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At least 775 records · Page 43

Photochemistry of biogenic emissions over the Amazon forest

The boundary layer chemistry over the Amazon forest during the dry season is simulated with a photochemical model. Results are in good agreement with measurements of isoprene, NO, ozone, and organic acids. Photochemical reactions of biogenic isoprene and NOx can supply most of the ozone observed in the boundary layer. Production of ozone is very sensitive to the availability of NOx, but is insensitive to the isoprene source strength. High concentrations of total odd nitrogen (NOy) are predicted for the planetary boundary layer, about 1 ppb in the mixed layer and 0.75 ppb in the convective cloud layer. Most of the odd nitrogen is present as PAN-type species, which are removed by dry deposition to the forest. The observed daytime variations of isoprene are explained by a strong dependence of the isoprene emission flux on sun angle. Nighttime losses of isoprene exceed rates of reaction with NO3 and O3 and appear to reflect dry-deposition processes. The 24-hour averaged isoprene emission flux is calculated to be 38 mg/sq m per day. Photooxidation of isoprene could account for a large fraction of the CO enrichment observed in the boundary layer under unpolluted conditions and could constitute an important atmospheric source of formic acid, methacrylic acid, and pyruvic acid.

Jacob, Daniel J.↗

Diel Variations in Optical Properties of Micromonas pusilla, a Prasinophyte

A laboratory experiment was conducted on cultures of Micromonas pusilla, a marine prasinophyte, to investigate how cell growth and division affect the optical properties over the light:dark cycle. Measurements were made of cell size and concentration, attenuation and absorption coefficients, flow cytometric light scattering (in forward and side directions), chlorophyll and carbon content. Refractive index was calculated using the anomalous diffraction approximation Cells were about 1.5 micrometers in diameter and exhibited phased division, with the major division burst occurring during the night. Typical diel variations were observed, with cells increasing in size and light scattering during the day as they photosynthesize and decreasing at night upon division. The cells were in ultradian growth, with more than one division per day, at a light level of 120 Mu-mol photons m/sq/sec. Since these cells are similar in size to small phytoplankton that are typically abundant in field samples, these results can be used in the interpretation of diel variations in light scattering in natural populations of phytoplankton.

DuRand, Michele D.↗

Estimating Terra MODIS Polarization Effect Using Ocean Data

Terra MODIS has been known since pre-launch to have polarization sensitivity, particularly in shortest-wavelength bands 8 and 9. On-orbit reflectance trending of pseudo-invariant sites show a variation in reflectance as a function of band and scan mirror angle of incidence consistent with time-dependent polarization effects from the rotating double-sided scan mirror. The MODIS Characterization Support Team [MCST] estimates the Mueller matrix trending from this variation as observed from a single desert site, but this effect is not included in Collection 6 [C6] calibration. Here we extend the MCSTs current polarization sensitivity monitoring to two ocean sites distributed over latitude to helpestimate the uncertainties in the derived Mueller matrix. The Mueller matrix elements derived for polarization-sensitive Band 8 for a given site are found to be fairly insensitive to surface brdf modeling. The site-to-site variation is a measure of the uncertainty in the Mueller estimation.Results for band 8 show that the polarization correction reduces mirror-side striping by up to 50% and reduces the instrument polarization effect on reflectance time series of an ocean target.

Wald, Andrew E.↗

Lower stratosphere measurements of variation with latitude of CF2Cl2, CFCl3, CCl4, and N2O profiles in the northern hemisphere

Measurements were made from a U-2 aircraft of profiles of CF2Cl2, CFCl3, CCl4 and N2O in the lower stratosphere in a meridional survey at a longitude of 159 deg W during the period October 1 to November 14, 1976. The latitude distributions obtained show a marked decrease in mixing ratio with increasing latitude from about 7 deg N in the Intertropical Convergence Zone to about 79 deg N. The results suggest the importance of meridional transport and mixing in the stratosphere in accounting, at least in part, for the observed profile variation with latitude. The contaminants C2F4Cl2, C2F3Cl3, CHCCl3 and SF6 were also detected but their mixing ratios were small and no accurate standards were prepared for them.

