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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42

Material Compatibility Study of Coated Metals to Maintain Biocidal Silver in a Spacecraft Potable Water System

Ionic silver-based biocide is an option of strong interest for future exploration and has been baselined for several emerging spacecraft potable water systems. A challenge for the use of silver biocide remains the depletion of ionic silver on wetted materials of construction. Consequently, the design and/or selection of materials that can be used as the wetted system components need specific consideration. As part of the strategy to address this issue, a multitiered approach is being investigated that looks at combinations of conventional and non-conventional spacecraft treatment processes and materials. In this study, eleven chemically-resistant polymer coatings were applied as surface treatments onto coupons that were cut out from three types of conventional spacecraft-grade metals (Titanium Grade 2, Inconel 718, and 316L Stainless Steel). The coated metals were immersed in a static 400 parts per billion silver biocide solution at a surface-area-to-volume ratio of 2.0 cm^-1 and left to soak for predefined periods of time. The concentration of the solution in contact with the coated samples were then analyzed via inductively coupled plasma mass spectrometry, and the data used to determine the extent to which the coatings provided a barrier to silver loss. This paper summarizes the coating selection process, the configuration of the test, and the performance of each coating-metal combination as a mitigation to silver depletion. The preliminary results demonstrate that select coatings are proving effective at maintaining biocidal silver concentrations. The knowledge acquired through this investigation will be used to assess the feasibility of using these coatings as a robust strategy for maintaining biocidal silver in the water systems. Future studies are planned to assess the specific use of these coatings and to better understand the implications of utilizing this material approach in the future spacecraft potable water system designs.

coatings↗

Material Compatibility Study of Coated Metals to Maintain Biocidal Silver in a Spacecraft Potable Water System

Ionic silver-based biocide is an option of strong interest for future exploration and has been baselined for several emerging spacecraft potable water systems. A challenge for the use of silver biocide remains the depletion of ionic silver on wetted materials of construction. Consequently, the design and/or selection of materials that can be used as the wetted system components need specific consideration. As part of the strategy to address this issue, a multitiered approach is being investigated that looks at combinations of conventional and non-conventional spacecraft treatment processes and materials. In this study, eleven chemically-resistant polymer coatings were applied as surface treatments onto coupons that were cut out from three types of conventional spacecraft-grade metals (Titanium Grade 2, Inconel 718, and 316L Stainless Steel). The coated metals were immersed in a static 400 parts per billion silver biocide solution at a surface-area-to-volume ratio of 2.0 cm^-1 and left to soak for predefined periods of time. The concentration of the solution in contact with the coated samples were then analyzed via inductively coupled plasma mass spectrometry, and the data used to determine the extent to which the coatings provided a barrier to silver loss. This paper summarizes the coating selection process, the configuration of the test, and the performance of each coating-metal combination as a mitigation to silver depletion. The preliminary results demonstrate that select coatings are proving effective at maintaining biocidal silver concentrations. The knowledge acquired through this investigation will be used to assess the feasibility of using these coatings as a robust strategy for maintaining biocidal silver in the water systems. Future studies are planned to assess the specific use of these coatings and to better understand the implications of utilizing this material approach in the future spacecraft potable water system designs.

coatings↗

Strain Gage Selection Criteria for Textile Composite Materials

This report will provide a review of efforts to establish a set of strain gage selection guidelines for textile reinforced composite materials. A variety of strain gages were evaluated in the study to determine the sensitivity of strain measurements to the size of the strain gage. The strain gages were chosen to provide a range of gage lengths and widths. The gage aspect ratio (the length-to-width ratio) was also varied. The gages were tested on a diverse collection of textile composite laminates. Test specimens featured eleven different textile architectures: four 2-D triaxial braids, six 3-D weaves, and one stitched uniweave architecture. All specimens were loaded in uniaxial tension. The materials' moduli were measured in both the longitudinal (parallel to the O deg. yarns) and the transverse (perpendicular to the O deg. yarns) directions. The results of these measurements were analyzed to establish performance levels for extensometers and strain gages on textile composite materials. Conclusions are expressed in a summary that discusses instrumentation practices and defines strain gage selection criteria.

Masters, John E.↗

Lightweight Thermal-Protection System

Hexagonal honeycomb panels secured by Y-shaped plates form lightweight, easily-maintained thermal-protection system. Honeycomb outer panel and fastener materials are selected to match local heating rates. Typical materials include composites, titanium, superalloys, and refractory metals. Advantages include complete symmetry of components--there are no left- or right-hand parts and no asymmetry in thermal expansion.

