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At least 775 records · Page 43

Thermomechanical design optimization for low metal footprint in hybrid metal-polymer heat exchanger

Material and maintenance costs of metal-based heat exchangers surpass profits in waste heat recovery (WHR) from ultra-low temperature (<100C) sources [1]. A low-cost alternative like polymer pipes suffer from poor thermal conductivity (~0.2 W/mK), and a low overall heat transfer coefficient. Polymers’ thermal conductivity have previously been enhanced through systematic molecular alignment by stretching [2], chemical vapor deposition of extended polymers [3], surface grating [4], etc. However, these approaches suffer from scalability issues for WHR heat exchangers in terms of cost [3], and thermomechanical considerations [5]. In this work, we propose novel hybrid metal-polymer heat exchangers that are made from polymer-copper strips. Through finite element method (FEM) simulations, we first optimize the placement of copper around polymer strips to enhance the transverse thermal conductivity of the strips. The copper cladded polymer strips are wound helically in a roll-to-roll system to form the pipes for a heat exchanger. We then optimize the design of helically wound pipes to reduce thermomechanical strains to < 0.2 % at 100C and 40 psi working conditions. At 25 % volume fraction of copper in the pipe, we predict up to 20 % enhancement in overall heat transfer from a base polymer with a thermal conductivity of 0.2 W/mK. We also compare and contrast the thermomechanical performance of the optimized metal-polymer strips to random metal matrix composites. Finally, we experimentally verify the thermal conductivity of the optimized strips through bulk thermal conductivity and thermal interface resistance measurement setup. By systematically improving the design through FEM and experimental measurements, we provide an optimized design of hybrid metal-polymer pipes that provides a low metal footprint and cost-effective means for harvesting waste heat from ultra-low temperature sources. Thekdi, Arvind, and Sachin U. Nimbalkar. Oak Ridge National Lab, 2015 Shen, Sheng, et al. Nature nanotechnology 5.4 (2010): 251. Xu, Yanfei, et al. Science advances 4.3 (2018): 3031. Smith, M. K., Singh, V., Kalaitzidou, K., & Cola, B. A. (2015). ACS nano, 9(2), 1080-1088. Aymonier, C., Bortzmeyer, D., Thomann, R., & M&uuml;lhaupt, R. (2003). Chemistry of Materials, 15(25), 4874-4878.

C Rajagopal, Manjunath↗

Process intensification approach to enhancing heat and mass transfer: Radio frequency (RF) assisted drying of paper and board

Conventional multi-cylinder drying of paper and board typically relies on both conductive drying from steam-heated cylinders and convective drying, where heated air flows over the paper web surface. Conduction primarily contributes to heat transfer, while convection is the main driver of mass transfer. However, conventional drying systems are heavily dependent on steam, usually powered by fossil fuels, and are often energy-inefficient with high levels of waste. Additionally, these surface-driven processes result in a lower percentage of energy absorption compared to the energy supplied, leading to significant energy losses. To improve this long-standing process, an experimental system was developed to investigate a process intensification approach involving the integration of Radio Frequency (RF) heating, a volumetric electromagnetic technology, alongside traditional conduction and convection drying methods. This study also emphasizes the use of sensors to continuously monitor key parameters such as moisture content, supply system temperatures, sample temperatures, air flows, and drying rates in real-time. The effect of RF as an auxiliary energy source in localized environments at varying moisture levels was explored to optimize industrial drying systems, quantify potential improvements, and provide insights for future studies. Experimental results from trials combining RF with convection and with the base case alternating conduction-convection drying processes are presented. It is shown that RF is a viable process intensification approach for paper drying improving the drying rate and energy intensity at higher moisture contents. These findings offer valuable insights for process intensification and contribute to the process development, modeling, and simulation of advanced paper drying techniques.

