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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43

Stress evolution and creep deformation in solid-oxide electrolysis cell systems – Dynamic modeling and multi-objective optimization to maximize stack life and efficiency

Here, this study develops a thermal stress model of solid-oxide electrolysis cells (SOECs) including a model for creep strain and failure probability that is integrated with a dynamic plant-wide model of a hydrogen production process. Uncertainties in key material properties of the cell are quantified to assess their impact on stress profile variability. The oxygen electrode is found to have about 10 times higher failure probability compared to the fuel electrode. The study shows that if the stack operation is not optimized, cycling operation would lead to stress build-up eventually leading to catastrophic failure. A dynamic optimization problem is set up for obtaining the optimal operational profile considering a variable hydrogen production rate. Due to the tradeoff between the efficiency and stress build-up, the dynamic optimization problem is multi-objective. It is observed that the optimizer can considerably reduce the stress build-up (i.e., can increase the stack life) albeit at the cost of a lower efficiency thus exhibiting strong tradeoffs between capital and operating costs. For example, if the stack would be replaced in 0.5 yr, specific energy requirement would be 48.5 kWh/kg H 2 while for a stack replacement time of about 6 yr, the specific energy requirement rises by about 4.2 %.

SOEC↗

a priori uncertainty quantification of reacting turbulence closure models using Bayesian neural networks

While many physics-based closure model forms have been posited for the sub-filter scale (SFS) in large eddy simulation (LES), vast amounts of data available from direct numerical simulations (DNS) create opportunities to leverage data-driven modeling techniques. Albeit flexible, data-driven models still depend on the dataset and the functional form of the model chosen. Increased adoption of such models requires reliable uncertainty estimates both in the data-informed and out-of-distribution regimes. Here, in this work, we employ Bayesian neural networks (BNNs) to capture both epistemic and aleatoric uncertainties in a reacting flow model. In particular, we model the filtered progress variable scalar dissipation rate which plays a key role in the dynamics of turbulent premixed flames. We demonstrate that BNN models can provide unique insights about the structure of uncertainty of the data-driven closure models. We also propose a method for the incorporation of out-of-distribution information in a BNN, which can be used for out-of-distribution query detection. The efficacy of the model is demonstrated by a priori evaluation on a dataset consisting of a variety of flame conditions and fuels.

97 MATHEMATICS AND COMPUTING↗

Dynamics of Bridgman-Stockbarger growth of non-dilute binary alloys

The coupling between heat and mass transfer in the Bridgman-Stockbarger growth of nondilute crystals induces growth rate transients that are longer than those caused by heat transfer alone. The dynamics of the diffusion-controlled growth for thermophysical properties representative of Pb(1-x)Sn(x)Te and Hg(1-x)Cd(x)Te are computed from a one-dimensional solidification model which includes melt-crystal phase behavior. Results show that the growth rate response to a step change in pull rate for both systems differs from the exponential decay observed for dilute alloys and that growth rates cannot be inferred from axial segregation data in nondilute systems due to the dependence of the segregation coefficient on composition.

Bourret, E. D.↗

Method for compression testing of composite materials at high strain rates

A method is presented for testing composite materials in compression at strain rates up to approximately 500 per s. The method uses a thin ring specimen (4 in. in diameter, 1 in. wide, six-eight plies thick) loaded dynamically by an external pressure pulse applied explosively through a liquid. Strains in the specimen and in a steel calibration ring are recoorded with a digital processing oscilloscope. Results are plotted by an x-y plotter in the form of a dynamic stress-strain curve. Data analysis is based on a numerical solution of the equation of motion. A computer program is used which involves smoothing and approximation of the strain magnitude, strain rate, and strain acceleration. Dynamic stress-strain curves obtained for 0-deg and 90-deg specimens of two graphite/epoxy composites are presented.

