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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43

Modelling of Wastewater Heat Recovery Heat Pump Systems

Wastewater heat recovery is currently an underutilized technology that could be part of solving the climate crisis. A large portion of the heat that leaves a building in the form of wastewater is potentially recoverable for pre-heating domestic hot water or other service water systems. While there are several different approaches to wastewater heat recovery, this project focused on creating detailed, integrated building models for wastewater heat recovery heat pump systems. EnergyPlus models were developed featuring inputs and assumptions corresponding to manufacturers’ specifications, performance lab test data and feedback from engineering consultants. EnergyPlus’s supervisory control Energy Management System objects were heavily relied upon to overcome modelling challenges. The developed EnergyPlus model was integrated into U.S. Department of Energy New Construction Reference Building models for various climate zones and building types to assess potential energy use, energy cost and greenhouse gas emission reductions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

H 2 O absorption spectroscopy via focused laser differential interferometry

A modification of focused laser differential interferometry (FLDI) is demonstrated with an infrared tunable diode laser (TDL) to achieve simultaneous absorption spectroscopy (AS) measurements. Measurements from this absorbing-FLDI (A-FLDI) are shown for a Hencken burner plume. Initial comparison measurements are recorded using TDLAS and an electrical hygrometer. Raw voltage and estimated absorbance measurements illustrate that the technique detects five distinct absorbance peaks of the methane–air flame while retaining the expected behavior of typical FLDI. This modification furthers efforts to enable FLDI to conduct analysis of the pressures, temperatures, and molecular densities of flows. It also explores the potential for reducing path-integration (PI) effects in absorption spectroscopy and potentially enabling spatially and temporally resolved local flow measurements. Reductions in PI length as high as 82%–84% are observed.

Holladay, Seth (ORCID:0009000650875421)↗

Application of Sequential Design of Experiments (SDoE) to Large Pilot-Scale Solvent-Based CO2 Capture Process at Technology Centre Mongstad (TCM)

The United States Department of Energy’s Carbon Capture Simulation for Industry Impact (CCSI2) program has developed a framework for sequential design of experiments (SDoE) that aims to maximize knowledge gained from budget- and schedule-limited pilot scale testing. SDoE was applied to the planning and execution of campaigns for testing CO2 capture systems at pilot-scale in order to optimally allocate resources available for the testing. In this methodology, a stochastic process model is developed by quantifying the parametric uncertainty in submodels of interest; for a solvent-based CO2 capture system, these may include physical properties and equipment performance submodels (e.g., mass transfer, interfacial area). This uncertainty is propagated through the full process model, over variable operating conditions, for estimating the resulting uncertainty in key model outputs (e.g., percentage of CO2 capture, solvent regeneration energy requirement). In developing a data collection plan, the predicted output uncertainty is incorporated into an algorithm that seeks simultaneously to select process operating conditions for which the predicted uncertainty is relatively high and to ensure that the entire space of operation is well represented. This test plan is then used to guide operation of the pilot plant at varying steady-state conditions, with resulting process data incorporated into the existing model using Bayesian inference to refine parameter distributions. The updated stochastic model, with reduced parametric uncertainty from data collected, is then used to guide additional data collection, thus the sequential nature of the experimental design. The SDoE process was implemented at the pilot test unit (12 MWe in scale) at Norway’s Technology Centre Mongstad (TCM) in a summer 2018 test campaign with aqueous monoethanolamine (MEA). During the test campaign, the varied operating conditions included the flowrates of circulated solvent, flue gas, and reboiler steam and the CO2 concentration in the flue gas. The process data were used to update probability distributions of mass transfer and interfacial area parameters of a stochastic process model developed by the CCSI2 team. Two iterations of the SDoE process were executed, resulting in the uncertainty in model predicted CO2 capture percentage decreasing by an average of 58.0 ± 4.7% over the full input space of interest. This work demonstrates the potential of the SDoE process for model refinement through reduction in process model parametric uncertainty, and ultimately risk in scale-up, in CO2 capture technology performance.

carbon capture↗

Disaggregating Future Retail Electricity Rate Growth [Slides]

