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At least 757 records · Page 42

Atomic-scale secondary electron imaging for heterogeneous catalysis research

Surface characterization at the atomic scale is essential for understanding the catalytic properties of supported metal nanoparticles. Secondary electron (SE) imaging in scanning transmission electron microscopy (STEM) provides three-dimensional surface topographic information, enabling the characterization of the size, morphology, and distribution of supported nanoparticles. Furthermore, real-time observation of catalyst materials in a gaseous environment would enhance the understanding of catalyst dynamics under operational conditions. Ongoing technical developments in SE-STEM and advancements in computational methods are expected to facilitate atomic-scale surface observations and enable more quantitative and statistical analyses. This progress will not only elucidate fundamental mechanisms at the atomic level but also provide comprehensive and universal insights into catalyst performances. Here, this minireview showcases the recent advancements and research findings in surface-sensitive SE imaging in STEM for the characterization of active catalyst materials.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Recurrent Activity from Active Asteroid (248370) 2005 QN 173 : A Main-belt Comet

We present archival observations of main-belt asteroid (248370) 2005 QN 173 (also designated 433P) that demonstrate this recently discovered active asteroid (a body with a dynamically asteroidal orbit displaying a tail or coma) has had at least one additional apparition of activity near perihelion during a prior orbit. We discovered evidence of this second activity epoch in an image captured 2016 July 22 with the DECam on the 4 m Blanco telescope at the Cerro Tololo Inter-American Observatory in Chile. As of this writing, (248370) 2005 QN 173 is just the eighth active asteroid demonstrated to undergo recurrent activity near perihelion. Our analyses demonstrate (248370) 2005 QN 173 is likely a member of the active asteroid subset known as main-belt comets, a group of objects that orbit in the main asteroid belt that exhibit activity that is specifically driven by sublimation. We implement an activity detection technique, wedge photometry, that has the potential to detect tails in images of solar system objects and quantify their agreement with computed antisolar and antimotion vectors normally associated with observed tail directions. We present a catalog and an image gallery of archival observations. The object will soon become unobservable as it passes behind the Sun as seen from Earth, and when it again becomes visible (late 2022) it will be farther than 3 au from the Sun. Our findings suggest (248370) 2005 QN 173 is most active interior to 2.7 au (0.3 au from perihelion), so we encourage the community to observe and study this special object before 2021 December.

79 ASTRONOMY AND ASTROPHYSICS↗

Galileo infrared imaging spectrometry measurements at the Moon

Imaging spectrometer observations were made of the surface of the Moon during the December 1990 flyby of the Earth-Moon system by the Galileo spacecraft. This article documents this data set and presents analyses of some of the data. The near infrared mapping spectrometer (NIMS) investigation obtained 17 separate mosaics of the Moon in 408 spectral channels between about 0.7 and 5.2 micrometers. The instrument was originally designed to operate in orbit about Jupiter and therefore saturates at many spectral channels for most measurement situations at 1 AU. However, sufficient measurements were made of the Moon to verify the proper operation of the instrument and to demonstrate its capabilities. Analysis of these data show that the NIMS worked as expected and produced measurements consistent with previous ground-based telescopic studies. These are the first imaging spectrometer measurements of this type from space for the Moon, and they illustrate several major points concerning this type of observation and about the NIMS capabilities specifically. Of major importance are the difference between framing and scanning instruments and the effects of the spacecraft and the scan platform on the performance of such and experiment. The science return of subsequent NIMS and other investigation measurements will be significantly enhanced by the experience and results gained.

Mccord, Thomas B.↗

Landsat 8 Remote Sensing Reflectance (Rrs) Products: Evaluations, Intercomparisons, and Enhancements

The Operational Land Imager (OLI) onboard Landsat-8 is generating high-quality aquatic science products, the most critical of which is the remote sensing reflectance (Rrs), defined as the ratio of water-leaving radiance to the total downwelling irradiance just above water. The quality of the Rrs products has not, however, been extensively assessed. This manuscript provides a comprehensive evaluation of Level-1B, i.e., top of atmosphere reflectance, and Rrs products available from OLI imagery under near-ideal atmospheric conditions in moderately turbid waters. The procedure includes a) evaluations of the Rrs products at sites included in the Ocean Color component of the Aerosol Robotic Network (AERONET-OC), b) intercomparisons and cross-calibrations against other ocean color products, and c) optimizations of vicarious calibration gains across the entire OLI observing swath. Results indicate that the near-infrared and shortwave infrared (NIR-SWIR) band combinations yield the most robust and stable Rrs retrievals in moderately turbid waters. Intercomparisons against products derived from the Visible Infrared Imaging Radiometer Suite (VIIRS) and the Moderate Resolution Imaging Spectroradiometer onboard the Aqua platform (MODISA) indicate slight across-track non-uniformities (<1%) associated with OLI scenes in the blue bands. In both product domains (TOA and Rrs), on average, the OLI products were found larger in radiometric responses in the blue channels. Following the implementation of updated vicarious calibration gains and accounting for across-track non-uniformities, matchup analyses using independent in-situ validation data confirmed improvements in Rrs products. These findings further support high-fidelity OLI-derived aquatic science products in terms of both demonstrating a robust atmospheric correction method and providing consistent products across OLI's imaging swath.