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Thermomechanical Design Optimization of Roll-to-Roll Manufactured Hybrid Metal Polymer Heat Exchanger

Metal based heat exchangers for ultra-low temperature (<100C) waste heat recovery (WHR) face high maintenance and material costs that surpass profits from recovery[1]. Low-cost polymer pipes suffer from poor thermal conductivity (~0.2 W/mK), and thus a low overall heat transfer coefficient. Thermal conductivity of polymers can be enhanced through systematic molecular alignment by stretching[2], chemical vapor deposition of extended polymers [3], surface grating [4], etc. However, these approaches suffer from scalability issues for WHR heat exchangers in terms of cost [3], and thermomechanical considerations [5]. In this work, we propose novel hybrid metal-polymer strips that are strategically designed to enhance thermal conductivity by cladding copper around polymer strips. The polymer strips with copper-clad edges are wound helically to form the pipes for a heat exchanger. Through finite element simulations, we optimize the design for enhanced thermal performance of the polymer-metal strips. We predict up to 20 % enhancement in overall heat transfer from a base polymer with a thermal conductivity of 0.2 W/mK. We show that the thermomechanical strains induced in the pipes can be reduced to < 0.2 % by strategically stacking and welding multiple polymer-metal strips. We verified the improved thermal performance of the roll-to-roll manufactured strips through a thermal conductivity measurement setup. The optimized design of hybrid metal-polymer pipes provides a scalable and cost-effective means for harvesting waste heat from ultra-low temperature sources. Thekdi, Arvind, and Sachin U. Nimbalkar. Oak Ridge National Lab, 2015 Shen, Sheng, et al. Nature nanotechnology 5.4 (2010): 251. Xu, Yanfei, et al. Science advances 4.3 (2018): 3031. Smith, M. K., Singh, V., Kalaitzidou, K., & Cola, B. A. (2015). ACS nano, 9(2), 1080-1088. Aymonier, C., Bortzmeyer, D., Thomann, R., & Mülhaupt, R. (2003). Chemistry of Materials, 15(25), 4874-4878.

C Rajagopal, Manjunath↗

Milestone Report #2: Direct Evaporator Leak and Flammability Analysis Modifications and Optimization of the Organic Rankine Cycle to Improve the Recovery of Waste Heat

The direct evaporator is a simplified heat exchange system for an Organic Rankine Cycle (ORC) that generates electricity from a gas turbine exhaust stream. Typically, the heat of the exhaust stream is transferred indirectly to the ORC by means of an intermediate thermal oil loop. In this project, the goal is to design a direct evaporator where the working fluid is evaporated in the exhaust gas heat exchanger. By eliminating one of the heat exchangers and the intermediate oil loop, the overall ORC system cost can be reduced by approximately 15%. However, placing a heat exchanger operating with a flammable hydrocarbon working fluid directly in the hot exhaust gas stream presents potential safety risks. The purpose of the analyses presented in this report is to assess the flammability of the selected working fluid in the hot exhaust gas stream stemming from a potential leak in the evaporator. Ignition delay time for cyclopentane at temperatures and pressure corresponding to direct evaporator operation was obtained for several equivalence ratios. Results of a computational fluid dynamic analysis of a pinhole leak scenario are given.

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Preliminary Reporting of Thermophysical Property Measurements for the Ghareb Formation

Accurate knowledge of thermophysical properties of rock is vital to develop meaningful models of high level nuclear waste emplacement scenarios. The Israel Atomic Energy Commission is considering storing high level nuclear waste in the Ghareb formation, a porous kerogen bearing chalk. Sandia is supporting this effort with an evolving lab- based geomechanics testing program. We have completed measurements of thermal properties up to 275C and room temperature hydrostatic compaction measurements. We report thermal conductivity, thermal diffusivity, specific heat, and mass loss from our thermal measurements, and we report bulk moduli and porosity loss from our compaction measurements. These values are crucial for the numerical models to simulate heat transfer and formation compressibility around a heat generating repository.