Recent Berkeley Lab research found that modest retail rate increases over the past 10 years were mostly driven by large increases in capital expenditures (CapEx) that were offset in part by substantial wholesale price reductions. Decision-makers are increasingly concerned about the potential future rate impacts of a number of policies and industry trends that support rapid decarbonization, electrification, and grid modernization. Using historical FERC Form 1 data and the existing literature on policies and industry trends that are likely to affect utility-incurred costs and retail sales, Berkeley Lab researchers developed ranges of forecasted growth rates for cost-related rate drivers (i.e., fuel and purchased power; transmission, distribution, generation, and other categories of both non-fuel operations & maintenance and CapEx) and non-cost related rate drivers (i.e., retail sales, peak demand, and customers). These were then used as inputs to a pro-forma utility financial model (FINDER) that estimated the growth in retail electric rates between 2020 and 2030 for a prototypical vertically-integrated investor-owned utility in the United States. The analysis produced the following results: 1. Assuming average growth rates in all rate drivers, future retail rate growth is driven by sizable increases in all CapEx costs, where fuel and purchased power costs are replaced by generation CapEx as the largest rate component between 2020 and 2030. 2. Growth in sales/peak demand/customers, generation CapEx costs, and fuel and purchased power (FPP) costs, in isolation, produce the most uncertainty in rate growth. Specifically, a 1% increase in the compound annual growth rate (CAGR) of retail sales, coincident peak demand (CP), and customers (Sales-CP-Cust) results in a 0.88-0.93% decrease in the CAGR of rates, in isolation. However, a 1% increase in the CAGR of generation CapEx budgets results in a 0.07-0.14% increase in the CAGR of rates, while a 1% increase in the CAGR of FPP costs causes a 0.10-0.14% increase in the CAGR of rates, all else being equal. 3. Taking into account the correlation and variability of the growth in all rate drivers jointly, generation CapEx is expected to be both the largest and most uncertain rate component by 2030 (20-25% share of the retail rate). Transmission and distribution CapEx, along with fuel and purchased power costs are each expected to comprise between 12% and 17% of retail rates.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Compressed Gas Energy Storage Integrated with Combined Heat and Power Plant

A new energy storage technology, Comrpessed Gas Energy Storage (CGES), seeks to achieve low-cost, long-duration eenrgy storage by combining mature commercially-available technology (compressors, high-pressure gas storage, expander generators) and utilizing existing infrastructure for transportation and distribution of industrial gases. CGES utilizes existing compressors to transform electricity into potential energy (pressure), existing pipelines or underground storage to store said potential energy, and adds new expander generators at pressure reduction points in the networkm to recover part of the energy used in compression and transform it into electricity. By adapting itself to widely available existing infrastructure, CGES recovers energy that is otherwise wasted in the gas value chain, reduces the cost of new facilities, and avoids many of the development huddles typically associated with other long-duration energy storage technologies (e.g., Compressed Air Energy Storage, CAES). This paper discusses the performance and economics associated with CGES as a standalone project and in combination with a thermal power plant, based on a concept for integration of the technology over an existing lateral pipeline transporting natural gas to an 85 MW combined heat and power plant that feeds power to a grid with increasing share of renewable power generation.

03 NATURAL GAS↗

Technical and Economic Assessment and Gap Analysis of Advanced Nuclear Reactor Integration with a Reference Oil Refinery

