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3,201 records · Page 42

Atomic- and Molecular-Scale Interphase Engineering for High-Performance Solid-State Batteries

Solid-state batteries (SSBs) promise a decisive advance beyond conventional Li-ion systems, yet their development remains constrained by persistent solid–solid interfacial instabilities that degrade performance and durability. Interfaces between solid electrolytes and both cathodes and Li metal often exhibit poor wettability, limited physical contact, and high charge–transfer resistance, leading to chemical decomposition, mechanical failure, and impedance growth. Overcoming these limitations requires interphase engineering with atomic-scale precision—capabilities that conventional coating methods cannot reliably deliver. Atomic layer deposition (ALD) and molecular layer deposition (MLD) uniquely meet this need by enabling ultrathin, conformal, and composition-tunable films that stabilize reactive surfaces, suppress parasitic reactions, and regulate Li-metal morphology. Importantly, this Perspective highlights ALD/MLD systems that have already demonstrated effectiveness in liquid-electrolyte cells and discusses how these validated strategies can be deliberately translated to solid-state architectures. By grounding future directions in experimentally proven concepts rather than speculative hypotheses, we outline how atomic- and molecular-scale design principles can accelerate the development of robust, high-performance SSB technologies.

atomic and molecular layer deposition

Detailed examination of LDEF's frame and the A0178 thermal blankets by the meteoroid and debris special investigations group

A responsibility of the group is to define the hypervelocity particle environment encountered by LDEF during its stay in low Earth orbit. LDEF's 6061-T6 aluminum frame and the 'Teflon silver-inconel paint' thermal blankets represent large surface areas that were widely distributed around the spacecraft. The results are reported of high resolution scans of approx. 0.36 and approx. 0.31 sq m for the intercostals and thermal blankets, respectively. The findings are in qualitative agreement with existing model predictions that suggest high differential bombardment histories for surfaces pointing into specific directions relative to the velocity vector of a non-spinning platform in LEO. The production rate for craters greater than or = 50 microns in diameter in aluminum and penetration holes greater than or = 100 microns in diameter in thin foil materials differ by more than a factor of 10 between forward and rearward facing surfaces. These are substantial differences that must be considered during the design of future long duration space platforms in LEO.

Thomas H. See

LDEF experiment M0003 meteoroid and debris survey

A survey of the meteoroid and space debris impacts on LDEF experiment M0003 was performed. The purpose was to document impact phenomenology and to obtain impact crater data for comparison to current debris and micrometeoroid models. The survey consists of photomicrographs of significant impacts in a variety of material types, accurate measurements of impact crater coordinates and dimensions for selected experiment surfaces and data basing of the crater data for reduction, manipulation, and comparison models. Large area surfaces which were studied include the experiment power and data system sunshields, environment exposure control canister sunshields, and the M0003 signal conditioning unit covers. Crater diameters down to 25 microns were measured and catalogued. Both leading and trailing edge surfaces were studied and compared. The results shows the different response of materials to hypervelocity impacts. Comparison of the data to curves derived from the Kessler debris model and the Cour-Palais micrometeoroid model indicates a marked tendency for overprediction of small impacts and underprediction of large impacts with there being better agreement for the medium sized impacts. Representative impact data is presented.

M. J. Meshishnek

Pocket nickel cadmium cell and battery evaluation

The Nickel Cadmium 129-ampere hour cell was tested in order to characterize the cell under controlled conditions. Results of charge characterization and discharge characterization are reported. Ampere hour efficiency, open circuit stand, and cycle life operation results are included. The battery is briefly described.

Lear, J. W.

Evaluation of Cycle Life and Characterization of YTP 45 Ah Li-Ion Battery for EMU

Li-ion batteries, with longer cycle life and higher energy density features, are now more and more attractive and applied in multiple fields. The YTP 45 Ah Li-ion battery has been evaluated here and may be employed in EMU in the future. Evaluations were on: (1) Cycle life tests - 500 cycles total (completed 40 cycles in simulated shuttle use mode and 460 cycles in an accelerated use mode, and recorded differential voltage of individual cell in battery); (2) Characterization test - discharge capacity measurement in environment temperature of -10, 25, 50 C before and after 500 cycles; and (3) Thermal testing - charge and discharge at 50 C and -10 C before and after 500 cycles. The battery showed less than a 9% drop of initial discharge capacity and energy within 500 cycles with 475 cycles 59% DOD plus 25 cycles 100% DOD. The EOD voltage ranged from 16.0 to 18.0 V, which fits the requirement for operating the EMU.

