, we show that both the spatial position of surface terminants and their relative positions have strong effects on NC properties as well. This is accomplished by investigating the ground-state HOMO-LUMO band-gap, the photo-absorption spectra, and the localization and overlap of HOMO and LUMO orbital densities for prototype ∼1.2 nm Si{sub 32–x}H{sub 42–2x}O{sub x} hydrogenated silicon NC with bridged oxygen atoms as surface terminations. It is demonstrated that the surface passivation geometry significantly alters the localization center and thus the overlap of frontier molecular orbitals, which correspondingly modifies the electronic and optical properties of NC.
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
The Chameleon Effect: Characterization Challenges Due to the Variability of Nanoparticles and Their Surfaces
Nanoparticles in a variety of forms are of increasing importance in fundamental research, technological and medical applications, and environmental or toxicology studies. Physical and chemical drivers that lead to multiple types of particle instabilities complicate both the ability to produce and consistently deliver well defined particles and their appropriate characterization, frequently leading to inconsistencies and conflicts in the published literature. This perspective suggests that provenance information, beyond that often recorded or reported, and application of a set of core characterization methods, including a surface sensitive technique, consistently applied at critical times can serve as tools in the effort minimize reproducibility issues.
characterization↗
Soil Moisture and Snow Cover: Active or Passive Elements of Climate
A key question is the extent to which surface effects such as soil moisture and snow cover are simply passive elements or whether they can affect the evolution of climate on seasonal and longer time scales. We have constructed ensembles of predictability studies using the NCAR CCM3 in which we compared the relative roles of initial surface and atmospheric conditions over the central and western U.S. in determining the subsequent evolution of soil moisture and of snow cover. Results from simulations with realistic soil moisture anomalies indicate that internal climate variability may be the strongest factor, with some indication that the initial atmospheric state is also important. Model runs with exaggerated soil moisture reductions (near-desert conditions) showed a much larger effect, with warmer surface temperatures, reduced precipitation, and lower surface pressures; the latter indicating a response of the atmospheric circulation. These results suggest the possibility of a threshold effect in soil moisture, whereby an anomaly must be of a sufficient size before it can have a significant impact on the atmospheric circulation and climate. Results from simulations with realistic snow cover anomalies indicate that the time of year can be crucial. When introduced in late winter, these anomalies strongly affected the subsequent evolution of snow cover. When introduced in early winter, however, little or no effect is seen on the subsequent snow cover. Runs with greatly exaggerated initial snow cover indicate that the high reflectivity of snow is the most important process by which snow cover can impact climate, through lower surface temperatures and increased surface pressures. The results to date were obtained for model runs with present-day conditions. We are currently analyzing runs made with projected forcings for the 21st century to see if these results are modified in any way under likely scenarios of future climate change. An intriguing new statistical technique involving 'clustering' is developed to assist in this analysis.
Oglesby, Robert J.↗
The Solar Spectrum on the Martian Surface and its Effect on Photovoltaic Performance
Solar cells operating on the surface of Mars receive a spectrum of illumination different from the AM0 spectrum, since the sunlight is filtered by dust suspended in the atmosphere. This spectrum changes with the amount of dust in the atmosphere, as well as with air mass change due to time of day and season. This spectral variation affects the performance of solar cells. We used data from Mars Exploration Rovers to measure this spectrum. By comparing the measured intensity with the known reflectance of the pancam calibration target on the rovers Spirit and Opportunity, we measure the solar spectrum reaching the surface. The effect of this spectrum on the performance of solar cells is then calculated based on the spectral response of several different solar cell types.
Landis, Geoffrey A.↗
The Solar Spectrum on the Martian Surface and Its Effect on Photovoltaic Performance
Solar cells operating on the surface of Mars receive a spectrum of illumination different from the AM0 spectrum, since the sunlight is filtered by dust suspended in the atmosphere. This spectrum changes with the amount of dust in the atmosphere, as well as with air mass change due to time of day and season. This spectral variation affects the performance of solar cells. We used data from Mars Exploration Rovers to measure this spectrum. By comparing the measured intensity with the known reflectance of the pancam calibration target on the rovers Spirit and Opportunity, we measure the solar spectrum reaching the surface. The effect of this spectrum on the performance of solar cells is then calculated based on the spectral response of several different solar cell types.
Landis, Geoffrey A.↗
Field-Effect Passivation by Desired Charge Injection into SiNx Passivation in Crystalline-Silicon Solar Cells
Effective surface passivation is a necessity for high efficiency crystalline silicon solar cells. The field effect passivation of p-type surfaces is typically accomplished using aluminum oxide (Al 2 O 3 ) which contains a high density of negative fixed charges. The accumulation layer formed by the negative charges prevents surface recombination loss of photo-generated carriers by repelling minority carriers (electrons) from the surface with interface state recombination centers. However, the Al 2 O 3 surface passivation technology has two key concerns of cost and safety associated with the precursor material tri-methyl-aluminum (TMA).
