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At least 757 records · Page 42

Structures with high number density of carbon nanotubes and 3-dimensional distribution

A composite is described having a three dimensional distribution of carbon nanotubes. The critical aspect of such composites is a nonwoven network of randomly oriented fibers connected at their junctions to afford macropores in the spaces between the fibers. A variety of fibers may be employed, including metallic fibers, and especially nickel fibers. The composite has quite desirable properties for cold field electron emission applications, such as a relatively low turn-on electric field, high electric field enhancement factors, and high current densities. The composites of this invention also show favorable properties for other an electrode applications. Several methods, which also have general application in carbon nanotube production, of preparing these composites are described and employ a liquid feedstock of oxyhydrocarbons as carbon nanotube precursors.

Chen, Zheng↗

Thermionic cathode life-test studies

A NASA-Lewis Research Center program for life testing commercial, high-current-density thermionic cathodes has been in progress since 1971. The purpose of the program is to develop long-life power microwave tubes for space communications. Four commercial-type cathodes are being evaluated in this investigation. They are the 'Tungstate', 'S' type, 'B' type, and 'M' type cathodes, all of which are capable of delivering 1 A/ sq cm or more of emission current at an operating temperature in the range of 1000-1100 C. The life test vehicles used in these studies are similar in construction to that of a high-power microwave tube and employ a high-convergence electron-gun structure; in contrast to earlier studies that used close-space diodes. These guns were designed for operation at 2 A/sq cm of cathode loading. The 'Tungstate' cathodes failed at 700 h or less and the 'S' cathode exhibited a lifetime of about 20,000 h. One 'B' cathode has failed after 27,000 h, the remaining units continuing to operate after up to 30,000 h. Only limited data are now available for the 'M' cathode, because only one has been operated for as long as 19,000 h. However, the preliminary results indicate the emission current from the 'M' cathode is more stable than the 'B' cathode and that it can be operated at a true temperature approximately 100 C lower than for the 'B' cathode.

Forman, R.↗

Conventional single-gap $s-$wave superconductivity and hidden peak effect in single crystals of Mo$_8$Ga$_{41}$ superconductor

London and Campbell penetration depths were measured in single crystals of the endohedral gallide cluster superconductor, Mo _8 8 Ga _41 41 . The full temperature range superfluid density, \rho_s(T) ρ s ( T ) , is consistent with the clean isotropic s- s − wave weak-coupling BCS theory without any signs of the second gap or strong coupling. The temperature dependence of the Campbell length is hysteretic between zero-field cooling (ZFC) and field-cooling (FC) protocols, indicating an anharmonic vortex pinning potential. The field dependence of the effective critical current density, j_{c}(H) j c ( H ) , reveals an unusual result. While in the ZFC protocol, j_{c}(H) j c ( H ) is monotonically suppressed by the magnetic field, it exhibits a profound “hidden” peak effect in the FC protocol, that is, without a vortex density gradient. We suggest a possible novel mechanism for such a peak effect, which involves both static and dynamic aspects of vortex pinning.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Effects of delta ray electrons on measurement uncertainties of harp system

A harp system, which is a multi-wire beam profile monitoring (MWPM) system, is planned upstream of the spallation target to make in situ calibration of beam current density configuration on the target along with beam imaging from luminescent coating on the beam entrance window at the Second Target Station (STS) of the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL). This beam interception-based beam diagnostics system on the target will be used to ensure that the maximum beam loads on the target are within the design range during neutron production. Current design of the harp consists of three layers of measurement wires each of which is sandwiched between voltage biasing wire planes. The signal obtained from each measurement wire layer is disturbed by secondary electrons (SE) and delta rays produced by beam-matter interactions in neighboring wires and ionization of residual gases in accelerator vacuum. While the backgrounds from SE can be suppressed by voltage biasing, the delta-ray electrons with kinetic energies above keV ranges overcome the electric potential bias. In this paper, we study the effects of delta-rays on the measurement uncertainties of MWPM using the particle transport simulation code FLUKA. Furthermore, the cases where the harp system is installed in the proximity of a large delta ray sources such as proton beam window or in the core vessel filled with sub-atmospheric gas have been studied.