Daniel, I. M.↗

A new approach to the design of time-varying control systems with application to the Space Shuttle Boost

A general approach to the analysis and design of closed-loop control for slowly time-varying linear systems is presented. The approach uses the method of generalized multiple scales in which slow and fast dynamics are systematically separated by employing different 'clocks' which measure time at varying rates. The clocks, which are necessarily nonlinear functions of time, are chosen in such a manner that the system dynamics are asymptotically invariant with respect to the new time scale. A transfer function relating the output to the input for general linear slowly time-varying systems is developed and represents the actual system under certain conditions. The clock function is shown to satisfy an algebraic characteristic equation and can be determined in terms of the coefficients. The approach can be viewed as an extension of time-invariant linear feedback control theory.

Ramanth, R. V.↗

A comparison of frequency estimation techniques for high-dynamic trajectories

A comparison is presented for four different estimation techniques applied to the problem of continuously estimating the parameters of a sinusoidal Global Positioning System (GPS) signal, observed in the presence of additive noise, under extremely high-dynamic conditions. Frequency estimates are emphasized, although phase and/or frequency rate are also estimated by some of the algorithms. These parameters are related to the velocity, position, and acceleration of the maneuvering transmitter. Estimated performance at low carrier-to-noise ratios and high dynamics is investigated for the purpose of determining the useful operating range of an approximate Maximum Likelihood (ML) estimator, an Extended Kalman Filter (EKF), a Cross-Product Automatic Frequency Control (CPAFC) loop, and a digital phase-locked loop (PPL). Numerical simulations are used to evaluate performance while tracking a common trajectory exhibiting high dynamics.

Vilnrotter, V. A.↗

Scalability analysis of heavy-duty gas turbines using data-driven machine learning

With the increasing integration of variable renewable energy sources into power systems, the role of flexible power generation technologies like gas turbines (GT) in rapid grid balancing remains crucial. This sustained importance underscores the need for scaled and precise modeling of GT to ensure effective integration within evolving energy frameworks. While physics-driven GT models integrate thermodynamics, fluid dynamics, and combustion principles, they often rely on approximate mathematical representations to accommodate scaling that may not capture the actual complex dynamics for GTs and inertial effects associated to GTs with different ratings. In this study, a data-driven model is proposed using machine learning (ML) techniques to conduct GT scalability analysis and performance evaluation with high accuracy. The ML model, trained on data from various operating conditions and performance parameters, aims to uncover intricate relationships and patterns, resembling GT characteristics at different scales (ratings). The model is developed to capture complex system interaction and to adapt to changing operational scenarios at different capacities, providing valuable insights of power system dynamics. In this study, the real-time digital simulator platform was employed to generate training data for the ML model and assess its dynamic characteristics. The ultimate objective was to develop a detailed modeling framework based on governing equations and data-driven ML capable of predicting key performance indicators, in thermal systems such as GTs, including power output, speed, fuel consumption, and exhaust temperature under diverse operating conditions at different scales. The developed ML framework demonstrated high accuracy, with mean relative errors for GT power prediction, reference speed, exhaust temperature, and compressor pressure ratio (CPR) parameters consistently below 0.1% across typical load fluctuation scenarios. Maximum deviations were limited to approximately 0.5 K for exhaust temperature and 0.009 for CPR, underscoring the model’s ability to replicating dynamic GT behavior with high precision. The adaptability of the ML model enables its application across diverse operational conditions and its extension to other thermal systems. By leveraging advanced ML techniques, this study presents a robust and scalable modeling framework that enhances GT simulation precision, facilitating improved integration into evolving power systems.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Group evaporation

Liquid fuel combustion process is greatly affected by the rate of droplet evaporation. The heat and mass exchanges between gas and liquid couple the dynamics of both phases in all aspects: mass, momentum, and energy. Correct prediction of the evaporation rate is therefore a key issue in engineering design of liquid combustion devices. Current analytical tools for characterizing the behavior of these devices are based on results from a single isolated droplet. Numerous experimental studies have challenged the applicability of these results in a dense spray. To account for the droplets' interaction in a dense spray, a number of theories have been developed in the past decade. Herein, two tasks are examined. One was to study how to implement the existing theoretical results, and the other was to explore the possibility of experimental verifications. The current theoretical results of group evaporation are given for a monodispersed cluster subject to adiabatic conditions. The time evolution of the fluid mechanic and thermodynamic behavior in this cluster is derived. The results given are not in the form of a subscale model for CFD codes.