Pahlevan, Nima↗

Spectral Dimensionality and Scale of Urban Radiance

Characterization of urban radiance and reflectance is important for understanding the effects of solar energy flux on the urban environment as well as for satellite mapping of urban settlement patterns. Spectral mixture analyses of Landsat and Ikonos imagery suggest that the urban radiance field can very often be described with combinations of three or four spectral endmembers. Dimensionality estimates of Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) radiance measurements of urban areas reveal the existence of 30 to 60 spectral dimensions. The extent to which broadband imagery collected by operational satellites can represent the higher dimensional mixing space is a function of both the spatial and spectral resolution of the sensor. AVIRIS imagery offers the spatial and spectral resolution necessary to investigate the scale dependence of the spectral dimensionality. Dimensionality estimates derived from Minimum Noise Fraction (MNF) eigenvalue distributions show a distinct scale dependence for AVIRIS radiance measurements of Milpitas, California. Apparent dimensionality diminishes from almost 40 to less than 10 spectral dimensions between scales of 8000 m and 300 m. The 10 to 30 m scale of most features in urban mosaics results in substantial spectral mixing at the 20 m scale of high altitude AVIRIS pixels. Much of the variance at pixel scales is therefore likely to result from actual differences in surface reflectance at pixel scales. Spatial smoothing and spectral subsampling of AVIRIS spectra both result in substantial loss of information and reduction of apparent dimensionality, but the primary spectral endmembers in all cases are analogous to those found in global analyses of Landsat and Ikonos imagery of other urban areas.

Small, Christopher↗

Scalable method for micro-CT analysis enables large scale quantitative characterization of brain lesions and implants

Anatomic evaluation is an important aspect of many studies in neuroscience; however, it often lacks information about the three-dimensional structure of the brain. Micro-CT imaging provides an excellent, nondestructive, method for the evaluation of brain structure, but current applications to neurophysiological or lesion studies require removal of the skull as well as hazardous chemicals, dehydration, or embedding, limiting their scalability and utility. Here we present a protocol using eosin in combination with bone decalcification to enhance contrast in the tissue and then employ monochromatic and propagation phase-contrast micro-CT imaging to enable the imaging of brain structure with the preservation of the surrounding skull. Instead of relying on descriptive, time-consuming, or subjective methods, we develop simple quantitative analyses to map the locations of recording electrodes and to characterize the presence and extent of hippocampal brain lesions.

3-D reconstruction↗

The use of computer graphic techniques for the determination of ventricular function.

Description of computer techniques employed to increase the speed, accuracy, reliability, and scope of angiocardiographic analyses determining human heart dimensions. Chamber margins are traced with a Calma 303 digitizer from projections of the angiographic films. The digitized margins of the ventricular images are filed in a computer for subsequent analysis. The margins can be displayed on the television screen of a graphics unit for individual study or they can be viewed in real time (or at any selected speed) to study dynamic changes in the chamber outline. The construction of three dimensional images of the ventricle is described.

Sandler, H.↗

The Einstein observatory stellar X-ray database - An overview

The paper presents the motivations for and the methodology followed in building the 'Einstein Observatory Stellar X-ray Database' based on the uniform analysis of all Einstein Observatory Imaging Proportional Counter fields obtained during the life of the HEAO-2 mission. The database has been implemented using the INGRES database system, so that statistical analyses of the properties of the full detection catalog are relatively easily and flexibly accomplished. Some illustrative examples will furnish a general view both of the kind and the amount of the archived information, and of the statistical approach used in analyzing the global properties of the data.