Lee, Yong Joong↗

Bodies in flowing plasmas - Laboratory studies

A brief review of early rudimentary laboratory studies of bodies in flowing, rarefied plasmas is presented (e.g., Birkeland, 1908), along with a discussion of more recent parametric studies conducted in steady plasma wind tunnels, which includes the study by Hall et al. (1964), in which a strong ion density enhancement in the center of the ion void created downstream from the body was observed. Good agreement was found between the experimental results and theoretical calculations which omit ion thermal motion. Examples in which in situ data on the interaction between satellites and the ionospheric plasma have been elucidated by the laboratory results are presented, and include evidence for a midwake axial ion peak, and ion current density in the near-wake region. The application of the ionospheric laboratory to basic space plasma physics is discussed, and its application to some types of solar system plasma phenomena is illustrated.

Stone, N. H.↗

Metals Electroprocessing in Molten Salts

The present study seeks to explain the poor quality of solid electrodeposits in molten salts through a consideration of the effects of fluid flow of the electrolyte. Transparent cells allow observation of electrolyte circulation by a laser schlieren optical technique during the electrodeposition of solid zinc from the molten salt electrolyte, ZnCl2 - LiCl-KCl. Experimental variables are current, density, electrolyte composition, and cell geometry. Based on the results of earlier electrodeposition studies as well as reports in the literature, these parameters are identified as having the primary influence on cell performance and deposit quality. Experiments are conducted to measure the fluid flow patterns and the electrochemical cell characteristics, and to correlate this information with the morphology of the solid electrodeposit produced. Specifically, cell voltage, cell current, characteristic time for dendrite evolution, and dendrite growth directions are noted. Their relationship to electrolyte flow patterns and the morphology of the resulting electrodeposit are derived. Results to date indicate that laser schlieren imaging is capable of revealing fluid flow patterns in a molten salt electrolyte.

Sadoway, D. R.↗

Fabrication of high-quality superconductor-insulator-superconductor junctions on thin SiN membranes

We have successfully fabricated high-quality and high-current density superconductor-insulator-superconductor (SIS) junctions on freestanding thin silicon nitride (SIN) membranes. These devices can be used in a novel millimeter-wave and THz receiver system which is made using micromachining. The SIS junctions with planar antennas were fabricated first on a silicon wafer covered with a SiN membrane, the Si wafer underneath was then etched away using an anisotropic KOH etchant. The current-voltage characteristics of the SIS junctions remained unchanged after the whole process, and the junctions and the membrane survived thermal cycling.

Garcia, Edouard↗

Development and simulation study of a new inverse-pinch high Coulomb transfer switch

The inverse-pinch plasma switch was studied using a computer simulation code. The code was based on a 2-D, 2-temperature magnetohydrodynamic (MHD) model. The application of this code was limited to the disk-type inverse-pinch plasma switch. The results of the computer analysis appear to be in agreement with the experimental results when the same parameters are used. An inverse-pinch plasma switch for closing has been designed and tested for high-power switching requirements. An azimuthally uniform initiation of breakdown is a key factor in achieving an inverse-pinch current path in the switch. Thus, various types of triggers, such as trigger pins, wire-brush, ring trigger, and hypocycloidal-pinch (HCP) devices have been tested for uniform breakdown. Recently, triggering was achieved by injection of a plasma-ring (plasma puff) that is produced separately with hypocycloidal-pinch electrodes placed under the cathode of the main gap. The current paths at switch closing, initiated by the injection of a plasma-ring from the HCP trigger are azimuthally uniform, and the local current density is significantly reduced, so that damage to the electrodes and the insulator surfaces is minimized. The test results indicate that electron bombardment on the electrodes and the insulator surfaces is minimized. The test results indicate that electron bombardment on the electrodes is four orders of magnitude less than that of a spark-gap switch for the same switching power. Indeed, a few thousand shots with peak current exceeding a mega-ampere and with hold-off voltage up to 20 kV have been conducted without showing measurable damage to the electrodes and insulators.

