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At least 775 records · Page 43

Interpreting the Strain Tensor During Injection into a Reservoir

A suite of well tests was conducted to evaluate the feasibility of measuring and interpreting the strain tensor during injection. Water was injected at 1 liter/s for a few days to a few weeks into a well completed at a depth of 530 m in the Bartlesville sandstone in the North Avant Field in Oklahoma. The strain tensor was measured using strainmeters at a depth of 30m and a distance of 220m from the well. We used a Gladwin strainmeter, a state-of-the-art geodetic strainmeter, as well as novel borehole strainmeters developed for the project. After processing, the horizontal strains were tensile and the vertical strain was compressive during injection. The radial strain was less than the circumferential strain. Strain magnitudes increased during injection and recovered afterward. The strain rate was as fast as 100 nanostrain/d at the start of injection, and decreased to 10 nanostrain/d after a few days. The normal strain signals were approximately proportional to the log of time during the first few days of injection, and the semi-log slope was 50 to 75 nanostrain. Data from the Gladwin strainmeter were essentially identical to data from a strainmeter we developed using optical fiber sensors. Tilt was measured using two tiltmeters, but the tilts were erratic compared to the normal strain and were of limited value. Strain data were analyzed using a strain type-curve method, an analytical solution to a poroelastic inhomogeneity, and a stochastic inversion method. Poroelastic simulations explain the data well. Results from the interpretation methods are consistent with each other, and with independent information characterizing the area. The hydraulic diffusivity is approximately 0.5 m2/s and the permeability is between 100 and 500 mD, according to analysis of the strain signals. This is consistent with measurements of permeability from cores, and with analyses of pressure transients. The analyses indicate that Young’s modulus of the reservoir is between 2 and 6 GPa. Strain interpretations indicate the well intersects a permeable lens with a maximum dimension of 500 to 1,000 m. An isopach map of coarse-grained sand confirms a feature roughly 1,000 m in lateral extent. The results demonstrate that the strain signal measured at shallow (30m) depth can be used to infer properties and heterogeneities in an underlying reservoir or aquifer.

Murdoch, Larry↗

Different measures of speckle and coherence at the output of a multimode optical fiber

Excitation of a multimode fiber with a focused spatially coherent light of finite bandwidth results in a partially coherent light at the output of the fiber. In this report, we observe the properties of speckle and classical coherence of such light with analytical theory, numerical modeling, and experimentally. Of particular interest is the relationship between measures of coherence and speckle and their dependence on input source bandwidth and fiber length. Speckle contrast is easy to measure experimentally and there exist at least two different methods to generate ensembles of random speckles. We demonstrate that speckle contrast evaluated over the ensemble of external diffusers is related to the number of effective modes—one of the characteristics of beam global coherence. The other speckle contrast measure evaluated over the ensemble of random bends and twists of the fiber is related to residual coherence, which is the pedestal on the average modulus of the complex degree of the coherence function on the output endface of the fiber.

47 OTHER INSTRUMENTATION↗

Spatiotemporal Observation of Quasi-Ballistic Transport of Electrons in Graphene

We report spatiotemporal observations of room-temperature quasi-ballistic electron transport in graphene, which is achieved by utilizing a four-layer van der Waals heterostructure to generate free charge carriers. The heterostructure is formed by sandwiching a MoS 2 and MoSe 2 heterobilayer between two graphene monolayers. Transient absorption measurements reveal that the electrons and holes separated by the type-II interface between MoS 2 and MoSe 2 can transfer to the two graphene layers, respectively. Transient absorption microscopy measurements, with high spatial and temporal resolution, reveal that while the holes in one graphene layer undergo a classical diffusion process with a large diffusion coefficient of 65 cm 2 s –1 and a charge mobility of 5000 cm 2 V –1 s –1 , the electrons in the other graphene layer exhibit a quasi-ballistic transport feature, with a ballistic transport time of 20 ps and a speed of 22 km s –1 , respectively. The different in-plane transport properties confirm that electrons and holes move independently of each other as charge carriers. Furthermore, the optical generation of ballistic charge carriers suggests potential applications for such van der Waals heterostructures as optoelectronic materials.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Femtosecond to picosecond transient effects in WSe 2 observed by pump-probe angle-resolved photoemission spectroscopy

Time-dependent responses of materials to an ultrashort optical pulse carry valuable information about the electronic and lattice dynamics; this research area has been widely studied on novel two-dimensional materials such as graphene, transition metal dichalcogenides (TMDs) and topological insulators (TIs). We report herein a time-resolved and angle-resolved photoemission spectroscopy (TRARPES) study of WSe 2 , a layered semiconductor of interest for valley electronics. The results for below-gap optical pumping reveal energy-gain and -loss Floquet replica valence bands that appear instantaneously in concert with the pump pulse. Energy shift, broadening, and complex intensity variation and oscillation at twice the phonon frequency for the valence bands are observed at time scales ranging from the femtosecond to the picosecond and beyond. Furthermore, the underlying physics is rich, including ponderomotive interaction, dressing of the electronic states, creation of coherent phonon pairs, and diffusion of charge carriers – effects operating at vastly different time domains.