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Scenario Development: Proposal of a Methodology for Different Host Rocks and Disposal Concepts - 19007

Scenario development is an essential part of the assessment of the long-term safety of a repository for radioactive waste. The new act on site selection in Germany in 2017 requires that salt, clay and crystalline rock are studied as possible sites for repositories. So far, a comprehensive methodology for scenario development has been developed only for a site in salt rock in Germany within the Preliminary Safety Analysis (VSG). The question arose whether this methodology is transferable to other host rocks and disposal concepts and which modifications may be necessary. The transferability was shown in the project ANSICHT for clay rock sites while introducing some modifications of the methodology. This project studied the transferability of crystalline rock sites, however, there is no suitable safety and disposal concept or even a generic site yet. To study the transferability, initial barriers and FEP for different concepts were selected and the first steps of the methodology for crystalline rock were applied and discussed. It was concluded that the definition of barriers as containment providing rock zone (CPRZ) is difficult but important for the application of the methodology. Concepts for crystalline rock can foresee a CPRZ within the host rock or above. If the concept is using engineered barriers only and no CPRZ, the number of initial barriers is low. This will subsequently lead to a more complex scenario development since long FEP chains have to be considered. Based on the discussion so far, the transferability of the methodology seems to be feasible in general. (authors)

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An Investigation into the Transportation of Irradiated Uranium/Aluminum Targets from a Foreign Nuclear Reactor to the Chalk River Laboratories Site in Ontario, Canada - 12249

This investigation required the selection of a suitable cask and development of a device to hold and transport irradiated targets from a foreign nuclear reactor to the Chalk River Laboratories in Ontario, Canada. The main challenge was to design and validate a target holder to protect the irradiated HEU-Al target pencils during transit. Each of the targets was estimated to have an initial decay heat of 118 W prior to transit. As the targets have little thermal mass the potential for high temperature damage and possibly melting was high. Thus, the primary design objective was to conceive a target holder to dissipate heat from the targets. Other design requirements included securing the targets during transportation and providing a simple means to load and unload the targets while submerged five metres under water. A unique target holder (patent pending) was designed and manufactured together with special purpose experimental apparatus including a representative cask. Aluminum dummy targets were fabricated to accept cartridge heaters, to simulate decay heat. Thermocouples were used to measure the temperature of the test targets and selected areas within the target holder and test cask. After obtaining test results, calculations were performed to compensate for differences between experimental and real life conditions. Taking compensation into consideration the maximum target temperature reached was 231 deg. C which was below the designated maximum of 250 deg. C. The design of the aluminum target holder also allowed generous clearance to insert and unload the targets. This clearance was designed to close up as the target holder is placed into the cavity of the transport cask. Springs served to retain and restrain the targets from movement during transportation as well as to facilitate conductive heat transfer. The target holder met the design requirements and as such provided data supporting the feasibility of transporting targets over a relatively long period of time. A suitable transport cask was selected and a device for housing irradiated targets for loading, unloading and transportation has been designed, built and validated. The device was successful in meeting all design requirements for this feasibility study. Experiments were conducted with a custom test facility to confirm that the design met the maximum temperature requirements during shipping. Results from tests showed that the peak temperature in the apparatus was 300 deg. C. By compensating for experimental considerations, such as reduced thermal conductivity of the test cask versus that of the actual cask the expected maximum target temperature reduces to 231 deg. C. This is below the designated peak value of 250 deg. C. It can therefore be concluded, based on the content of this paper and from a heat-removal standpoint, the feasibility of transporting targets from a foreign nuclear reactor to Canada is possible, although further testing with irradiated targets and a full size cask would be a recommended next step. (authors)

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DEVELOPMENT OF AN ANTIFOAM TRACKING SYSTEM AS AN OPTION TO SUPPORT THE MELTER OFF-GAS FLAMMABILITY CONTROL STRATEGY AT THE DWPF

