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At least 757 records · Page 42

Topological structure prediction in binary nanoparticle superlattices

Systems of spherical nanoparticles with capping ligands have been shown to self-assemble into beautiful superlattices of fascinating structure and complexity. Here, I show that the spherical geometry of the nanoparticle imposes constraints on the nature of the topological defects associated with the capping ligand and that such topological defects control the structure and stability of the superlattices that can be assembled. Furthermore, all of these considerations form the basis for the orbifold topological model (OTM) described in this paper. Finally, the model quantitatively predicts the structure of super-lattices where capping ligands are hydrocarbon chains in excellent agreement with experimental results, explains the appearance of low packing fraction lattices as equilibrium, why certain similar structures are more stable (bccAB 6 vs. CaB 6 , AuCu vs. CsCl, etc.) and many other experimental observations.

36 MATERIALS SCIENCE↗

Graphene quantum dots: effect of size, composition and curvature on their assembly

Graphene Quantum Dots (GQDs) are a relatively new class of molecules that have ignited tremendous research interest due to their extraordinary and tunable optical, electrical, chemical and structural properties. In this paper, we report a molecular-level elucidation of the key mechanisms and physical–chemical factors controlling the assembly and stability of nanostructures formed by GQDs in an aqueous environment, using molecular dynamics simulations. We observe the general tendency to form small aggregates and three recurring configurations, one of them with a single layer of water separating two GQDs. The type and characteristics of the structure are mostly determined by the hydrophobicity of the GQDs as well as the steric hindrance of the dangling groups. The composition of the terminal groups plays a key role in determining the configuration of the GQDs, which is also markedly affected by the formation of clusters. Notably, the aggregated GQDs assume strongly correlated shapes and, in some cases, display a radically different conformation distribution compared to single molecules. This cooperative effect prolongs the lifetime of the GQD configurations and can explain the observed persistence of chiral conformations that are only marginally more stable than their specular images.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Coupling of an atmospheric pressure microplasma ionization source with an Orbitrap Fusion Lumos Tribrid 1M mass analyzer for ultra-high resolution isotopic analysis of uranium

The coupling of a combined atomic and molecular (CAM) ionization source, the liquid sampling-atmospheric pressure glow discharge (LS-APGD) microplasma to an Orbitrap Fusion Lumos Tribrid 1M mass spectrometer is described as a significant step towards the elimination of isobaric interferences in elemental/isotopic mass spectrometry. The developed setup permits broadband, elemental mass spectra to be easily acquired at a mass resolution (m/Δm) of 500 000. A new ion source housing and integrated control system provide enhanced stability and sensitivity of the microplasma ion source in comparison to the previous designs. Detailed evaluation of the ion sampling parameters provided insight into differences with other Orbitrap platforms leading to a 5-fold increase in resolution in elemental/isotopic analysis. The roles of data acquisition/ion processing parameters were evaluated with regards to the precision and accuracy of 235 U/ 238 U isotope ratios. Significantly, the precision of those measurements improves as a function of pre-set mass resolution up to a value of 1 000 000, where a precision of 0.086% RSD is obtained for uranium concentrations of 100 ng mL− 1 . Analytical response curves (log–log), acquired for the two uranium isotopes at a resolution of 120 000 were linear (R 2 = 0.9969) over more than 5 orders of magnitude, with limits of detection of 1 pg mL −1 for U. Based on 60 μL injection volumes, this represents a mass of 70 fg 235 U. These figures of merit satisfy International Target Values (ITVs) for Measurement Uncertainties in Safeguarding Nuclear Materials set by the International Atomic Energy Agency (IAEA). Ultimately, and totally unique from beam-type instruments, the move to the higher-resolution Orbitrap platform provides all of the benefits of high mass resolution, with no penalties in sensitivity, precision, or dynamic range for uranium analysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Optimization of magneto-resistive response of ion-irradiated exchange biased films through zigzag arrangement of magnetization

Exchange coupled ferromagnetic-antiferromagnetic Ni{sub 81}Fe{sub 19}/Ir{sub 23}Mn{sub 77} films with a zigzag alignment of magnetization are prepared by local ion irradiation. The anisotropic magneto-resistive behavior of the magnetic thin film structures is correlated to the magnetic structure and modeled. A unique uniaxial field sensitivity along the net magnetization alignment is obtained through the orthogonally modulated and magnetic domain wall stabilized magnetic ground state. Controlling local thin film magnetization distributions and, thus, the overall magnetization response opens unique ways to tailor the magneto-resistive sensitivity of functional magnetic thin film devices.

