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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Diffusion in the system K2O-SrO-SiO2. II - Cation self-diffusion coefficients.

The self-diffusion coefficients were measured by introducing a slab of glass previously irradiated in a reactor between two slabs of unirradiated glass. By heating the specimens, etching them sequentially and determining the radioactivity, self-diffusion coefficients for K and Sr were measured. It is pointed out that the results obtained in the investigations appear to support the proposal that the network of the base glass predominantly controls the activation energy for the diffusion of ions.

Varshneya, A. K.↗
NASA NTRS1974

The modulation of low energy galactic cosmic rays

It has been clearly established by several different experiments that following the last solar maximum (about 1969), there was a significant phase lag or hysteresis effect between changes in the low rigidity galactic cosmic rays and the high rigidity components. It was possible to explain this in terms of the diffusion-convection-modulation theory by varying either the diffusion coefficient or the size of the modulation region as a function of time. During the ensuing recovery phase of the solar modulated spectra, at the mid point toward the minimum of the solar activity, new striking features have been observed, and these new observations are discussed.

Van Hollebeke, M. A. I.↗
NASA NTRS1982

An electrochemical study of Ni/2+/, Co/2+/, and Zn/2+/ ions in melts of composition CaMgSi2O6

Results are reported for a study of the behavior of Ni(2+), Co(2+), and Zn(2+) in molten diopside, determined by cyclic voltametry, as a first step in adapting electrochemical methods for use in experimental geochemistry. The techniques used are described, the theory is briefly discussed, and it is demonstrated that Ni(2+), Co(2+), and Zn(2+) can be reduced, then reoxidized in an uncomplicated case of reversible charge transfer at the Pt electrode. This implies that the neutral metal atoms remain undissolved in the melt. The kinetics of the reduction process, the effects of concentration, the standard reduction potentials, and the diffusion coefficients are discussed in detail. The observations are consistent with the mechanism of Ni(2+) diffusion by transport from site to site. As the proportion of SiO2 in the melt increases, a higher activation energy is required for Ni(2+) to move, and the rate of diffusion is lowered.

Semkow, K. W.↗
NASA NTRS1989

Tribological reactions of perfluoroalkyl polyether oils with stainless steel under ultrahigh vacuum conditions at room temperature

The reaction between three types of commercial perfluoroalkyl polyether (PFPE) oils and stainless steel 440C was investigated experimentally during sliding under ultrahigh vacuum conditions at room temperature. It is found that the tribological reaction of PFPE is mainly affected by the activity of the mechanically formed fresh surfaces of metals rather than the heat generated at the sliding contacts. The fluorides formed on the wear track act as a boundary layer, reducing the friction coefficient.

Mori, Shigeyuki↗
NASA NTRS1997

Membrane Transport Phenomena (MTP)

The activities during the fourth semi-annual period of the MTP project have involved the completion of the Science Concept Review (SCR) presentation and peer review, continuation of analyses for the mass transfer coefficients measured from MTA experiment data, and development of the second generation (MTP-II) instrument. The SCR panel members were generated several recommendations for the MTP project recommendations are : Table 1 Summary of Primary SCR Panel Recommendations (1) Continue and refine development of mass transfer coefficient analyses (2) Refine and upgrade analytical modeling associated with the MTP experiment. (3) Increase resolution of measurements in proximity of the membrane interface. (4) Shift emphasis to measurement of coupled transport effects (i.e., development of MTP phase II experiment concept).

Mason, Larry W.↗
DOE OSTI2018

Improving the Lubricity of Extended Reach Well Drilling Equipment Using Non-Fluorescent Extreme Pressure Cationic Lubricants

