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All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

Subsurface Sampling and Sensing Using Burrowing Moles

Finding evidence for life on Mars will likely require accessing the subsurface since the Martian surface is both hostile to life and to preservation of biosignatures due to the cold dry conditions, the strong W environment, and the presence of strong oxidants. Systems are needed to probe beneath the sun and oxidant baked surface of Mars and return samples to the surface for analysis or to bring the instrument sensing underground. Recognizing this need, the European Space Agency incorporated a small subsurface penetrometer or Mole onto the Beagle 2 Mars lander. Had the 2003 landing been successful, the Mole would have collected samples from 1-1.5 m depth and delivered them to an organic analysis instrument on the surface. The de- vice called the Planetary Underground Tool (PLUTO), also measured soil mechanical and thermophysical properties. Constrained by the small mass and volume allowance of the Beagle lander, the PLUTO mole was a slender cylinder only 2 cm diameter and 28 cm long equipped with a small sampling device designed to collect samples and bring them to the surface for analysis by other instrument. The mass of the entire system including deployment mechanism and tether was 1/2 kg. sensor package underground to make in situ measurements. The Mars Underground Mole (MUM) is a larger Mole based on the PLUTO design but incorporating light collection optics that interface to a fiber optic cable in the tether that transmits light to a combined stimulated emission Raman Spectrometer and Short Wave Infrared (SWIR) reflectance Spectrometer with sensitivity from 0.7 to 2.5 micrometers. This instrument is called the Dual Spectral Sensor and uses a Digital Array Scanning Interferometer as the sensor technology, a type of fourier transform interferometer that uses fixed element prisms and thus is highly rugged compared to a Michaelson interferometer. Due to the size limitations of an on-Mole instrument compartment, and the availability of a tether, the sensor head, light sources, and control electronics for the instrument are on the surface. The DSS sensor is capable of sensing a wide range of minerals relevant to Mars Astrobiology objectives including hydrated minerals, clays, carbonates, sulfates, and ice. Additionally, Raman spectroscopy is effective for detecting organics. The MUM is designed to achieve a maximum depth of penetration of 5 m in Mars regolith and can be repeatedly deployed and retrieved. The ability to perform repeated sampling, combined with the low mass and power requirements, means that Moles could be incorporated into a rover mission as well as used on a stationary platform. The Mole mechanism is a pointed slender cylinder that advances into soil by way of an internal sliding hammer mechanism. Part of the energy released by the spring-loaded hammer with each shock is transferred to the Mole casing and from there to the soil, resulting in penetration by displacing and compressing the surrounding soil. A backwards-directed impulse as a re- action to each forward shock is transferred via a suppressor mass against a second weaker spring allowing forward motion without requiring reactive forces provided by the lander. The Mole tip can be opened to collect soil samples. The Mole casing is tethered to a supporting mechanism that supplies power. Components supporting the Mole on the surface include a launch tube, tether reel and winch for pulling in tether, in addition to the tether itself.

Stoker, C. R.↗
DOE OSTI2020

Lab-Scale, Closed-Loop Experimental Characterization, Model Refinement, and Validation of a Hydrokinetic Energy-Harvesting Ocean Kite

This paper presents a study wherein we experimentally characterize the dynamics and control system of a lab-scale ocean kite, and then refine, validate, and extrapolate this model for use in a full-scale system. Ocean kite systems, which harvest tidal and ocean current resources through high-efficiency cross-current motion, enable energy extraction with an order of magnitude less material (and cost) than stationary systems with the same rated power output. However, an ocean kite represents a nascent technology that is characterized by relatively complex dynamics and requires sophisticated control algorithms. In order to characterize the dynamics and control of ocean kite systems rapidly, at a relatively low cost, the authors have developed a lab-scale, closed-loop prototyping environment for characterizing tethered systems, whereby 3D printed systems are tethered and flown in a water channel environment. While this system has been shown to be capable of yielding similar dynamic characteristics to some full-scale systems, there are also fundamental limitations to the geometric scales and flow speeds within the water channel environment, making many other real-world scenarios impossible to replicate from the standpoint of dynamic similarity. Here, to address these scenarios, we show how the lab-scale framework is used to refine and validate a scalable dynamic model of a tethered system, which can then be extrapolated to full-scale operation. In this work, we present an extensive case study of this model refinement, validation, and extrapolation on an ocean kite system intended for operation in the Gulf Stream or similar current environments.