Shen, Hayley H.↗

On CCN Effects upon Convective Cold Pool Timing and Features

Abstract Cold pools produced by deep convection can initiate new convection, and their representation in larger-scale weather and climate models could improve prediction of the extent and timing of upscale growth. Cold pools originate from latent cooling from precipitation changing phase, but little attention has been paid to microphysical influences on cold pool characteristics, particularly CCN effects. Datasets obtained from the CACTI and RELAMPAGO field campaigns, along with idealized numerical modeling, are utilized to investigate the hypothesis that convective storms forming in higher-CCN environments generate their first surface rainfall later, delaying cold pool initiation. Aircraft observations of CCN and shallow convection on 9 days do suggest a CCN effect. Those ingesting more CCN contained fewer drizzle drops, although a decreased cloud depth with increasing CCN was also likely a limiting factor. In three of those cases that later developed into deep convection, the timing of cold pool onset was not ubiquitously delayed in environments with more CCN. Idealized numerical simulations suggest that an ordinary thunderstorm can experience small delays in cold pool onset with increasing CCN due to changes in graupel production, but CCN effects on the cold pool from a supercell thunderstorm can be easily overpowered by its unique dynamics. A strong inverse relationship between cold pool strength, expansion rate, and depth with increasing CCN is suggested by the results of the ordinary thunderstorm simulation. Further consideration of CCN appears warranted for future cold pool parameterization development, but other environmental factors affecting storm morphology and precipitation cannot be ignored.

Meteorology & Atmospheric Sciences↗

Variable Dynamic Testbed Vehicle: Dynamics Analysis

The Variable Dynamic Testbed Vehicle (VDTV) concept has been proposed as a tool to evaluate collision avoidance systems and to perform driving-related human factors research. The goal of this study is to analytically investigate to what extent a VDTV with adjustable front and rear anti-roll bar stiffnesses, programmable damping rates, and four-wheel-steering can emulate the lateral dynamics of a broad range of passenger vehicles.

Variable Dynamic Testbed Vehicle VDTV collision av↗

Depth-Resolved Lithiated Gradients in Pristine and Laser-Ablated Anodes During Fast Charging

Laser ablating 3D electrode microstructures is a technique to improve Li-ion battery fast-charge performance. This technique has been theoretically proposed and electrochemically validated previously in the literature. The fundamental principle underlying laser ablation is that the ablated features reduce Li-ion transport pathways, improving access to the electrode active material near the current collector. This, in turn, promotes more homogeneous electrode utilization. The present study seeks to directly affirm the physics attributed to laser ablation using operando high-speed synchrotron X-ray diffraction. In this study, depth-resolved graphite lithiation gradients are measured operando during high-rate (15 min) charging. The depth-resolved lithiation dynamics of both ablated and non-ablated anodes are compared. The results highlight that the laser-ablated graphite electrode has notably more homogeneous utilization as compared to the non-ablated electrode. Additionally, the ablated electrode has a significant delay in reaching the maximum graphite lithiation at the separator, indicating less propensity for lithium plating. During low rate delithiation/discharge (2 hr), the two cells' lithiation gradients converge. Notably, a calibrated physics-based electrochemical model accurately reflects experimental findings, suggesting the potential to use pseudo-4D models not only to optimize laser ablation parameters in fast-charge capable electrodes but also to guide fast charging protocols that avoid lithium plating.

25 ENERGY STORAGE↗

Quasi-Uniform High Speed Foam Crush Testing Using a Guided Drop Mass Impact

A relatively simple method for measuring the dynamic crush response of foam materials at various loading rates is described. The method utilizes a drop mass impact configuration with mass and impact velocity selected such that the crush speed remains approximately uniform during the entire sample crushing event. Instrumentation, data acquisition, and data processing techniques are presented, and limitations of the test method are discussed. The objective of the test method is to produce input data for dynamic finite element modeling involving crash and energy absorption characteristics of foam materials.