36 MATERIALS SCIENCE↗

Zerovalent Copper Intercalated Birnessite as a Cathode for Lithium Ion Batteries: Extending Cycle Life

Birnessite type layered manganese dioxides (δ-MnO 2 ) have attracted considerable attention in recent years as 2D intercalation cathodes for rechargeable Li + , Na + , and Mg 2+ batteries due to fast ion diffusion through their negatively charged δ-MnO 2 sheets separated by interlayer cations and a stable Mn 3+/4+ redox couple. Here we report the preparation and electrochemistry of zero and divalent copper co-intercalated birnessite type manganese dioxide (Cu 0 0.03 Cu 2+ 0.21 Na 0.12 MnO 2 ·0.9H 2 O). The copper intercalated birnessite materials were fully characterized utilizing powder X-ray diffraction (XRD), inductively coupled plasma optical emission spectroscopy (ICP-OES), transmission electron microscopy (TEM). The mixed valent nature of intercalated Cu 0 and Cu 2+ was confirmed by X-ray photoelectron spectroscopy (XPS) and electron energy loss spectroscopy (EELS). Electrochemical evaluation results show that zero valent copper intercalated birnessite exhibits higher discharge capability, improved cyclability, and lower impedance compared to the Cu 2+ only intercalated (Cu 0.26 MnO 2 ·1.0H 2 O) and Cu free Na birnessite (Na 0.40 MnO 2 ·1.0H 2 O) materials. Remarkably, zero valent copper birnessite shows almost no fade after 10 cycles at 0.1 mV/s. Electrochemical impedance spectroscopy results suggest that charge transfer resistivity of Cu 0 modified samples was much lower than that of Cu 2+ and Cu free birnessite, indicating that the presence of a small amount of Cu 0 improves the conductivity of birnessite and results in better electrochemical cyclability, rate capability, and lower impedance.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Next Generation Photovoltaic Technologies For High-Performance Remote Power Generation (Final Report)

A unique, micro-scale architecture is proposed to create a novel hybrid concentrated photovoltaic system. Micro-scale (sub-millimeter wide), multi-junction cells are attached to a large-area silicon cell backplane (several inches wide) that can optimally collect both direct and diffuse light. By using multi- junction III-V cells, we can get the highest possible efficiency of the direct light input. In addition, by collecting the diffuse light in the large-area silicon cell, we can produce power on cloudy days when the concentrating cells would have minimal output. Through the use of micro-scale cells and lenses, the overall assembly will provide higher efficiency than conventional concentrators and flat plates, while keeping the form factor of a flat plate module. This report describes the hybrid concept, the design of a prototype, including the PV cells and optics, and the experimental results.

14 SOLAR ENERGY↗

CARMA Survey toward Infrared-bright Nearby Galaxies (STING). IV. Spatially Resolved {sup 13}CO in Spiral Galaxies

We present a {sup 13}CO(J=1→0) mapping survey of 12 nearby galaxies from the CARMA STING sample. The line intensity ratio R≡I[{sup 12}CO(J=1→0)]/I[{sup 13}CO(J=1→0)] is derived to study the variations in molecular gas properties. For 11 galaxies where it can be measured with high significance, the spatially resolved R on (sub)kiloparsec scales varies by up to a factor of 3–5 within a galaxy. Lower R values are usually found in regions with weaker {sup 12}CO. We attribute this apparent trend to a bias against measuring large R values when {sup 12}CO is weak. Limiting our analysis to the {sup 12}CO-bright regions that are less biased, we do not find that R on (sub)kiloparsec scales correlate with galactocentric distance, velocity dispersion, or the star formation rate. The lack of correlation between star formation rate and R indicates that the CO optical depth is not sensitive to stellar energy input, or that any such sensitivity is easily masked by other factors. Extending the analysis to all regions with {sup 12}CO emission by spectral stacking, we find that 5 out of 11 galaxies show higher stacked R for galactocentric radii of ≳1 kpc and Σ{sub SFR}≲0.1 M{sub ⊙} yr{sup −1} kpc{sup −2}, which could result from a greater contribution from diffuse gas. Moreover, significant galaxy-to-galaxy variations are found in R, but the global R does not strongly depend on dust temperature, inclination, or metallicity of the galaxy.