Vedder, J. F.↗

Experimental observation of the geodesic acoustic frequency limit for the NBI-driven Alfvén eigenmodes in TJ-II

We study Alfvén Eigenmodes (AEs) in the TJ-II heliac in hydrogen plasmas heated by hydrogen cofield NBI. Taking advantage of the unique TJ-II flexibility in varying plasma current, we have observed strong variation of the AE frequency from f AE ~ 30 to ~ 220 kHz for selected modes. An advanced heavy ion beam probe diagnostic determines the spatial location and internal amplitudes of the modes. The modes satisfy a local AE dispersion relation including the geodesic acoustic frequency that represents the lowest frequency of the mode. Linear MHD-modeling with STELLGAP and FAR3D codes shows that the calculated temporal evolution of the mode frequency reproduces the observed maxima and minima at the same time intervals with a similar frequency range and the radial profile peaks near the outer edge of the observed one.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

One-dimensional temperature measurement of supersonic jet flow by resonantly ionized photoemission thermometry of molecular nitrogen

As the field of fluid dynamics progresses, the demand for sophisticated diagnostic methods to accurately assess flow conditions rises. In this work, resonantly ionized photoemission thermometry (RIPT) has been used to directly target and ionize diatomic nitrogen (N 2 ) to measure one-dimensional (1D) temperature profiles in a supersonic jet flow. This technique can be considered non-intrusive as the premise uses resonantly enhanced multiphoton ionization (REMPI) to target molecular nitrogen. This resonance excites N 2 into absorption bands of the P, Q, and R rotational branches of N 2 ( b 1 Π u ). The ideal (3 + 1) REMPI scheme excites from the ground state and ionizes N 2 ( b 1 Π u ← X 1 Σ g + ) where de-excitation results in photoemission from the first negative band of ionized N 2 + ( B 2 Σ u + → X 2 Σ g + ) as nitrogen returns to the ground state. The resulting emission can be observed using an intensified camera, thus permitting inference of the rotational temperature of ground-state molecular nitrogen. A linearly regressive Boltzmann distribution is applied based on previous calibration data for this technique to quantify the temperature along the ionized line. This work applies this technique to a pure N 2 supersonic jet in cross-flow and counter-flow orientations to demonstrate N 2 RIPT’s applications in a supersonic flow. Temperature variations are observed at different locations downstream of the exit in cross-flow, and axisymmetric in counter-flow, to generate profiles characterizing the flow dynamics. Due to the collisional effects resulting from the number density of N 2 at higher pressures, a (3 + 2) REMPI scheme is observed throughout this text.

Clark, Aleksander (ORCID:0009000855600042)↗

Magnetic Variations Associated With Solar Flares

A report summarizes an investigation of helioseismic waves and magnetic variations associated with solar flares, involving analysis of data acquired by the Michelson Doppler Imager (MDI) aboard the Solar and Heliocentric Observatory (SOHO) spacecraft, the Yohkoh spacecraft, and the Ramaty High Energy Solar Spectroscopic Imager (RHESSI) spacecraft. Reconstruction of x-ray flare images from RHESSI data and comparison of them with MDI magnetic maps were performed in an attempt to infer the changes in the geometry of the magnetic field. It was established that in most flares observed with MDI, downward propagating shocks were much weaker than was one observed in the July 9, 1996 flare, which caused a strong helioseismic response. It was concluded that most of the observed impulsive variations result from direct impact of high-energy particles. Computer codes were developed for further study of these phenomena.

Petrosian, Vahe↗

Exosat and IUE observations of SW UMa during superoutburst

IUE and Exosat observations obtained during the March 1986 superoutburst of the SU UMa type dwarf nova SW UMa are presented. The observations show the presence of a hot, extensive, optically thick disk. The UV fluxes show an increase of 1000 over the quiescent values, implying a large increase in mass accretion rate. The Exosat obserations show an increase in the soft X-ray count rate by a factor of 44 over quiescence, while the medium-energy flux remains undetected. The most surprising result is that the softness ratio in superoutburst is similar to the quiescent value of 0.3. No variation at the orbital or spin periods or at the superhump period are evident in the superoutburst X-ray data. A transient variation is observed at 5.1 minutes similar to that observed in the optical a few days after the X-ray observations.