Efforts to identify the most-economic methods to decarbonize several sectors of the U.S. economy are underway. Industrial processes such as crude-oil refining rely heavily on energy-dense and easily stored and transported fossil fuels for powering their operations. Refineries use large amounts of energy, primarily derived from fossil sources to separate crude-oil components, break down heavier hydrocarbons into lighter compounds, remove impurities, reform hydrocarbon molecules, and generate steam and electricity for pumps and compressors and other various auxiliary systems. Crude-oil refining operations such as distillation, cracking, desulfurization, reforming, utilities systems and some offsite facilities collectively account for most of the energy consumption. Other operations such as hydrocracking or hydrotreating also require hydrogen for developing hydrogenation reactions which involve substantial heating to keep the reactors at high-temperature and pressure levels. All heat and energy demands are typically provided by natural gas (NG), oil, or other fuels, which makes refinery industry one of the most-difficult sectors to decarbonize. Nuclear power is a viable and energy-dense source of clean electricity, heat, and hydrogen to provide the large, sustainable energy supply that the refining industry demands. The U.S. Department of Energy’s (DOE’s) Integrated Energy Systems (IES) program is working to perform research and development, design, economic siting, and risk analysis. This state-of-the-art work will enable the first on-site demonstrations and commercial deployments of advanced small modular nuclear reactors (SMNRs) integrated with industries such as chemical production, refining, iron and steel making, and more. IES seeks to demonstrate the ability of advanced nuclear reactors to meet the heat and power demands of these industries while reducing carbon emissions in a sustainable and cost-competitive way. The primary objective of this research effort is to analyze industrial-scale SMNR integration intended to decarbonize refining facilities. The foreseen outcome is the provision of reliable, cost-competitive, and sustainable clean energy, alongside a reduction of carbon emissions. Specifically, the focus of this work lies on meeting the reference facilities’ heat and electricity demands with nuclear power while also supplying clean hydrogen via integrated high-temperature steam electrolysis (HTSE). This report presents a comprehensive technical and economic assessment of the integration of advanced nuclear reactors into a reference refinery, leveraging financial incentives from the Inflation Reduction Act (IRA). The evaluation aims to explore the potential economic benefits and challenges associated with incorporating advanced nuclear reactors into refinery operations, particularly in terms of energy efficiency, economic implications and environmental impact. By examining both the technical feasibility and economic viability, this analysis seeks to identify existing gaps and propose solutions for successful nuclear integration implementation. The findings are intended to provide valuable insights for stakeholders considering the adoption of advanced nuclear reactors in the refining sector. A refinery reference-plant was developed, using an open-source refinery model, Petroleum Refinery Lifecycle Inventory Model (PRELIM) and expert assessment, as a base case for comparison with various nuclear integration options. The capacity of 100 kbd/day (KBD) of heavy crude-oil feed was selected to represent a general coking-type refinery with deep conversion capabilities (incorporating heavy-oil upgrading with FCC, coking, and associated hydrotreating process units), using a heavy crude-oil feed, which represents about 70% of U.S. refineries configurations. A summary of all cases considered in this study is shown in Table 1.

13 HYDRO ENERGY↗

Technoeconomic Analysis of Kraft Pulp Mill Integration with an Advanced Nuclear Reactor

This study focuses on post-combustion capture and oxy-fuel combustion for the boilers at the mill, as well as steam integration with the nuclear power plant. The primary goal of the research outlined in this report is to design, analyze, and document the integration of industrial-scale HTGR with a reference Kraft Pulp Mill. The purpose is to deliver reliable, cost-effective, and sustainable clean energy alternatives while reducing CO2 emissions. Specifically, this study focuses on 6 different scenarios that include carbon capture equipment and some of them use nuclear power to meet the heat and electricity needs of the reference plant. Also, 2 of these scenarios are created while also producing clean hydrogen through integrated High-Temperature Steam Electrolysis (HTSE). This report offers a detailed techno-economic assessment of different scenarios for a Kraft Pulp Mill, including an analysis of tax credits (section 45V, 45Q, and 48E) provided by the Inflation Reduction Act (IRA) of 2022. The evaluation explores the potential economic benefits and challenges of incorporating different configurations, including nuclear energy, into Kraft Pulp Mill operations, with particular attention to energy efficiency, economic implications, and environmental impact. By assessing both the technical feasibility and economic viability, this analysis aims to identify existing gaps and propose solutions for the successful implementation of nuclear integration. The findings are intended to provide valuable insights for stakeholders considering the adoption of advanced nuclear reactors in the pulp and paper industries.

08 HYDROGEN↗

Effective Mechanisms for Improving Seed Oil Production in Pennycress (Thlaspi arvense L.) Highlighted by Integration of Comparative Metabolomics and Transcriptomics

Pennycress is a potentially lucrative biofuel crop due to its high content of long-chain unsaturated fatty acids, and because it uses non-conventional pathways to achieve efficient oil production. However, metabolic engineering is required to improve pennycress oilseed content and make it an economically viable source of aviation fuel. Research is warranted to determine if further upregulation of these non-conventional pathways could improve oil production within the species even more, which would indicate these processes serve as promising metabolic engineering targets and could provide the improvement necessary for economic feasibility of this crop. To test this hypothesis, we performed a comparative biomass, metabolomic, and transcriptomic analyses between a high oil accession (HO) and low oil accession (LO) of pennycress to assess potential factors required to optimize oil content. An evident reduction in glycolysis intermediates, improved oxidative pentose phosphate pathway activity, malate accumulation in the tricarboxylic acid cycle, and an anaplerotic pathway upregulation were noted in the HO genotype. Additionally, higher levels of threonine aldolase transcripts imply a pyruvate bypass mechanism for acetyl-CoA production. Nucleotide sugar and ascorbate accumulation also were evident in HO, suggesting differential fate of associated carbon between the two genotypes. An altered transcriptome related to lipid droplet (LD) biosynthesis and stability suggests a contribution to a more tightly-packed LD arrangement in HO cotyledons. In addition to the importance of central carbon metabolism augmentation, alternative routes of carbon entry into fatty acid synthesis and modification, as well as transcriptionally modified changes in LD regulation, are key aspects of metabolism and storage associated with economically favorable phenotypes of the species.

