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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43

Update on Risk Reduction Activities for a Liquid Advanced Booster for NASA's Space Launch System

Dynetics has designed innovative structure assemblies; manufactured them using Friction Stir Welding (FSW) to leverage NASA investments in tools, facilities, and processes; conducted proof and burst testing, demonstrating viability of design/build processes Dynetics/AR has applied state-of-the-art manufacturing and processing techniques to the heritage F-1, reducing risk for engine development Dynetics/AR has also made progress on technology demonstrations for ORSC cycle engine, which offers affordability and performance for both NASA and other launch vehicles Full-scale integrated oxidizer-rich test article. Testing will evaluate performance and combustion stability characteristics. Contributes to technology maturation for ox-rich staged combustion engines.

Crocker, Andy↗

Multitude Characterization and Prediction of DOE Advanced Biofuels Properties

Advanced multitude of experiments ranging from the liquid fuel to combustion are conducted on Co-OPTIMA fuels to aid the characterization of the fuels. The series of targeted experiments characterized Co-OPTIMA fuel spray atomization, flame topology, flame speed, autoignition, volatility, viscosity, soot/coking, and compatibility. The fuels are selected and prioritized based on input from national lab members. The research characterized and predicted biomass-based, low greenhouse gas fuels and blends combustion, autoignition, and physical properties of mixtures of identified compounds at engine-relevant conditions, in particular those properties that blend non-linearly. The main challenge of Co-OPTIMA is the evaluation of a variety of biofuels and blends in all the reaction conditions that might be encountered in new high-efficiency engines. Despite the improved high-throughput experimental techniques, it seems unlikely that all of the performance metrics could be measured for all relevant petroleum derived, bio-derived molecules and mixtures, and reaction conditions. A series of targeted experiments ranging from the liquid fuel to the combustion process is required, and to extract the maximum information from each experiment. These targeted experiments evaluated how a specific fuel will perform in an engine. The series of targeted experiments are as follows: (a) Spray Atomization, Vaporization and Droplet Formation (b) Combustion Flame and Local Fuel/Air Image-Based Measurements (c) Laminar Flame Speed Measurements (d) Autoignition and Soot Measurements (e) Synchrotron Coupled Fundamental Autoignition Experiments (f) Fuel Coking and Hot Surface Deposit g) Fuel Volatility Measurements (h) Viscosity Measurements (i) Seal Flexible Fuel Compatibility These experimental processes provide an essential pathway for the prediction of fuel behaviors in engines and systematic process for fuel down select.

09 BIOMASS FUELS↗

Cradle-to-Grave Lifecycle Analysis of U.S. Light-Duty Vehicle-Fuel Pathways: A Greenhouse Gas Emissions and Economic Assessment of Current (2020) and Future (2030-2035) Technologies

This study provides a comprehensive life cycle analysis (LCA), or cradle-to-grave (C2G) analysis, of the cost and greenhouse gas (GHG) emissions of a variety of vehicle-fuel pathways, the levelized cost of driving (LCD) and cost of avoided GHG emissions. The C2G analysis assesses light duty midsize sedans and small sport utility vehicles (SUVs) across a variety of vehicle-fuel technology pathways, including conventional internal combustion engine vehicles (ICEVs), flexible hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), battery electric vehicles (BEVs) with varying vehicle ranges, and fuel cell electric vehicles (FCEVs). Coming at a timely manner, given the marked increase, since 2016, in climate aspirations announced by governmental institutions and private firms both in the US and across the globe, this analysis builds on a previous comprehensive life cycle analysis, updating that study’s 2016 assumptions and methods (Elgowainy et al. 2016). These updates incorporate technological advances and changes in energy supply sources that have emerged during the intervening period. Utilizing these updated assumptions and methods, alongside more recent data, the present report accounts for a broader range of vehicle technologies and considers both current (2020) and expected future (2030-2035) conditions. Reflecting increased research interest in synthetic liquid fuels produced using renewable low-carbon electricity and CO 2 sources, electro-fuels (a.k.a. e-fuels) were added to the potential future fuel technologies that are evaluated. This study takes a “pathway” approach rather than a “scenario” approach; hence distinct, technically feasible, routes or sequences of processes starting with one or more feedstocks and ending with an intermediate or a final product are examined, not necessarily constrained by practical feedstock, economic, policy, and market considerations.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Detailed fuel spray analysis techniques

Detailed fuel spray analyses are a necessary input to the analytical modeling of the complex mixing and combustion processes which occur in advanced combustor systems. It is anticipated that by controlling fuel-air reaction conditions, combustor temperatures can be better controlled, leading to improved combustion system durability. Thus, a research program is underway to demonstrate the capability to measure liquid droplet size, velocity, and number density throughout a fuel spray and to utilize this measurement technique in laboratory benchmark experiments. The research activities from two contracts and one grant are described with results to data. The experiment to characterize fuel sprays is also described. These experiments and data should be useful for application to and validation of turbulent flow modeling to improve the design systems of future advanced technology engines.