42 ENGINEERING↗
NASA NTRS1985

Summary Presentation of the Transportation Panel

Space mission scenarios are presented in which tethering is utilized. The technical and cost benefits are considered along with practicality and operational requirements. The mission scenarios considered include: (1) space shuttle delivery of payloads to higher orbits; (2) the downward release of the external tank from a shuttle; (3) space station altitude reboost using shuttle angular momentum; (4) shuttle docking to space station tether; (5) using shuttle based tether to assist launch of upper stage to higher energy orbits; (6) using space station tether to deploy payloads to higher orbits with momentum accumulator; (7) using tethers to discard first stages or apogee motors; and (8) planetary applications of tethers.

Hunter, M. W.↗
NASA NTRS1985

The excitation of plasma waves by a current source moving in a magnetized plasma - The MHD approximation

Alfven waves are important in natural-space phenomena, and studies of these waves have been conducted by performing active experiments in space plasma. One method to study these waves involves the use of an electrodynamic tether. The electrodynamic tether consists of a subsatellite with a conducting outer surface connected to the Space Shuttle by an insulator-clad, conducting wire about 20 kilometers in length. The emf generated by the motion of the tether across the geomagnetic field will act to drive a current through the tethered system. It is pointed out that this current in the tether acts as a source for exciting the shear-Alfven wave. In the present investigation it is shown that fringing effects play a dominant role in determining the radiation pattern for currently envisioned deployments of the tether. The current paper is the first of three papers concerned with the excitation of low-frequency waves arising from a current source moving through a cold, magnetized plasma.

Rasmussen, C. E.↗
NASA NTRS1986

Transportation

A summary of tether transportation is given. Four steps were used over a period of time. First, theoretical engineering feasibility and technology requirements were determined. Then the survivors of that effort went into step two in the analysis of promising candidates. Those survivors went into the third phase which is engineering design and cost benefits. Survivors entered into the demonstration mission definition phase. Transportation studies have covered two kinds of deployments. First, steady state deployment was studied. Like the TSS, it's nearly vertical. It takes a long time to deploy and involves relatively high tether tension. Secondly, dynamic deployment was studied. Deployment started in an almost horizontal direction under a very shallow angle which allows a high deployment rate under very low tension. Momentum transfer here occurs by libration. Specific payloads were used to study tethered transportation benefits. Four transportation concepts were studied with regard to cost benefits. A tethered orbiter deboost from the space station, an OTV boost up from the Space Station, a science platform on a tether with a possible micro-g lab moving in between platform and station, and a tethered boost of payloads fromthe orbiter are the four concepts. These benefits are examined in detail.

Vontiesenhausen, G.↗
NASA NTRS1998

Propulsive Small Expendable Deployer System (ProSEDS) Space Demonstration

The Propulsive Small Expendable Deployer System (ProSEDS) space experiment will demonstrate the use of an electrodynamic tether propulsion system. The flight experiment is a precursor to the more ambitious electrodynamic tether upper stage demonstration mission which will be capable of orbit raising, lowering and inclination changes-all using electrodynamic thrust. ProSEDS, which is planned to fly in 2000, will use the flight proven Small Expendable Deployer System (SEDS) to deploy a tether (5 km bare wire plus 15 km spectra) from a Delta II upper stage to achieve approx. 0.4N drag thrust, thus deorbiting the stage. The experiment will use a predominantly "bare" tether for current collection in lieu of the endmass collector and insulated tether approach used on previous missions. ProSEDS will utilize tether-generated current to provide limited spacecraft power. In addition to the use of this technology for orbit transfer and upper stages, it may also be an attractive option for future missions to Jupiter and any other planetary body with a magnetosphere.

Johnson, Les↗
NASA NTRS1996

SEDSAT 1 Technologies

The original goals of this project were to support the development of SEDSAT 1 for a tethered launch in July of 1997. This specifically required: (1) Monitoring development progress against a comprehensive delivery plan; (2) Incremental development and release of CDS and SEASIS software; (3) Supporting the integration of version 1.0 SEASIS software that will allow minimal autonomous operation without a software reload. These algorithms would include image quality evaluation, attitude determination, and autonomous earth imaging; and (4) Developing software requirements and design for ground segment software, concentrating on command and data download capability; and interface to external development efforts for a more comprehensive software suite to be used after the initial mission. Because of an unfavorable space shuttle safety review of the SEDS-3 tether deployer, and cost and schedule problems in upgrading the deployer, the mission was changed to an independent launch of SEDSAT. The original plan was to do a tether-less deployment from the space shuttle. Since this would have resulted in an unacceptable orbital lifetime, the mission was changed again to a tethered launch from a Delta II in June 1998. As a result of Marshall Space Flight Center's redirection of the SEDS-3 mission away from a tether launch, the whole question of a tether endmass had to be reconsidered. The net result of these multiple changes was twofold. First, we completed work needed to define some aspects of ground software on SEDSAT 1 that would remain constant no matter the launch mode. Second, we developed a set of concepts for using SEDSAT 1 technology to support alternative endmass missions on SEDS-3. Both of these are included.