59 BASIC BIOLOGICAL SCIENCES↗

Benefits and Challenges of California Offshore Wind Electricity: An Updated Assessment

Offshore wind (OSW) technology has recently been included in California’s plans to achieve 100% carbon-free electricity by 2045. As an emerging technology, many features of OSW are changing more rapidly than established renewable options and are shaped by local circumstances in unique ways that limit transferrable experiences globally. This paper fills a gap in the literature by providing an updated technological assessment of OSW in California to determine its viability and competitiveness in the state’s electricity generation mix to achieve its near-term energy and environmental goals. Through a critical synthesis and extrapolation of technical, social, and economic analyses, we identify several major improvements in its potential. First, we note that while estimates of OSW’s costs per MWh of installed capacity have generally documented and projected a long-term decline, recent technical, microeconomic, and macroeconomic factors have caused significant backsliding of this momentum. Second, we project that the potential dollar value benefits of OSW’s greenhouse gas reduction capabilities have increased by one to two orders of magnitude, primarily due to major upward revisions of the social cost of carbon. Several co-benefits, including enhanced reliability, economic growth, and environmental justice, look to be increasingly promising due to a combination of technological advances and policy initiatives. Despite these advancements, OSW continues to face several engineering and broader challenges. We assess the current status of these challenges, as well as current and future strategies to address them. We conclude that OSW is now overall an even more attractive electricity-generating option than at the beginning of this decade.

Rose, Adam (ORCID:0000000333477684)↗

2021 Component Innovation Project Awardee: Bergey Windpower

In recent years, the cost of small wind turbines for homes, farms, and small businesses has decreased dramatically thanks to advances in American technology made possible by research and development support from the U.S. Department of Energy. But further reductions are needed to realize the gigawatt-scale potential of distributed wind energy to help electrify rural America, reduce carbon emissions, and create jobs. Currently, for residential- and farm-scale wind turbines with direct-drive, permanent-magnet alternators, the alternator is the highest-cost component of the wind turbine (excluding the tower). The Bergey Windpower Excel 15 wind turbine incorporates advanced technology in its rotor and controls and will soon incorporate advanced power electronics - but its alternator is based on technology that is more than a decade old. To help reduce capital expenditures of the Excel 15 wind turbine, Bergey Windpower is developing an advanced, lower- cost, permanent-magnet alternator.

CIP↗

On-Detector Machine Learning for Beam-Induced Background Rejection at a 10 TeV Muon Collider

A 10 TeV Muon Collider is a compelling candidate for a future energy-frontier facility, offering unprecedented opportunities to explore the fundamental laws of particle physics. Muon decays in the collider ring produce intense beam-induced background (BIB) that can overwhelm detector occupancy and exceed readout bandwidth constraints. We investigate the potential of on-detector Machine Learning for BIB rejection in the vertex detector, exploiting pixel cluster shapes to distinguish background from collision products. We study three classes of lightweight neural-network architectures, and evaluate their implementation feasibility using high-level synthesis. Selected architectures achieve 88 to 90% data reduction at 99% signal efficiency, while requiring hardware resources compatible with potential ASIC implementation. These results demonstrate the potential of performing substantial BIB rejection directly in the pixel readout, providing a strategy for meeting the tracker readout requirements at a future Muon Collider.