14 SOLAR ENERGY↗
Ni coarsening under humid atmosphere in the electrode of solid oxide cells: A combined study of density-functional theory and phase-field modeling
Ni coarsening in solid oxide cell (SOC) electrodes is known to be significantly faster under a humid atmosphere. The underlying mechanisms, though, have not been fully understood. In this work, we examine the surface diffusion of Ni(OH) x by a combination of density-functional theory and phase-field modeling. Here, density-functional theory is used to evaluate the adsorption and diffusion of the Ni(OH) x species on Ni (111) surface, and the results are used to obtain the effective surface diffusivity of Ni versus steam and hydrogen gas partial pressures. This diffusivity is used as an input for a phase-field model to investigate the Ni coarsening in SOC electrodes. It is found that Ni(OH) x formed through chemical reaction cannot accelerate coarsening unless an extremely high steam to hydrogen ratio is reached. However, if Ni(OH) x is formed through electrochemical reactions near triple phase boundaries (TPBs), surface diffusion of Ni(OH) x may cause faster Ni coarsening in fuel cell mode under a large overpotential. Specifically, surface diffusion of Ni(OH) may be comparable to or faster than that of Ni under an overpotential that is large but still possible under fuel cell operating conditions.
25 ENERGY STORAGE↗
Lateral stability and control tests of the XP-77 airplane in the NACA full-scale tunnel, 16 June 1944
Tests were made in the NACA full-scale tunnel to determine the lateral stability and control characteristics of the XP-77 airplane. Measurements were made of the forces and moments on the airplane at various angles of attack and angles of yaw. The measurements were made with the propeller removed and with the propeller installed and operating at various thrust coefficients, and with the landing flaps retracted and deflected. The effects of aileron, elevator, and rudder deflection on control surface effectiveness and hinge moments were determined. The tests were planned to obtain the data required to evaluate as completely as possible the Army Air Force requirements on lateral stability and control for pursuit-type airplanes.
Czarnecki, K. R.↗
Mobile Lid Convection Beneath Enceladus' South Polar Terrain
Enceladus' south polar region has a large heat flux, 55-110 milliwatts per square meter (or higher), that is spatially associated with cryovolcanic and tectonic activity. Tidal dissipation and vigorous convection in the underlying ice shell are possible sources of heat; however, prior predictions of the heat flux carried by stagnant lid convection range from F(sub conv) ~15 to 30 milliwatts per square meter, too low to explain the observed heat flux. The high heat flux and increased cryovolcanic and tectonic activity suggest that near-surface ice in the region has become rheologically and mechanically weakened enough to permit convective plumes to reach close to the surface. If the yield strength of Enceladus' lithosphere is less than ~1-10 kPa, convection may instead occur in the mobile lid" regime, which is characterized by large heat fluxes and large horizontal velocities in the near-surface ice. I show that model ice shells with effective surface viscosities between 10(exp 16) and 10(exp 17) Pa s and basal viscosities between 10(exp 13) and 10(exp 15) Pa s have convective heat fluxes comparable to that observed by the Cassini Composite Infrared Spectrometer. If this style of convection is occurring, the south polar terrain should be spreading horizontally with v~1-10 millimeter per year and should be resurfaced in ~0.1-10 Ma. On the basis of Cassini imaging data, the south polar terrain is ~0.5 Ma old, consistent with the mobile lid hypothesis. Maxwell viscoelastic tidal dissipation in such ice shells is not capable of generating enough heat to balance convective heat transport. However, tidal heat may also be generated in the near-surface along faults as suggested by Nimmo et al. and/or viscous dissipation within the ice shell may occur by other processes not accounted for by the canonical Maxwell dissipation model.
Barr, Amy C.↗
Results of investigations (OA77 and OA78) on an 0.015-scale 140A/B configuration space shuttle vehicle orbiter model 49-0 in the AEDC VKF B and C wind tunnels, revision A
Aerodynamic data obtained from wind tunnel tests of an 0.015-scale 140A/B configuration SSV Orbiter model in the AEDC VKF B and C wind tunnels are presented. Tests were conducted at Mach numbers of 6 and 8 in the B tunnel and at a Mach number of 10 to in the C tunnel to verify hypersonic stability and control characteristics, determine control surface effectiveness, and investigate Reynolds number effects of the 140A/B configuration. Force data were obtained for various control surface settings and Reynolds numbers in the angle-of-attack range of 15 deg to 45 deg and at angles of sideslip of -5 deg to +10 deg. Data were obtained for a few configurations at angles of attack from -27 deg to 45 deg. Control surface variables included elevon, rudder, speedbrake and bodyflap deflections. The effects of an alternate wing leading edge shape were investigated to determine its hypersonic stability and control characteristics.