Szkody, Paula↗

Proteogenomic characterization of difficult-to-treat breast cancer with tumor cells enriched through laser microdissection

Abstract Background Breast cancer (BC) is the most commonly diagnosed cancer and the leading cause of cancer death among women globally. Despite advances, there is considerable variation in clinical outcomes for patients with non-luminal A tumors, classified as difficult-to-treat breast cancers (DTBC). This study aims to delineate the proteogenomic landscape of DTBC tumors compared to luminal A (LumA) tumors. Methods We retrospectively collected a total of 117 untreated primary breast tumor specimens, focusing on DTBC subtypes. Breast tumors were processed by laser microdissection (LMD) to enrich tumor cells. DNA, RNA, and protein were simultaneously extracted from each tumor preparation, followed by whole genome sequencing, paired-end RNA sequencing, global proteomics and phosphoproteomics. Differential feature analysis, pathway analysis and survival analysis were performed to better understand DTBC and investigate biomarkers. Results We observed distinct variations in gene mutations, structural variations, and chromosomal alterations between DTBC and LumA breast tumors. DTBC tumors predominantly had more mutations inTP53,PLXNB3, Zinc finger genes, and fewer mutations inSDC2,CDH1,PIK3CA,SVIL, andPTEN. Notably, Cytoband 1q21, which contains numerous cell proliferation-related genes, was significantly amplified in the DTBC tumors. LMD successfully minimized stromal components and increased RNA–protein concordance, as evidenced by stromal score comparisons and proteomic analysis. Distinct DTBC and LumA-enriched clusters were observed by proteomic and phosphoproteomic clustering analysis, some with survival differences. Phosphoproteomics identified two distinct phosphoproteomic profiles for high relapse-risk and low relapse-risk basal-like tumors, involving several genes known to be associated with breast cancer oncogenesis and progression, includingKIAA1522,DCK,FOXO3,MYO9B,ARID1A,EPRS,ZC3HAV1, andRBM14. Lastly, an integrated pathway analysis of multi-omics data highlighted a robust enrichment of proliferation pathways in DTBC tumors. Conclusions This study provides an integrated proteogenomic characterization of DTBC vs LumA with tumor cells enriched through laser microdissection. We identified many common features of DTBC tumors and the phosphopeptides that could serve as potential biomarkers for high/low relapse-risk basal-like BC and possibly guide treatment selections.

Oncology↗

SABER (TIMED) and MLS (UARS) Temperature Observations of Mesospheric and Stratospheric QBO and Related Tidal Variations

More than three years of temperature observations from the SABER (TIMED) and MLS WARS) instruments are analyzed to study the annual and inter-annual variations extending from the stratosphere into the upper mesosphere. The SABER measurements provide data from a wide altitude range (15 to 95 km) for the years 2002 to 2004, while the MLS data were taken in the 16 to 55 km altitude range a decade earlier. Because of the sampling properties of SABER and MLS, the variations with local solar time must be accounted for when estimating the zonal mean variations. An algorithm is thus applied that delineates with Fourier analysis the year-long variations of the migrating tides and zonal mean component. The amplitude of the diurnal tide near the equator shows a strong semiannual periodicity with maxima near equinox, which vary from year to year to indicate the influence from the Quasi-biennial Oscillation (QBO) in the zonal circulation. The zonal mean QBO temperature variations are analyzed over a range of latitudes and altitudes, and the results are presented for latitudes from 48"s to 48"N. New results are obtained for the QBO, especially in the upper stratosphere and mesosphere, and at mid-latitudes. At Equatorial latitudes, the QBO amplitudes show local peaks, albeit small, that occur at different altitudes. From about 20 to 40 km, and within about 15" of the Equator, the amplitudes can approach 3S K for the stratospheric QBO or SQBO. For the mesospheric QBO or MQBO, we find peaks near 70 km, with temperature amplitudes reaching 3.5"K, and near 85 km, the amplitudes approach 2.5OK. Morphologically, the amplitude and phase variations derived from the SABER and MLS measurements are in qualitative agreement. The QBO amplitudes tend to peak at the Equator but then increase again pole-ward of about 15" to 20'. The phase progression with altitude varies more gradually at the Equator than at mid-latitudes. A comparison of the observations with results from the Numerical Spectral Model (NSM) reveals that there is qualitative agreement. The NSM generates the QBO extending from the stratosphere into the upper mesosphere, with temperature variations extending to mid latitudes, but the predicted amplitudes are smaller than those observed.