Abadjiev, Daniel [Chicago U.]↗

Energy Analysis: Ways to Save Energy and Reduce the Emissions in Wastewater Treatment Plants

The key of this study is to explore the primary energy consumers in wastewater treatment plants, which is considered as one of the major energy consumers, and introduces the best solution to save energy and reduce emissions in these facilities. This study is based on the energy assessment and analyses of eleven wastewater treatment plants. Through the investigation, it was found that plants can save up to 44,158 MWh of the energy consumption which is 47% from the total electricity consumption with a 17% reduction in the total utility bills and that about 2.5 million dollars cost savings after reviewing the currently facilitated energy system. Additionally, an average of five years' payback period resulted in most energy-saving recommendations. A vast potential of greenhouse gas emissions can be reduced with a total range reduction between 13 to 35 million kg of CO 2 based on the speed reduction percentage.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Universal Solvent Viscosity Reduction via Hydrogen Bonding Disruptors

Liquid Ion Solutions LLC (DBA RoCo Global) in partnership with Carnegie Mellon University and Carbon Capture Scientific LLC, has performed lab-scale development and evaluation of novel additives that lower the viscosity of water-lean amine solvents for post-combustion carbon dioxide capture. This project focuses on developing additives that minimize the formation of long-range electrostatic and hydrogen bonding (HB) networks, decreasing the solvent viscosity, improving diffusion, and improving the process economics. The project objectives included: 1) performing computer simulation to understand the molecular interactions of the additive molecules in water-lean CO 2 capture solvents, 2) design and synthesis of HB disruptors additives, 3) performance testing with additive molecules on model amine solvents, and 4) demonstration of the effectiveness of the optimized additives in the presence of synthetic flue gas. To meet the abovementioned objectives, the project team utilized a holistic approach that combines molecular simulation, experimental testing, and economic analysis studies. The project team developed ab initio molecular model and then perform computer simulation to develop relationship between hydrogen bonding, viscosity, and performed quantitative analysis of additive on the viscosity of the solvent. The team completed computational comparative study on a range of organic functional groups such as ethers, esters, cyclic carbonates, alkanes, and ammonium salts for their effect on viscosity gaining key insights into molecular interactions and the impact of various functional groups and molecular shapes on viscosity. Assisted with molecular simulation insights, the project team conducted additive synthesis and testing, including a proof-of-concept study, additive screening, optimization, and synthetic flue gas testing. The experimental proof-of-concept study proved that the hydrogen bonding acceptors result in significant decrease of viscosities. Detailed additive screening (exploring various functionalities and molecular structures) has been performed. Several promising additives showed excellent reduction in viscosity (30-41%) at 5% additive loading, and over 50% viscosity reduction at 10% additive loading for the model solvents. The team also performed complex screening studies on additive loadings and mixing effect among additives using the design of experiments. Based on multiple screening experiments, one additive-solvent candidate was down-selected for synthetic flue gas testing. A 100-hour continuous absorption/desorption study was conducted under simulated flue gas using a lab-scale continuous capture and separation system. No degradation (for both solvent and additive) was observed based on the GC results of the solvent samples collected from the continuous study. The team conducted preliminary engineering analyses and cost-benefit analyses to quantify the potential economic benefits of the additive approach for solvent viscosity reduction. Based on the experimental data, CO 2 capture cost savings from the capital and operating cost savings are estimated at $\$$4.7/tonne and $\$$0.3/tonne CO 2 captured, respectively. Considering the additive cost, the net benefit is estimated to be between $\$$4.32~$\$$4.86/tonne CO 2 captured.

20 FOSSIL-FUELED POWER PLANTS↗

Bound states of Ω baryons in light nuclei

Here, we investigate bound states of light Ω 3⁢𝑥 clusters (𝑥=𝑠,𝑐), motivated by the Ω 3⁢𝑠 ⁢𝑁 potential recently developed by the HAL QCD collaboration. To regularize this potential, we remove the deeply attractive core at 𝑟 < 0.4 fm and parametrize the long-range component (𝑟 > 0.4 fm) using a two-range Gaussian form. This procedure preserves the relevant two-body bound-state energy while having a negligible effect on the Ω 3⁢𝑠⁢ 𝑁⁢𝑁 and Ω 3⁢𝑠⁢ Ω 3⁢𝑠 ⁢𝑁 systems. An effective Ω 3⁢𝑠 ⁢𝛼 potential is then constructed by fitting a two-range Gaussian function to the long-range component of the folding potential, enabling calculations of the bound-state energies of the Ω 3⁢𝑠⁢ 𝛼, Ω 3⁢𝑠⁢ 𝛼⁢𝛼, and Ω 3⁢𝑠 ⁢Ω 3⁢𝑠 ⁢𝛼 systems. The regularization procedure leads to a substantial reduction in bound-state energies compared to those obtained with the original potential. We further extend the analysis to Ω 3⁢𝑐 -cluster systems by introducing an Ω 3⁢𝑐 ⁢𝑁 interaction, derived by comparing the existing Ω 3⁢𝑠⁢ Ω 3⁢𝑠 and Ω 3⁢𝑐 ⁢Ω 3⁢𝑐 potentials. Our results suggest that several parametrizations predict bound states in Ω 3⁢𝑐 -containing clusters. Finally, the Ω 3⁢𝑠 ⁢Ω 3⁢𝑠 interaction is described using a contactlike potential approach, motivated by the effective field theory.