Sciortino, S.↗

The gamma ray continuum spectrum from the galactic center disk and point sources

A light curve of gamma-ray continuum emission from point sources in the galactic center region is generated from balloon and satellite observations made over the past 25 years. The emphasis is on the wide field-of-view instruments which measure the combined flux from all sources within approximately 20 degrees of the center. These data have not been previously used for point-source analyses because of the unknown contribution from diffuse disk emission. In this study, the galactic disk component is estimated from observations made by the Gamma Ray Imaging Spectrometer (GRIS) instrument in Oct. 1988. Surprisingly, there are several times during the past 25 years when all gamma-ray sources (at 100 keV) within about 20 degrees of the galactic center are turned off or are in low emission states. This implies that the sources are all variable and few in number. The continuum gamma-ray emission below approximately 150 keV from the black hole candidate 1E1740.7-2942 is seen to turn off in May 1989 on a time scale of less than two weeks, significantly shorter than ever seen before. With the continuum below 150 keV turned off, the spectral shape derived from the HEXAGONE observation on 22 May 1989 is very peculiar with a peak near 200 keV. This source was probably in its normal state for more than half of all observations since the mid-1960's. There are only two observations (in 1977 and 1979) for which the sum flux from the point sources in the region significantly exceeds that from 1E1740.7-2942 in its normal state.

Gehrels, Neil↗

Cloud and Precipitation Analyses using Merged Datasets from Two Airborne Microwave Radiometers Covering 10–183 GHz

Microwave radiometers provide valuable insight into the structure and characteristics of clouds and precipitation. In NASA’s airborne remote-sensing arsenal, the Advanced Microwave Precipitation Radiometer (AMPR) and the Conical Scanning Millimeter-wave Imaging Radiometer (CoSMIR) have been used extensively in field campaigns throughout the world. AMPR operates with four channels between 10.7 and 85.5 GHz, while CoSMIR operates with nine channels ranging from 50.3 to 183.31 GHz. Although these datasets provide key information when used separately, the combination of these radiometers covers virtually the full range of frequencies used by the Global Precipitation Measurement (GPM) Microwave Imager (GMI), enabling suborbital observations to compare with GPM spaceborne measurements. This presentation will detail the merger of AMPR and CoSMIR data during two NASA airborne field campaigns: the Integrated Precipitation and Hydrology Experiment (IPHEx) and the Olympic Mountains Experiment / Radar Definition Experiment (OLYMPEX/RADEX). Other field campaigns, such as the Investigation of Microphysics and Precipitation for Atlantic Coast-Threatening Snowstorms (IMPACTS), may be included as well. Using the merged brightness temperature dataset, features of precipitating and non-precipitating clouds containing liquid and/or ice hydrometeors will be discussed from selected flight segments. Geophysical retrievals derived from these brightness temperatures using a one-dimensional variational (1DVAR) technique and/or multi-linear regression equations will also be employed in these analyses. Observed transitions between precipitating and non-precipitating systems will be explored in greater detail. Dropsonde data will be used to provide environmental contexts throughout each flight, and additional observations (e.g., from airborne and/or land-based radar) will be incorporated to supplement the radiometer-based results. The broader implications of these results and pathways for future work will also be discussed.

Corey G. Amiot↗

Satellite Image Mapping of Tree Mortality in the Sierra Nevada Region of California from 2013 to 2016

Extreme drought from 2013 to 2015 has been linked to extensive tree dieback in the Sierra-Nevada region of California. Landsat satellite imagery was analysed for the region from Lake Tahoe to the southern Sequoia National Forest with the objective of understanding the patterns of tree mortality in the years of 2013 to 2015 and into the near-normal precipitation year of 2016. The main mapping results for Landsat moisture index differences from year-to-year showed that the highest coverage of tree dieback was located in the Sierra and Sequoia National Forests, at four to five times greater area each year than within any other National Park or National Forest unit. Since 2013, over 50% of the Sierra Nevada forest dieback area was detected in the mid elevation zone of 1000-2000 m. The total area of tree mortality in the lower elevation zone of 500-1000 m did not grow notably from 2015 to 2016. Within the largest California river drainages in the Sierra region, new tree mortality in 2015 was detected mainly below 1200 m elevation, whereas new tree mortality in 2016 was detected mainly at higher elevations, up to about 2200 m. In three out of the four years studied, results showed that about 60% of all new tree mortality areas were located on north-facing hill slopes.