Huang, Frank T.↗

Convective Weather Forecast Accuracy Analysis at Center and Sector Levels

This paper presents a detailed convective forecast accuracy analysis at center and sector levels. The study is aimed to provide more meaningful forecast verification measures to aviation community, as well as to obtain useful information leading to the improvements in the weather translation capacity models. In general, the vast majority of forecast verification efforts over past decades have been on the calculation of traditional standard verification measure scores over forecast and observation data analyses onto grids. These verification measures based on the binary classification have been applied in quality assurance of weather forecast products at the national level for many years. Our research focuses on the forecast at the center and sector levels. We calculate the standard forecast verification measure scores for en-route air traffic centers and sectors first, followed by conducting the forecast validation analysis and related verification measures for weather intensities and locations at centers and sectors levels. An approach to improve the prediction of sector weather coverage by multiple sector forecasts is then developed. The weather severe intensity assessment was carried out by using the correlations between forecast and actual weather observation airspace coverage. The weather forecast accuracy on horizontal location was assessed by examining the forecast errors. The improvement in prediction of weather coverage was determined by the correlation between actual sector weather coverage and prediction. observed and forecasted Convective Weather Avoidance Model (CWAM) data collected from June to September in 2007. CWAM zero-minute forecast data with aircraft avoidance probability of 60% and 80% are used as the actual weather observation. All forecast measurements are based on 30-minute, 60- minute, 90-minute, and 120-minute forecasts with the same avoidance probabilities. The forecast accuracy analysis for times under one-hour showed that the errors in intensity and location for center forecast are relatively low. For example, 1-hour forecast intensity and horizontal location errors for ZDC center were about 0.12 and 0.13. However, the correlation between sector 1-hour forecast and actual weather coverage was weak, for sector ZDC32, about 32% of the total variation of observation weather intensity was unexplained by forecast; the sector horizontal location error was about 0.10. The paper also introduces an approach to estimate the sector three-dimensional actual weather coverage by using multiple sector forecasts, which turned out to produce better predictions. Using Multiple Linear Regression (MLR) model for this approach, the correlations between actual observation and the multiple sector forecast model prediction improved by several percents at 95% confidence level in comparison with single sector forecast.

Wang, Yao↗

Multidecadal Trends in Ozone Chemistry in the Baltimore-Washington Region

Over the past four decades, policy-led reductions in anthropogenic emissions have improved air quality over the Baltimore-Washington region (BWR). Most of the improvements in meeting the ozone air quality metrics (NAAQS) did not occur until the early 2000s despite large reductions in ozone precursors (NOx, CO, and volatile organic compounds (VOCs)) in the prior decades. We use observations of ozone and ozone precursors from satellites, ground-based sites, and the 2011 DISCOVER-AQ aircraft campaign in Maryland to illustrate how ozone chemistry in the BWR evolved between 1972 and 2019. Analysis of weekday vs weekend probability of ozone exceedance indicates the BWR transitioned to the NOx-limited regime by 2000–2003. A data-constrained box model agrees with this transition period and illustrates the key roles of reduced emissions of formaldehyde (HCHO), aromatics, and other VOCs since 1996, which reduced the peak of ozone production at the time of the transition and likely prevented the BWR from experiencing worsening surface air quality as the region transitioned to NOx-limited chemistry. Analysis of satellite observations of tropospheric column HCHO to NO2 analyzed using a new approach for evaluation of chemical regimes derived from DISCOVER-AQ data also provide a consistent depiction of the timing of the transition period that we infer from ground-based observations and the box model. Finally, despite significant improvements in air quality over the past two decades, the BWR still has not met the EPA standard for surface ozone. With predominantly NOx-limited ozone chemistry over the BWR, continued decreases in emission of NOx will slow the rate of ozone production and help improve air quality. We highlight emissions of NO2 from the diesel truck fleet as a worthwhile focus for future policy because emissions from this source appear to influence day-of-week variations in observed NO2, with an accompanying effect on ozone.