Macconochie, I. O.↗

Response of composite materials to the Space Station orbit environment

The rationale for selecting composite materials with an anodized aluminum foil coating for the Space Station is presented. Data on the effects of the space service environment on these materials are given. Results are also presented on the effect of optical properties of an aluminum/aluminum oxide coating on the thermal balance of the cylindrical structural members. The resistance of this coating to solar ultraviolet degradation is discussed.

Tompkins, S. S.↗

Design and Control of a Proof-of-Concept Active Jet Engine Intake Using Shape Memory Alloy Actuators

The design and control of a novel proof-of-concept active jet engine intake using Nickel-Titanium (Ni-Ti or Nitinol) shape memory alloy (SMA) wire actuators is used to demonstrate the potential of an adaptive intake to improve the fuel efficiency of a jet engine. The Nitinol SMA material is selected for this research due to the material's ability to generate large strains of up to 5 percent for repeated operations, a high power-to-weight ratio, electrical resistive actuation, and easy fabrication into a variety of shapes. The proof-of-concept engine intake employs an overlapping leaf design arranged in a concentric configuration. Each leaf is mounted on a supporting bar that rotates upon actuation by SMA wires electrical resistive heating. Feedback control is enabled through the use of a laser range sensor to detect the movement of a leaf and determine the radius of the intake area. Due to the hysteresis behavior inherent in SMAs, a nonlinear robust controller is used to direct the SMA wire actuation. The controller design utilizes the sliding-mode approach to compensate for the nonlinearities associated with the SMA actuator. Feedback control experiments conducted on a fabricated proof-of-concept model have demonstrated the capability to precisely control the intake area and achieve up to a 25 percent reduction in intake area. The experiments demonstrate the feasibility of engine intake area control using the proposed design.

Song, Gangbing↗

Real-Time Simulation of Aeroheating of the Hyper-X Airplane

A capability for real-time computational simulation of aeroheating has been developed in support of the Hyper-X program, which is directed toward demonstrating the feasibility of operating an air-breathing ramjet/scramjet engine at mach 5, mach 7, and mach 10. The simulation software will serve as a valuable design tool for initial trajectory studies in which aerodynamic heating is expected to exert a major influence in the design of the Hyper-X airplane; this tool will aid in the selection of materials, sizing of structural skin thicknesses, and selection of components of a thermal-protection system (TPS) for structures that must be insulated against aeroheating.

Gong, Les↗

Material Compatibility with Space Storable Propellants. Design Guidebook

An important consideration in the design of spacecraft for interplanetary missions is the compatibility of storage materials with the propellants. Serious problems can arise because many propellants are either extremely reactive or subject to catalytic decomposition, making the selection of proper materials of construction for propellant containment and control a critical requirement for the long-life applications. To aid in selecting materials and designing and evaluating various propulsion subsystems, available information on the compatibility of spacecraft materials with propellants of interest was compiled from literature searches and personal contacts. The compatibility of both metals and nonmetals with hydrazine, monomethyl hydrazine, nitrated hydrazine, and diborance fuels and nitrogen tetroxide, fluorine, oxygen difluoride, and Flox oxidizers was surveyed. These fuels and oxidizers encompass the wide variety of problems encountered in propellant storage. As such, they present worst case situations of the propellant affecting the material and the material affecting the propellant. This includes material attack, propellant decomposition, and the formation of clogging materials.

Uney, P. E.↗

Materials testing for spacecraft use

A technique has been developed for determining the outgassing characteristics of materials intended for spacecraft use. A measurement of the total mass loss (TML) and of the collected volatile condensable materials (CVCM) is used as a guide for selecting those materials low in outgassing. The data were used to compare the outgassing from two conductive black paints. In addition, the apparatus was also used in an attempt to simulate expected launch temperatures by collecting the outgassed molecules on a glass plate, which simulates a nearby thermal control surface. The glass plate was then irradiated in vacuum by simulated sunlight. Transmittance patterns of the clean glass plate and also with the condensed material on it were compared with the transmittance pattern after irradiation of the condensate. The transmittance patterns showed a drastic change. The resultant discoloration indicated the detrimental effects of the contamination and aided in selecting the better conductive paint. Additional tests utilizing an aluminized mirror collector plate have been run to show the effect of irradiation upon the CVCM from certain different classes of materials often used on spacecraft.

Park, J. J.↗

Conversion of type of quantum well structure

A method for converting a Type 2 quantum well semiconductor material to a Type 1 material. A second layer of undoped material is placed between first and third layers of selectively doped material, which are separated from the second layer by undoped layers having small widths. Doping profiles are chosen so that a first electrical potential increment across a first layer-second layer interface is equal to a first selected value and/or a second electrical potential increment across a second layer-third layer interface is equal to a second selected value. The semiconductor structure thus produced is useful as a laser material and as an incident light detector material in various wavelength regions, such as a mid-infrared region.