The Savannah River National Laboratory (SRNL) has been working with the Savannah River Remediation (SRR) Defense Waste Processing Facility (DWPF) in the development and implementation of an additional strategy for confidently satisfying the flammability controls for DWPF’s melter operation. An initial strategy for implementing the operational constraints associated with flammability control in DWPF was based upon an analytically determined carbon concentration from antifoam. Due to the conservative error structure associated with the analytical approach, its implementation has significantly reduced the operating window for processing and has led to recurrent Slurry Mix Evaporator (SME) and Melter Feed Tank (MFT) remediation. To address the adverse operating impact of the current implementation strategy, SRR issued a Technical Task Request (TTR) to SRNL requesting the development and documentation of an alternate strategy for evaluating the carbon contribution from antifoam. The proposed strategy presented in this report was developed under the guidance of a Task Technical and Quality Assurance Plan (TTQAP) and involves calculating the carbon concentration from antifoam based upon the actual mass of antifoam added to the process assuming 100% retention. The mass of antifoam in the Additive Mix Feed Tank (AMFT), in the Sludge Receipt and Adjustment Tank (SRAT), and in the SME is tracked by mass balance as part of this strategy. As these quantities are monitored, the random and bias uncertainties affecting their values are also maintained and accounted for. This report documents: 1) the development of an alternate implementation strategy and associated equations describing the carbon concentration from antifoam in each SME batch derived from the actual amount of antifoam introduced into the AMFT, SRAT, and SME during the processing of the batch. 2) the equations and error structure for incorporating the proposed strategy into melter off-gas flammability assessments. Sample calculations of the system are also included in this report. Please note that the system developed and documented in this report is intended as an alternative to the current, analytically-driven system being utilized by DWPF; the proposed system is not intended to eliminate the current system. Also note that the system developed in this report to track antifoam mass in the AMFT, SRAT, and SME will be applicable beyond just Sludge Batch 8. While the model used to determine acceptability of the SME product with respect to melter off-gas flammability controls must be reassessed for each change in sludge batch, the antifoam mass tracking methodology is independent of sludge batch composition and as such will be transferable to future sludge batches.

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Exploring the Nature of f-Element Soft Donor Interactions Using Electronically Tunable Azolate Ionic Liquids

This project was undertaken to advance the understanding of how f-elements interact with moderately soft donors, a heavily investigated yet open question which is of prime importance in spent nuclear fuel processing and fundamental inorganic chemistry. During the course of the project, based on exciting results, a stretch goal was developed to study the hydrolysis products of transuranic actinide metals, a somewhat understudied field even with its significance in nuclear fuel cycle and impacts in environmental chemistry. The stretch goal was to take our serendipitous discovery of an easy route to isolation of crystalline multinuclear ƒ-element hydrolysis products, and apply it to gaining a mechanistic understanding of Pu(III/IV) colloid formation. The simplicity of our techniques should lend themselves to the remote handling required for study of many transuranic elements. We developed several methodologies using azolium azolate chemistry to overcome ƒ-element hydrolysis problems that prohibit the isolation of ƒ-element soft donor complexes and to build a crystallographic library of ƒ-element N-donor complexes as a means to understand the fundamental differences between actinide and lanthanide interactions with moderately soft donor ligands. Our next major endeavor will be to transfer this chemistry from 4ƒ elements to transuranic elements, particularly in the study of hydrolysis of Pu(III/IV). While our work is fundamental in nature, applications of the knowledge we are generating should be felt in such diverse fields as catalysis, separations in general, nuclear waste remediation specifically, and many other applications in f-element magnetic and luminescent properties. The potential ramifications of the consistent and robust formation of hydrolysis controlled hexanuclear lanthanide structures are enormous, with future uses being catalyst formation, higher-nuclearity structure synthesis using our hexanuclear motif as a fundamental building block, Pu waste remediation, separations, and many other potential applications resulting from characteristic magnetic and luminescent properties of lanthanide polynuclear structures. Three synthetic methodologies (direct mixing with variable stoichiometries, use of volatile solvent, metathesis) were developed starting with 7 acidic and 6 basic azoles to obtain ionic liquids suitable for f-element coordination. Proton transfer by acidic/basic azole combination led to suitable low melting salts and two cocrystals. Acid/base reaction of azoles with soft-donor permanent cations of ([X 4444 ][OH] (where [X 4444 ] + = tetrabutylammonium [N 4444 ] + or tetrabutylphosphonium [P 4444 ] + ) with weakly acidic azoles including imidazole, 1,2,3-triazole, 1,2,4-triazole, 5-aminotetrazole, 4,5-dicyanoimidazole, and 2-amino-4,5-dicyanoimidazole) revealed several suitable low-melting salts. Metathesis reactions of Na(azolate) were conducted by first using weakly acidic azoles including 4,5-dicyanoimidazole, 2-amino-4,5-dicyanoimidazole, 5-aminotetrazole, and 1,2,4-triazole to form sodium or lithium salts using group(I) hydroxides in methanolic solutions. The best results were obtained by reacting the basic and acidic azoles directly in 1:1 or 3:1 ratios at elevated temperatures. Twenty-two azole mixtures were identified which are either low melting solids or room temperature liquids. Each of the low melting solids was confirmed to be a new solid phase, each of which is being further characterized. The liquids and solids are anticipated to be ILs, eutectics, or partially ionized systems, all of which will be suitable for the dissolution of f-element salts. Five new synthetic methodologies were developed to finding suitable crystallization conditions for f-element complexation with the goal of finding simple one pot reaction syntheses and crystallization strategies that could be used under the demanding conditions of transuranic chemistries. These synthetic methods yield many new crystalline phases which were studied by single crystal X-ray diffraction.