79 ASTRONOMY AND ASTROPHYSICS↗

Monte Carlo study of non-diffusive relaxation of a transient thermal grating in thin membranes

In this paper, the impact of boundary scattering on non-diffusive thermal relaxation of a transient grating in thin membranes is rigorously analyzed using the multidimensional phonon Boltzmann equation. The gray Boltzmann simulation results indicate that approximating models derived from previously reported one-dimensional relaxation model and Fuchs-Sondheimer model fail to describe the thermal relaxation of membranes with thickness comparable with phonon mean free path. Effective thermal conductivities from spectral Boltzmann simulations free of any fitting parameters are shown to agree reasonably well with experimental results. These findings are important for improving our fundamental understanding of non-diffusive thermal transport in membranes and other nanostructures.

36 MATERIALS SCIENCE↗

MASCOT: molecular gas depletion times and metallicity gradients – evidence for feedback in quenching active galaxies

ABSTRACT We present results from the first public data release of the MaNGA-ARO Survey of CO Targets (MASCOT), focusing our study on galaxies whose star formation rates and stellar masses place them below the ridge of the star-forming main sequence. In optically selected type 2 AGN/low-ionization nuclear emission regions (LINERs)/Composites, we find an empirical relation between gas-phase metallicity gradients ∇Z and global molecular gas depletion times $t_{\rm dep} = M_{\rm H_2} /{\rm SFR}$ with ‘more quenched’ systems showing flatter/positive gradients. Our results are based on the O3N2 metallicity diagnostic (applied to star-forming regions within a given galaxy), which was recently suggested to also be robust against emission by diffuse ionized gas (DIG) and LINERs. We conduct a systematic investigation into possible drivers of the observed ∇Z − tdep relation (ouflows, gas accretion, in situ star formation, mergers, and morphology). We find a strong relation between ∇Z or tdep and centralized outflow strength traced by the [O iii] velocity broadening. We also find signatures of suppressed star formation in the outskirts in AGN-like galaxies with long depletion times and an enhancement of metals in the outer regions. We find no evidence of inflows impacting the metallicity gradients, and none of our results are found to be significantly affected by merger activity or morphology. We thus conclude that the observed ∇Z–tdep relation may stem from a combination of metal redistribution via weak feedback, and a connection to in situ star formation via a resolved mass-metallicity–SFR relation.

Astronomy & Astrophysics↗

Mild hydrothermal crystal growth of new uranium(IV) fluorides, Na{sub 3.13}Mg{sub 1.43}U{sub 6}F{sub 30} and Na{sub 2.50}Mn{sub 1.75}U{sub 6}F{sub 30}: Structures, optical and magnetic properties

Two new uranium(IV) fluorides, Na{sub 3.13}Mg{sub 1.43}U{sub 6}F{sub 30} (1) and Na{sub 2.50}Mn{sub 1.75}U{sub 6}F{sub 30} (2), were synthesized through an in situ mild hydrothermal route, and were structurally characterized by single crystal X-ray diffraction. The compounds exhibit complex crystal structures composed of corner- or edge-shared UF{sub 9} and MF{sub 6} (M=Mg, Mn) polyhedra, forming hexagonal channels in the three-dimensional framework, in which ordered or disordered divalent metal and sodium atoms reside. The large hexagonal voids contain the nearly regular M(II)F{sub 6} octahedra and sodium ions, whereas the small hexagonal cavities include M(II) and sodium ions on a mixed-occupied site. Magnetic susceptibility measurements yielded effective magnetic moments of 8.36 and 11.6 µ{sub B} for 1 and 2, respectively, confirming the presence and oxidation states of U(IV) and Mn(II). The large negative Weiss constants indicate the spin gap between a triplet and a singlet state in the U(IV). Magnetization data as a function of applied fields revealed that 2 exhibits paramagnetic behavior due to the nonmagnetic singlet ground state of U(IV) at low temperature. UV–vis diffuse reflectance and X-ray photoelectron spectroscopy data were also analyzed. - Graphical abstract: Two new quaternary U(IV) fluorides, Na{sub 3.13}Mg{sub 1.43}U{sub 6}F{sub 30} and Na{sub 2.50}Mn{sub 1.75}U{sub 6}F{sub 30}, were crystallized via an in situ reduction step of U(VI) to U(IV) under mild hydrothermal conditions. The compounds show complex crystal structures based on the 3-D building block of U{sub 6}F{sub 30}. Magnetic property measurements revealed that the U(IV) exhibits a nonmagnetic singlet ground state at low temperature with a spin gap. - Highlights: • Na{sub 3.13}Mg{sub 1.43}U{sub 6}F{sub 30} and Na{sub 2.50}Mn{sub 1.75}U{sub 6}F{sub 30} have been synthesized and characterized. • The U(IV) fluorides exhibit complex three-dimensional crystal structures. • The optical properties were investigated. • Magnetic susceptibility data were collected.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Ultrafast transient absorption measurements of photocarrier dynamics in PdSe 2