Deng, Yi

Contrasting structural reversibility and magnetic correlations in isostructural honeycomb magnets CrCl3 and 𝛼−RuCl3

We report a comparative neutron single crystal diffraction study of the structural and magnetic properties of layered halides CrCl3 and 𝛼−RuCl3. They host a honeycomb arrangement of transition metal ions with distinct electronic configurations and undergo a first-order structural transition between high-temperature 𝐶⁢2/𝑚 and low-temperature 𝑅⁢‾‾‾3. Both compounds show a step-like change in the 𝑐-lattice parameter across the structure transition. In contrast, the in-plane lattice response is quite different: 𝛼−RuCl3 exhibits an abrupt hysteretic change across the transition accompanied by progressive crystalline degradation upon thermal cycling, whereas CrCl3 shows a smooth in-plane lattice evolution and remains structurally robust. Magnetically, CrCl3 orders into an A-type antiferromagnetic structure at 𝑇𝑁=14 K and exhibits pronounced diffuse magnetic scattering extending up to about 40 K. 𝛼−RuCl3 shows no observable magnetic diffuse scattering above its zigzag antiferromagnetic ordering temperature 𝑇𝑁=7.6 K. These results suggest that the contrasting structural responses arise from an interplay between interlayer sliding energetics, stacking-strain coupling, and elastic accommodation of the stacking transition. The distinct chemical bonding and electronic configurations of the two compounds provide a microscopic basis for their different lattice responses to the structure transition and magnetic correlations.

Morgan, Zachary [ORNL] (ORCID:0000000243625911)

Fifth Annual Workshop on Space Operations Applications and Research (Soar 1991), Volume 1

More than 110 papers were presented at this Symposium, sponsored by the U.S. Air Force Phillips Laboratory, the University of Houston-Clear Lake, and NASA JSC. The technical areas covered were Intelligent Systems, Automation and Robotics, Human Factors and Life Sciences, and Environmental Interactions. The U.S. Air Force and NASA programmatic overviews and panel discussions were also held in each technical area. These proceedings, along with the comments and suggestions made by the panelists and keynote speakers, will be used in assessing the progress made in joint USAF/NASA projects and activities. Furthermore, future collaborative/joint programs will also be identified. The symposium proceedings includes papers covering various disciplines presented by experts from NASA, the Air Force, universities, and industry.

Mars missions

Aerodynamics and Acoustics of Propellers

A state of the art review of the aerodynamic design and testing of modern propellers, acoustic and vibration environmental problems and their solutions, and considerations in the integration of the propeller(s) and airframe is presented. Propellers have recently become a focus of attention after having been neglected for many years. The efficient use of propellers as a propulsion medium up to Mach 0.6 was realized at the expense of high noise and vibration. Since the mid-1970s there have been many developments, including the propfan, with an aerodynamic efficiency of 80% at Mach 0.8 now seriously challenges the fanjet. The advent of the supercritical airfoil is another significant development beginning to influence propeller design.

Design

Intelsat Battery and Power System Design

The orbit data for the Intelsat 4 spacecraft is described. The performance and characteristics of the battery used for this spacecraft are discussed. Graphs are presented which relate battery voltage to various eclipse seasons.

J Dunlop

Aerodynamic Performance and Acoustic Impacts of Varying Tip Speeds and Tripping Conditions on Small Rotors in an Anechoic Hover Chamber

Performance and acoustic measurements were taken in a hover chamber for various optimum hovering rotors (OPT2) and a commercial-off-the-shelf (COTS) rotor. A total of 10 rotors are included in this report, all of which have two blades and a tip radius of 0.1905 m (7.5 in.). For the OPT2, results for three additive manufacturing methods of fabrication are presented: stereolithography(SLA) using Accura Xtreme, SLA using FormLabs 10K resin, and selective laser sintering (SLS) using mineral-filled PA12 nylon material. All but one set of rotors were designed with a trailing edge bluntness that is 3% of the chord length, and one set was designed with a bluntness that is 1% of the chord length. Spanwise boundary layer trips were applied to the SLA, FormLabs and COTS rotors. Performance comparisons between untripped and tripped configurations demonstrate the impact of boundary layer state on rotor efficiency. Acoustic results, including periodic and broadband noise components, are presented. The effects of tripping these rotors near the leading edge are also presented. For some of the rotors, acoustic spectra of tip speed sweeps are presented to show how the frequency content changes with tip speed. Amplitude and frequency scaling methods are used to collapse broadband spectra at various tip speeds towards a unified curve. These findings contribute to the understanding of small rotor aeroacoustics and provide valuable datasets for computational model validation in urban air mobility applications.

eVTOL