36 MATERIALS SCIENCE↗

Minimization of nanosatellite low frequency magnetic fields

Small weight and dimensions of the micro- and nanosatellites constrain researchers to place electromagnetic sensors on short booms or on the satellite body. Therefore the electromagnetic cleanliness of such satellites becomes a central question. This paper describes the theoretical base and practical techniques for determining the parameters of DC and very low frequency magnetic interference sources. One of such sources is satellite magnetization, the reduction of which improves the accuracy and stability of the attitude control system. We present design solutions for magnetically clean spacecraft, testing equipment, and technology for magnetic moment measurements, which are more convenient, efficient, and accurate than the conventional ones.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Simultaneous measurement of specific heat and thermal conductivity in pulsed magnetic fields

Here we report an experimental setup for simultaneously measuring specific heat and thermal conductivity in feedback-controlled pulsed magnetic fields of 50 ms duration at cryogenic temperatures. A stabilized magnetic field pulse obtained by the feedback control, which dramatically improves the thermal stability of the setup and sample, is used in combination with the flash method to obtain absolute values of thermal properties up to 37.2 T in the 22–16 K temperature range. We describe the experimental setup and demonstrate the performance of the present method with measurements on single-crystal samples of the geometrically frustrated quantum spin-dimer system SrCu 2 (BO 3 ) 2 . Our proof-of-principle results show excellent agreement with data taken using a standard steady-state method, confirming the validity and convenience of the present approach.

47 OTHER INSTRUMENTATION↗

Scenario optimization for the tokamak ramp-down phase in RAPTOR: Part A. Analysis and model validation on ASDEX Upgrade

We discuss how the combination of experimental observations and rapid modeling has enabled to improve understanding of the tokamak ramp-down phase in ASDEX Upgrade. A series of dedicated experiments has been performed, to disentangle the effect of individual actuators like plasma current, auxiliary heating and plasma shaping. Optimized discharge termination strategies with increased margin with respect to radiative and vertical stability limits are proposed and tested in experiment. Radiative collapse of the edge $T$ $e$ profile after the HL back-transition is avoided by initially maintaining auxiliary heating during L-mode, showing beneficial effects even after the auxiliary heating is turned off. The capability of the RAPTOR code to model the time evolution of the internal inductance $\ell$ $i3$ has been validated, including the effect of a change in the $I$ $p$ ramp-down rate and the HL transition timing. The reduction of $\ell$ $i3$ caused by rapid compression of the plasma cross-section has been quantitatively recovered in simulations. Successful modeling of the $\ell$ $i3$ time evolution is essential to optimize ramp-down scenarios for future fusion reactors, for which vertical stability and power balance control will be more challenging.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Phase-field approach to cellular blebbing

Bulges in the plasma membrane of cells known as blebs can form spontaneously in a wide range of biological processes, but what controls their shape and stability remains incompletely understood. Here, to address this we introduce a dual phase-field model with coupled order parameters representing the cell cortex and plasma membrane that can quantitatively model blebbing in three dimensions. Simulations and sharp-interface analyses reveal that, depending on whether blebbing occurs by detachment of the plasma membrane or rupture of the actin cortex, blebs can form discontinuously through a saddle-node bifurcation or continuously with increasing cortical tension. The model predictions are in good quantitative agreement with existing experimental data for laser-induced cortex rupture.

Biological and medical sciences↗

Temperature and Strain Sensing Characteristics of a 128° YX-Cut LiNbO 3 Rayleigh-Mode SAW Sensor From Room to Cryogenic Temperatures

Accurate, passive, and wireless monitoring of cryogenic hardware is essential for high-energy physics, space propulsion, and biomedical instrumentation. Here, this study quantifies the coupled temperature-strain behavior of Rayleigh-mode surface acoustic-wave (SAW) delay-line sensors fabricated on 128° YX-cut LiNbO 3 . A nonlinear finite element (FE) model incorporating Varshni-based elastic constants, higher-order thermal expansion, and temperature-dependent piezo- and dielectric coefficients was developed and validated experimentally between 280K and 80K. Free-standing (first test condition) and bonded/wired (second test condition) devices exhibited indistinguishable thermal responses; the average temperature coefficient of delay (TCD) in the critical cryogenic range from 130K down to 80K differed by only 0.15 ppm/K (0.32%), confirming that bonding-induced stress is negligible. Over 280-80K the measured TCD was 61.77 ppm/K, while the FE model predicted an equivalent temperature coefficient of frequency (TCF) of −62.74 ppm/K with an overall coefficient of determination R2 = 0.998. In the critical cryogenic interval 130-80K the TCD fell to 47.66 ppm/K, indicating improved thermal stability at low temperature. Controlled loading (0-300 με) revealed a strain coefficient of delay (SCD) that rises from 0.53 ± 0.02 ppm/με at 300K to 1.05 ± 0.02 ppm/με at 80K. This modest sensitivity confirms that, for temperature sensing, strain is a second-order perturbation above 135K but must be compensated at deeper cryogenic levels. Overall, this work establishes a predictive multiphysics model together with repeatable wired measurements that confirm the suitability of SAW sensors for temperature and strain monitoring in extreme cryogenic environments, while also providing a baseline for future wireless implementations.