We investigate the photocarrier dynamics in bulk PdSe 2 , a layered transition metal dichalcogenide with a novel pentagonal structure and unique electronic and optical properties. Using femtosecond transient absorption microscopy, we study the behavior of photocarriers in mechanically exfoliated bulk PdSe 2 flakes at room temperature. By employing a 400 nm ultrafast laser pulse, electron–hole pairs are generated, and their dynamics are probed using an 800 nm detection pulse. Our findings reveal that the lifetime of photocarriers in bulk PdSe 2 is approximately 210 ps. Furthermore, by spatially resolving the differential reflection signal, we determine a photocarrier diffusion coefficient of about 7.3 cm 2 s –1 . Based on these results, we estimate a diffusion length of around 400 nm and a photocarrier mobility of approximately 300 cm 2 V –1 s –1 . Furthermore, these results shed light on the ultrafast optoelectronic properties of PdSe 2 , offer valuable insights into photocarriers in this emerging material, and enable design of high-performance optoelectronic devices based on PdSe 2 .

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Is it possible to deduce the ground state OH density from relative optical emission intensities of the OH(A 2 Σ + -X 2 Π i ) transition in atmospheric pressure non-equilibrium plasmas?—An analysis of self-absorption

The measurement of absolute densities of reactive species and radicals such as OH is of growing interest for many plasma applications. Here, we extend the use of a self-absorption model for atomic emission spectroscopy to molecular emission spectroscopy. The proposed analysis of self-absorbed molecular emission spectra is a simple and inexpensive method to determine OH(X) densities and rotational temperatures compared to laser induced fluorescence. We compare the recorded absolute OH density in a non-equilibrium diffuse atmospheric-pressure RF glow discharge by this method with broadband UV absorption considering a number of rotational lines with J' ≤ 6.5, the detection limit of the line integrated OH(X) density with this method is of the order of 2 × 10 19 m –2 . The accuracy of the density is sensitive to the rotational temperature of the OH(A) state and the non-equilibrium rotational population distribution.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Optical waveguides in lithium niobate: Recent developments and applications

The state of the art of optical waveguide fabrication in lithium niobate is reviewed, with particular emphasis on new technologies and recent applications. The attention is mainly devoted to recently developed fabrication methods, such as femtosecond laser writing, ion implantation, and smart cut waveguides as well as to the realization of waveguides with tailored functionalities, such as photorefractive or domain engineered structures. More exotic systems, such as reconfigurable and photorefractive soliton waveguides, are also considered. Classical techniques, such as Ti in-diffusion and proton exchange, are cited and briefly reviewed as a reference standpoint to highlight the recent developments. In all cases, the application-oriented point of view is preferred, in order to provide the reader with an up-to date panorama of the vast possibilities offered by lithium niobate to integrated photonics.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

X-ray properties of high-richness CAMIRA clusters in the Hyper Suprime-Cam Subaru Strategic Program field

Abstract We present the first results of a pilot X-ray study of 37 rich galaxy clusters at 0.1 < z < 1.1 in the Hyper Suprime-Cam Subaru Strategic Program field. Diffuse X-ray emissions from these clusters were serendipitously detected in the XMM-Newton fields of view. We systematically analyze X-ray images of 37 clusters and emission spectra of a subsample of 17 clusters with high photon statistics by using the XMM-Newton archive data. The frequency distribution of the offset between the X-ray centroid or peak and the position of the brightest cluster galaxy was derived for the optical cluster sample. The fraction of relaxed clusters estimated from the X-ray peak offsets in 17 clusters is 29 ± 11(±13)%, which is smaller than that of the X-ray cluster samples such as HIFLUGCS. Since the optical cluster search is immune to the physical state of X-ray-emitting gas, it is likely to cover a larger range of the cluster morphology. We also derive the luminosity–temperature relation and found that the slope is marginally shallower than those of X-ray-selected samples and consistent with the self-similar model prediction of 2. Accordingly, our results show that the X-ray properties of the optical clusters are marginally different from those observed in the X-ray samples. The implication of the results and future prospects are briefly discussed.