In this study, non-fluorescent cationic extreme pressure lubricant JDLUB-1 was prepared to improve the lubricity for extended reach well drilling. The lubricant was mainly composed of synthetic base oil, oil-soluble and spherical nano-silica, sulfur-phosphorus-molybdenum anti-friction and anti-extreme pressure additives. The mixture was emulsified with primary emulsifier cycloalkane group condensed fatty amines and a fatty alcohol polyoxyethylene ether co-emulsifier. The fluorescence level did not exceed 4, satisfying the standard requirements. The properties including extreme pressure lubrication, temperature resistance and compatibility with conventional drilling fluid additives were evaluated. The results indicated that the extreme pressure lubricity coefficient could reach 0.0283 after addition of JDLUB-1. Meanwhile, the product was stable at high temperature of 130 °C, and compatible with common additives. The lubricity mechanism of JDLUB-1 was investigated by measuring the zeta potential, particle size distribution, adsorption, and anti-wear evaluation at extreme pressure. The results indicated that the positively charged lubricant oil droplets could be actively adsorbed onto the surface of N80 steel casing coupon. An adsorption film composed of oil soluble and spherical nano-silica and sulfur-phosphorus-molybdenum compounds was formed with a low melting point and low shear strength. During friction, the formation of molybdenum disulfide film leads to repair of the metal surface and formation of a stable sliding friction between the drill string and the wellbore with a low friction coefficient. The JDLUB-1 lubricant was successfully applied in several high-angle deviated wells and extended reach wells in Jidong oilfield (China). The results demonstrated that JDLUB-1 could effectively reduce torque and drag and show potential field application in the future.

36 MATERIALS SCIENCE↗
DOE OSTI2022

The elphbolt ab initio solver for the coupled electron-phonon Boltzmann transport equations

elphbolt is a modern Fortran (2018 standard) code for efficiently solving the coupled electron–phonon Boltzmann transport equations from first principles. Using results from density functional and density functional perturbation theory as inputs, it can calculate the effect of the non-equilibrium phonons on the electronic transport (phonon drag) and non-equilibrium electrons on the phononic transport (electron drag) in a fully self-consistent manner and obeying the constraints mandated by thermodynamics. It can calculate the lattice, charge, and thermoelectric transport coefficients for the temperature gradient and electric fields, and the effect of the mutual electron–phonon drag on these transport properties. The code fully exploits the symmetries of the crystal and the transport-active window to allow the sampling of extremely fine electron and phonon wave vector meshes required for accurately capturing the drag phenomena. The corray feature of modern Fortran, which offers native and convenient support for parallelization, is utilized. The code is compact, readable, well-documented, and extensible by design.

electron drag↗
DOE OSTI2021

The CH(X 2 Π) + H 2 O reaction: two transition state kinetics

he reaction of ground state methylidyne (CH) with water vapor (H 2 O) is theoretically re-investigated using high-level coupled cluster computations in combination with semi-classical transition state theory (SCTST) and two-dimensional master equation simulations. Insertion of CH into a H–O bond of H 2 O over a submerged barrier via a well-skipping mechanism yielding solely H and CH 2 O is characterized. The reaction kinetics is effectively determined by the formation of a pre-reaction van der Waals complex (PRC, HC—OH 2 ) and its subsequent isomerization to activated CH 2 OH in competition with PRC re-dissociation. The tunneling effects are found to be minor, while variational effects in the PRC → CH 2 OH step are negligible. The calculated rate coefficient k ( T ) is nearly pressure-independent, but strongly depends on temperature with pronounced down-up behavior: a high value of 2 x 10 -10 cm 3 s -1 at 50 K, followed by a fairly steep decrease down to 8 × 10 -12 cm 3 s -1 at 900 K, but increasing again to 5 × 10 -11 cm 3 s -1 at 3500 K. Over the T-range of this work, k ( T ) can be expressed as: k ( T , P = 0) = 2.31 × 10 -11 ( T /300 K) -1.615 exp(-38.45/ T ) cm 3 s -1 for T = 50-400 K k ( T , P = 0) = 1.15 × 10 -12 ( T /300 K) 0.8637 exp(892.6/ T ) cm 3 s -1 for T = 400-1000 K k ( T , P = 0) = 4.57 × 10 -15 ( T /300 K) 3.375 exp(3477.4/ T ) cm 3 s -1 for T = 1000–3500 K.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Effects of confinement and pressure on the structure and dynamics of carbon dioxide in silica slit pores

An understanding of carbon dioxide fluid properties within geological mesopores is important in applications ranging from carbon sequestration to shale oil recovery. Here, a molecular dynamics study is presented that aims to shed light on these systems by simulation of CO 2 fluid confined in β-cristobalite silica slit pores with different pore widths and pressure conditions. The weakly associating nature of carbon dioxide leads to little difference in structural and interfacial dynamical properties for different pore sizes and pressures. Rather, the behavior is found to be dominated by the entropic effects, namely, how the CO 2 organizes next to the silica surface. The CO 2 self-diffusion coefficient shows the strongest pore size dependence. It is strongly diminished in small pores and does not reach the bulk fluid value even in 6 nm pores. It also decreases with pressure, yielding an activation volume that increases with pore size. These results provide new insight into the behavior of a compressible fluid in nanoscale confinement.