Satellite↗

Geobotanical information contained in Landsat Thematic Mapper images covering southern Missouri

Landsat Thematic Mapper (TM) data collected in the late summer, fall, and winter of 1982 over forested bedrocks in southeastern Missouri were used in conjunction with forest surveys, field work, aerial photographs, and laboratory analyses to evaluate multispectral and seasonal information from visible and reflected IR data. The forested bedrock included granites, rhyolites, carbonates, and sandstones. High reflectance in band 4 (760-900 nm) in the summer scene corresponds to regions of xeric forest type. The fact that the xeric regions tend to develop flat-topped canopies, as opposed to irregular canopy surfaces of the wetter mesic areas, may partially control the TM response in bands 4, 5 (155-175 nm) and 7 (208-235 nm). The xeric regions correlated with soils having poor water retention capabilities, such as rhyolites and certain carbonate rocks with nonporous residum layers. An opposite relationship between xeric and mesic forest biomass was noted, if the commonly used TM band ratio 4/3 was used as a surrogate biomass measure. The high band 4 response over xeric forests gives anomalously high biomass estimates.

Green, G.↗

A phenomenological approach to multisource data integration: Analysing infrared and visible data

A new method is described for combining multisensory data for remote sensing applications. The approach uses phenomenological models which allow the specification of discriminatory features that are based on intrinsic physical properties of imaged surfaces. Thermal and visual images of scenes are analyzed to estimate surface heat fluxes. Such analysis makes available a discriminatory feature that is closely related to the thermal capacitance of the imaged objects. This feature provides a method for labelling image regions based on physical properties of imaged objects. This approach is different from existing approaches which use the signal intensities in each channel (or an arbitrary linear or nonlinear combination of signal intensities) as features - which are then classified by a statistical or evident approach.

Nandhakumar, N.↗

The S-PLUS Fornax Project (S+FP): A first 12-band glimpse of the Fornax galaxy cluster

ABSTRACT The Fornax galaxy cluster is the richest nearby (D ∼ 20 Mpc) galaxy association in the southern sky. As such, it provides a wealth of opportunities to elucidate on the processes where environment holds a key role in transforming galaxies. Although it has been the focus of many studies, Fornax has never been explored with contiguous homogeneous wide-field imaging in 12 photometric narrow and broad bands like those provided by the Southern Photometric Local Universe Survey (S-PLUS). In this paper, we present the S-PLUS Fornax Project (S+FP) that aims to comprehensively analyse the galaxy content of the Fornax cluster using S-PLUS. Our data set consists of 106 S-PLUS wide-field frames (FoV∼1.4 × 1.4 deg2) observed in five Sloan Digital Sky Survey-like ugriz broad bands and seven narrow bands covering specific spectroscopic features like [O ii], Ca ii H+K, Hδ, G band, Mg b triplet, Hα, and the Ca ii triplet. Based on S-PLUS specific automated photometry, aimed at correctly detecting Fornax galaxies and globular clusters in S-PLUS images, our data set provides the community with catalogues containing homogeneous 12-band photometry for ∼3 × 106 resolved and unresolved objects within a region extending over ∼208 deg2 (∼5 Rvir in RA) around Fornax’ central galaxy, NGC 1399. We further explore the eagle and IllustrisTNG cosmological simulations to identify 45 Fornax-like clusters and generate mock images on all 12 S-PLUS bands of these structures down to galaxies with M⋆ ≥ 108 M⊙. The S+FP data set we put forward in this first paper of a series will enable a variety of studies some of which are briefly presented.

Astronomy & Astrophysics↗

Coordination and establishment of centralized facilities and services for the University of Alaska ERTS survey of the Alaskan environment

The author has identified the following significant results. Specifications have been prepared for the engineering design and construction of a digital color display unit which will be used for automatic processing of ERTS data. The color display unit is a disk refresh memory with computer interfaced input and a color cathode ray tube output display. The system features both analog and digital post disk data manipulation and a versatile color coding device suitable for displaying not only images, but also computer generated graphics such as diagrams, maps, and overlays. Input is from IBM compatible 9 track, 800 BPI tapes, as generated by an IBM 360 computer. ERTS digital tapes are read into the 360, where various analyses such as maximum likelihood classification are performed and the results are written on a magnetic tape which is the input to the color display unit. The greatest versatility in the data manipulation area is provided by the minicomputer built into the color display unit, which is off-line from the main 360 computer. The minicomputer is able to read any line from the refresh disk and place it in its 4K-16 bit memory. Considerable flexibility is available for post-processing enhancement of images by the investigator.