Jones, Lisa E.↗

Growth-induced Donnan exclusion influences swelling kinetics in highly charged dynamic polymerization hydrogels

Polymeric gels crosslinked by DNA sequences can exploit DNA strand-displacement reactions to promote swelling through dynamic polymerization. The degree of swelling and the rate of swelling must be directly tunable to achieve the promise of programmable soft matter. Though the kinetics of the strand-displacement reaction provide insertion rates up to 10 4 /Molar/second as measured in bulk solution, DNA hydrogel swelling can take upwards of 30 h to complete. Computational modeling of the reaction-induced swelling of these gels with our recently-developed reactive electrochemomechanical theory (Zimmerman et al., 2024) suggests that their extraordinarily slow swelling is partly due to a scaling mismatch between the addition of charge and the addition of fluid volume, leading to a large transient increase in the fixed charge density. The significant increase in the gel’s fixed charge density, due to the binding of negatively charged DNA, sharply restricts the concentration of mobile hairpins through the phenomenon of Donnan charge exclusion, an effect commonly exploited in nanofiltration applications using polymeric membranes. The scaling problem is overcome when the mean additional swelling provided to the hydrogel by addition of a crosslink is above a critical value, thus the swelling outpaces the charge accumulation, leading the fixed charge density to drop and significantly accelerating the swelling process. This study shows that Donnan exclusion can explain the kinetics of DNA hydrogel swelling, and studies ways to modulate the reaction speed by either modifying the salt concentration or increasing or decreasing the number of base pairs in each DNA sequence.

42 ENGINEERING↗

Skeletal Kinetics Reduction for Astrophysical Reaction Networks

A novel methodology is developed to extract accurate skeletal reaction models for nuclear combustion. Local sensitivities of isotope mass fractions with respect to reaction rates are modeled based on the forced optimally time-dependent (f-OTD) scheme. These sensitivities are then analyzed temporally to generate skeletal models. The methodology is demonstrated by conducting skeletal reduction of constant density and temperature burning of carbon and oxygen relevant to Type Ia supernovae (SNe Ia). The 495-isotopes Torch model is chosen as the detailed reaction network. A map of maximum production of 56 Ni in SNe Ia is produced for different temperatures, densities, and proton-to-neutron ratios. The f-OTD simulations and the sensitivity analyses are then performed with initial conditions from this map. A series of skeletal models are derived and their performances are assessed by comparison against currently existing skeletal models. Previous models have been constructed intuitively by assuming the dominance of α-chain reactions. The comparison of the newly generated skeletal models against previous models is based on the predicted energy release and 44 Ti and 56 Ni abundances by each model. The consequences of ye ≠ 0.5 in the initial composition are also explored where ye is the electron fraction. The simulated results show that 56 Ni production decreases by decreasing ye as expected, and that the 43 Sc is a key isotope in proton and neutron channels toward 56 Ni production. It is shown that an f-OTD skeletal model with 150 isotopes can accurately predict the 56Ni abundance in SNe Ia for ye ≲ 0.5 initial conditions.

79 ASTRONOMY AND ASTROPHYSICS↗

Hexacopter Flight Dynamics on Earth and Martian Surfaces

Since the atmospheric conditions and gravitational field are different for Mars and Earth, the operating flight environments are different, and necessitate Earth-based appropriate modeling, analysis, and simulation for Mars flight vehicles. This paper compares a hexacopter’s flight dynamics in the two environments. The analysis is necessary to determine if a dynamically matched surrogate hexacopter can be designed to conduct reliable testing on Earth, with the goal of successfully operation on Mars. To answer the question, the comprehensive tool FLIGHTLAB® is used to model the hexacopter flight dynamics. Frequency responses in heave, pitch, roll, and yaw rates of the hexacopter in hover are analyzed. The simulation result shows that each attitude response of the designed hexacopter responds very differently in the two environments. The closed-loop response of the hexacopter can be made stable on Earth but not on Mars. Therefore, the proportional feedback technique cannot be utilized to stabilize all four responses altogether. Due to the dynamics of the model being very different in each atmosphere, it is yet not feasible to create a dynamically matched surrogate helicopter that can operate in both environments.