25 ENERGY STORAGE↗

Virtual Dynamic Grid Impedance and Its Impacts on Harmonics and Stability of Inverter Based Resources Plant

Nowadays, a large number of inverter-based resources (IBRs) are integrated into the grid at a single connection point as an IBR plant. In this article, a virtual dynamic grid impedance concept is introduced to evaluate the harmonics and stability for grid integration of an IBR plant containing multiple IBRs. First, a detailed theoretical study is conducted to build a foundation of the virtual grid impedance concept, which is a dynamic impedance that changes with the number of IBRs added into an IBR plant. Then, based on the new virtual dynamic grid impedance concept, frequency spectrum analysis is performed to explore harmonic impact at the interconnection point for an IBR plant with IBRs having L, LC, and LCL filters, respectively. An electromagnetic transient (EMT) simulation model of a grid-connected IBR plant is developed to explore the harmonics and stability of the IBR plant connected to the grid as well as the reliable operation of IBRs within the plant from the novel virtual equivalent dynamic grid impedance point of view. Hardware experiments are conducted to validate the EMT simulation evaluation. The results show that the number of IBRs added into an IBR plant influences the grid impedance, i.e., grid strength, and the grid impedance variation has multiple impacts on the IBR plant and IBRs within the plant depending on the grid-connected filters of the IBRs.

grid impedance↗

Power System Dynamic State Estimation: Motivations, Definitions, Methodologies and Future Work

This paper summarizes the technical activities of the Task Force on Power System Dynamic State and Parameter Estimation. This Task Force was established by the IEEE Working Group on State Estimation Algorithms to investigate the added benefits of dynamic state and parameter estimation for the enhancement of the reliability, security, and resilience of electric power systems. The motivations and engineering values of dynamic state estimation (DSE) are discussed in detail. Then, a set of potential applications that will rely on DSE is presented and discussed. Furthermore, a unified framework is proposed to clarify the important concepts related to DSE, forecasting-aided state estimation, tracking state estimation and static state estimation. An overview of the current progress in DSE and dynamic parameter estimation is provided. The paper also provides future research needs and directions for the power engineering community.

task force, dynamic state estimation, Parameter Es↗

Coherent light control of a metastable hidden state

Metastable phases present a promising route to expand the functionality of complex materials. Of particular interest are light-induced metastable phases that are inaccessible under equilibrium conditions, as they often host new, emergent properties switchable on ultrafast timescales. However, the processes governing the trajectories to such hidden phases remain largely unexplored. Here, using time- and angle-resolved photoemission spectroscopy, we investigate the ultrafast dynamics of the formation of a hidden quantum state in the layered dichalcogenide 1T-TaS 2 upon photoexcitation. Our results reveal the nonthermal character of the transition governed by a collective charge-density-wave excitation. Using a double-pulse excitation of the structural mode, we show vibrational coherent control of the phase-transition efficiency. Our demonstration of exceptional control, switching speed, and stability of the hidden state are key for device applications at the nexus of electronics and photonics.

36 MATERIALS SCIENCE↗

Analytic study of the conditions required for longitudinal stability of dual-wing aircraft

