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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42

Ringing Artifact Reduction Method for Ultrasound Reconstruction Using Multi-Agent Consensus Equilibrium

Non-destructive characterization of multi-layered structures that can be accessed from only a single side is important for applications such as well-bore integrity inspection. Existing methods related to Synthetic Aperture Focusing Technique (SAFT) rapidly produce acceptable results but with significant artifacts. Recently, ultrasound model-based iterative reconstruction (UMBIR) approaches have shown significant improvements over SAFT. However, even these methods produce ringing artifacts due to the high fractional-bandwidth of the excitation signal.In this paper, we propose a ringing artifact reduction method for ultrasound image reconstruction that uses a multi-agent consensus equilibrium (RARE-MACE) framework. Our approach integrates a physics-based forward model that accounts for the propagation of a collimated ultrasonic beam in multi-layered media, a spatially varying image prior, and a denoiser designed to suppress the ringing artifacts that are characteristic of reconstructions from high-fractional bandwidth ultrasound sensor data. We test our method on simulated and experimental measurements and show substantial improvements in image quality compared to SAFT and UMBIR.

Alanazi, Abdulrahman M↗

A daily, 250 m and real-time gross primary productivity product (2000–present) covering the contiguous United States

Abstract. Gross primary productivity (GPP) quantifies the amount of carbon dioxide (CO2) fixed by plants through photosynthesis. Although as a key quantity of terrestrial ecosystems, there is a lack of high-spatial-and-temporal-resolution, real-time and observation-based GPP products. To address this critical gap, here we leverage a state-of-the-art vegetation index, near-infrared reflectance of vegetation (NIRV), along with accurate photosynthetically active radiation (PAR), to produce a SatelLite Only Photosynthesis Estimation (SLOPE) GPP product for the contiguous United States (CONUS). Compared to existing GPP products, the proposed SLOPE product is advanced in its spatial resolution (250 m versus >500 m), temporal resolution (daily versus 8 d), instantaneity (latency of 1 d versus >2 weeks) and quantitative uncertainty (on a per-pixel and daily basis versus no uncertainty information available). These characteristics are achieved because of several technical innovations employed in this study: (1) SLOPE couples machine learning models with MODIS atmosphere and land products to accurately estimate PAR. (2) SLOPE couples highly efficient and pragmatic gap-filling and filtering algorithms with surface reflectance acquired by both Terra and Aqua MODIS satellites to derive a soil-adjusted NIRV (SANIRV) dataset. (3) SLOPE couples a temporal pattern recognition approach with a long-term Cropland Data Layer (CDL) product to predict dynamic C4 crop fraction. Through developing a parsimonious model with only two slope parameters, the proposed SLOPE product explains 85 % of the spatial and temporal variations in GPP acquired from 49 AmeriFlux eddy-covariance sites (324 site years), with a root-mean-square error (RMSE) of 1.63 gC m−2 d−1. The median R2 over C3 and C4 crop sites reaches 0.87 and 0.94, respectively, indicating great potentials for monitoring crops, in particular bioenergy crops, at the field level. With such a satisfactory performance and its distinct characteristics in spatiotemporal resolution and instantaneity, the proposed SLOPE GPP product is promising for biological and environmental research, carbon cycle research, and a broad range of real-time applications at the regional scale. The archived dataset is available at https://doi.org/10.3334/ORNLDAAC/1786 (download page: https://daac.ornl.gov/daacdata/cms/SLOPE_GPP_CONUS/data/, last access: 20 January 2021) (Jiang and Guan, 2020), and the real-time dataset is available upon request.

54 ENVIRONMENTAL SCIENCES↗

Integrating Earth Observations and Socioeconomic Data to Address Health, Equity, and Environmental Justice

Access to reliable data about the characteristics of populations is a crucial component of decision making, policy development, and the assessment of progress towards strategic goals. Social determinants of health provide insight into the status of social and economic conditions within populations that have profound effects on public health, equity, and vulnerability. International frameworks such as the Sustainable Development Goals (SDGs) fundamentally focus on equality, but to efficiently address targets and indicators, socioeconomic data and Earth observations must be integrated to help identify populations most vulnerable to the impacts of climate change, natural disasters, health disparities, and poor policy planning. The ability to identify vulnerable populations with data analysis has the potential to empower community stakeholders with spatial awareness needed to inform decision-making that addresses equity and environmental justice issues within their communities. The EPA defines environmental justice (EJ) as “the fair treatment and meaningful involvement of all people regardless of race, color, national origin, or income with respect to the development, implementation and enforcement of environmental laws, regulations and policies.” NASA’s Earth Science Division (ESD) recognizes the benefits that Earth observations with NASA satellites create by equipping individuals with the knowledge to address community challenges. NASA’s Socioeconomic Data and Applications Center (SEDAC) supports the integration of socioeconomic and Earth science data as an “informational gateway.” This integration of data is advancing health, equity, and environmental justice initiatives.