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Innovative Waste Packaging and Associated Venting/Hydrogen Management - 16594

The original strategy for managing intermediate level waste (ILW) was developed in the 1980s by the UK Nuclear Industry Radioactive Waste Executive (NIREX), which is now the Radioactive Waste Management Limited (RWM), a wholly owned subsidiary of the Nuclear Decommissioning Authority (NDA). The strategy involved retrieving ILW, sorting and encapsulating it in cement based grout within thin walled stainless steel containers. The containers would then be transferred to a large purpose-built shielded ILW store on site, where they would be stored until the planned final deep geological disposal facility becomes available. In recognition of the high up-front costs of such a strategy, which requires remote facilities for the encapsulation and storage, and coupled with the long programme duration for the design, construction and commissioning of these facilities, waste management organisations responsible for managing the clean-up of legacy facilities within the UK have, in recent years, sought innovative solutions which could potentially both accelerate clean-up and hazard reduction on sites, and with a lower overall programme lifecycle cost. Many of the recent innovative solutions are focused around a new family of packaging designs known as robust shielded containers (RSCs). These are self-shielded containers manufactured from materials such as ductile cast iron or fabricated steel. These containers offer the potential to package wastes for disposal without encapsulation and avoid the need for a highly engineered remote handled shielded store for interim storage. The paper provides a high level overview of the generic concepts of RSCs developed by Croft and focuses on the specific challenges of wasteform evolution on waste package integrity and performance. In particular, the integrity and performance of the filtered vent system required to manage internal pressurisation and to ensure sufficient venting capacity of hydrogen and other evolved gases. The paper summarises the analysis by ARUP undertaken to substantiate the RSC integrity under detonation/deflagration explosion loadings arising from hydrogen accumulation. Analyses of the structural response of the filter assembly were undertaken for both detonation and deflagration explosion scenarios, with the loadings applied to the filter housing rim and to the filter vent cover. The paper also presents evidence of the mechanical performance of the filter medium in terms of pressure transients during deflagration events and the degree to which filtration efficiency is maintained. (authors)

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Modelling uranium dioxide corrosion under repository conditions: A pore-scale study of the chemical and thermal processes

