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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43

High Gradient Magnetic Simulation Final Report 2025

Over the course of nearly 2 years, the goal of this project has been to identify methods for the separation of uranium oxide particles from other geologic materials. The primary motivation is to assess methods for enhancing the extraction and throughput of actinide particles from environmental samples, enabling the evaluation of these trace actinides through more traditional methods such as thermal ionization mass spectrometry or secondary ion mass spectrometry.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Atmospheric Gases as Quantitative Indicators of Urbanization Across Land-Use Gradients

The urban heat island (UHI) effect is a significant phenomenon characterized by higher surface temperatures in cities compared to surrounding rural areas. This change in the Earth's energy balance presents considerable challenges for urban populations, increasing heat exposure, straining energy infrastructure, and exacerbating health vulnerabilities. Quantifying UHI intensity is challenging due to blurred distinctions between urban and rural areas as land-use patterns evolve. To address this challenge, the present study builds on the framework established by Salvador et al. (2025) and investigates the use of atmospheric constituents, specifically volatile organic compounds (VOCs) and inorganic gases, as tracers of urbanization levels. A key improvement in this approach is the inclusion of a designated true rural site for comparison. Field measurements were conducted at two locations in the Southeastern United States during the summer of 2025. Inorganic gases were monitored continuously, while VOC samples were collected biweekly and analyzed using a proton transfer reaction time-of-flight mass spectrometer. The urban site exhibited elevated concentrations of anthropogenic inorganic gases, with carbon monoxide and nitrogen dioxide averaging 878 ppb and 17.99 ppb, respectively. In contrast, the rural site showed lower levels of these pollutants, 796 ppb for carbon monoxide and 12.46 ppb for nitrogen dioxide, while displaying higher concentrations of biogenic VOCs, including isoprene and monoterpenes at 1.24 ppb and 0.08 ppb, respectively. Extended mass spectral analyses revealed distinct chemical differences between the two sites, supporting the observed variability of major gases. Overall, these findings are consistent with our previous research and highlight the value of atmospheric constituents as effective indicators of urbanization, thereby improving our understanding of UHI dynamics.

54 ENVIRONMENTAL SCIENCES↗

Multi-fidelity is the new annealing: Gradient-free learning of posterior densities via transport maps

To tackle concentrated, multi-modal Bayesian inference problems, we propose using an annealed importance sampling procedure. To do this, we form a sequence of annealed distributions and employ transport maps to act as a surrogate of each distribution. This process is demonstrated on a few examples, favorably showing its potential for efficiently parallelizing the process of PDE evaluations and allowing for surrogates that we can sample from exactly.

van Bloemen Waanders, Bart G [Sandia National Labo↗

Ionic Liquids for Direct Air Capture of CO 2 using Electric‐Field‐Mediated Moisture Gradient Process (Final Technical Report)

The final report provides executive summary, a list of publications, and information on training graduate students and postdoctoral researchers. We carried out computational and experimental research on understanding molecular-level mechanism of how CO 2 is absorbed in a solution containing ethylene glycol as the solvent and KOH as the salt in the presence of ionic liquids and under the influence of electric field. In doing so, we developed an automated high-throughput method which allowed us to measure the solubility of CO 2 in a large number of ionic liquids, considerably speeding up the CO 2 solubility measurement. We also demonstrated how varying the concentration of ionic liquids in ethylene glycol can result in a maximum in ionic conductivity. Reaction of CO 2 and subsequent release results in a 50% reduction when the process is operated at an ionic liquid-ethylene glycol concentration yielding maximum ionic conductivity amongst all the ionic liquid-ethylene glycol combinations studied as a part of this research. We utilized machine learning models to identify unique ionic liquid-solvent combinations with ionic conductivity much higher than that measured for ionic liquid-ethylene glycol combinations. We demonstrated that the rate of CO 2 reaction with KOH in ethylene glycol can be optimized with the type of ionic liquid and its concentration. Overall, the research led to publication of 10 peer-reviewed research articles and several presentations at national conferences. We are also in the process of developing additional manuscripts based on the research carried out as a part of this project. Two graduate students and two postdoctoral researchers were supported on the funding.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Particle Size gradients in Modeled Vibrated beds of continuously sized powders

Ensuring powder mixture homogeneity is paramount for modern powder processing techniques. A promising recent development in the field of powder processing, resonant acoustic mixing (RAM), proposes to use low-frequency vertical vibration to deliver well-mixed powders without relying on mechanical agitators. However, an undesirable outcome of vibrations applied to granular materials comprised of non-uniform particle sizes is the tendency towards size segregation. In this work, we experimentally ex

Renfroe, Steven Emad [Sandia National Laboratories↗

Studies of whistler propagation along a plasma density gradient that is parallel to the magnetic field

Low frequency plasma wave generation in space is important for both scientific and practical applications. One of the most promising techniques for doing this is to directly inject whistler waves into the space environment from an antenna onboard one or more satellites. This technique has been discussed for years, but there are still open questions about the best way to generate plasma waves. So far, most theoretical [Kondrat92], lab based [Pribyl2010, Stenzel2016] and space-based experiments [DSX] have focused on studying the generation of whistler waves from an electric dipole antenna. However, a dipole antenna is very inefficient because it puts a lot of energy in waves that are not effective for most applications. Theoretical [Kondrat92] and lab experimental [Stenzel2016] results indicate that a loop antenna is much more efficient at generating whistler waves than a dipole antenna. A satellite experiment will need to be developed to demonstrate that whistler waves can be generated from a loop antenna in the space environment. The challenge is that to efficiently transmit whistler modes in the natural plasma environment of space, the loop antenna will have to be very large. For example, at L=2 (one earth radius away from the surface of the earth) a loop antenna would need a radius on the order of ~200 m to radiate efficiently, as shown in fig. 1, left. The antenna size and complexity would require a prohibitively large and expensive satellite mission. Our proposed innovation is to exploit the fact that the characteristic wavelength of whistler waves decreases in more dense plasma, which reduces the size needed for an antenna to radiate efficiently. Fortunately, a technique already exists for enhancing the local plasma density in space, called a plasma contactor [Kovaleski2001]. A plasma contactor can be used to create a local environment where the plasma density is enhanced around the satellite, which in turn reduces the size of an antenna that is needed to radiate efficiently (Fig. 1, right).

42 ENGINEERING↗