Godahewa, Sahan M. [Univ. of Kansas, Lawrence, KS ↗
DOE OSTI2025

Adaptive Interface-PINNs (AdaI-PINNs): An Efficient Physics-Informed Neural Networks Framework for Interface Problems

Here, we present an efficient physics-informed neural networks (PINNs) framework, termed Adaptive Interface-PINNs (AdaI-PINNs), to improve the modeling of interface problems with discontinuous coefficients and/or interfacial jumps. This framework is an enhanced version of its predecessor, Interface PINNs or I-PINNs (Sarma et al.; https://doi.org/10.1016/j.cma.2024.117135), which involves domain decomposition and assignment of different predefined activation functions to the neural networks in each subdomain across a sharp interface, while keeping all other parameters of the neural networks identical. In AdaI-PINNs, the activation functions vary solely in their slopes, which are trained along with the other parameters of the neural networks. This makes the AdaI-PINNs framework fully automated without requiring preset activation functions. Comparative studies on one-dimensional, two-dimensional, and three-dimensional benchmark elliptic interface problems reveal that AdaI-PINNs outperform I-PINNs, reducing computational costs by 2-6 times while producing similar or better accuracy.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS1977

Variations of temporal, spectral and angular radar backscattering coefficient of vegetation

Results of an experimental program is reviewed which over the past five years has succeeded in documenting the variations of the radar backscattering coefficient of a variety of crop types as a function of time, signal frequency (1-18 GHz), angular range (nadir to 80 deg) and polarization (HH, VV and HV). The systems were the microwave active spectrometers (MAS); one MAS system covers the 1-8 GHz band and the other system covers the 8-18 GHz band. Each MAS system was mounted on a mobile truck-mounted boom and was operated by a computer controller. To date, these two systems have acquired over 3 million data points from agricultural crops, bare ground and trees.

Ulaby, F. T.↗
NASA NTRS1977

Microwave remote sensing of hydrologic parameters

A perspective on the implementation of microwave sensors in future airborne and spaceborne observations of hydrologic parameters is presented. The rationale is based on a review of the status and future trends of active (radar) and passive (radiometer) microwave research as applied to the remote sensing of soil moisture content, snowpack water equivalent, freeze/thaw boundaries, lake ice thickness, surface water area, and the specification of watershed runoff coefficients. Analyses and observations based on data acquired from ground based, airborne and spaceborne platforms, and an evaluation of advantages and limitations of microwave sensors are included.

Ulaby, F. T.↗
NASA NTRS2021

Comparison of soil dielectric mixing models for Soil Moisture Retrieval using SMAP Brightness Temperature over croplands in India

The accurate estimation of soil moisture (SM) using microwave remote sensing depends mostly on careful selection of retrieval parameters among which the soil dielectric mixing model is the important one. These models are often categorized into empirical, semi-empirical or volumetric based on their methodologies and input data requirements. To study in detail, the comparative performance of four dielectric mixing models -- Wang & Schmugge model, Hallikainen model, Dobson model and Mironov model were used with Soil Moisture Active Passive (SMAP) L-band brightness temperature and Single Channel Algorithm for SM retrieval over agricultural landscapes in India. The highest performance statistics combination in terms of Root Mean Square Error (RMSE), correlation coefficient (R^(2)) and percentage bias (PBIAS) against the concurrent in-situ SM measurements were calculated at the selected validation sites. The overall results indicate that the best performance was given by the Mironov model (RMSE = 0.07 cu. m/cu. m), followed by Wang & Schmugge model (RMSE = 0.08 cu. m3/cu. m), Hallikainen model (RMSE = 0.09 cu. m/cu. m), Dobson model (RMSE = 0.10 cu. m/cu. m) and original SMAP radiometer SM (RMSE = 0.12 cu. m/cu. m). Findings of this study provides important insights into application and performance of dielectric mixing models in mapping surface SM variations. This study also underlines the pivotal role of local conditions for SM retrieval which should be carefully included in the algorithms.