Gillins, R. L.↗
Polyelectrolyte Surface Diffusion in a Nanoslit Geometry
The surface diffusion of poly-l-lysine (PLL) in a planar nanoslit was studied using convex lens-induced confinement (CLiC) single-molecule tracking microscopy. Here, three surface chemistries were employed to understand the interplay of electrostatic and short-range interactions: an amine-functionalized silica surface, an oligo(ethylene oxide) (OEG)-modified surface, and a 1:1 mixture of the two ligands. Effective surface diffusion coefficients increased rapidly with slit height until saturating for slit heights <30 nm. While diffusion at a semi-infinite interface was significantly faster for OEG surfaces, the diffusion coefficient increased most rapidly with slit height for amine-functionalized surfaces, resulting in surface diffusion within very thin slits being nearly independent of surface chemistry. Intermittent random walks were simulated within a planar slit geometry, using experimentally measured parameters obtained from diffusion at a single interface to account for the characteristic short-range interactions between PLL and each surface chemistry, and were in good agreement with experimental measurements.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Enhancement of surface area and wettability properties of boron doped diamond by femtosecond laser-induced periodic surface structuring
We demonstrate the formation of laser-induced periodic surface structures (LIPSS) in boron-doped diamond (BDD) by irradiation with femtosecond near-IR laser pulses. The results show that the obtained LIPSS are perpendicular to the laser polarization, and the ripple periodicity is on the order of half of the irradiation wavelength. The surface structures and their electrochemical properties were characterized using Raman micro-spectroscopy, in combination with scanning electron and atomic force microscopies. The textured BDD surface showed a dense and large surface area with no change in its structural characteristics. The effective surface area of the textured BDD electrode was approximately 50% larger than that of a planar substrate, while wetting tests showed that the irradiated area becomes highly hydrophilic. Lastly, our results indicate that LIPSS texturing of BDD is a straightforward and simple technique for enhancing the surface area and wettability properties of the BDD electrodes, which could enable higher current efficiency and lower energy consumption in the electrochemical oxidation of toxic organics.
36 MATERIALS SCIENCE↗
A Novel Laser-Aided Machining and Polishing Process for Additive Manufacturing Materials with Multiple Endmill Emulating Scan Patterns
In additive manufacturing (AM), the surface roughness of the deposited parts remains significantly higher than the admissible range for most applications. Additionally, the surface topography of AM parts exhibits waviness profiles between tracks and layers. Therefore, post-processing is indispensable to improve surface quality. Laser-aided machining and polishing can be effective surface improvement processes that can be used due to their availability as the primary energy sources in many metal AM processes. While the initial roughness and waviness of the surface of most AM parts are very high, to achieve dimensional accuracy and minimize roughness, a high input energy density is required during machining and polishing processes although such high energy density may induce process defects and escalate the phenomenon of wavelength asperities. In this paper, we propose a systematic approach to eliminate waviness and reduce surface roughness with the combination of laser-aided machining, macro-polishing, and micro-polishing processes. While machining reduces the initial waviness, low energy density during polishing can minimize this further. The average roughness (Ra=1.11μm) achieved in this study with optimized process parameters for both machining and polishing demonstrates a greater than 97% reduction in roughness when compared to the as-built part.
42 ENGINEERING↗
Proposed method for degassing metals for extreme low pressures
Metal outgassing currently limits the pressures attained in vacuum chambers. The dominant residual gas in a carefully degassed metal system is usually hydrogen. The atomic hydrogen within bulk metals could be removed by diffusion processes if surface effects did not interfere. It is proposed that removing the surface hydrogen during vacuum bakeout by continuous electron bombardment (or similar irradiation) would allow the diffusion to proceed and lead to lower outgassing rates and operating pressures.
Moore, B. C.↗
Determination of lifetimes and recombination currents in p-n junction solar cells, diodes, and transistors
New methods are presented and illustrated that enable the accurate determination of the diffusion length of minority carriers in the narrow regions of a solar cell or a diode. Other methods now available are inaccurate for the desired case in which the width of the region is less than the diffusion length. Once the diffusion length is determined by the new methods, this result can be combined with measured dark I-V characteristics and with small-signal admittance characteristics to enable determination of the recombination currents in each quasi-neutral region of the cell - for example, in the emitter, low-doped base, and high-doped base regions of the BSF (back-surface-field) cell. This approach leads to values for the effective surface recombination velocity of the high-low junction forming the back-surface field of BSF cells or the high-low emitter junction of HLE cells. These methods are also applicable for measuring the minority-carrier lifetime in thin epitaxial layers grown on substrates with opposite conductivity type.
Neugroschel, A.↗