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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

The effect of copper additives on hybrid Zr-based chemical conversion coating morphology and chemical compositions

In the realm of corrosion protection, Zr-based conversion coatings offer an environmentally friendly, chromate-free alternative to conventional coating. This study uses advanced X-ray, electron microscopy and electrochemical testing techniques to better understand the impact of varying Cu²⁺ ion concentrations on the characteristics of Zr-based coatings on Fe substrates. Our findings demonstrate that within the tested conditions, higher Cu²⁺ additive concentrations at 40 ppm enhance surface characteristics, increasing stability towards anti-corrosion capability, particularly under NaCl treatment. Conversely, at a lower Cu²⁺ concentration of 20 ppm, coatings exhibited more significant dissolution of Cu clusters and increased vulnerability to chloride-induced degradation. X-ray photoelectron spectroscopy and synchrotron X-ray fluorescence (XRF) and X-ray absorption near edge structure (XANES) spectroscopy analyses revealed Cu²⁺ formation in Cu20, while Cu40 retained its metallic state (Cu⁰) with a slower reaction rate. Cu20 offers some protection but lacks durability, whereas in Cu40, lower I corr , and enhance corrosion resistance, making it ideal for protective coatings in salt-water environments. This study underscores the importance of balancing Cu²⁺ ions concentration in the coating solution to optimize performance, highlighting the role of Cu in enhancing both surface properties and long-term stability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Oxygen and Proton Transport in Flooded Graphene Pores with N-Dopants and Defects

Reactant transport is an important consideration in the design of ideal electrode structures. For the oxygen reduction reaction catalyzed by Pt/C in proton exchange membrane fuel cell cathodes, O 2 and H + delivery to Pt surfaces and H 2 O transport away are required. Some Pt nanoparticles may only be accessible via micropores that are too small for ionomer molecules to enter, possibly requiring flooding for H + transport. Here, to test if these “buried” Pt particles can play a role in activity through this proposed transport mechanism, we have performed atomic-scale simulations based on reactive force field molecular dynamics with an emphasis on confinement below 20 Å. Diffusion coefficients as a function of the molar concentration and local environment have been evaluated in water domains confined in two-dimensional graphene nanochannels of various channel heights representing a morphological model for micropores in proton exchange fuel cell cathodes. Our study shows that local atomic-scale structures can strongly modify H + , O 2 , and H 2 O transport rates in flooded micropores less than 20 Å in size. We find that there is a critical crossover in diffusion behavior around the 20 Å spacing with larger pores having bulk-like diffusion properties and confinement below 20 Å monotonically decreases diffusion rates. As pore size decreases, we observe locally dispersed water regions that ultimately strand reactants from long-distance transport. These findings suggest that flooded micropores may in fact be viable transport pathways for relevant reactants and products if the pore walls on opposite sides remain separated by ≥10 Å separation. Furthermore, the confinement effect is so strong that N-doping and C-vacancy defects in the C pore wall have only a minimal impact on diffusion rates and their effects are counterintuitively more apparent at larger spacings. These findings provide valuable insight regarding cathode performance and the role “stranded” catalyst particles may play in fuel cell cathodes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Open library of g-functions for 34,321 configurations

Thermal response functions, known as g-functions, are commonly used in ground heat exchanger design tools and whole building energy simulation programs to simulate the ground heat exchanger performance. Calculation of g-functions can be quite computationally time-consuming, particularly as the number of boreholes gets large. However, once the g-function is computed, the actual simulation time can be quite short, particularly if a hybrid time-step (Cullin and Spitler 2011) approach is used. Because of this, pre-computed g-function libraries are commonly used in design tools and building simulation tools. This paper describes development of a new, publicly available library containing g-functions for 34,321 borehole field configurations; for each configuration, gfunctions are provided for 5 depths to allow interpolation between different borehole-to-height ratios. The available configurations include configurations in standard shapes: lines, rectangles, open rectangles, L-shapes, and U-shapes. It also includes new configurations: C-shapes, lopsided-U-shapes, and zoned rectangles, which are rectangular configurations with different interior and perimeter spacing of the boreholes.

Spitler, Jeffery↗
DOE OSTI2026

Vertical Structure of Local Disk Galaxies Revealed by DESI Imaging Data

The vertical structure of galactic disks is an important probe of the disk assembly history. Here we investigate the vertical structure of a sample of 79 local disk galaxies within 50 Mpc using data from the Dark Energy Spectroscopic Instrument Legacy Imaging Surveys. Vertical luminosity profiles as a function of radius in the g, r, and z bands are extracted and fitted using a single-component sech2 model to determine scale height and its radial variation (i.e., flaring). Our measurements indicate local galactic disks are overall thin with negligible flaring. The median scale heights at 1 R e are 0.21, 0.22, and 0.22 kpc in the g, r, and z bands, respectively, while the median radial gradients of scale height are −0.006, 0.003, and 0.001 in these bands. These values are consistent with that of the geometric thin disk of the Milky Way represented by metal-rich, low-[α/Fe] populations, confirming the weak flaring of the geometric thin disk. A clear positive correlation of scale height with stellar mass is observed down to the low-mass end of 10 7 M ⊙ . These results provide a homogeneous benchmark for the vertical structure of nearby disk galaxies and establish the cosmological representativeness of the Milky Way thin disk.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1973

Application of a pulsed laser for measurements of bathymetry and algal fluorescence.