Recent studies of new, fuel-efficient transport aircraft have considered designs, which make use of two principal lifting surfaces to provide the required lift as well as trim and static stability. Such designs include open tandem-wings as well as closed joined and box-wings. As a group, these aircraft can be termed dual-wing designs. Our study developed a new analytic model, which takes into account the downwash from the two main wings and is sensitive to three important design variables: the relative areas of each wing, the streamwise separation of the wings, and the center of gravity position. This model was used to better understand trends in the dual-wing geometry on the stability, maneuverability, and lift-to-drag ratio of the aircraft. Dual-wing aircraft have been shown to have reduced the induced drag compared to the conventional designs. In addition, further drag reductions can be realized as the horizontal tail can be removed if the dual-wings have sufficient streamwise stagger to provide the moments necessary for trim and longitudinal stability. As both wings in a dual-wing system carry a significant fraction of the total lift, trends in such designs that led to longitudinal stability can differ from those of the conventional aircraft and have not been the subject of detailed investigation. Results from the analytic model showed that the longitudinal stability required either a reduction of the fore wing area or shifting the center of gravity forward from the midpoint of both wings' aerodynamic centers. Additionally, for wing configurations of approximately equal fore and aft wing areas, increasing the separation between the two wings decreased the stability of the aircraft. The source of this unusual behavior was the asymmetric distribution of downwash upstream and downstream of the wing. These relationships between dual-wing geometry and stability will provide initial guidance on the conceptual design of dual-wing aircraft and aid in the understanding of the results of more complex studies of such designs, furthering the development of future transport aircraft.

33 ADVANCED PROPULSION SYSTEMS↗

Distribution of nickel(II) ions adsorbed at the muscovite mica (001)-water interface determined by in-situ resonant anomalous X-ray reflectivity

Mineral-water interfaces mediate adsorption, ion exchange, and secondary mineral formation that control element mobility in natural and engineered systems. Reliable prediction and control of these processes require a fundamental understanding of the interfacial structure that links adsorbed ion speciation to macroscopic sorption capacity and strength. Here, we determine atomic-scale changes in hydration and distribution of Ni(II) at the muscovite mica (001)-water interface using in situ high-resolution X-ray reflectivity (XR) and resonant anomalous X-ray reflectivity (RAXR) at 1 mM NiCl2 and pH 5.7. XR reveals reorganization of the primary hydration structure relative to that in deionized water: the water layer adsorbed in the cavity sites at a height of ~1.3 Å disappears, while distinct solution layers emerge at ~2.3, ~4.1, and ~5.6 Å above the basal oxygen plane. RAXR resolves three interfacial Ni(II) species: a dominant outer-sphere complex at 3.65 Å (~80% of the total coverage), a minor inner-sphere complex at 0.75 Å, and a low-coverage, more distant outer-sphere species at 5.63 Å. These three adsorbed Ni(II) species account for a total Ni(II) coverage of 0.54 ± 0.02 ion per unit cell area that compensates for the surface charge. These results highlight the role of interfacial hydration in controlling the speciation and stability of adsorbate cations on the negatively charged mica surface, providing quantitative insight into predicting the geochemical behavior of divalent metal cations in the aqueous environments.

Lee, Sang Soo↗

Start-to-End Simulation of the Drive-Beam Longitudinal Dynamics for Beam-Driven Wakefield Acceleration

Collinear beam-driven wakefield acceleration (WFA) relies on shaped driver beam to provide higher accelerating gradient at a smaller cost and physical footprint. This acceleration scheme is currently envisioned to accelerate electron beams capable of driving free-electron laser *. Start-to-end simulation of drive-bunch beam dynamics is crucial for the evaluation of the design of accelerators built upon WFA. We report the start-to-end longitudinal beam dynamics simulations of an accelerator beamline capable of producing high charge drive beam. The generated wakefield when it passes through a corrugated waveguide results in a transformer ratio of 5. This paper especially discusses the challenges and criteria associated with the generation of temporally-shaped driver beam, including the beam formation in the photoinjector, and the influence of energy chirp control on beam transport stability.

43 PARTICLE ACCELERATORS↗

Completion Report for Well ER-4-1 Corrective Action Unit 97: Yucca Flat/Climax Mine, Revision 0

