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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Lidar Observation of Aerosol and Temperature Stratification over Urban Area During the Formation of a Stable Atmospheric PBL

In recent years, the processes in the atmospheric planetary boundary layer (PBL) over urban areas were intensely investigated, due to ecological problems related to the air, soil, and water pollution. New pollution sources in new residential districts, when in contradiction to the microclimate and topography requirements of that region, create a number of considerable hazards and problems. The present study is a continuation of our preceding investigations and aims at revealing the aerosol structure and stratification during the transition after sunset as measured by two lidars. Such observation of the nocturnal, stable PBL formation over an urban area in Bulgaria has not been reported before. The lidars' high time and spatial resolutions allow the changes of the internal structure of the PBL's part located above the surface layer to be observed.

Kolev, I.↗
DOE OSTI2019

Improved methodologies for Earth system modelling of atmospheric soluble iron and observation comparisons using the Mechanism of Intermediate complexity for Modelling Iron (MIMI v1.0)

Abstract. Herein, we present a description of the Mechanism of Intermediate complexity for Modelling Iron (MIMI v1.0). This iron processing module was developed for use within Earth system models and has been updated within a modal aerosol framework from the original implementation in a bulk aerosol model. MIMI simulates the emission and atmospheric processing of two main sources of iron in aerosol prior to deposition: mineral dust and combustion processes. Atmospheric dissolution of insoluble to soluble iron is parameterized by an acidic interstitial aerosol reaction and a separate in-cloud aerosol reaction scheme based on observations of enhanced aerosol iron solubility in the presence of oxalate. Updates include a more comprehensive treatment of combustion iron emissions, improvements to the iron dissolution scheme, and an improved physical dust mobilization scheme. An extensive dataset consisting predominantly of cruise-based observations was compiled to compare to the model. The annual mean modelled concentration of surface-level total iron compared well with observations but less so in the soluble fraction (iron solubility) for which observations are much more variable in space and time. Comparing model and observational data is sensitive to the definition of the average as well as the temporal and spatial range over which it is calculated. Through statistical analysis and examples, we show that a median or log-normal distribution is preferred when comparing with soluble iron observations. The iron solubility calculated at each model time step versus that calculated based on a ratio of the monthly mean values, which is routinely presented in aerosol studies and used in ocean biogeochemistry models, is on average globally one-third (34 %) higher. We redefined ocean deposition regions based on dominant iron emission sources and found that the daily variability in soluble iron simulated by MIMI was larger than that of previous model simulations. MIMI simulated a general increase in soluble iron deposition to Southern Hemisphere oceans by a factor of 2 to 4 compared with the previous version, which has implications for our understanding of the ocean biogeochemistry of these predominantly iron-limited ocean regions.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2007

Probing the Depths of Space Weathering: A Cross-sectional View of Lunar Rock 76015

The term "space weathering" refers to the cumulative effects of several processes operating at the surface of any solar system body not protected by a thick atmosphere. These processes include cosmic and solar ray irradiation, solar wind implantation and sputtering, as well as melting and vaporization due to micrometeorite bombardment. Space weathering discussions have generally centered around soils but exposed rocks will also incur the effects of weathering. Rocks have much longer surface lifetimes than an individual soil grain and thus record a longer history of exposure. By studying the weathering products which have built up on a rock surface, we can gain a deeper perspective on the weathering process and better assess the relative importance of various weathering components. The weathered coating, or patina, of the lunar rock 76015 has been previously studied using SEM and TEM. It is a noritic breccia with both "glazed" (smooth glassy) and "classic" (microcratered and pancake-bearing) patina coatings. Previous TEM work on 76015 relied on ultramicrotomy to prepare cross sections of the patina coating, but these sections were limited by the "chatter" and loss of material in these brittle samples. Here we have used a focused ion beam (FIB) instrument to prepare cross sections in which the delicate stratigraphy of the patina coating is beautifully preserved.

Noble, Sarah K.↗
DOE OSTI2017

Connecting the failure of K-theory inside and above vegetation canopies and ejection-sweep cycles by a large eddy simulation