Natasha Johnson-Griffin↗

Geospatial Information, Metadata, and Maps for Global River Corridor Science Focus Area Sites (v5)

This dataset provides geospatial information, metadata, and maps for the Pacific Northwest National Laboratory (PNNL) River Corridor Science Focus Area (RC-SFA; https://www.pnnl.gov/projects/river-corridor) sites. The RC-SFA works to transform understanding of spatial and temporal dynamics in river corridor hydrobiogeochemical functions from molecular reaction to watershed and basin scales. The knowledge we gain is used to formulate and test hypotheses and to improve mechanistic representation of river corridor processes and their response to disturbances in multiscale models of integrated hydrobiogeochemical function. The data provided includes Site ID, latitude, longitude, stream name, and common ID (COMID) for sites used across the RC-SFA. The COMID can be used to find and download data from NHDPlus (https://www.epa.gov/waterdata/nhdplus-national-hydrography-dataset-plus) and other platforms. The sites included are non-exhaustive. Sites (including past sites) will be added to this data package in the future. Data generated from the RC SFA can be accessed at https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA. This data package was originally published in April 2023. It was updated in June 2023 (v2; modified files), December 2023 (v3; modified files), January 2025 (v4; modified files), and December 2025 (v5; modified files). See the change history section in the readme for more details. This dataset is comprised of one main data folder. The data folder consists of (1) file-level metadata; (2) data dictionary; (3) readme; (4) methods codes; (5) geospatial information for all RC SFA sites including International Generic Sample Number (IGSN); (6) maps of all sites and sites in Washington State, USA; and (7) a subfolder with the shapefile of all sites. All files are .csv, .pdf, .shp, .cpg, .dbf, .prj, .qmd, or .shx. We thank the Confederated Tribes and Bands of the Yakama Nation for access to field locations where some data were collected in Washington state. We also thank the Yakama Nation Tribal Council and Yakama Nation Fisheries for working with us to facilitate sample collection and optimization of data usage according to their values and worldview.

54 ENVIRONMENTAL SCIENCES↗

Overview of the Third Convection and Moisture EXperiment (CAMEX-3)

The Convection And Moisture EXperiment (CAMEX) is a series of field research investigations sponsored by the National Aeronautics and Space Administration (NASA). The third field campaign in the CAMEX series (CAMEX-3) is scheduled for 6 August - 23 September, 1998 to study tropical cyclone development, tracking, intensification, and landfalling impacts using NASA-funded aircraft remote sensing instrumentation. This study will yield high spatial and temporal information of hurricane structure, dynamics, and motion. These data, when analyzed within the context of more traditional aircraft, satellite, and ground-based radar observations, should provide additional insight to hurricane modelers and forecasters who continually strive to improve hurricane predictions. During CAMEX-3, NASA will deploy a high attitude ER-2 and medium altitude DC-8 aircraft from Patrick Air Force Base, Florida. Ground-based instrumentation will also be stationed on Andros Island, Bahamas. Opportunities for coordinated aircraft missions with the National Oceanic and Atmospheric Administration (NOAA) Hurricane Research Division are also being planned. This presentation will provide an overview of the CAMEX-3 missions and key case studies sampled. Data availability and access will also be discussed.

Hood, Robbie↗

Deciphering the Evolution of Current Distribution in Hybrid Silver Vanadium Oxide / Carbon Monofluoride Cathodes within Lithium Primary Batteries