This paper investigates the corrosion behaviors of spent uranium dioxide (UO 2 ) fuel when placed in geological repositories. We performed pore-scale reactive transport simulations of the UO 2 corrosion process in a defective fuel rod with different orientations of breach or fracture on its clad. It is found that the corrosion rate has strong dependency on the breach orientation. The highest corrosion rate of UO 2 is calculated when the angle between the groundwater flow direction and the clad fracture reaches 180°. UO 2 corrosion simulations with different flow rates are compared. The results show the higher flow rate accelerates the corrosion of UO 2 fuel. The effect of pH on the corrosion process is also determined. It is indicated that higher pH can limit the corrosion of UO 2 by reducing the reaction rate. The dependence of reaction rate and time on reactive surface area is explored. Spent fuel with lower surface area demonstrates longer lifetime under corrosion conditions. A numerical model coupling thermal conduction and chemical reactions is developed to assess the impact of temperature on the process of UO 2 corrosion. The results show that higher temperature leads to larger corrosion rates for UO 2 . Here, the predicted reaction rates are higher in comparison with the isothermal results. Hence, our results can help improve the fundamental understanding of UO 2 corrosion in geological repositories for long-term storage of spent nuclear fuels and provide guidance for the safe operations and selection of appropriate repositories.

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Modifications and Optimization of the Organic Rankine Cycle to Improve the Recovery of Waste Heat, Milestone Report #5: Prototype Test

The opportunity for recovery of lost energy in thermal processes is estimated to be approximately 80 GW in the United States. In other words, this could save approximately 450 MM tons of CO 2 from entering the atmosphere. A significant fraction of this energy (about 10.7 GW) is emitted as exhaust (waste) heat from gas turbines at temperatures between 450 and 600°C. Existing waste heat recovery processes (e.g., the OREGEN Organic Rankine Cycle [ORC]) attempt to recover this energy from such high-temperature exhaust streams by employing an intermediate heat transfer oil that protects the ORC working fluid from exposure to the high temperatures in the exhaust stream because the high temperatures (about 300°C) would cause thermal breakdown of the organic working fluid in the ORC. The direct evaporator technology developed as part of this project allows direct contact between the hot exhaust and the ORC working fluid and mitigates the risk of fluid degradation by employing a “protective staging” (shown in Figure 1). The direct evaporator experiment conducted as part of this work aims to validate the premise of the direct evaporator in an ORC cycle: heat transfer from a hot exhaust gas at 500°C to a cyclopentane working fluid at conditions representative of an ORC cycle with boiling and superheating of the cyclopentane without risking thermal degradation. In addition, the following related data were collected for the 300-hour duration test: • Data that show the temperature of the working fluid did not exceed 300°C, • Degradation data from samples of the working fluid collected at various times during the test, and • A measure of fouling in the heat exchanger (HX) tubes (caused by thermal breakdown of the working fluid).

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Bioelectrochemical Biorefining

Bioelectrochemical biorefining is a new concept which has evolved from the field of microbial fuel cells and electrolysis cells. It targets integration of microbial electrochemical cells into the biorefinery. The idea is to use low value resources to generate electrons and then use the electrons to produce value-added products. This can enable production of fuels and chemicals from waste and biomass using electrons as intermediates. Thus, the name: Bioelectrochemical Biorefining. Electrons are the simplest and most common ‘energy carriers’ of many energy transfer systems and energetic molecules. Thus, using them as the vehicle for conversion of existing renewable resources into products needed for the 21st century is the primary goal of this marriage between microbial electrochemical technology and biorefineries.