Choi, Sang H.↗

Navigation Challenges in the MAVEN Science Phase

The MAVEN spacecraft will explore Mars' upper atmosphere. The primary science phase will last one (Earth) year, during which the spacecraft will be in an elliptical 4.5 hour orbit at an inclination of 75 degrees. The 75 degree inclination results in the orbit periapsis oscillating between +/-75 degrees latitude, thus naturally covering most Mars latitudes during the primary mission. The orbit will be controlled via maneuvers so that the maximum orbit density remains in a density corridor. This results in the MAVEN science phase being in a light aerobraking type orbit of around 160 km for an extended period. In addition, the mission has significantly less tracking data than aerobraking phases of other missions, and even less than other NASA Mars orbiter primary phases. This results in significant challenges for the Navigation Team. They can be summarized as a difficulty in determining the current density profile, which maps into degraded trajectory predictions and less accurate control over the spacecraft location in the targeted density corridor via maneuvers. This paper describes these challenges and the Navigation Team's plans to meet them.

MAVEN↗

Author Correction: Proton irradiation-decelerated intergranular corrosion of Ni-Cr alloys in molten salt

In the original version of this article, numbers for the beam current densities were incorrectly given as 1.5, 2.0, and 2.5 mA cm -2 in various locations, instead of the correct values 0.3, 0.4, and 0.5 mA cm -2 . This was owing to a measurement error coming from the indirect correspondence between the Faraday cup and the beam profile monitor (BPM) on the accelerator as the proton beam traveling along the beamline resulted in mismatching between calculated values and real beam currents, which were obtained by ex-situ calibration. The following changes have been made in the correct version. The eighth sentence of the Results, and the figure legend of Fig. 2j state '0.3, 0.4, 0.5 mA cm -2 ' in place of '1.5, 2.0, 2.5 mA cm -2 '. The figure legend of Fig. 1j–l states '0.5, 0.4, 0.3 mA cm -2 ' in place of '2.5, 2.0, 1.5 mA cm -2 '. Figure 1e states '0.5 mA cm -2 ' in place of '2.5 mA cm -2 ', Fig. 1h states '0.4 mA cm -2 ' in place of '2.0 mA cm -2 ', and Fig. 1k states ‘0.3 mA cm -2 ' in place of ‘1.5 mA cm -2 '. Figure 2c states '0.5 mA cm -2 ' in place of '2.5 mA cm -2 ', Fig. 2d states '0.4 mA cm -2 ' in place of '2.0 mA cm -2 ', and Fig. 2e states '0.3 mA cm -2 ' in place of '1.5 mA cm -2 '. Figure 2j and k states ‘0.3 mA cm -2 ', '0.4 mA cm -2 ', '0.5 mA cm -2 ' in place of '1.5 mA cm -2 ', '2.0 mA cm -2 ', and '2.5 mA cm -2 ', respectively. The figure legend of Fig. 3b states '0.4 mA cm -2 ' in place of '2.0 mA cm -2 '. The figure legend of Supplementary Fig. 1 states '0.5 mA cm -2 ' in place of '2.5 mA cm -2 '. This has been corrected in the PDF and HTML versions of the Article.

36 MATERIALS SCIENCE↗

Magnetic field fluctuations during substorms

Before a magnetospheric substorm and during its early phases the magnetic field magnitude in the geomagnetic tail increases and field lines in the nighttime hemisphere assume a more tail-like configuration. Before the substorm onset a minimum amount of magnetic flux is observed to cross the neutral sheet which means that the neutral sheet currents attain their most earthward locations and their greatest current densities. This configuration apparently results from an increased transport of magnetic flux to the tail caused by a southward interplanetary magnetic field. The field begins relaxing toward a more dipolar configuration at the time of a substorm onset with the recovery probably occurring first between 6 and 10 R sub E. This recovery must be associated with magnetospheric convection which restores magnetic flux to the dayside hemisphere. Field aligned currents appear to be required to connect magnetospheric currents to the auroral electrojets, implying that a net current flows in a limited range of longitudes. Space measurements supporting current systems are limited. More evidence exists for the occurrence of double current sheets which do not involve net current at a given longitude.