For batteries to function effectively all active material must be accessible requiring both electron and ion transport to each particle. A common approach to generating the needed conductive network is the addition of carbon to create a composite electrode. An alternative approach is the electrochemically induced formation of conductive reaction products where the electrochemically generated materials are in intimate contact with the active material contributing to effective connection of each active particle. Furthermore, this study probes silver vanadium oxide (Ag 2 V 4 O 11 , SVO), carbon monofluoride (CF x ), and hybrid SVO/CF x electrodes in lithium batteries. Ex situ XRD identifies Ag 0 as a reduction product from SVO and LiF from CF x that can be followed as a function of depth-of-discharge (DOD). Spatially-resolved operando energy dispersive x-ray diffraction reveals that the presence of SVO alleviates reaction heterogeneity in the electrodes which are electron transfer limited in the absence of sufficient Ag 0 . Synchrotron X-ray tomography on discharged cathodes reveals the distribution of silver particles where the particles are more closely spaced near the current collector indicating multiple nucleation sites for their formation. Finally, operando isothermal microcalorimetry is used to determine the heat dissipation of the parent and hybrid battery types. Using material enthalpy potentials, we determine the current distribution between the two active materials for the discharging hybrid cathode adding further insight to the diffraction analysis. Taken together, these results provide a comprehensive understanding of hybrid SVO/CF x cathodes and give guidance on optimal compositions that balance power and energy density considerations.

36 MATERIALS SCIENCE↗

High-order matrix-free incompressible flow solvers with GPU acceleration and low-order refined preconditioners

In this work, we present a matrix-free flow solver for high-order finite element discretizations of the incompressible Navier-Stokes and Stokes equations with GPU acceleration. For high polynomial degrees, assembling the matrix for the linear systems resulting from the finite element discretization can be prohibitively expensive, both in terms of computational complexity and memory. For this reason, it is necessary to develop matrix-free operators and preconditioners, which can be used to efficiently solve these linear systems without access to the matrix entries themselves. The matrix-free operator evaluations utilize GPU-accelerated sum-factorization techniques to minimize memory movement and maximize throughput. The preconditioners developed in this work are based on a low-order refined methodology with parallel subspace corrections, as described for diffusion problems in [1]. The saddle-point Stokes system is solved using block-preconditioning techniques, which are robust in mesh size, polynomial degree, time step, and viscosity. For the incompressible Navier-Stokes equations, we make use of projection (fractional step) methods, which require Helmholtz and Poisson solves at each time step. The performance of our flow solvers is assessed on several benchmark problems in two and three spatial dimensions.

97 MATHEMATICS AND COMPUTING↗

An Update on the Hydrological Land Surface Data and Services at NASA GES DISC

"The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) is one of twelve NASA Earth Observing System data centers that document, process, archive and distribute data from Earth science missions and related projects. The GES DISC hosts many hydrological land surface data products including North American Land Data Assimilation System (NLDAS), Global Land Data Assimilation System (GLDAS), the Famine Early Warning Systems Network (FEWS NET) Land Data Assimilation System (FLDAS), and assimilated-Gravity Recovery and Climate Experiment (GRACE). The Land Surface Model (LSM) products contain model output, including heat fluxes, rain, snow, soil temperature, soil moisture and runoff; and observational forcing data, including surface pressure, temperature, precipitation, downward shortwave and longwave radiation, humidity, and wind. The temporal resolution of the hydrology data at the GES DISC ranges from hourly to monthly and the spatial resolution 0.1 degree to 1.0 degree. The variability of Earth’s water and energy cycles can be characterized with these spatially and temporally consistent, and quality controlled hydrological land surface data. These data could support ongoing modeling activities, and help improve our understanding of land-surface-atmosphere interactions and their impact on climate. Over the years, new data is added, and older data is reprocessed and updated. This presentation provides a summary table of the hydrological data and discusses recent updates to the data and data services at the GES DISC. New data products include (1) GRACE Global Version 3.0 drought indicators and (2) FLDAS monthly global and Central Asia daily data. Reprocessed and updated products include (1) NLDAS Version 2.0 and (2) GRACE United States Version 4.0 drought indicators. Lastly, this presentation will discuss the opportunities for accessing some of our hydrology data from the cloud. As the hydrology land surface data is moved to the cloud, users can expect faster service for longer time series, notably the hydrology data rods time series service."

Ashley Heath↗

Quantifying transport and electrocatalytic reaction processes in a gastight rotating cylinder electrode reactor via integration of Computational Fluid Dynamics modeling and experiments