The technique of measuring water depths with an airborne pulsed dye laser is studied, with emphasis on the degrading effect of some environmental and operational parameters on the transmitted and reflected laser signals. Extrapolation of measurements of laser stimulated fluorescence, performed as a function of both the algal cell concentration and the distance between the algae and the laser/receiver, indicate that a laser system operating from a height of 500 m should be capable of detecting chlorophyll concentrations as low as 1.0 mg/cu m.-

Hickman, G. D.↗
NASA NTRS1982

The relationship between wind vector and normalized radar cross section used to derive Seasat-A Satellite Scatterometer winds

The Seasat-A Satellite Scatterometer (SASS) ocean normalized radar cross section (NRCS) dependence on the 19.5-m neutral stability wind vector may be specified as a function of radar incidence angle, the angle between wind direction and radar azimuth, and the neutral stability wind speed expressed in m/sec at a height of 19.5 m. An account is given of the development of models both expressing this relationship and providing the basis of inversion of NRCS to SASS winds, from initially aircraft scatterometer measurement-based forms to three Seasat field-validation experiments which furnish model NRCS versus surface windspeed data for comparison with SASS data.

Schroeder, L. C.↗
NASA NTRS1984

Antenna induced range smearing in MST radars

There is considerable interest in developing stratosphere troposphere (ST) and mesosphere stratosphere troposphere (MST) radars for higher resolution to study small-scale turbulent structures and waves. At present most ST and MST radars have resolutions of 150 meters or larger, and are not able to distinguish the thin (40 - 100 m) turbulent layers that are known to occur in the troposphere and stratosphere, and possibly in the mesosphere. However the antenna beam width and sidelobe level become important considerations for radars with superior height resolution. The objective of this paper is to point out that for radars with range resolutions of about 150 meters or less, there may be significant range smearing of the signals from mesospheric altitudes due to the finite beam width of the radar antenna. At both stratospheric and mesospheric heights the antenna sidelobe level for lear equally spaced phased arrays may also produce range aliased signals. To illustrate this effect the range smearing functions for two vertically directed antennas have been calculated, (1) an array of 32 coaxial-collinear strings each with 48 elements that simulates the vertical beam of the Poker Flat, Glaska, MST radar; and (2) a similar, but smaller, array of 16 coaxial-collinear strings each with 24 elements.

Watkins, B. J.↗
NASA NTRS1990

Monthly mean global climatology of temperature, wind, geopotential height and pressure for 0-120 km

This paper presents a monthly mean climatology of zonal mean temperature, zonal wind, and geopotential height with nearly pole-to-pole coverage (80 deg S-80 deg N) for 0-120 km which can be used as a function of altitude and pressure. This climatology reproduces most of the characteristic features of the atmosphere such as the lowering and cooling of the mesopause and the lowering and warming of the stratopause during the summer months at high latitudes. A series of zonal wind profiles is also presented comparing this climatological wind with monthly mean climatological direct wind measurements in the upper mesosphere and lower thermosphere. The two data sets compare well below 80 km, with some general seasonal trend agreement observed above 80 km. The zonal wind at the equator presented here simulates the observed features of the semiannual oscillation in the upper stratosphere and mesosphere.

Chandra, Sushil↗
NASA NTRS1990

The extent of the unstable Monin-Obukhov layer for temperature and humidity above complex hilly grassland

An analysis is given of radiosonde measurements of the potential temperature, specific humidity, and wind profiles under unstable windy conditions during the First International Satellite Land Surface Climatology Project Field Experiment in Kansas. It is found that about 86 percent of the profiles have a height range over which the Monin-Obukhov (1954) similarity is valid. It is shown that the Businger-Dyer version of the similarity functions (Businger, 1988) is satisfactory for analyzing radiosonde profiles.