Fairfield, D. H.↗

Characterization of reaction kinetics in a porous electrode

A continuum-model approach, analogous to porous electrode theory, was applied to a thin-layer cell of rectangular and cylindrical geometry. A reversible redox couple is assumed, and the local reaction current density is related to the potential through the formula of Hubbard and Anson for a uniformily accessible thin-layer cell. The placement of the reference electrode is also accounted for in the analysis. Primary emphasis is placed on the effect of the solution-phase ohmic potential drop on the voltammogram characteristics. Correlation equations for the peak-potential displacement from E(sup 0 prime) and the peak current are presented in terms of two dimensionless parameters.

Fedkiw, Peter S.↗

Physical Characteristics of Unstructured Coronal Clouds

Active regions in the inner solar corona, when observed in X-ray emission, consist of bright, hot loops surrounded by unstructured clouds. The emission from the clouds extends to a height of≈4–5×104km at temperatures of ≈2–3 MK. These “hot clouds” are variable, but persist for many days and do not appear to connect directly to the active region streamers or other large-scale structures observed higher in the corona. We present an observational analysis of these diffuse structures to establish basic plasma parameters such as magnetic field strength, particle density, and temperature. The values ofβ, the ratio of the plasma pressure to the magnetic field pressure, were found to be generally less than unity, though often approaching unity in the upper portions of the active region, where the hot clouds are located. The magnetic field may therefore only partially confine these regions and inhibit flare-like instabilities that could otherwise be driven by gradients of plasma pressure and current density.

The Sun↗

Operando neutron imaging-guided gradient design of Li-ion solid conductor for high-mass-loading cathodes

High-mass-loading cathodes are crucial for achieving high energy density in all-solid-state batteries from the lab scale to industry. However, as mass-loading increases, electrochemical performance is significantly compromised due to sluggish kinetics. In this work, operando neutron imaging is deployed on a high-mass-loading NMC 811 cathode of 33 mg/cm 2 (5.0 mAh/cm 2 ) and directly visualizes the lithiation prioritization of the cathode active material (CAM) from the solid electrolyte membrane side to the current collector side. In addition to the tortuosity, another key limitation on ion transfer in the cathode arises from the mismatch between the uniform distribution of the solid electrolyte (catholyte) in the conventional composite cathode and the non-uniform Li + flux generated by the faradaic reaction of CAMs. Therefore, we engineer a gradient in the catholyte concentration to match the Li + flux distribution as a means of eliminating the ion transfer obstacle. This approach demonstrates enhanced rate performance, even with high-mass-loading cathodes. A LiCoO 2 composite cathode with 100 mg/cm 2 high-mass-loading exhibits an areal capacity of 10.4 mAh/cm 2 at a current density of 2.25 mA/cm 2 . This work provides insight into the ion-transport limitation in thick cathodes and demonstrates an effective gradient design to overcome the kinetic barrier and achieve high battery performance.

Batteries↗

A round bobbin critical current measurement and thermal runaway simulation of REBCO coated conductors

A round bobbin test has been widely used to measure critical current Ic of practical superconductors including Nb–Ti, Nb3Sn, and Bi-2212 round strands at 4.2 K and in high magnetic fields but rarely used for rare earth-barium-copper-oxide (REBCO) coated conductor tapes. Here, we applies this method to REBCO tapes and test their Ic at 77 K, self-field, and 4.2 K with a magnetic field of 14 T applied parallel to the tape. The sample carries very high current densities; it is 1.3 m long and has a dense array of voltage taps that allows probing localized thermal runaways and correlation with Ic variations along the length. At 77 K, the Ic values of all sections were measured and found to be rather uniform. However, at 4.2 K, we found that a 3 cm section has 90% of the overall voltage drop and it went into thermal runaways upon further increasing current. Thus, at 4.2 K, we were prevented by localized thermal runaways and unable to determine Ic of most of the REBCO conductor sections; this behavior is different from Bi-2212 and Bi-2223 for which Ic of all turns of a round barrel sample can be determined. We simulate REBCO tapes during current ramping to a thermal runaway and analyze impacts of various factors including cooling, conductor n-values, and thickness of stabilizer on the thermal runaway current Iq. The combined experiments and simulations identify n-value as a crucial factor that leads to the observed differences between Bi-2212 and REBCO. Together with cooling and the standard deviation of Ic variations along the length, the n-value determines whether Iq is above or below the average Ic of a long piece of conductor and their ratio Iq/Ic,ave, greatly affecting quench detection and thermal runaway prevention strategies of Bi-2212 and REBCO magnets.