Parameterizations of biosphere-atmosphere interaction processes in climate models and other hydrological applications require characterization of turbulent transport of momentum and scalars between vegetation canopies and the atmosphere, which is often modeled using a turbulent analogy to molecular diffusion processes. However, simple flux-gradient approaches (K-theory) fail for canopy turbulence. One cause is turbulent transport by large coherent eddies at the canopy scale, which can be linked to sweep-ejection events, and bear signatures of non-local organized eddy motions. K-theory, that parameterizes the turbulent flux or stress proportional to the local concentration or velocity gradient, fails to account for these non-local organized motions. The connection to sweep-ejection cycles and the local turbulent flux can be traced back to the turbulence triple moment $\overline{C'W'W'}$. In this work, we use large-eddy simulation to investigate the diagnostic connection between the failure of K-theory and sweep-ejection motions. Analyzed schemes are quadrant analysis (QA) and a complete and incomplete cumulant expansion (CEM and ICEM) method. The latter approaches introduce a turbulence timescale in the modeling. Furthermore, we find that the momentum flux needs a different formulation for the turbulence timescale than the sensible heat flux. In conclusion, accounting for buoyancy in stratified conditions is also deemed to be important in addition to accounting for non-local events to predict the correct momentum or scalar fluxes.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1991

Development of an Accelerated Test Method for the Determination of Susceptibility to Atmospheric Corrosion

The theoretical rationale is presented for use of a repetitive cyclic current reversal voltammetric technique for characterization of localized corrosion processes, including atmospheric corrosion. Applicability of this proposed experimental protocol is applied to characterization of susceptibility to crevice and pitting corrosion, atmospheric corrosion and stress corrosion cracking. Criteria upon which relative susceptibility is based were determined and tested using two iron based alloys commonly in use at NASA-Kennedy; A36 (a low carbon steel) and 4130 (a low alloy steel). Practicality of the procedure was demonstrated by measuring changes in anodic polarization behavior during high frequency current reversal cycles of 25 cycles per second with 1 mA/sq cm current density amplitude in solutions containing Cl anions. The results demonstrated that, due to excessive polarization which affects conductivity of barrier corrosion product layers, A36 was less resistant to atmospheric corrosion than its 4130 counterpart; behavior which was also demonstrated during exposure tests.

Ambrose, John R.↗
NASA NTRS2010

Martian Dust Devil Electron Avalanche Process and Associated Electrochemistry

Mars' dynamic atmosphere displays localized dust devils and larger, global dust storms. Based on terrestrial analog studies, electrostatic modeling, and laboratory work these features will contain large electrostatic fields formed via triboelectric processes. In the low-pressure Martian atmosphere, these fields may create an electron avalanche and collisional plasma due to an increase in electron density driven by the internal electrical forces. To test the hypothesis that an electron avalanche is sustained under these conditions, a self-consistent atmospheric process model is created including electron impact ionization sources and electron losses via dust absorption, electron dissociation attachment, and electron/ion recombination. This new model is called the Dust Devil Electron Avalanche Model (DDEAM). This model solves simultaneously nine continuity equations describing the evolution of the primary gaseous chemical species involved in the electrochemistry. DDEAM monitors the evolution of the electrons and primary gas constituents, including electron/water interactions. We especially focus on electron dynamics and follow the electrons as they evolve in the E field driven collisional gas. When sources and losses are self-consistently included in the electron continuity equation, the electron density grows exponentially with increasing electric field, reaching an equilibrium that forms a sustained time-stable collisional plasma. However, the character of this plasma differs depending upon the assumed growth rate saturation process (chemical saturation versus space charge). DDEAM also shows the possibility of the loss of atmospheric methane as a function of electric field due to electron dissociative attachment of the hydrocarbon. The methane destruction rates are presented and can be included in other larger atmospheric models.

Jackson, Telana L.↗
NASA NTRS2002

The Influence of Tropospheric Processes in Modeling the Middle Atmosphere with Gravity Waves

Our Numerical Spectral Model (NSM) extends from the ground up into the thermosphere and has a vertical grid point resolution of about 0.5 km to resolve the interactions of gravity waves (GWs) described with Hines' Doppler Spread Parameterization (DSP). This model produces in the stratosphere and mesosphere the major features of QBO, SAO, tides, and planetary waves. The purpose of this paper is to discuss results from an initial study with our 3D model that shows how certain tropospheric processes can affect the dynamics of the middle atmosphere. Under the influence of tropospheric heating, and augmented by GW interactions, two distinct but related processes can be identified. (1) A meridional circulation develops in the stratosphere, with rising motions at low latitudes that are in magnitude comparable to the downward propagation of the QBO. As Dunkerton pointed out, a larger GW source is then required to reproduce the observed QBO, which tends to move us closer to the values recommended for the DSP. This has significant consequences for our model results that describe the upper mesosphere, considering the general importance of GWs for this region and in influencing planetary waves (e.g., 2-day wave) and tides in particular. (2) Tropospheric heating produces zonal jets near the tropopause that are related to latitudinal variations in pressure and reversing temperature variations (resembling the dynamical conditions near the mesopause), which in turn is conducive to generate baroclinic instability. Modeling results show that our ability to generate the QBO critically depends on the magnitude of the temperature reversal that is a measure of this instability. Planetary waves are generated in this process, which can apparently interfere with or augment the GW interactions. As originally demonstrated by Lindzen and Holton, the eastward propagating Kelvin waves and westward propagating Rossby gravity waves (generated by tropospheric convection) can in principle provide the acceleration to influence the QBO, and we were able to confirm this with our 3D model.