Hexacopter↗

Sensor Spatial Distortion, Visual Latency, and Update Rate Effects on 3D Tracking in Virtual Environments

Several common defects that we have sought to minimize in immersing virtual environments are: static sensor spatial distortion, visual latency, and low update rates. Human performance within our environments during large amplitude 3D tracking was assessed by objective and subjective methods in the presence and absence of these defects. Results show that 1) removal of our relatively small spatial sensor distortion had minor effects on the tracking activity, 2) an Adapted Cooper-Harper controllability scale proved the most sensitive subjective indicator of the degradation of dynamic fidelity caused by increasing latency and decreasing frame rates, and 3) performance, as measured by normalized RMS tracking error or subjective impressions, was more markedly influenced by changing visual latency than by update rate.

Ellis, S. R.↗

Vibration-translation energy transfer in vibrationally excited diatomic molecules

A semiclassical collision model is applied to the study of energy transfer rates between a vibrationally excited diatomic molecule and a structureless atom. The molecule is modeled as an anharmonic oscillator with a multitude of dynamically coupled vibrational states. Three main aspects in the prediction of vibrational energy transfer rates are considered. The applicability of the semiclassical model to an anharmonic oscillator is first evaluated for collinear encounters. Second, the collinear semiclassical model is applied to obtain numerical predictions of the vibrational energy transfer rate dependence on the initial vibrational state quantum number. Thermally averaged vibration-translation rate coefficients are predicted and compared with CO-He experimental values for both ground and excited initial states. The numerical model is also used as a basis for evaluating several less complete but analytic models. Third, the role of rational motion in the dynamics of vibrational energy transfer is examined. A three-dimensional semiclassical collision model is constructed with coupled rotational motion included. Energy transfer within the molecule is shown to be dominated by vibration-rotation transitions with small changes in angular momentum. The rates of vibrational energy transfer in molecules with rational frequencies that are very small in comparison to their vibrational frequency are shown to be adequately treated by the preceding collinear models.

Mckenzie, R. L.↗

Constraints on the Martian cratering rate imposed by the SNC meteorites and Vallis Marineris layered deposits

Following two independent lines of evidence -- estimates of the age and formation time of a portion of the Martian geologic column exposed in the layered deposits and the crystallization and ejection ages of the SNC meteorites -- it appears that the Martian cratering rate must be double the lunar rate or even higher. This means models such as NHII or NHIII (Neukum and Hiller models II and III), which estimate the Martian cratering rate as being several times lunar are probably far closer to reality on Mars than lunar rates. The effect of such a shift is profound: Mars is transformed from a rather Moon-like place into a planet with vigorous dynamics, multiple large impacts, erosion, floods, and volcanism throughout its history. A strong shift upward in cratering rates on Mars apparently solves some glaring problems; however, it creates others. The period of time during which Earth-like atmospheric conditions existed, the liquid water era on Mars, persists in NHIII up to only 0.5 b.y. ago. Scenarios of extended Earth-like conditions on Mars have been discounted in the past because they would have removed many of the craters from the early bombardment era found in the south. It does appear that some process of crater removal was quite vigorous in the north during Mars' past. Evidence exists that the northern plains may have been the home of long-lived seas or perhaps even a paleo-ocean, so models exist for highly localized destruction of craters in the north. However, the question of how the ancient crater population could be preserved in the south under a long liquid-water era found in any high-cratering-rate models is a serious question that must be addressed. It does appear to be a higher-order problem because it involves low-energy dynamics acting in localized areas, i.e., erosion of craters in the south of Mars, whereas the two problems with the low-cratering-rate models involve high-energy events acting over large areas: the formation of the Vallis Marineris, the SNC ejecting impacts, and the global atmospheric pressure and temperature conditions that allow liquid water to exist as a robust entity anywhere on the Martian surface. In any case, it appears Mars is a more complex and dynamic planet than previously supposed. It has canyons dating from the middle to late period of its history that contain apparent lake sediments bedded deeper than most sediments on Earth. Recent multiple, violent impacts on Mars have apparently provided us with multiple random samples of its surface that all crystallized less than 1.5 b.y. ago. These things cannot be accommodated in our present cratering chronologies of Mars, based on 1x lunar cratering rates, without great difficulties. These difficulties suggest that a new chronology, probably based on NHII or even NHIII, should be adopted; this new chronology will provide us with a new view of Mars as a dynamic planet of rich history.

Brandenburg, J. E.↗