Ozone↗

Constraining the Sulfur Dioxide Degassing Flux from Turrialba Volcano, Costa Rica Using Unmanned Aerial System Measurements

Observed sulfur dioxide (SO2)mixing ratios onboard unmanned aerial systems (UAS) duringMarch 11-13, 2013 are used to constrain the three-day averaged SO2 degassing flux fromTurrialba volcanowithin a Bayesian inverse modeling framework. A mesoscale model coupled with Lagrangian stochastic particle backward trajectories is used to quantify the source-receptor relationships at very high spatial resolutions (i.e., b1 km). The model shows better performance in reproducing the near-surface meteorological properties and observed SO2 variations when using a first-order closure non-local planetary boundary layer (PBL) scheme. The optimized SO2 degassing fluxes vary from 0.59 +/- 0.37 to 0.83 +/- 0.33 kt d−1 depending on the PBL scheme used. These fluxes are in good agreement with ground-based gas flux measurements, and correspond to corrective scale factors of 8-12 to the posteruptive SO2 degassing rate in the AeroCom emission inventory. The maximum a posteriori solution for the SO2 flux is highly sensitive to the specification of prior and observational errors, and relatively insensitive to the SO2 loss term and temporal averaging of observations. Our results indicate relatively low degassing activity but sustained sulfur emissions from Turrialba volcano to the troposphere during March 2013. This study demonstrates the utility of low-cost small UAS platforms for volcanic gas composition and flux analysis.

Xi, Xin↗

DESI 2024 II: sample definitions, characteristics, and two-point clustering statistics

We present the samples of galaxies and quasars used for DESI 2024 cosmological analyses, drawn from the DESI Data Release 1 (DR1). We describe the construction of largescale structure (LSS) catalogs from these samples, which include matched sets of synthetic reference ‘randoms’ and weights that account for variations in the observed density of the samples due to experimental design and varying instrument performance. We detail how we correct for variations in observational completeness, the input ‘target’ densities due to imaging systematics, and the ability to confidently measure redshifts from DESI spectra. We then summarize how remaining uncertainties in the corrections can be translated to systematic uncertainties for particular analyses. We describe the weights added to maximize the signalto-noise of DESI DR1 2-point clustering measurements. We detail measurement pipelines applied to the LSS catalogs that obtain 2-point clustering measurements in configuration and Fourier space. The resulting 2-point measurements depend on window functions and normalization constraints particular to each sample, and we present the corrections required to match models to the data. We compare the configuration- and Fourier-space 2-point clustering of the data samples to that recovered from simulations of DESI DR1 and find they are, generally, in statistical agreement to within 2% in the inferred real-space over-density field. The LSS catalogs, 2-point measurements, and their covariance matrices will be released publicly with DESI DR1.