Mayr, H. G.↗
NASA NTRS1987

Investigation of the feasibility of an analytical method of accounting for the effects of atmospheric drag on satellite motion

An analytic technique for accounting for the joint effects of Earth oblateness and atmospheric drag on close-Earth satellites is investigated. The technique is analytic in the sense that explicit solutions to the Lagrange planetary equations are given; consequently, no numerical integrations are required in the solution process. The atmospheric density in the technique described is represented by a rotating spherical exponential model with superposed effects of the oblate atmosphere and the diurnal variations. A computer program implementing the process is discussed and sample output is compared with output from program NSEP (Numerical Satellite Ephemeris Program). NSEP uses a numerical integration technique to account for atmospheric drag effects.

Bozeman, Robert E.↗
DOE OSTI2021

Detection of an Atmosphere on a Rocky Exoplanet

We report the detection of an atmosphere on a rocky exoplanet, GJ 1132 b, which is similar to Earth in terms of size and density. The atmospheric transmission spectrum was detected using Hubble WFC3 measurements and shows spectral signatures of aerosol scattering, HCN, and CH{sub 4} in a low mean molecular weight atmosphere. We model the atmospheric loss process and conclude that GJ 1132 b likely lost the original H/He envelope, suggesting that the atmosphere that we detect has been reestablished. We explore the possibility of H{sub 2} mantle degassing, previously identified as a possibility for this planet by theoretical studies, and find that outgassing from ultra-reduced magma could produce the observed atmosphere. In this way we use the observed exoplanet transmission spectrum to gain insights into magma composition for a terrestrial planet. The detection of an atmosphere on this rocky planet raises the possibility that the numerous powerfully irradiated super-Earth planets, believed to be the evaporated cores of sub-Neptunes, may, under favorable circumstances, host detectable atmospheres.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1983

A general circulation model of a Venus-like atmosphere

Heat and momentum budgets are investigated for a three-dimensional general circulation model of a Venus-like, massive and slowly rotating atmosphere which is forced with an axisymmetric radiative heating/cooling distribution. Model results confirm the suggestions of Gierasch (1975) and Rossow and Williams (1979), with a mean meridional circulation which, despite its multicellular form, interacts with quasi-barotropic eddies produced by zonal flow shear instability to yield a weak superrotation of the entire model atmosphere. This process is sufficiently general to encourage the conclusion that it will occur in all slowly rotating atmospheres. Whether it can accelerate wind speeds as large as those observed on Venus cannot presently be determined.

Rossow, W. B.↗
NASA NTRS2004

A New Approach to Using a Cloud-Resolving Model to Study the Interactions between Clouds, Precipitation and Aerosols

Recently Grabowski and Khairoutdinov and Randall have proposed and demonstrated, the feasibility of using 2D CRMs (these did not include detailed land processes and used periodic lateral boundary conditions) as 'super-parameterizations or a multi-scale modeling framework MMF' for cloud processes within atmospheric generation circulation models (GCMs). In the MMF, a fine-resolution 2D CRM takes the place of the single-column parameterization that is used in conventional GCMs. An overview of this approach is given by Randall et al.. Since a CRM can explicitly simulate cloud processes at the natural space and time scales of clouddynamical processes, it's possible to compute statistics of cloud fields, including radiances and radar backscatters, directly simulated/produced by the CRM. A seed fund is available at NASA Goddard to build a MMF based on a 2D GCE model and the Goddard fvGCM. A prototype MMF will be developed at end of 2004. The major objectives are to test and evaluate its performance using the GCE model as the super parameterization and compare its results with other super parameterizations, conventional GCMs and observations. Recently, a detailed spectral-bin microphysical scheme was implemented into the Goddard Cumulus Ensemble (WE) model. The GCE model is a CRM and it has been improved and applied to study the precipitation processes in the past two decades. Atmospheric aerosols are also described using number density size-distribution functions. The model is tested by studying the evolution of deep tropical clouds in the west Pacific warm pool region and summertime convection over a mid-latitude continent with different concentrations of CCN: a low 'clean' concentration and a high 'dirty' concentration. The impact of atmospheric aerosol concentration on cloud and precipitation will be investigated. In addition, the similarities and differences between bulk- and spectral-bin microphysics will be presented,

Tao, Wei-Kuo↗
DOE OSTI2025

A minor respiratory process with major global implications: is atmospheric methane oxidation in tree stems driven by stem respiration rather than microbial methanotrophy?