Brutsaert, Wilfried↗
DOE OSTI2021

First-principles theory for Schottky barrier physics

We develop a first-principles theory for Schottky barrier physics. The Poisson equation is solved selfconsistently with the electrostatic charge density over the entire barrier using the density functional theory (DFT) electronic structure converged locally, allowing computation of a Schottky barrier entirely from DFT involving thousands of atomic layers in the semiconductor (SC). Here, the induced charge in the bulk consists of conduction and valence band charges from doping and band bending, as well as charge from the evanescent states in the gap of the SC. The Schottky barrier height (SBH) is determined when the induced charge density and the induced electrostatic potential reach self-consistency. Tests on the GaAs-graphene and Si/Al heterostructures yield SBH, width, along with depletion and inversion layers obtained self-consistently as functions of temperature and bulk doping.

36 MATERIALS SCIENCE↗
NASA NTRS1999

Advanced Techniques for Assessment of Postural and Locomotor Ataxia, Spatial Orientation, and Gaze Stability

In addition to adapting to microgravity, major neurovestibular problems of space flight include postflight difficulties with standing, walking, turning corners, and other activities that require stable upright posture and gaze stability. These difficulties inhibit astronauts' ability to stand or escape from their vehicle during emergencies. The long-ter7n goal of the NSBRI is the development of countermeasures to ameliorate the effects of long duration space flight. These countermeasures must be tested with valid and reliable tools. This project aims to develop quantitative, parametric approaches for assessing gaze stability and spatial orientation during normal gait and when gait is perturbed. Two of this year's most important findings concern head fixation distance and ideal trajectory analysis. During a normal cycle of walking the head moves up and down linearly. A simultaneous angular pitching motion of the head keeps it aligned toward an imaginary point in space at a distance of about one meter in front of a subject and along the line of march. This distance is called the head fixation distance. Head fixation distance provides the fundamental framework necessary for understanding the functional significance of the vestibular reflexes that couple head motion to eye motion. This framework facilitates the intelligent design of counter-measures for the effects of exposure to microgravity upon the vestibular ocular reflexes. Ideal trajectory analysis is a simple candidate countermeasure based upon quantifying body sway during repeated up and down stair stepping. It provides one number that estimates the body sway deviation from an ideal sinusoidal body sway trajectory normalized on the subject's height. This concept has been developed with NSBRI funding in less than one year. These findings are explained in more detail below. Compared to assessments of the vestibuo-ocular reflex, analysis of vestibular effects on locomotor function is relatively less well developed and quantified. We are improving this situation by applying methodologies such as nonlinear orbital stability to quantify responses and by using multivariate statistical approaches to link together the responses across separate tests. In this way we can exploit the information available and increase the ability to discriminate between normal and pathological responses. Measures of stability and orientation are compared to measures such as dynamic visual acuity and with balance function tests. The responses of normal human subjects and of patients having well documented pathophysiologies are being characterized. When these studies are completed, we should have a clearer idea about normal and abnormal patterns of eye, head, and body movements during locomotion and their stability in a wide range of environments. We plan eventually to use this information to validate the efficacy of candidate neurovestibular and neuromuscular rehabilitative techniques. Some representative studies made during this year are summarized.

Wall, Conrad., III↗
DOE OSTI2018

Enhancement of effective linear RF surface resistance of superconducting surfaces by microscopic topography

Minimization of Radio-Frequency (RF) dissipation on superconducting surfaces is of interest for many applications. A prominent one is the use of Superconducting RF (SRF) cavities for charged particle acceleration. In addition to our previous investigation which characterized the occurrence of high-field non-linear losses by microscopic surface topography, the topic of increased linear losses as a function of surface topographic character merits consideration. Surfaces with isotropic homogeneous surface topography may be well characterized by power spectral density (PSD) derived from systematic height measurements. PSD characterizations of representative niobium cavity surface treatments have been developed: Electro-Polishing (EP), Nano-Mechanical Polishing (NMP) and Centrifugal Barrel Polishing (CBP) A perturbation model based on PSD statistical analysis is used to calculate additional RF loss on these surfaces when superconducting. The model assesses the penetration depth effects for a superconductor. We thus estimate the RF power dissipation ratio between these rough surfaces and an ideal smooth surface.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2018

Intermediate range order in supercooled water

The temperature dependence of the heights of the first and second x-ray diffraction peaks in supercooled water measured down to 244 K are found to display very different behaviours. While the first peak intensity remains essentially constant, the second peak increases strongly with decreasing temperature. In real space this is concomitant with the reduction of the number of non-bonded interstitial molecules between the first and second shells. It is found that although the first O-O shell in supercooled water is unchanged upon supercooling, the variations in intermediate range order are mainly associated with the growth of a predominantly tetrahedral network that is distinctly different from ice-Ih. Moreover, in this temperature regime we find a direct correlation between the height of the second diffraction peak and the intensity changes in the 2nd, 3rd, 4th and 5th peaks in the oxygen-oxygen pair distribution function.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2021