Borole, Abhijeet↗

Oak Ridge Cleanup Vision: Moving to the Future by Cleaning Up the Past - 13291

The Oak Ridge Office of Environmental Management (EM) strives to be the leader in the Department of Energy's (DOE's) EM Complex regarding successful and safe project execution and stakeholder interactions that yield positive results. EM's goal has been to become 'Investment Worthy' and, in order to accomplish that important objective, has also had to improve communications both within and outside of the Department. One of our most important missions is to assist the Department in achieving the sustainability goals set forth in Executive Order 13514. In this regard, EM's primary role is to return land to beneficial use and reduce energy impacts and maintenance costs by demolishing unneeded and deteriorating structures and remediating environmental contamination. Recent accomplishments toward meeting these goals include significant progress in the decontamination and demolition of the country's largest facility, the former K-25 Gaseous Diffusion Building, constructed in 1942 to enrich uranium to help end World War II; the disposition of the first phase of Uranium-233 material from the Oak Ridge National Laboratory (ORNL) which involved the transfer of Zero Power Reactor Plates to the National Nuclear Security Administration (NNSA); and a host of other project successes associated with transuranic (TRU) waste processing, hot cell decontamination and demolition, remediation of highly contaminated soils and burial grounds, and removal of mercury from storm sewers and surface waters. With regard to successful stakeholder interactions, recent accomplishments include a new method for collaboration that has renewed EM's working relationship with the regulators, and success in completing an extensive consultation process with over a dozen parties on the historic preservation of the former Oak Ridge Gaseous Diffusion Plant, which is now called the East Tennessee Technology Park (ETTP). Regarding improved communications, EM has successfully revised Program priorities and has received buy-in from the leadership in Headquarters, the regulators, and the community. Issues EM was facing in 2009 are presented. Resulting lessons learned and subsequent changes that the Office has gone through in the past several years in order to improve performance in the safe execution of work, relationships with external stakeholders, and communications both internally and externally are discussed. Results of these efforts are provided as a summary of Program accomplishments, including a strong focus on the future. EM's motto, Moving to the Future by Cleaning up the Past, will be demonstrated through the Program's mission, which includes protecting the region's health and environment; ensuring the continuation of ongoing vital missions being conducted by DOE on the Oak Ridge Reservation; and making clean land available for future use at all three sites, with a near-term focus on Re-industrialization of ETTP. (authors)

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MY EXES and EDM for Automated Remediation Data Quality Assessments - 19053

MY Electronic data exchange and Evaluation System (EXES) is a new web-based technology providing external admin access and full control to the Web-based EXES tool developed by GD for EPA for automated environmental remediation data quality assessments. EXES replaces most manual assessment processes, reducing remediation data review time and costs and ensuring that data are of known and documented quality. This tool is available from EPA to federal agencies and remediation firms and has successfully been used to support over 190 site investigations, 105 Remedial investigations and over 20 compliance monitoring efforts. The new MY EXES functionality has been developed for project managers and decision makers to setup projects, track receipt of environmental remediation monitoring data, assess data quality, and manage data. It is designed to be flexible and configurable to meet any government agency's data review and data management needs. It is accessible 24/7 through a secure portal. MY EXES efficiently evaluates analytical data regardless of the underlying method and data reporting requirements. It is a centralized project and data assessment tool that is scalable, flexible and configurable; improving data quality while reducing cost through the following: - Provides users with the ability to create a project and to specify the analytical methods corresponding to the data that will be submitted for that project. A project can be modified and managed anytime during the project's life cycle. - Allows users to manage a library of analytical methods that can be made available for association to their projects. - Users can specify the automated tests and assessment that needs to be performed on the analytical data deliverables based on specific requirements in the project's Quality Assurance Project Plan (QAPP). - Users specify: - The format of the incoming data deliverables from the laboratory; - The type and level of review services to be performed; - The assessment deliverables to be generated - output spreadsheets and reports; - Project owner sets up system access and permissions for members of the project team. - A faster (600%) and less expensive (85%) process than the traditional data usability/validation. The EXES Data Manager application (EDM) provides a centralized data repository to view and retrieve generated reports, spreadsheets, and other data deliverables as defined by the client, eliminating the need for data transfer between project team members. (authors)

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Results of Hg speciation testing on DWPF SMECT-4, SMECT-6, and RCT-2 samples