Belon, A. E.↗

Impact of Salinity on Ground Ice Distribution Across an Arctic Coastal Polygonal Tundra Environment

The heterogeneous distribution of ground ice in the Arctic is a key driver of uneven ground subsidence as permafrost thaws, significantly impacting infrastructure and surface/subsurface hydrology. These topographic and hydrological changes contribute to major uncertainties in energy and carbon fluxes and storage in a warming Arctic. This study aims to improve our understanding of the controls on ground ice and organic matter distribution within the top 3 m of permafrost in coastal polygonal tundra near Utqiagvik, Alaska. To this end, we apply a neural network approach to bulk density distributions derived from nondestructive X-ray tomography of soil cores, trained with laboratory analyses, to improve the resolution and spatial coverage of estimates of dry bulk density, ice content, and organic matter content. In addition, we use capacitively coupled geophysical imaging to map soil electrical conductivity and salinity variations. The results show that sedimentary deposits from ocean transgressions, along with subsequent ice wedge polygon geomorphological processes, jointly influence the distribution of ice content at various scales. The impact of the latter decreases with depth, whereas the influence of salinity and sedimentary history increases. Although the controls on the distribution of soil organic matter content (g/cm 3 ) remain unclear, the pronounced heterogeneity in bulk density strongly influences its calculation from laboratory mass fraction measurements (g/g). From a methodological perspective, the interdependencies among soil components and the need for increased data coverage underscore the value of high-resolution density measurements, such as using X-ray tomography. Overall, this study emphasizes the importance of considering salinity constraints on ice content distribution in coastal permafrost regions. The results are expected to aid in the development of data products and process representations in geomorphological and ecosystem models.

Dafflon, Baptiste [Lawrence Berkeley National Labo↗

Understanding the structural and morphological effects of synthesis route on NpO 2

The availability of actinide standard materials for use in nuclear safeguard applications is critical, as is thorough characterization thereof. Although accurate trace element compositions and isotopic considerations are paramount for deployment of reference standards, structural characterization is also essential towards accurately describing the chemical form and potential matrix effects in candidate materials. Here, to this end, samples of NpO 2 were synthesized via a direct denitration (DD) method and probed with powder X-ray diffraction (PXRD), Raman spectroscopy, and scanning electron microscopy (SEM) for structural and morphological characterization and comparison with NpO 2 materials produced via modified direct denitration (MDD). PXRD confirmed the bulk identity of NpO 2 , and no additional phases were identified using this method. Analysis of Raman data collected using a 532 nm excitation wavelength indicates that samples are mostly phase pure; however, some variability in spectral features is observed. Analysis of additional spectroscopic data collected with a 785 nm excitation wavelength revealed variability in the relative intensity of spectral features. Raman spectroscopy indicates that the sample is primarily NpO 2 ; however, additional signals indicate possible structural disorder, oxidized species, or potential contributions from other Np phases. To further investigate the possibility of additional phase contributions within the sample of NpO 2 , Raman spectroscopic mapping was employed to examine the homogeneity of the sample produced via DD. From this analysis, we determined that despite variability in the intensity of Raman-active vibrational modes, consistent spectra are obtained throughout the area of the sample investigated. SEM images show aggregates with variable sizes and shapes, with rounded, primary particles possessing an average diameter of approximately 100 nm. Comparison of the results of these multimodal analyses to the literature indicates that the crystal chemical, spectroscopic, and microstructural properties of NpO 2 vary based on synthesis method, even if X-ray diffraction data indicate that the bulk phase is NpO 2 .

Direct denitration↗

Uncovering the truth about M101, NGC 3938, and their significant others through radiative transfer

ABSTRACT Solving the inverse problem in spiral galaxies, that allows the derivation of the spatial distribution of dust, gas, and stars, together with their associated physical properties, directly from panchromatic imaging observations, is one of the main goals of this work. To this end, we used radiative transfer models to decode the spatial and spectral distributions of the nearby face-on galaxies M101 and NGC 3938. In both cases, we provide excellent fits to the surface-brightness distributions derived from GALEX, SDSS, 2MASS, Spitzer, and Herschel imaging observations. Together with previous results from M33, NGC 628, M51, and the Milky Way, we obtain a small statistical sample of modelled nearby galaxies that we analyse in this work. We find that in all cases Milky Way-type dust with Draine-like optical properties provide consistent and successful solutions. We do not find any ‘submm excess’, and no need for modified dust-grain properties. Intrinsic fundamental quantities like star-formation rates (SFR), specific SFR (sSFR), dust opacities, and attenuations are derived as a function of position in the galaxy and overall trends are discussed. In the SFR surface density versus stellar mass surface density space, we find a structurally resolved relation (SRR) for the morphological components of our galaxies, that is steeper than the main sequence (MS). Exception to this is for NGC 628, where the SRR is parallel to the MS.

Pricopi, D.↗