Swati Suman↗
NASA NTRS1994

Experiment K-7-31: Studies of Vestibular Primary Afferents and Eye Movements in Normal, Hypergravity and Hypogravity - Axon Cosmos Flight 2044

Fourteen days of active head movements in microgravity appear to modify the gain and neural adaptation properties of the horizontal semicircular canals in the rhesus monkey. This is the first demonstration of adaptive plasticity in the sensory receptor. Reversing prisms, for example, do not modify the gain of the primary afferent response. Pulse yaw rotation, sinusoidal rotation, and sum of sinusoidal rotation testing during the first day following recovery revealed that the gain of a sample of afferents was significantly greater than the gain derived from afferent responses obtained during pre-flight and control monkey testing. There was no strong evidence of tilt sensitivity in the sample of afferents that we tested either during the pre-flight or control tests or during the first day post-flight. Two irregular afferents tested on postflight day 2 showed changes with tilt but the responses were not systematic. The spontaneous discharge did not change following flight. Mean firing rate and coefficient of variation remained constant during the post flight tests and was near the value measured during pre flight tests. The change in gain of horizontal canal afferents might be adaptive. The animals were required to look at a target for food. This required active head and eye movements. Active head movements have been shown to be hypometric and eye movements have been shown to be hypermetric during the first few days of past Cosmos flights (see introduction). It might be that the increased gain in the horizontal semicircular canals permit accurate target acquisition during hypometric head movements by driving the eyes to greater angles for smaller angles of head movement. The mechanism by which the semicircular canals recalibrate (increase their gain) is unknown. The efferent vestibular system is a logical candidate. Horizontal nystagmus during rotation about an earth vertical axis with the horizontal semicircular canals in the plane of rotation produced the same response during postflight day 1 and post-flight day 9. But when the head was pitched down 45? the nystagmus slow phase velocity was greater and the duration was about twice during post-flight day 1. Apparently, this response involving the interaction of the horizontal and vertical semicircular canals and the otoliths did not recalibrate during post-flight day 1. The 'DC' bias of the slow phase velocity of the horizontal nystagmus during constant velocity horizontal axis rotation was roughly 4 times for one flight monkey and roughly 2 times for the other on post-flight day 1 compared to post-flight day 9. These results suggest that the otolith mediated response during constant velocity rotation also did not recalibrate on post-flight day 1.

Correia, M. J.↗
NASA NTRS2021

JPSS-1 ATMS Post-launch Active Geolocation Analysis

A NOAA-20 (N20) ATMS active geolocation test was performed around Jan. 2018 with 24 pre-selected coastline crossing scenes. After comprehensive analysis of ATMS stare data and the corresponding VIIRS data, the ATMS pitch, roll and yaw pointing angle errors are found from the nadir perpendicular, the nadir oblique shallow angle, and the off-nadir perpendicular coastline crossing data, respectively. In this study, we first determine the ATMS radiometric coastline crossing time by using the ATMS radiometric count data. Since the coastline can be located anywhere within one ATMS FOV from the passive (regular scanning) geolocation data, depending on the scan starting time, it is not a valid assumption for the inflection point being the same as the coastline location. Consequently, using the passive geolocation data to validate the sensor’s on-orbit pointing angle performance is limited. After finding the ATMS radiometric coastline crossing time from the ATMS data, we compare it with the VIIRS effective time stamp (see main text). Specifically the VIIRS M3, M4 & M5 (true color) & M15 and M16 bands (thermal) data have a much smaller footprint size. Using the differences of the ATMS and VIIRS (effective) coastlines crossing times, the N20 ATMS pitch, roll and yaw pointing angle errors are found to be -0.09o, -0.24o and 0.28o, respectively. To determine ATMS geolocation properly, these on-orbit pointing errors need to be corrected, adding to the ATMS SDR Processing Coefficient Table, and passed on to the operational geolocation processing code.