Understanding the complexity of the multiple processes of mass, momentum, charge, and heat transport, and how these affect reaction kinetics at the electrode/electrolyte interface is one of the major challenges in the field of energy and catalysis. The rapid and rational scale-up of electrocatalytic systems to industrial scales require a detailed understanding of nonlinear transport-reaction processes, accessible only through the building of multi-physics models that capture with high fidelity the complexity of real-world devices. The gastight rotating cylinder electrode (RCE) reactor is a promising lab-scale tool that can decouple transport from intrinsic kinetics to generate data for first-principle models useful in the design of industrial, electrochemical reactors. Computational Fluid Dynamics (CFD) studies have previously been used to investigate the bulk flow in RCE reactors for simple corrosion and electroplating processes. However, the quantification of changes in local concentration within the viscous layer where catalysis takes place requires capturing the correct flow conditions inside the hydrodynamic boundary layer near the surface of the electrode. Further, this requires simulations with spatial resolution in the nm and μm scale and temporal resolutions between ms and s scales that are similar to the timescales for reactions on the electrode surface. In this study, experimental electrocatalysis is combined with CFD modeling to elucidate and parameterize the hydrodynamics in a gastight RCE reactor. CFD simulations of the electrochemical ferricyanide reduction reaction under mass transport limited conditions are used to evaluate the validity of the CFD model parameters by comparing calculated dimensionless mass transport descriptors to dimensionless correlations obtained experimentally. Justifications for assumptions and details of the simulation methods used in this study are presented to provide a detailed understanding of the effect that each model parameter has on the ability to accurately simulate electrocatalysis in RCE systems. The simulation methodology reported here is a first step towards the development of multi-scale models for the study of transport dependent electrocatalytic processes, such as the electrochemical transformation of CO 2 to fuels and chemicals.

42 ENGINEERING↗

Co-designing Spectral Transformation Oracles with Hybrid Oscillator-Qubit Quantum Processors: From Algorithms to Compilation

We co-design a family of quantum eigenvalue transformation oracles that can be efficiently implemented on hybrid discrete- or continuous-variable (qubit or qumode) hardware. To illustrate the oracle’s representation-theoretic power and near-term experimental accessibility, we encode a Gaussian imaginary time-evolution spectral filter. As a result, we define a continuous linear combination of unitaries block encoding. Due to the ancillary qumode’s infinite-dimensional nature, continuous-variable qumodes constitute a powerful compilation tool for encoding continuous spectral functions without discretization errors while minimizing resource requirements. We then focus on the ubiquitous task of preparing eigenstates in quantum spin models. For completeness, we provide an end-to-end compilation which expresses high-level oracles in terms of an experimentally realizable instruction set architecture in both 1D and 2D. Finally, we examine the leading-order effects of physical errors and highlight open research directions. Our algorithms scale linearly with the spatial extent of the target system and are applicable to both near-term and large-scale quantum processors.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

MISR Browse data (MISBR_V5)

A MISR Browse Tool is available to allow easy access to ellipsoid-derived, true-color images for each camera reduced to 2.2 km resolution. The MISR red, green and blue bands are used to create the true-color image in JPEG format. The image is intentionally clipped and gamma-stretched to make cloud, ocean and land features visible. The user may find the Browse Tool helpful before ordering data. The tool's purpose is to search and view images in the on-line user interface. However, the browse product can be ordered separately. The Browse Tool page has Orbit-to-Date and Lat/Lon-to-Path/Block conversion tools to help identify particular MISR geographic locations and data files. [Temporal_Coverage: Start_Date=2000-02-24; Stop_Date=] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=180] [Data_Resolution: Latitude_Resolution=2.2 km; Longitude_Resolution=2.2 km; Horizontal_Resolution_Range=1 km - < 10 km or approximately .01 degree - < .09 degree; Temporal_Resolution=about 15 orbits/day; Temporal_Resolution_Range=Daily - < Weekly].

EOSDIS↗

A Living Catalog of Stream Interaction Regions in the Parker Solar Probe Era

Stream interaction regions (SIRs) and corotating interaction regions (CIRs) are important phenomena in heliospheric physics. These large-scale structures vary temporally and spatially, both in latitude and with radial distance. The additions of Parker Solar Probe(PSP) and Solar Orbiter have allowed for investigations into the radial evolution of these structures over a wide range of heliocentric distances for the first time since the Helios era. To better enable investigations of SIRs and CIRs within the inner heliosphere, we have developed a living catalog of SIR and CIR observations by Parker Solar Probe with corresponding observations by STEREO-A as well as ACE and Wind at 1 au. The methodology used for the identification of events and the generation of this catalog, the initial catalog of PSP observations spanning orbits one through five along with corresponding 1 au observations, and information on accessing the living catalog for future studies is described. This list of SIR and CIR events from PSP and corresponding observations from other heliophysics missions will enable case studies utilizing unique orbital arrangements, as well as aid in future statistical studies to further understand the properties and evolution of these structures.