The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team.i,ii The fifteenth shipment of samples was designated to include Defense Waste Processing Facility (DWPF) Slurry Mix Evaporator Condensate Tank (SMECT) samples from Sludge Receipt and Adjustment Tank (SRAT) Batch 738 and a Recycle Condensate Tank (RCT) sample from SRAT Batch 736. The DWPF sample designations for the three samples analyzed are provided in Table 1. The Batch 738 ‘Baseline’ SMECT sample was taken prior to Precipitate Reactor Feed Tank (PRFT) addition and concentration and therefore, precedes the SMECT-5 sample reported previously. iii The Batch 738 ‘End of SRAT Cycle’ SMECT sample was taken at the conclusion of SRAT operations for this batch (PRFT addition/concentration, acid additions, initial concentration, MCU addition, and steam stripping). Batch 738 experienced a sludge slurry carryover event, which introduced sludge solids to the SMECT that were particularly evident in the SMECT-5 sample, but less evident in the ‘End of SRAT Cycle’ SMECT-6 sample. The Batch 736 ‘After SME’ RCT sample was taken after completion of SMECT transfers at the end of the SME cycle.

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An On-line Technology Information System (OTIS) for Advanced Life Support

OTIS is an on-line communication platform designed for smooth flow of technology information between advanced life support (ALS) technology developers, researchers, system analysts, and managers. With pathways for efficient transfer of information, several improvements in the ALS Program will result. With OTIS, it will be possible to provide programmatic information for technology developers and researchers, technical information for analysts, and managerial decision support. OTIS is a platform that enables the effective research, development, and delivery of complex systems for life support. An electronic data collection form has been developed for the solid waste element, drafted by the Solid Waste Working Group. Forms for other elements (air revitalization, water recovery, food processing, biomass production and thermal control) will also be developed, based on lessons learned from the development of the solid waste form. All forms will be developed by consultation with other working groups, comprised of experts in the area of interest. Forms will be converted to an on-line data collection interface that technology developers will use to transfer information into OTIS. Funded technology developers will log in to OTIS annually to complete the element- specific forms for their technology. The type and amount of information requested expands as the technology readiness level (TRL) increases. The completed forms will feed into a regularly updated and maintained database that will store technology information and allow for database searching. To ensure confidentiality of proprietary information, security permissions will be customized for each user. Principal investigators of a project will be able to designate certain data as proprietary and only technical monitors of a task, ALS Management, and the principal investigator will have the ability to view this information. The typical OTIS user will be able to read all non-proprietary information about all projects.Interaction with the database will occur over encrypted connections, and data will be stored on the server in an encrypted form. Implementation of OTIS will initiate a community-accessible repository of technology development information. With OTIS, ALS element leads and managers will be able to carry out informed technology selection for programmatic decisions. OTIS will also allow analysts to make accurate evaluations of technology options. Additionally, the range and specificity of information solicited will help educate technology developers of program needs. With augmentation, OTIS reporting is capable of replacing the current fiscal year-end reporting process. Overall, the system will enable more informed R&TD decisions and more rapid attainment of ALS Program goals.

Levri, Julie A.↗

Assessment of Feasibility of the Beneficial Use of Waste Heat from the Advanced Test Reactor

This report investigates the feasibility of using waste heat from the Advanced Test Reactor (ATR). A proposed glycol waste heat recovery system was assessed for technical and economic feasibility. The system under consideration would use waste heat from the ATR secondary coolant system to preheat air for space heating of TRA-670. A tertiary coolant stream would be extracted from the secondary coolant system loop and pumped to a new plate and frame heat exchanger, where heat would be transferred to a glycol loop for preheating outdoor air in the heating and ventilation system. Historical data from Advanced Test Reactor operations over the past 10 years indicates that heat from the reactor coolant was available (when needed for heating) for 43.5% of the year on average. Potential energy cost savings by using the waste heat to preheat intake air is $\$$242K/yr. Technical, safety, and logistics considerations of the glycol waste heat recovery system are outlined. Other opportunities for using waste heat and reducing water usage at ATR are considered.

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