Mosat, Marek↗

Single-gap isotropic s- wave superconductivity in single crystals AuSn 4

In this article, London, λ L (T), and Campbell, λ C (T), penetration depths were measured in single crystals of a topological superconductor candidate AuSn 4 . At low temperatures, λ L (T) is exponentially attenuated and, if fitted with the power law, λ(T) ~ T n , gives exponents n > 4, indistinguishable from the isotropic single s- wave gap Bardeen-Cooper-Schrieffer (BCS) asymptotic. The superfluid density fits perfectly in the entire temperature range to the BCS theory. The superconducting transition temperature, T c = 2.40 ± 0.05 K, does not change after 2.5 MeV electron irradiation, indicating the validity of the Anderson theorem for isotropic s- wave superconductors. Campbell penetration depth before and after electron irradiation shows no hysteresis between the zero-field cooling (ZFC) and field cooling (FC) protocols, consistent with the parabolic pinning potential. Interestingly, the critical current density estimated from the original Campbell theory decreases after irradiation, implying that a more sophisticated theory involving collective effects is needed to describe vortex pinning in this system. In general, our thermodynamic measurements strongly suggest that the bulk response of the AuSn 4 crystals is fully consistent with the isotropic s- wave weak-coupling BCS superconductivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Development and Characterization of High-Efficiency, High-Specific Impulse Xenon Hall Thrusters

This dissertation presents research aimed at extending the efficient operation of 1600 s specific impulse Hall thruster technology to the 2000 to 3000 s range. Motivated by previous industry efforts and mission studies, the aim of this research was to develop and characterize xenon Hall thrusters capable of both high-specific impulse and high-efficiency operation. During the development phase, the laboratory-model NASA 173M Hall thrusters were designed and their performance and plasma characteristics were evaluated. Experiments with the NASA-173M version 1 (v1) validated the plasma lens magnetic field design. Experiments with the NASA 173M version 2 (v2) showed there was a minimum current density and optimum magnetic field topography at which efficiency monotonically increased with voltage. Comparison of the thrusters showed that efficiency can be optimized for specific impulse by varying the plasma lens. During the characterization phase, additional plasma properties of the NASA 173Mv2 were measured and a performance model was derived. Results from the model and experimental data showed how efficient operation at high-specific impulse was enabled through regulation of the electron current with the magnetic field. The electron Hall parameter was approximately constant with voltage, which confirmed efficient operation can be realized only over a limited range of Hall parameters.

Hofer, Richard R.↗

Passivation‐Induced Species Dynamics and Microstructural Evolution in Solid‐State Lithium–Sulfur Cathodes

Solid-state lithium–sulfur (SSLS) batteries offer high theoretical energy density, yet their practical viability is hindered by poor sulfur utilization and limited rechargeability. At the core of this challenge lies the passivating nature of Li 2 S, which restricts ionic and electronic transport, suppresses interfacial activity, and severely impedes the reversibility of electrochemical reactions. In this study, we elucidate the mechanistic origins of these limitations by resolving how charge and discharge species form, grow, and spatially evolve within the cathode microstructure under varied current densities and electrode compositions. By resolving the species distribution at the particle scale and coupling it with Raman spectroscopy and X-ray diffraction, we demonstrate how Li 2 S formation induces localized surface passivation that progressively limits electrochemical accessibility within the cathode microstructure. Sulfur utilization is found to be strongly governed by the interplay between sulfur loading, residual porosity, and interfacial architecture. High sulfur contents result in buried, electrochemically isolated domains due to poor solid electrolyte (SE) percolation, while low sulfur contents trigger SE degradation via parasitic reactions. The resulting sulfur-porosity maps delineate the mechanistic boundaries between reversible and transport-limited regimes, offering actionable design guidance for SSLS cathodes with enhanced sulfur utilization.

electrode microstructure↗