Well ER-4-1 was drilled for the U.S. Department of Energy, Nevada National Security Administration Nevada Field Office in support of the Underground Test Area (UGTA) Activity. The well was drilled and completed from March 23 to April 13, 2016, as part of the Corrective Action Investigation Plan (CAIP) for Yucca Flat/Climax Mine Corrective Action Unit (CAU) 97. The primary purpose of the well was to collect hydrogeologic data to assist in validating concepts of the groundwater flow system within the Yucca Flat/Climax Mine CAU, and to test for potential radionuclides in groundwater from the STRAIT (U4a) underground test. The completed well includes one piezometer (p1), to a depth of 663.16 meters (m) (2,175.71 feet [ft]) below ground surface (bgs) and open from the Alluvial aquifer (AA3) to the Oak Spring Butte confining unit (OSBCU) hydrostratigraphic units; and a main completion (m1), which includes 6.625-inch (in.) casing with slotted interval (m1) installed to 906.80 m (2,975.05 ft) bgs in the Lower carbonate aquifer (LCA). A 13.375-in. diameter surface casing was installed from the surface to a depth of 809.00 m (2,654.21 ft) bgs. Well ER-4-1 experienced a number of technical issues during drilling, including borehole instability and sloughing conditions. An intermediate, 10.75-in./9.625-in. casing string was installed to 856.94 m (2,811.48 ft) bgs to control these issues. Borehole stability and erosion problems appear to be associated with the Tunnel Formation (Tn) and the Older tunnel beds (Ton). Overall efforts to stabilize the borehole were successful. Data collected during borehole construction include composite drill cutting samples collected every 3.0 m (10 ft), a partial suite of geophysical logs to a maximum depth of 766.57 m (2,515 ft) bgs, water-quality measurements (including tritium), water-level measurements, and two depth-discrete bailer samples collected at 538.89 m and 646.18 m (1,768 ft and 2,120 ft) bgs respectively. The well penetrated 187.45 m (615 ft) of Quaternary/Tertiary alluvium (QTa), 671.47 m (2,203 ft) of Tertiary Volcanic rocks (Tv), and 66.20 m (217.19 ft) of Paleozoic rocks (|). The stratigraphy and lithology were generally as expected with some exceptions. The top of Paleozoic rocks (|) was predicted to occur at 822.35 m (2,698 ft) bgs and was intercepted at 858.93 m (2,818 ft), a difference of 36.58 m (120 ft). As expected, the Paleozoic rocks (|) are the principal water producing formation in Well ER-4-1. Depth to water was measured after drilling as follows: In the piezometers: p1 at 320.39 m (1,051.16 ft) bgs, (measured January 4, 2017); and in the main production casing interval: m1 at 539.17 m (1,768.92 ft) bgs, (measured December 12, 2016) Geophysical logs and depth-discrete bailer sample analytical results suggest likely zones of prompt injection (underground-test-related) fission products from 472.44 to 481.48 m (1,550 to 1,580 ft) bgs and at approximately 539.50 m (1,770 ft) bgs. Subsequent work at Well ER-4-1 will be included in future reports. Field measurements for tritium were mostly below the Safe Drinking Water Act limit (20,000 picocuries per liter) with the exception of two zones showing elevated tritium concentrations. The first zone is located at approximately 365.76 to 390.14 m (1,200 to 1,280 ft) bgs and a second zone at approximately 542.54 to 566.93 m (1,780 to 1,860 ft) bgs. All Fluid Management Plan requirements were met.

54 ENVIRONMENTAL SCIENCES↗

Introduction to Grid Forming Inverters: A Key to Transforming our Power Grid [Slides]

A grid-forming (GFM) inverter-based resource (IBR) controls maintain an internal voltage phasor that is constant or nearly constant in the sub-transient to transient time frame. This definition means that the GFM IBR will nearly immediately respond to changes in the external system and attempt to maintain IBR control during challenging network conditions to maintain grid stability. In GFM IBR, the voltage phasor is controlled to maintain synchronism with other devices in the grid while regulating the active and reactive power appropriately to support the grid. This contrasts with conventional GFL IBR controls wherein immediately after a disturbance (0-5 cycles), within the normal operating range of voltage, the output current phasor magnitude and angle remain unchanged, and the current phasor begins changing only within the transient time frame (tens of cycles) to strictly control the active and reactive power being injected into the network. This presentation gives an introduction to GFM IBR and presents the current state of the art in this area.

24 POWER TRANSMISSION AND DISTRIBUTION↗

PIP-II LLRF Master Oscillator and Precision Reference Line - Station Level Design and Testing

The PIP-II superconducting linac at Fermilab requires a highly stable RF Reference Line to maintain phase syn- chronization throughout the accelerator. Temperature- induced changes in the electrical length of long coaxial cables can introduce phase drift and measurement errors. The reference-line architecture mitigates these effects by phase averaging the forward and reflected RF signals, while a phase-locked loop anchors the system to the mas- ter oscillator. This work focuses on the characterization, validation, and mechanical integration of station-level RF assemblies using CAD modeling, vector network analyzer measurements, and spectrum analyzer testing. PID-controlled thermal plates will stabilize critical RF components and further reduce temperature-dependent phase and amplitude variations. These methods sup- port repeatable, standardized designs that can be reliably integrated across the different reference-line stations.

Mosher, Alexander [U. Illinois, Chicago]↗