Maier, Mark W.↗
NASA NTRS1998

Propulsive Small Expendable Deployer System (ProSEDS) Space Demonstration

The Propulsive Small Expendable Deployer System (ProSEDS) space experiment will demonstrate the use of an electrodynamic tether propulsion system. The flight experiment is a precursor to the more ambitious electrodynamic tether upper stage demonstration mission which will be capable of orbit raising, lowering and inclination changes-all using electrodynamic thrust. ProSEDS which is planned to fly in 2000, will use the flight proven Small Expendable C, Deployer System (SEDS) to deploy a tether (5 km bare wire plus 15 km spectra) from a Delta II upper stage to achieve approximately 0.4N drag thrust, thus deorbiting the stage. The experiment will use a predominantly 'bare' tether for current collection in lieu of endmass collector and insulated tether approach used on previous missions. ProSEDS will utilize tether-generated current to provide limited spacecraft power. In addition to the use of this technology to provide orbit transfer of payloads and upper stages from LEO to higher orbits it may also be an attractive option for future missions to Jupiter and any other planetary body with a magnetosphere.

Johnson, Les↗
NASA NTRS1998

Propulsive Small Expendable Deployer System (ProSEDS) Space Experiment

The Propulsive Small Expendable Deployer System (ProSEDS) space experiment will demonstrate the use of an electrodynamic tether propulsion system. The flight experiment is a precursor to the more ambitious electrodynamic tether upper stage demonstration mission which will be capable of orbit raising, lowering and inclination changes-all using electrodynamic thrust. ProSEDS which is planned to fly in 2000, will use the flight proven Small Expendable Deployer System (SEDS) to deploy a tether (5km bare wire plus 15 km spectra) from a Delta II upper stage to achieve approximately 0.4N drag thrust, thus demonstrating deorbit thrust. The experiment will use a predominantly 'bare' tether for current collection in lieu of endmass collector and insulated tether approach used on previous missions. ProSEDS will utilize tether-generated current to provide limited spacecraft power. In addition to the use of this technology to provide orbit transfer of payloads and upper stages from LEO to higher orbits it may also be an attractive option for future missions to Jupiter and any other planetary body with a magnetosphere.

Johnson, Les↗
NASA NTRS1999

The Propulsive Small Expendable Deployer System Experiment

Relatively short electrodynamic tethers can extract orbital energy to 'push' against a planetary magnetic field to achieve propulsion without the expenditure of propellant. The Propulsive Small Expendable Deployer System experiment will use the flight-proven Small Expendable Deployer System (SEDS) to deploy a 5 km bare copper tether from a Delta II upper stage to achieve approximately 0.4 N drag thrust, thus lowering the altitude of the stage. The experiment will use a predominantly 'bare' tether for current collection in lieu of the endmass collector and insulated tether approach used on previous missions. The flight experiment is a precursor to a more ambitious electrodynamic tether upper stage demonstration mission which will be capable of orbit raising, lowering and inclination changes - all using electrodynamic thrust. The expected performance of the tether propulsion system during the experiment is described.

Johnson, Les↗
NASA NTRS2000

The ProSEDS Mission

Relatively short electrodynamic tethers can extract orbital energy to "push" against a planetary magnetic field and achieve propulsion without the expenditure of propellant. The Propulsive Small Expendable Deployer System experiment will use the flight-proven Small Expendable Deployer System to deploy a 5-km bare aluminum tether from a Delta II upper stage to achieve approximately equal 0.4-N drag thrust, thus lowering the altitude of the stage. The experiment will use a predominantly "bare" tether for current collection in lieu of the endmass collector and insulated tether approach used on previous missions. The flight experiment is a precursor to a more ambitious electrodynamic tether upper stage demonstration mission which will be capable of orbit raising, lowering, and inclination changes--all using electrodynamic thrust. An overview of the mission and the expected performance of the tether propulsion system during the experiment are described.