Ota, Naomi (ORCID:0000000227843652)↗

Coherent optical imaging of moving objects hidden in a heavily scattering random medium

Experimental results are presented that provide insight into the physics of statistical imaging in heavily scattering random media based on measured speckle correlations as a function of the change in position of a moving object. In this way, definitive interpretation of a rather complex and earlier theory is achieved, making this work an experimental complement to that theory paper []. Motion could be natural, where the set of positions is estimated or separately obtained, or directed, where a mechanical stage can be used to adjust the object's position. In the experiment, a coherent laser illuminates two scattering diffusers, while an object is translated between them in the resulting speckled field and images are collected in a transmission configuration. Results are shown for various objects of differing size and geometry, allowing the theory to be validated and interpreted with new understanding. This work demonstrates imaging opportunities, and applications include material characterization, environmental imaging and sensing, and deep-tissue imaging. Published by the American Physical Society 2025

Hastings, Ryan L. (ORCID:0009000095977807)↗

Influence of surface nano-patterning on the placement of InAs quantum dots

We have examined the influence of spontaneous nano-patterning on the placement of InAs quantum dots (QDs) on (Al)GaAs surfaces using an experimental-computational approach. Both atomically flat and mounded surfaces, generated via a surface instability induced by the Ehrlich- Schwoebel barrier, are employed as templates for the subsequent deposition of InAs QDs. Using height profiles from atomic-force micrographs, we simulate QD deposition with a 2D phase field model, which describes the time evolution of the InAs layer driven by a chemical potential gradient. For flat surfaces, phase-field simulations result in QD densities comparable to experimental observations. For mounded surfaces, the simulations reveal QDs preferentially positioned in regions of positive curvature (substrate valleys), e.g., at the edge of surface mounds, consistent with the anisotropic QD placement observed experimentally. We discuss the role of curvaturedriven diffusion in the spontaneous ordering of QDs, demonstrating the applicability of this mechanism to AlGaAs mounds.

36 MATERIALS SCIENCE↗

Towards C P -violation studies on superheavy molecules: Theoretical and experimental perspectives

Molecules containing superheavy atoms can be artificially created to serve as sensitive probes to study symmetry-violating phenomena. Here, we provide detailed theoretical studies of quantities relevant to the electron electric dipole moment (eEDM) and nucleus-electron scalar-pseudoscalar interactions in diatomic molecules containing superheavy lawrencium nuclei. The sensitivity to parity and time (or, equivalently, CP) reversal violating properties is studied for different neutral and ionic molecules. The effective electric fields in these systems are found to be about 3–4 times larger than other known molecules on which eEDM experiments are being performed. Similarly, these superheavy molecules exhibit an enhancement of more than 3 times for CP-violating scalar-pseudoscalar nucleus-electron interactions. Our preliminary analysis using the Woods-Saxon nuclear model also demonstrates that these results are sensitive to the diffuse surface interactions inside the Lr nucleus. We also briefly comment on some experimental aspects by discussing the production of these systems.

74 ATOMIC AND MOLECULAR PHYSICS↗

Enhanced beam-beam modeling to include longitudinal variation during weak-strong simulation

Beam-beam interactions pose substantial challenges in the design and operation of circular colliders, significantly affecting their performance. In particular, the weak-strong simulation approach is pivotal for investigating single-particle dynamics during the collider design phase. This paper evaluates the limitations of existing models in weak-strong simulations, noting that while they accurately account for energy changes due to slingshot effects, they fail to incorporate longitudinal coordinate changes ( z variation). To address this gap, we introduce two novel transformations that enhance Hirata’s original framework by including both z variation and slingshot effect-induced energy changes. Through rigorous mathematical analysis and extensive weak-strong simulation studies, we validate the efficacy of these enhancements in achieving a more precise simulation of beam-beam interactions. Our results reveal that although z variation constitutes a higher-order effect and does not substantially affect the emittance growth rate within the specific design parameters of the Electron-Ion Collider, the refined model offers improved accuracy, particularly in scenarios involving the interaction between beam-beam effects and other random diffusion processes, as well as in simulations incorporating realistic lattice models. Published by the American Physical Society 2024

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