Active Geolocation↗
DOE OSTI2023

Electrochemical Performance of Mixed Redox-Active Organic Molecules in Redox Flow Batteries

Designing electrolytes based on mixture of different organic redox active molecules brings the opportunity of enhancing the volumetric energy density of flow batteries and removes the requirement of high solubility for individual organic species in the mixture. Here, in the present work, we conduct computational and experimental analysis to investigate the electrochemical performance of mixed redox-active organic molecules. A zero-dimensional transient model is employed to investigate the changes in the half-cell potential and the concentrations and partial currents of individual redox reactions in a mixture of organic molecules over time. The model demonstrates the effects of individual properties of species such as kinetic rate constants, mass transfer coefficients, concentration ratios and standard redox potentials and reports the effect of energy-losing homogenous chemical redox reaction on the voltage efficiency and concentration ratios of the mixed species. Pairs of anthraquinone negolyte species were selected for an experimental case study. A mixture of 2,6-N-TSAQ and 2,6-DHAQ showed 40% increase in the volumetric energy density compared to the performance of 2,6-DHAQ alone. Based on the results of the experimental and computational analysis, we propose guidelines for the design of suitable mixed redox-active organic species.

25 ENERGY STORAGE↗
DOE OSTI2017

Pressure Induced Phase Transformations in Ceramics

The study of materials with unusual properties offers new insight into structure-property relations as well as promise for the design of novel composites. In this spirit, the PIs seek to (1) understand fundamental mechanical phenomena in ceramics that exhibit pressure-induced phase transitions, negative coefficient of thermal expansion (CTE), and negative compressibility, and (2) explore the effect of these phenomena on the mechanical behavior of composites designed with such ceramics. The broad and long-term goal is to learn how to utilize these unusual behaviors to obtain desired mechanical responses. While the results are expected to be widely applicable to many ceramics, most of the present focus is on silicates, as they exhibit remarkable diversity in structure and properties. Eucryptite, a lithium aluminum silicate (LiAlSiO 4 ), is specifically targeted because it exhibits a pressure-induced phase transition at a sufficiently low pressure to be accessible during conventional materials processing. Thus, composites with eucryptite may be designed to exhibit a novel type of transformation toughening. The PIs have performed a combination of activities that encompass synthesis and processing to control structures, atomistic modeling to predict and understand structures, and characterization to study mechanical behavior. Several materials behavior discoveries were made. It was discovered that small amounts of Zn (as small as 0.1 percent by mol) reverse the sign of the coefficient of thermal expansion of beta-eucryptite from negative to slightly positive. The presence of Zn also significantly mitigates microcracking that occurs during thermal cycling of eucryptite. It is hypothesized that Zn disrupts the Li ordering in beta-eucryptite, thereby altering the thermal expansion behavior. A nanoindentation technique developed to characterize incipient plasticity was applied to examine the initial stages of the pressure induced phase transformation from beta to epsilon-eucryptite and show that the transformation nucleation is related to the motion of the tetrahedral units making up the structure. It was revealed that the conduction of Li ions through the structure is also dictated by the tetrahedral unit arrangement and how their positions change with temperature. The critical pressure to obtain the high pressure phase of eucryptite was shown to depend on the grain size. The structure of the high pressure phase was determined with a combination of atomistic modeling and in situ x-ray diffraction experiments.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Active Recycling Control Through Lithium Injection in EAST

The coating of tokamak walls with thin layers of lithium has been demonstrated to reduce plasma recycling from the plasma-facing surfaces and to improve overall plasma performance. These effects, including reduced divertor D α emission, the elimination of edge-localized modes, and increased energy confinement have been observed in multiple experiments when lithium coatings are applied before plasma discharges. However, this coating technology does not extrapolate to future long-pulse devices, since the lithium coatings will be passivated by the continual plasma flux onto the surface. In order to provide active conditioning capability, a new technology has been developed that is capable of injecting lithium powder into the scrape-off layer plasma during plasma discharges, where it quickly liquefies and turns into an aerosol. The use of this “lithium dropper” is under study at the Experimental Advanced Superconducting Tokamak (EAST), where the potential benefits of real-time wall conditioning via lithium injection are being tested. Here, we present an analysis of the recycling characteristics during EAST experiments testing active lithium injection in order to assess recycling reduction and control. Lithium aerosol was injected from the top of the machine, with one system dropping lithium near the X-point and another into the low-field side divertor leg. The injection of lithium into the SOL reduced divertor recycling, as evidenced by reduced D α emission with ion flux measured by probes relatively unchanged. This effect is strongest in the active divertor, confirming the lithium is transported to strongly plasma-wetted areas. Furthermore, quantitative analysis of the recycling changes using the SOLPS edge plasma and neutral transport code indicated a ~20% reduction in recycling coefficient with lithium injection.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