binding energy & masses↗

Editors’ Choice—Review—Recent Advances in Mixed Potential Sensors

Gas sensors are widely used in environmental monitoring and provide controls especially when working with toxic gases. YSZ based λ-sensors have been utilized in the automobile industry for exhaust gas monitoring for more than 40 years. However, recent regulations on emissions reduction has forced further development of toxic gases monitoring in various applications. Mixed potential sensors with YSZ electrolyte are receiving increased attention due to their higher sensitivity and durability under harsh conditions. This review focuses on recent (past 5 years) developments made on electrode and electrolyte structure along with new sensing electrode materials towards detecting gases such as NO x , NH 3 , H 2 , CO and hydrocarbons (HCs). The theory of mixed potential sensors is discussed along with recent developments in detection of multi-gas mixtures using the output from an array of sensors in a mathematical model. Future directions for mixed potential sensor research, and methodologies to improving sensing characteristics are also outlined

47 OTHER INSTRUMENTATION↗

CORSIA: The first internationally adopted approach to calculate life-cycle GHG emissions for aviation fuels

The aviation sector has grown at a significant pace in recent years, and despite improvements in aircraft efficiency, the sector's impact on climate change is a growing concern. To address this concern, the International Civil Aviation Organization (ICAO) established the Carbon Offsetting and Reduction Scheme for International Aviation (CORSIA) to help reduce aviation greenhouse gas (GHG) emissions. This paper presents a methodology agreed by the 193 ICAO member states to evaluate the life-cycle GHG emissions of sustainable aviation fuels (SAFs), in the CORSIA system. The core life-cycle assessment and induced land use change values of SAFs are presented to determine the GHG savings of certified pathways. The paper aims to present that a number of SAFs can yield significant life-cycle emission reductions compared to petroleum-derived jet fuel. This implies the potentially major role of SAFs in reducing aviation's carbon footprint.

54 ENVIRONMENTAL SCIENCES↗

Analysis of Carbon Capture Retrofits for Cement Plants

The objective of this study is to provide an estimate of the cost to capture CO 2 in retrofit applications at cement plants. The cement plant configurations considered in this study include natural gas and solid fuel (coal and coke) cases, and both wet- and dry kiln-fed plant designs, however the base cement plants in this study were not evaluated other than characterization of their kiln off-gas stream and high-level quantification of heat integration potential at the existing plant. In each case, the base cement plant produces 1.5 M tonnes per year of finished cement, assuming 91.4 percent clinker content. This analysis includes a 10 percent retrofit cost increase for process integration and low grade heat recovery, when compared to the analogous non-heat integration case. Heat integration is considered as a potential offset to capture system heating demands (i.e., as a percentage reduction). Recovery and reuse of excess heat from the base cement plant can provide economic benefits—primarily by reducing the need to purchase supplemental natural gas for CO 2 solvent regeneration—but any process improvement must be great enough to overcome the cost increases (i.e., capital and O&M) necessary to realize those benefits. With heat integration potential of 10 percent and 30 percent, that benefit wasn’t significant enough to offset the increase in capital and operating costs, and a cost of capture increase was observed based on the assumptions in this report. Benefits of heat integration potential may be realized when natural gas prices are higher, as demonstrated in the sensitivity to natural gas price where crossover points exist between heat integration cases and their respective non-heat integration cases. Four of the base cases were further evaluated to explore the cost implications of deeper levels of gas pre-treatment to remove oxides of nitrogen (NOx) and oxides of sulfur (SOx) from the kiln off-gas stream prior to CO 2 capture, purification, and compression. The results of these additional case analyses showed a 7.4–18.8 percent increase in cost of capture over the respective base case (i.e., analogous cases without SOx/NOx removal).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