Johnson, Charles L.↗
NASA NTRS2001

Life Testing of the Hollow Cathode Plasma Contactor for the ProSEDS Mission

The Propulsive Small Expendable Deployer System (ProSEDS) mission is designed to provide an on-orbit demonstration of the electrodynamic propulsion capabilities of tethers in space. The ProSEDS experiment will be a secondary payload on a Delta 11 unmanned expendable booster. A 5-km conductive tether is attached to the Delta 11 second stage and collects current from the low Earth orbit (LEO) plasma. A hollow cathode plasma contactor emits the collected electrons from the Delta II, completing the electrical circuit with the ambient plasma. The current flowing through the tether generates thrust based on the Lorentz Force Law. The thrust will be generated opposite to the velocity vector, slowing down the spacecraft and causing it to de-orbit in approximately 14 days compared to the normal 6 months. A 10-km non-conductive tether is between the conductive tether and an endmass containing several scientific instruments. The ProSEDS mission lifetime was set at I day because most of the primary objectives can be met in that time. The extended ProSEDS mission will be for as many days as possible, until the Delta 11 second stage burns up or the tether is severed by a micrometeoroid or space debris particle. The Hollow Cathode Plasma Contactor (HCPC) unit has been designed for a 12-day mission. Because of the science requirements to measure the background ambient plasma, the HCPC must operate on a duty cycle. Later in the ProSEDS mission, the HCPC is operated in a manner to allow charging of the secondary battery. Due to the unusual operating requirements by the ProSEDS mission, a development unit of the HCPC was built for thorough testing. This developmental unit was tested for a simulated ProSEDS mission, with measurements of the ability to start and stop during the duty cycle. These tests also provided valuable data for the ProSEDS software requirements. Qualification tests of the HCPC flight hardware are also discussed.

Vaughn, Jason A.↗
NASA NTRS2006

MXER Simulation Study (Appendix A)

In this study, we consider the dynamics of a spinning tether system in an elliptical orbit in application to the Momentum Exchange Electrodynamic Reboost system. Momentum exchange tether systems have been studied in a variety of applications since Hans Moravec's early publication. It has recently been suggested that momentum exchange systems can be enhanced with electrodynamic reboost between payload transfers. The Momentum Exchange Electrodynamic Reboost system (MXER) has a projected tether span of up to 100 km, and spins rapidly with a period of 6-7 min. It is placed in an orbit with a low perigee of about 400 km and a high apogee of about 8000 km. To capture a payload at a perigee rendezvous, within a window of a few seconds, the motion of the system has to be predicted with very high precision, having acceptable position errors on the order of 1 m. While this level of precision is routinely achieved today for conventional (non-tethered) satellites, it is much more difficult to achieve for a 100 km long flexible tether system. It is the goal of this study to investigate theoretical aspects of the dynamics and offer a practical approach to high precision dynamic modeling of a typical momentum exchange tether system.