Tree stem surfaces are widely recognized as sites of carbon dioxide (CO₂) efflux and oxygen (O₂) influx, reflecting the dynamics of aerobic respiration of photosynthate substrates, such as sugars, delivered via the phloem. Stems are also largely considered passive conduits for methane (CH₄) produced in anoxic soils via microbial methanogenesis, where CH₄ is thought to be transported upward through the transpiration stream and/or diffusion and emitted through stem surfaces and the canopy. However, recent observations from dynamic stem chambers suggest that stems may also act as active sinks for atmospheric CH₄. Despite these findings, the extent and drivers of stem CH₄ consumption remain poorly characterized across biomes, species, and environmental gradients, and its quantitative relationship to stem respiration has not been established. Moreover, previous studies captured only snapshot fluxes, leaving diurnal patterns of CH₄ exchange uncharacterized. Here, we address these limitations by combining real-time measurements of stem CH₄ and O₂ uptake under ambient conditions in a California cherry tree, using a dynamic stem gas exchange system with three chambers receiving a continuous flow of ambient air and automated chamber and reference air sampling every 10 min. Our results confirm that stems of upland trees can actively consume both atmospheric CH₄ and O₂, but with decreasing temperature sensitivity as daily temperatures increase. Early mornings were marked by rapid influxes of both gases, followed by declining uptake as temperatures rose further. Methane uptake was tightly coupled with O₂ influx and represented a minor (0.012% ± 0.002%) fraction of stem respiratory activity, as determined by concurrent O₂ uptake. These findings suggest that while atmospheric CH₄ oxidation is a minor respiratory process in stems, it is strongly linked with stem physiological activity. This challenges the current assumption that terrestrial CH₄ uptake is driven solely by microbial methanotrophy and raises the possibility that living stem tissues may contribute to CH₄ oxidation through an as-yet-unidentified plant-based mechanism.

Atmospheric greenhouse gases↗
NASA NTRS2014

The Deuterium to Hydrogen Ratio in the Water that Formed the Yellowknife Bay Mudstones in Gale Crater

A suite of isotope ratios of light elements in the present martian atmosphere (13C/12C, 15N/14N, 18O/16O, 38Ar/36Ar, and D/H) are all substantially enriched in the heavy element suggesting atmospheric loss to space over the past billions of years with preferential loss of the lighter isotope from each pair. In situ measurements from MSL's Sample Analysis at Mars (SAM) instrument [e.g. 1,2,3] have considerably refined previous measurements from the Viking mass spectrometers [e.g. 4], from remote spectroscopic observations [e.g. 5,6], and from martian meteorite studies [e.g. 7,8]. The persistence of habitable environments such as the ancient Yellowknife Bay lake recently revealed by measurements from the Curiosity rover [9] depends on the surface temperatures and the duration of an atmosphere thicker than that at present. Current and planned measurements from orbit with the Mars Express and MAVEN missions respectively intend to study the processes of atmospheric escape including solar wind interaction, sputtering, thermal escape, and dissociative recombination, and determine or refine the current rate of atmospheric loss caused by these and other mechanisms. The goal of these programs is to understand the physical processes sufficiently well so that robust extrapolations over the past billions of years can be made D/H is measured by both the Tunable Laser Spectrometer (TLS) and the Quadrupole Mass Spectrometer (QMS) of the SAM suite. to predict the atmospheric and surface conditions on early Mars. However, the study of the history of martian atmospheric evolution will be greatly facilitated if we are able to also directly measure the isotopic composition of volatiles captured in rocks that are representative of the ancient atmosphere. To date, D/H is one of the most promising candidates for this study since water is the most abundant volatile thermally released from the Yellowknife Bay phylosilicates discovered by the SAM and CheMin experiments of MSL and its

Yellowknife Bay↗
DOE OSTI2013

On the connection between continental-scale land surface processes and the tropical climate in a coupled ocean-atmosphere-land system