Catalogs↗

Towards Spatial Control of Reaction Selectivity on Photocatalysts using Area Selective Atomic Layer Deposition on Model Dual Site Electrocatalyst Platform

Photocatalytic water splitting is a promising route to low-cost H2; however, this approach is currently limited by solar-to-hydrogen (STH) conversion efficiencies in the sub-10% range. Z-scheme water splitting, in which H2 and O2 evolving particles are operated in separate compartments and electronically coupled by a soluble redox mediator, offers improvements in STH efficiency but introduces high rates of undesired side and back reactions. Nanoscopic oxide coatings (e.g., CrOx, and SiOx) have previously been used to selectively block undesired reactants from reaching active sites; however, a coating encapsulating the entire photocatalyst particle limits activity as the particle can no longer facilitate both half reactions. In contrast to photodeposition, which may produce non-uniform overlayers due to the difficulty of controlling local electrochemical reactivity on the surface, area-selective atomic layer deposition (AS-ALD) can be used to deposit conformal ultrathin oxide coatings while preserving access to non-growth areas of a substrate surface. To develop this technique for Z-scheme photocatalysts, we performed AS-ALD of TiO2 on a dual site planar electrocatalyst based on interdigitated arrays of Pt and Au. Self-assembled monolayers of 1-octadecanethiol (ODT) were used to block growth on the Au array, resulting in a patterned surface in which only the Pt sites were encapsulated with TiO2. These electrocatalysts demonstrated localized reaction selectivity for hydrogen evolution reaction (HER) over the TiO2/Pt sites, while the uncoated Au sites retained activity towards Fe(II)/Fe(III) redox (FeRR). Under independent potential control, these microelectrodes showed that selectively deposited TiO2 coatings can suppress the rate of back reactions on neighboring active sites by an order of magnitude compared to uncoated control samples.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Effect of Spatially Varying Collision Frequency on the Development of the Rayleigh–Taylor Instability

Abstract The Rayleigh–Taylor (RT) instability is ubiquitously observed, yet has traditionally been studied using ideal fluid models. Collisionality can vary strongly across the fluid interface, and previous work demonstrates the necessity of kinetic models to completely capture dynamics in certain collisional regimes. Where previous kinetic simulations used spatially and temporally constant collision frequency, this work presents five-dimensional (two spatial, three velocity dimensions) continuum-kinetic simulations of the RT instability using a more realistic spatially varying collision frequency. Three cases of collisional variation are explored for two Atwood numbers: low to intermediate, intermediate to high, and low to high. The low-to-intermediate case exhibits no RT instability growth, while the intermediate-to-high case is similar to a fluid-limit kinetic case with interface widening biased toward the lower-collisionality region. A novel contribution of this work is the low-to-high collisionality case that shows significantly altered instability growth through an upward movement of the interface and damped spike growth due to increased free-streaming particle diffusion in the lower region. Contributions to the energy flux from the non-Maxwellian portions of the distribution function are not accessible to fluid models and are greatest in magnitude in the spike and regions of low collisionality. Increasing the Atwood number results in greater RT instability growth and reduced upward interface movement. Deviation of the distribution function from Maxwellian is inversely proportional to collision frequency and concentrated around the fluid interface. The linear phase of RT instability growth is well described by theoretical linear growth rates accounting for viscosity and diffusion.

79 ASTRONOMY AND ASTROPHYSICS↗

Single-Chip FPGA Azimuth Pre-Filter for SAR

A field-programmable gate array (FPGA) on a single lightweight, low-power integrated-circuit chip has been developed to implement an azimuth pre-filter (AzPF) for a synthetic-aperture radar (SAR) system. The AzPF is needed to enable more efficient use of data-transmission and data-processing resources: In broad terms, the AzPF reduces the volume of SAR data by effectively reducing the azimuth resolution, without loss of range resolution, during times when end users are willing to accept lower azimuth resolution as the price of rapid access to SAR imagery. The data-reduction factor is selectable at a decimation factor, M, of 2, 4, 8, 16, or 32 so that users can trade resolution against processing and transmission delays. In principle, azimuth filtering could be performed in the frequency domain by use of fast-Fourier-transform processors. However, in the AzPF, azimuth filtering is performed in the time domain by use of finite-impulse-response filters. The reason for choosing the time-domain approach over the frequency-domain approach is that the time-domain approach demands less memory and a lower memory-access rate. The AzPF operates on the raw digitized SAR data. The AzPF includes a digital in-phase/quadrature (I/Q) demodulator. In general, an I/Q demodulator effects a complex down-conversion of its input signal followed by low-pass filtering, which eliminates undesired sidebands. In the AzPF case, the I/Q demodulator takes offset video range echo data to the complex baseband domain, ensuring preservation of signal phase through the azimuth pre-filtering process. In general, in an SAR I/Q demodulator, the intermediate frequency (fI) is chosen to be a quarter of the range-sampling frequency and the pulse-repetition frequency (fPR) is chosen to be a multiple of fI. The AzPF also includes a polyphase spatial-domain pre-filter comprising four weighted integrate-and-dump filters with programmable decimation factors and overlapping phases. To prevent aliasing of signals, the bandwidth of the AzPF is made 80 percent of fPR/M. The choice of four as the number of overlapping phases is justified by prior research in which it was shown that a filter of length 4M can effect an acceptable transfer function. The figure depicts prototype hardware comprising the AzPF and ancillary electronic circuits. The hardware was found to satisfy performance requirements in real-time tests at a sampling rate of 100 MHz.