79 ASTRONOMY AND ASTROPHYSICS↗

Far-Reaching Impacts of African Dust- A Calipso Perspective

African dust can transport across the tropical Atlantic and reach the Amazon basin, exerting far-reaching impacts on climate in downwind regions. The transported dust influences the surface-atmosphere interactions and cloud and precipitation processes through perturbing the surface radiative budget and atmospheric radiative heating and acting as cloud condensation nuclei and ice nuclei. Dust also influences biogeochemical cycle and climate through providing nutrients vital to the productivity of ocean biomass and Amazon forests. Assessing these climate impacts relies on an accurate quantification of dust transport and deposition. Currently model simulations show extremely large diversity, which calls for a need of observational constraints. Kaufman et al. (2005) estimated from MODIS aerosol measurements that about 144 Tg of dust is deposited into the tropical Atlantic and 50 Tg of dust into the Amazon in 2001. This estimated dust import to Amazon is a factor of 3-4 higher than other observations and models. However, several studies have argued that the oversimplified characterization of dust vertical profile in the study would have introduced large uncertainty and very likely a high bias. In this study we quantify the trans-Atlantic dust transport and deposition by using 7 years (2007-2013) observations from CALIPSO lidar. CALIPSO acquires high-resolution aerosol extinction and depolarization profiles in both cloud-free and above-cloud conditions. The unique CALIPSO capability of profiling aerosols above clouds offers an unprecedented opportunity of examining uncertainties associated with the use of MODIS clear-sky data. Dust is separated from other types of aerosols using the depolarization measurements. We estimated that on the basis of 7-year average, 118142 Tg of dust is deposited into the tropical Atlantic and 3860 Tg of dust into the Amazon basin. Substantial interannual variations are observed during the period, with the maximum to minimum ratio of about 1.6 and 2.5 for the deposition to the tropical Atlantic and Amazon, respectively. The MODIS-based estimates appear to fall within the range of CALIPSO-based estimates; and the difference between MODIS and CALIPSO estimates can be largely attributed to the interannual variability, which is corroborated by long-term surface dust concentration observations in the tropical Atlantic. Considering that CALIPSO generally tends to underestimate the aerosol loading, our estimate is likely to represent a low bound for the dust transport and deposition estimate. The finding suggests that models have substantial biases and considerable effort is needed to improve model simulations of dust cycle.

dust↗

Effect of Residual Accelerations on the Crystal Growth of II-VI Semiconductors in Low Earth Orbit

The paper compares and summarizes the effects of residual acceleration during crystal growth on the compositional variation of two II-VI solid solution binary alloys (Hg(0.8)Cd(0.2)Te and Hg(0.84)Zn(0.16)Te). The crystals were grown by directional solidification on the second United States Microgravity Payload (USMP-2) and the first United States Microgravity Laboratory (USML-1) missions, respectively. For both alloys, changes in the direction and magnitude of the quasisteady acceleration vector (approximately 0.4- 1 mu g) caused large changes in the radial compositional distribution that demonstrates the importance of residual accelerations, even in the submicrogravity range, for large density gradients in the melt and slow solidification rates. The observed compositional variations will be correlated to changes in the radial flow velocities ahead of the solidification interface.

Gillies, D. C.↗

Comprehensive Validation of an Intermittency Transport Model for Transitional Low-Pressure Turbine Flows

A transport equation for the intermittency factor is employed to predict transitional flows under the effects of pressure gradients, freestream turbulence intensities, Reynolds number variations, flow separation and reattachment. and unsteady wake-blade interactions representing diverse operating conditions encountered in low-pressure turbines. The intermittent behaviour of the transitional flows is taken into account and incorporated into computations by modifying the eddy viscosity, Mu(sub t), with the intermittency factor, gamma. Turbulent quantities are predicted by using Menter's two-equation turbulence model (SST). The onset location of transition is obtained from correlations based on boundary-layer momentum thickness, acceleration parameter, and turbulence intensity. The intermittency factor is obtained from a transport model which can produce both the experimentally observed streamwise variation of intermittency and a realistic profile in the cross stream direction. The intermittency transport model is tested and validated against several well documented low pressure turbine experiments ranging from flat plate cases to unsteady wake-blade interaction experiments. Overall, good agreement between the experimental data and computational results is obtained illustrating the predicting capabilities of the model and the current intermittency transport modelling approach for transitional flow simulations.

Suzen, Y. B.↗

On the brightness variations of Comet Halley at large heliocentric distances

Sporadic variations of its intrinsic brightness of up to 500 percent, with time scales as short as a few hours, has been exhibited by Halley's comet at large heliocentric distances (11-8 AU). It is shown that many of these brightness enhancements are closely correlated to the encounter of high-speed solar wind streams by the comet. It is proposed that during such periods, the night side of the comet gets charged to numerically large negative electrostatic potentials, with consequent electrostatic levitation and blow-off of fine charged dust grains lying on it. This gives rise to the observed brightness variations.

Flammer, K. R.↗