The impact of global tropical climate to perturbations in land surface processes (LSP) are evaluated using perturbations given by different LSP representations of continental-scale in a global climate model that includes atmosphere-ocean interactions. One representation is a simple land scheme, which specifies climatological albedos and soil moisture availability. The other representation is the more comprehensive Simplified Simple Biosphere Model, which allows for interactive soil moisture and vegetation biophysical processes. The results demonstrate that LSP processes such as interactive soil moisture and vegetation biophysical processes have strong impacts on the seasonal mean states and seasonal cycles of global precipitation, clouds, and surface air temperature. The impact is especially significant over the tropical Pacific. To explore the mechanisms for such impact, different LSP representations are confined to selected continental-scale regions where strong interactions of climate-vegetation biophysical processes are present. We find that the largest impact is mainly from LSP perturbations over the tropical African continent. The impact is through anomalous convective heating in tropical Africa due to changes in the surface heat fluxes, which in turn affect basinwide teleconnections in the Pacific through equatorial wave dynamics. The modifications in the equatorial Pacific climate are further enhanced by strong air-sea coupling between surface wind stress and upwelling, as well as effect of ocean memory. Our results further suggest that correct representations of land surface processes, land use change and the associated changes in the deep convection over tropical Africa are crucial to reducing the uncertainty when performing future climate projections under different climate change scenarios.

Ma, Hsi-Yen↗
DOE OSTI2018

Understanding Composition, Formation, and Aging of Organic Aerosols in Wildfire Emissions via Combined Mountain Top and Airborne Measurements

Wildfires are an important source of global aerosols that have pronounced impacts on regional air quality and global climate. A major component of wildfire emissions is organic, including primary organic aerosols (POA) and large amounts of gases that can be oxidized to form secondary organic aerosols (SOA). The environmental impacts of wildfire emissions are strongly correlated with the chemical, optical, and microphysical properties of biomass-burning organic aerosols (BBOA), which are dependent, in a complex manner, on combustion and atmospheric aging processes. Here we discuss results from recent field and laboratory studies aimed at understanding the chemical composition, formation, and evolution of BBOA in wildfire emissions. Comprehensive analysis of a large number of fresh and aged (up to days of aging) fire plumes originating in the Pacific Northwest region of the United States reveals that the enhancement of BBOA mass concentrations relative to the enhancement of the sum of CO and CO2 in wildfire smokes is primarily driven by combustion efficiency, whereas the composition and properties of the BBOA are strongly influenced by atmospheric oxidation and other aging processes. These results shed light on organic aerosol formation and transformation in biomass burning emissions.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2017

Atmospheric Capture On Mars (and Processing)

The ultimate destination of NASA's human exploration program is Mars. In Situ Resource Utilization (ISRU) is a key technology required to enable such missions, as first proposed by Prof. Robert Ash in 1976. This presentation will review progress in the systems required to produce rocket propellant, oxygen, and other consumables on Mars using the carbon dioxide atmosphere and other potential resources. For many years, NASA, commercial companies, and academia have been developing, and demonstrating techniques to capture and purify Martian atmospheric gases for their utilization for the production of hydrocarbons, oxygen, and water in ISRU systems. Other gases will be required to be separated from Martian atmospheric gases to provide pure CO2 for processing elements. Significant progress has been demonstrated in CO2 collection via adsorption by molecular sieves, freezing, and direct compression. Early stage work in adsorption in Ionic Liquids followed by electrolysis to oxygen is also underway. In addition, other Martian gases, such as nitrogen and argon, occur in concentrations high enough to be useful as buffer gas and could be captured as well. Gas separation requirements include, but are not limited to the selective separation of: (1) methane and water from unreacted carbon oxides (CO2-CO) and hydrogen typical of a Sabatier-type process, (2) carbon oxides and water from unreacted hydrogen from a Reverse Water-Gas Shift process, and (3) carbon oxides from oxygen from a trash/waste processing reaction.

propellant production↗
NASA NTRS1990

Theoretical studies of important processes in planetary and comet atmospheres

Dissociative recombination (DR) reactions in planetary and comet atmospheres are discussed. A computer program was developed which determines DR cross sections and rates using potential curves and electronic capture widths. It uses Multi-Channel Quantum Defect Theory (MQDT) to include excited Rydberg resonance levels in the DR cross section and rate calculations. Each vibrational level of a molecular ion is the limit for an infinite series of Rydberg states. Above each ion vibrational level are Rydberg vibrational levels having higher ion levels as their series limit. These Rydberg vibrational levels are resonances, i.e., neutral states which are imbedded in the electron-molecular ion continuum. The process in which the Rydberg level causes an abrupt perturbation in the cross section for DR (because of interference between capture into the Rydberg level and capture into the repulsive dissociative state) is referred to as indirect recombination. The process in which the Rydberg levels are excluded and recombination goes from the entrance channel to the repulsive state is called direct recombination. The full DR process, i.e., both direct and indirect recombination, is the process of importance for planetary atmospheres. These ideas are illustrated with the new results for DR from excited ion vibrational levels of O2(+) into the dissociative state which leads to O(1S) + O(1D).

Guberman, Steven L.↗