High fusion performance in Super H-mode experiments on Alcator C-Mod and DIII-D

The ‘Super H-Mode’ regime is predicted to enable pedestal height and fusion performance substantially higher than standard H-Mode operation. This regime exists due to a bifurcation of the pedestal pressure, as a function of density, that is predicted by the EPED model to occur in strongly shaped plasmas above a critical pedestal density. Experiments on Alcator C-Mod and DIII-D have achieved access to the Super H-Mode (and Near Super H) regime, and obtained very high pedestal pressure, including the highest achieved on a tokamak (pped ~ 80 kPa) in C-Mod experiments operating near the ITER magnetic field. DIII-D Super H experiments have demonstrated strong performance, including the highest stored energy in the present configuration of DIII-D (W ~ 2.2–3.2 MJ), while utilizing only about half of the available heating power (Pheat ~ 7–12 MW). These DIII-D experiments have obtained the highest value of peak fusion gain, QDT,equiv ~ 0.5, achieved on a medium scale (R < 2 m) tokamak. Sustained high performance operation (βN ~ 2.9, H98 ~ 1.6) has been achieved utilizing n = 3 magnetic perturbations for density and impurity control. Pedestal and global confinement has been maintained in the presence of deuterium and nitrogen gas puffing, which enables a more radiative divertor condition. A pair of simple performance metrics is developed to assess and compare regimes. Super H-Mode access is predicted for ITER and expected, based on both theoretical prediction and observed normalized performance, to allow ITER to achieve its goals (Q = 10) at Ip < 15 MA, and to potentially enable more compact, cost effective pilot plant and reactor designs.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1972

A real time spectrum to dose conversion system

A system has been developed which permits the determination of dose in real time or near real time directly from the pulse-height output of a radiation spectrometer. The technique involves the use of the resolution matrix of a spectrometer, the radiation energy-to-dose conversion function, and the geometrical factors, although the order of matrix operations is reversed. The new technique yields a result which is mathematically identical to the standard method while requiring no matrix manipulations or resolution matrix storage in the remote computer. It utilizes only a single function for each type dose required and each geometric factor involved.

Farmer, B. J.↗
NASA NTRS1977

Theoretical aspects of tidal and planetary wave propagation at thermospheric heights

A simple semiquantitative model is presented which allows analytic solutions of tidal and planetary wave propagation at thermospheric heights. This model is based on perturbation approximation and mode separation. The effects of viscosity and heat conduction are parameterized by Rayleigh friction and Newtonian cooling. Because of this simplicity, one gains a clear physical insight into basic features of atmospheric wave propagation. In particular, we discuss the meridional structures of pressure and horizontal wind (the solutions of Laplace's equation) and their modification due to dissipative effects at thermospheric heights. Furthermore, we solve the equations governing the height structure of the wave modes and arrive at a very simple asymptotic solution valid in the upper part of the thermosphere. That 'system transfer function' of the thermosphere allows one to estimate immediately the reaction of the thermospheric wave mode parameters such as pressure, temperature, and winds to an external heat source of arbitrary temporal and spatial distribution. Finally, the diffusion effects of the minor constituents due to the global wind circulation are discussed, and some results of numerical calculations are presented.

Volland, H.↗
NASA NTRS1979

Particle size and velocity measurement in flames by laser anemometer

Simultaneous droplet size and velocity measurements by a particle counting Laser Doppler Anemometer (LDA) in kerosene fuel sprays under burning and non-burning conditions are presented. Particle sizes are derived from pulse height analysis of the mean LDA signals and velocities are simultaneously determined by measuring Doppler shift frequencies. The measurements show that droplet velocity is a function of droplet diameter for burning and non-burning conditions, and spatially averaged size distributions are derived from velocity data. A comparison of results obtained under burning and non-burning conditions show changes in size distribution due to preferential vaporization of small droplets, acceleration due to thermal expansion of gases, and corresponding changes in droplet momentum.

Chigier, N. A.↗
NASA NTRS1984

Estimates of the geostrophic stream function in the western North Pacific from XBT surveys

Bernstein and White (1981) have argued that the 300 m temperature field in the western North Pacific reflects the 100/1000 dbar geostrophic stream function of the upper ocean where 100/1000 dbar implies the 100 dbar surface relative to the 1000 dbar surface. The correlation between upper ocean dynamic height and temperature in this region provides the basis for their argument. The involved relationship suggests that it may be possible to monitor the relative upper ocean geostrophic transport, as well as energy relations and heat fluxes with expendable bathythermograph (XBT) surveys. Certain discrepancies between data from different sources are felt to result from problems with the XBT observations. The present investigation is concerned with the determination of the ability of XBT surveys to estimate geostrophic currents, taking into account a comparison of directly measured data with estimated shears. Discrepancies are found to be related to an underestimation of the dynamic height gradients.

Koblinsky, C. J.↗