Gudim, Mimi↗

MISR Browse data (MISBR_V3)

A MISR Browse Tool is available to allow easy access to ellipsoid-derived, true-color images for each camera reduced to 2.2 km resolution. The MISR red, green and blue bands are used to create the true-color image in JPEG format. The image is intentionally clipped and gamma-stretched to make cloud, ocean and land features visible. The user may find the Browse Tool helpful before ordering data. The tool's purpose is to search and view images in the on-line user interface. However, the browse product can be ordered separately. The Browse Tool page has Orbit-to-Date and Lat/Lon-to-Path/Block conversion tools to help identify particular MISR geographic locations and data files. [Location=GLOBAL] [Temporal_Coverage: Start_Date=2000-02-24; Stop_Date=] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=180] [Data_Resolution: Latitude_Resolution=2.2 km; Longitude_Resolution=2.2 km; Horizontal_Resolution_Range=1 km - < 10 km or approximately .01 degree - < .09 degree; Temporal_Resolution=about 15 orbits/day; Temporal_Resolution_Range=Daily - < Weekly].

EOSDIS↗

MISR Browse data (MISBR_V4)

A MISR Browse Tool is available to allow easy access to ellipsoid-derived, true-color images for each camera reduced to 2.2 km resolution. The MISR red, green and blue bands are used to create the true-color image in JPEG format. The image is intentionally clipped and gamma-stretched to make cloud, ocean and land features visible. The user may find the Browse Tool helpful before ordering data. The tool's purpose is to search and view images in the on-line user interface. However, the browse product can be ordered separately. The Browse Tool page has Orbit-to-Date and Lat/Lon-to-Path/Block conversion tools to help identify particular MISR geographic locations and data files. [Location=GLOBAL] [Temporal_Coverage: Start_Date=2000-02-24; Stop_Date=] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=180] [Data_Resolution: Latitude_Resolution=2.2 km; Longitude_Resolution=2.2 km; Horizontal_Resolution_Range=1 km - < 10 km or approximately .01 degree - < .09 degree; Temporal_Resolution=about 15 orbits/day; Temporal_Resolution_Range=Daily - < Weekly].

IMAGE↗

Quantitative Effects of Disorder on Chemically Modified Amorphous Carbon Electrodes

Real materials are disordered. This disorder influences the properties of these materials and the chemical processes that occur at their interfaces. Gaining a molecular-level understanding of the underlying physical manifestations caused by disordered materials is crucial to unraveling and ultimately controlling the efficiency and performance of these materials in a range of energy-related devices. This understanding necessitates measurement techniques through which disorder can be detected, quantified, and monitored. However, such quantitative measurements are notoriously difficult, as effects often average out in ensemble measurements. In this work, we describe how a combination of electrochemical and spatially resolved surface spectroscopy measurements illuminate a molecular-level picture of disorder in materials. Using amorphous carbon as an intrinsically disordered material, we covalently attached a monolayer of ferrocene. Interfacial electron transfer across the amorphous carbon–ferrocene interface is highly sensitive to disruptions of order. Here, by systematically varying linker properties and surface loadings, the influence of lateral interactions between nonuniformly distributed ferrocene headgroups on ensemble electrochemical measurements is demonstrated. Electrochemical and imaging data collectively indicate that conformational flexibility of the ferrocene moieties provides a mechanism to elude repulsive and unbalanced lateral interactions, while rigid linkages provide direct information about the underlying disorder of the material. This study is the first of its kind to quantify and visualize molecular disorder and heterogeneity with an experimental model accessed through ensemble measurements.

36 MATERIALS SCIENCE↗