Levin, E. M.↗
NASA NTRS2010

Progress in Development of the Axel Rovers

Progress has been made in the development of a family of robotic land vehicles having modular and minimalist design features chosen to impart a combination of robustness, reliability, and versatility. These vehicles at earlier stages of development were described in two previous NASA Tech Briefs articles: "Reconfigurable Exploratory Robotic Vehicles" (NPO-20944), Vol. 25, No. 7 (July 2001), page 56; and "More About Reconfigurable Exploratory Robotic Vehicles" (NPO-30890), Vol. 33, No. 8 (August 2009), page 40. Conceived for use in exploration of the surfaces of Mars and other remote planets, these vehicles could also be adapted to terrestrial applications, including exploration of volcanic craters or other hostile terrain, military reconnaissance, inspection of hazardous sites, and searching for victims of earthquakes, landslides, avalanches, or mining accidents. In addition, simplified versions of these vehicles might be marketable as toys. The most basic module in this family of reconfigurable robots is the Axel rover, which has a cylindrical body with two main wheels and a trailing link. Inside its body are three motors and associated mechanisms for driving the two wheels and for rotating the link 360 around its symmetrical body. The actuated link serves several purposes: It is used as a lever arm to react to the wheels thrust to move Axel in multiple directions. It is used to rotate the Axel housing in order to tilt, to the desired angle, any sensors and instruments mounted on or in the Axel housing. It provides an alternative mobility mode, which is primarily used in its tethered configuration. Turn ing the link into the ground in lieu of driving the wheels causes the Axel housing and wheels to roll as a unit and thereby leads to a tumbling motion along the ground. With a tether mounted around Axel s cylindrical body, the link serves as a winch mechanism to reel and unreel the tether raising and lowering Axel over steep and vertical surfaces (Figure 1). Sensors, computation, and communication modules are also housed inside Axel s body. A pair of stereo vision cameras provides three-dimensional view for autonomous navigation and avoiding obstacles. Inertial sensors determine the tilt of the robot and are used for estimating its motion. In a fully developed version, power would be supplied by rechargeable batteries aboard Axel; at the time of reporting the information for this article, power was supplied from an external source via a cable. In and of itself, the Axel rover is fully capable of traversing and sampling terrains on planetary surfaces. By use of only the two main wheel actuators and the caster link actuator, Axel can be made to follow an arbitrary path, turn in place, and operate upside- down or right-side-up. If operated in a tethered configuration, as shown in Figure 1, it can be made to move down and up a steep crater wall, descend from an overhang to a cave, and ascend from the cave back to the overhang, all by use of the same three actuators. Such tethered operation could be useful in searching for accident victims or missing persons in mines, caves, and rubble piles. Running the tether through the caster link enhances the stability of Axel and provides a restoring force that keeps the link off the ground for the most part during operation on a steep slope. In its extended configuration, two Axel modules can dock to either side of a payload module to form the four wheeled Axel2 rover (Figure 2). Additional payload and Axel modules can dock to either side of the Axel2 to form the Axel3 rover, extending its payload capacity and its mobility capabilities.

Nesnas, Issa A.↗
NASA NTRS2013

NanoTHOR: Low-Cost Launch of Nanosatellites to Deep Space

The rapid development of high-performance nanosatellite platforms is enabling NASA and commercial ventures to consider performing missions to the asteroids, the Moon, and Mars at lower cost and on shorter timelines than traditional large spacecraft platforms. Currently, however, opportunities to launch secondary payloads to Earth escape are rare, and using chemical rockets to propel secondary payloads from LEO rideshares to escape is problematic due to the risks posed to primary payloads. The NanoTHOR effort has explored the technical feasibility and value proposition for using a simple momentum-exchange tether system to scavenge orbital energy from an upper stage in geostationary transfer orbit in order to boost nanosatellites to Earth escape. A NanoTHOR module will accomplish rapid transfer of a nanosatellite to an escape trajectory by deploying the nanosat at the end of a long, slender, high-strength tether and then using winching in the Earth's gravity!gradient to convert orbital angular momentum into rotational angular momentum. In the Phase I effort, we developed and simulated methods for controlling tether deployment and retraction to spin up a tether system, and these simulations demonstrated the feasibility of providing delta-Vs on the order of 800 m/s with a simple, low-mass tether system. Moreover, the NanoTHOR tether can act as a reusable in-space upper stage, boosting multiple nanosatellites on a single launch and doing so with a mass requirement lower than that of conventional rocket technologies. Serving as an escape-injection stage, NanoTHOR can enable a 6U CubeSat to deliver small payloads to Mars orbit, lunar orbit, and rendezvous with at least 110 of the known near-Earth asteroids. Evaluation of the technology readiness of the component technologies required for NanoTHOR indicate that the hardware required is all mid-TRL, and the lower-TRL controls and integration components can be advanced to mid-TRL with modest investment. By scavenging orbital energy from upper stages without any stored energy or propellant requirements, NanoTHOR permits deep-space nanosat missions to launch on rideshare opportunities, enabling NASA and commercial ventures to conduct affordable and frequent missions to explore deep space destinations.

Hoyt, Robert↗
NASA NTRS2016

Unique Results and Lessons Learned From the TSS Missions

The Tethered Satellite System (TSS) Space Shuttle missions, TSS-1 in 1993 and TSS-1R in 1996, were the height of space tether technology development in the U.S. Altogether, the investment made by NASA and the Italian Space Agency (ASI) over the thirteen-year period of the TSS Program totaled approximately $400M-exclusive of the two Space Shuttle flights provided by NASA. Since those two pioneering missions, there have been several smaller tether flight experiments, but interest in this promising technology has waned within NASA as well as the DOD agencies. This is curious in view of the unique capabilities of space tether systems and the fact that they have been flight validated in earth orbit and shown to perform better than the preflight dynamic or electrodynamic theoretical predictions. While it is true that the TSS-1 and TSS-1R missions experienced technical difficulties, the causes of these early developmental problems are now known to have been engineering design flaws, material selection, and procedural issues that (1) are unrelated to the basic viability of space tether technology, and (2) can be readily corrected. The purpose of this paper is to review the dynamic and electrodynamic fundamentals of space tethers and the unique capabilities they afford (that are enabling to certain types of space missions); to elucidate the nature, cause, and solution of the early developmental problems; and to provide an update on progress made in development of the technology.