Ning, Cun-Zheng↗

Conversion of Type of Quantum Well Structure

A method for converting a Type 2 quantum well semiconductor material to a Type 1 material. A second layer of undoped material is placed between first and third layers of selectively doped material, which are separated from the second layer by undoped layers having small widths. Doping profiles are chosen so that a first electrical potential increment across a first layer-second layer interface is equal to a first selected value and/or a second electrical potential increment across a second layer-third layer interface is equal to a second selected value. The semiconductor structure thus produced is useful as a laser material and as an incident light detector material in various wavelength regions, such as a mid-infrared region.

Ning, Cun-Zheng↗

Energy absorption of composite materials

Results of a study on the energy absorption characteristics of selected composite material systems are presented and the results compared with aluminum. Composite compression tube specimens were fabricated with both tape and woven fabric prepreg using graphite/epoxy (Gr/E), Kevlar (TM)/epoxy (K/E) and glass/epoxy (Gl/E). Chamfering and notching one end of the composite tube specimen reduced the peak load at initial failure without altering the sustained crushing load, and prevented catastrophic failure. Static compression and vertical impact tests were performed on 128 tubes. The results varied significantly as a function of material type and ply orientation. In general, the Gr/E tubes absorbed more energy than the Gl/E or K/E tubes for the same ply orientation. The 0/ + or - 15 Gr/E tubes absorbed more energy than the aluminum tubes. Gr/E and Gl/E tubes failed in a brittle mode and had negligible post crushing integrity, whereas the K/E tubes failed in an accordian buckling mode similar to the aluminum tubes. The energy absorption and post crushing integrity of hybrid composite tubes were not significantly better than that of the single material tubes.

Farley, G. L.↗

Preventing Chemical-Vapor Deposition In Selected Areas

Method for prevention of chemical-vapor deposition of material in selected areas developed. Gas shroud isolates specific area from rest of deposition system. Inert gas flowing from beneath substrate prevents deposition between substrate and outer ring. Method extremely successful in selective deposition of SiC in chemical-vapor-deposition reactor. Used in deposition of SiC mirror blanks in Large Mirror Substrate and Lidar Mirror programs. Critical element in overall chemical-vapor-deposition process for producing large, lightweight mirrors.

Keeley, Joseph T.↗

Subcritical crack growth of selected aerospace pressure vessel materials

This experimental program was undertaken to determine the effects of combined cyclic/sustained loads, stress level, and crack shape on the fatigue crack growth rate behavior of cracks subjected to plane strain conditions. Material/environment combinations tested included: 2219-T87 aluminum plate in gaseous helium, room air, and 3.5% NaCl solution at room temperature, liquid nitrogen, and liquid hydrogen; 5Al-2.5 Sn (ELI) titanium plate in liquid nitrogen and liquid hydrogen and 6AL-4V (ELI) STA titanium plate in gaseous helium and methanol at room temperature. Most testing was accomplished using surface flawed specimens instrumented with a clip gage to continuously monitor crack opening displacements at the specimen surface. Tapered double cantilever beam specimens were also tested. Static fracture and ten hour sustained load tests were conducted to determine fracture toughness and apparent threshold stress intensity values. Cyclic tests were performed using sinusoidal loading profiles at 333 MHz (20 cpm) and trapezoidal loading profiles at both 8.3 MHz (0.5 cpm) and 3.3 MHz (0.2 cpm). Data were evaluated using modified linear elastic fracture mechanics parameters.

Hall, L. R.↗

Emission spectra of selected SSME elements and materials

Stennis Space Center (SSC) is pursuing the advancement of experimental techniques and theoretical developments in the field of plume spectroscopy for application to rocket development testing programs and engine health monitoring. Exhaust plume spectral data for the Space Shuttle Main Engine (SSME) are routinely acquired. The usefulness of this data depends upon qualitative and quantitative interpretation of spectral features and their correlation with the engine performance. A knowledge of the emission spectral characteristics of effluent materials in the exhaust plume is essential. A study of SSME critical components and their materials identified 30 elements and 53 materials whose engine exhaust plume spectral might be required. The most important were evaluated using SSC's Diagnostic Testbed Facility Thruster (DTFT), a 1200-lbf, liquid oxygen/gaseous hydrogen rocket engine which very nearly replicates the temperature and pressure conditions of the SSME exhaust plume in the first Mach diamond. This report presents the spectral data for the 10 most important elements and 27 most important materials which are strongly to moderately emitting in the DTFT exhaust plume. The covered spectral range is 300 to 426 nm and the spectral resolution is 0.25 nm. Spectral line identification information is provided and line interference effects are considered.

Tejwani, Gopal D.↗