Stone, Nobie H.↗
NASA NTRS2017

Conceptual Design of an Electric Sail Technology Demonstration Mission Spacecraft

There is great interest in examining the outer planets of our solar system and Heliopause region (edge of Solar System) and beyond regions of interstellar space by both the Planetary and Heliophysics communities. These needs are well docu-mented in the recent National Academy of Sciences Decadal Surveys. There is significant interest in developing revolutionary propulsion techniques that will enable such Heliopause scientific missions to be completed within 10 to15 years of the launch date. One such enabling propulsion technique commonly known as Electric Sail (E-Sail) propulsion employs positively charged bare wire tethers that extend radially outward from a rotating spacecraft spinning at a rate of one revolution per hour. Around the positively charged bare-wire tethers, a Debye Sheath is created once positive voltage is applied. This sheath stands off of the bare wire tether at a sheath diameter that is proportional to the voltage in the wire coupled with the flux density of solar wind ions within the solar system (or the location of spacecraft in the solar system. The protons that are expended from the sun (solar wind) at 400 to 800 km/sec are electrostatically repelled away from these positively charged Debye sheaths and propulsive thrust is produced via the resulting momentum transfer. The amount of thrust produced is directly proportional to the total wire length. The Marshall Space Flight Center (MSFC) Electric Sail team is currently funded via a two year Phase II NASA Innovative Advanced Concepts (NIAC) awarded in July 2015. The team's current activities are: 1) Developing a Particle in Cell (PIC) numeric engineering model from the experimental data collected at MSFC's Solar Wind Facility on the interaction between simulated solar wind interaction with a charged bare wire that can be applied to a variety of missions, 2) The development of the necessary tether deployers and tethers to enable successful de-ployment of multiple, multi km length bare tethers, 3) Controllability of the space-craft via a voltage bias to steer itself through the solar system to destinations of discovery. These activities once demonstrated analytically, will require a technology demonstration mission (TDM) around the year2020 to demonstrate that all systems work together seamlessly before a Heliophysics Electrostatic Rapid Transit System (HERTS) mission could be initiated. A notional TDM spacecraft that meets the requirements of such a mission will be showcased in this paper.

Wiegmann, Bruce M.↗
DOE OSTI2022

Impacts of Bond Type and Grafting Density on the Thermal, Structural, and Transport Behaviors of Nanoparticle Organic Hybrid Materials–Based Electrolytes

Nanoscale Organic Hybrid Materials (NOHMs) consist of polymers tethered to a nanoparticle surface, and NOHMs formed with an ionic bond between the polymer and nanoparticle have been proposed for electrochemical applications. NOHMs exhibit negligible vapor pressure, chemical tunability, oxidative thermal stability, and high ionic conductivity making them attractive in reactive and separation systems. In this study, NOHMs are synthesized by tethering Jeffamine M2070 (HPE) to SiO 2 nanocores via ionic (NOHM-I-HPE) and covalent (NOHM-C-HPE) bonding to investigate the effect of the bond type on the thermal, structural and transport properties of the tethered HPE. In the neat state, NOHM-C-HPE displays the highest thermal stability in a nitrogen atmosphere, while NOHM-I-HPE is the most stable under oxidative conditions. Small-angle neutron scattering (SANS) reveals the presence of multiple types of HPE polymers in aqueous solutions of NOHM-I-HPE (i.e., tethered, interacting, and free), whereas only tethered HPE is observed in NOHM-C-HPE systems. Moreover, the SANS profiles identify clustering of NOHM-C-HPE in aqueous solutions, but not in the corresponding NOHM-I-HPE solutions, suggesting that the free HPE chains stabilize the dispersion of NOHM-I-HPE. Furthermore, the results of this study elucidate how the bond type and grafting density can be used to tune the properties of NOHMs.

25 ENERGY STORAGE↗