Mularz, E. J.↗

Combustor technology for future small gas turbine aircraft

To enhance fuel efficiency, future advanced small gas turbine engines will utilize engine cycles calling for overall engine pressure ratios, leading to higher combustor inlet pressures and temperatures. Further, the temperature rise through the combustor and the corresponding exit temperature are also expected to increase. This report describes future combustor technology needs for small gas turbine engines. New fuel injectors with large turndown ratios which produce uniform circumferential and radial temperature patterns will be required. Uniform burning will be of greater importance because hot gas temperatures will approach turbine material limits. The higher combustion temperatures and increased radiation at high pressures will put a greater heat load on the combustor liners. At the same time, less cooling air will be available as more of the air will be used for combustion. Thus, improved cooling concepts and/or materials requiring little or no direct cooling will be required. Although presently there are no requirements for emissions levels from small gas turbine engines, regulation is anticipated in the near future. This will require the development of low emission combustors. In particular, nitrogen oxides will increase substantially if new technologies limiting their formation are not evolved and implemented. For example, staged combustion employing lean, premixed/prevaporized, lean direct injection, or rich burn-quick quench-lean burn concepts could replace conventional single stage combustors. Due to combustor size considerations, staged combustion is more easily accommodated in large engines. The inclusion of staged combustion in small engines will pose greater combustor design challenges.

Lyons, Valerie J.↗

Design and Checkout of a High Speed Research Nozzle Evaluation Rig

The High Flow Jet Exit Rig (HFJER) was designed to provide simulated mixed flow turbojet engine exhaust for one- seventh scale models of advanced High Speed Research test nozzles. The new rig was designed to be used at NASA Lewis Research Center in the Nozzle Acoustic Test Rig and the 8x6 Supersonic Wind Tunnel. Capabilities were also designed to collect nozzle thrust measurement, aerodynamic measurements, and acoustic measurements when installed at the Nozzle Acoustic Test Rig. Simulated engine exhaust can be supplied from a high pressure air source at 33 pounds of air per second at 530 degrees Rankine and nozzle pressure ratios of 4.0. In addition, a combustion unit was designed from a J-58 aircraft engine burner to provide 20 pounds of air per second at 2000 degrees Rankine, also at nozzle pressure ratios of 4.0. These airflow capacities were designed to test High Speed Research nozzles with exhaust areas from eighteen square inches to twenty-two square inches. Nozzle inlet flow measurement is available through pressure and temperature sensors installed in the rig. Research instrumentation on High Speed Research nozzles is available with a maximum of 200 individual pressure and 100 individual temperature measurements. Checkout testing was performed in May 1997 with a 22 square inch ASME long radius flow nozzle. Checkout test results will be summarized and compared to the stated design goals.

Castner, Raymond S.↗

A modular chemo-selective oxygen production unit to deliver oxygen for advanced combustion systems

Commercial oxygen generation technologies deploy either cryogenic air separation or vacuum pressure swing adsorption (VPSA). These technologies can provide nearly pure oxygen but are only economically viable at oxygen production rates of 100-7,000 tonnes/day. The state-of-theart cryogenic air separation plants are impending the theoretical limits of thermodynamic efficiency but cannot be scaled down to cater future needs. Therefore, there is great incentive to develop a new approach for oxygen separation that can accommodate the upcoming demands. Our proposed research approach address to find novel methodologies to provide energy efficient modular O 2 on demand systems for modular gasification and other applications. Small scale modular systems for O 2 production offer certain benefits including enhanced energy efficiency, reduced operating costs and flexibility to tailor location specific needs. Our hypothesis is that a small modular system could be engineered using solvent-based capture and thermal release of oxygen, to enable “oxygen on demand” for any combustion-related technology.

42 ENGINEERING↗

Development of a rate-based ENRTL-RK process model for a water-lean solvent

Advanced water-lean solvents (WLS) for post-combustion CO2 capture offer several advantages over the aqueous amine solvents . WLS have lower parasitic energy penalty, lower corrosion, lower temperature and high-pressure CO2 regeneration leading to lower cost of CO2 capture. RTI International, with funding from the US Department of Energy, has been developing its novel water-lean solvent, that has shown specific reboiler duty of 2.3 GJ/t-CO2 at the 60-kWe pilot testing unit (Tiller Plant, SINTEF, Norway) and 2.6 GJ/t-CO2 at the engineering scale testing system (12 MWe) at the Technology Centre Mongstad (TCM) in Norway. All heat duties, including the one from TCM testing, were consistent with Aspen Plus modeling of the specific configuration of each test plant. This work focuses on the development of a detailed process model using in-house laboratory measurements and process data at pilot scale. The eNTRL-RK model used in this work is based on an unsymmetric activity coefficient model with the reference states chosen to be pure liquids for solvents and ideal dilute solution at unit solute molality (resulting in activity coefficient of unity at infinite dilution) for electrolytes. It uses the Redlich-Kwong equation of state for vapor phase properties and Henry’s law for solubility of supercritical gases. The model was validated using process data from the pilot-scale campaign at the Tiller plant, and the engineering scale test campaign at TCM. Data on CO2 capture rate, absorber, and regenerator temperature profiles and specific reboiler duties from two different test campaigns at Tiller and TCM, were used to further refine and validate the model and the model compares favorably to experimental data. The validation results against TCM campaign will be presented in this work.

CO2 capture↗

Quantifying the impacts of micro- and mild- hybrid vehicle technologies on fleetwide fuel economy and electrification

Micro- and mild-hybridization (jointly labeled as M-HEV) is gaining popularity as a cost-effective technology for fuel economy improvement, but whether and how M-HEV may compete against less efficient conventional internal combustion engine vehicles (ICEV), more efficient full hybrid electric vehicles (HEV), and plug-in electric vehicles (PEV) is not well understood. As such, this study aims at evaluating the impact of the market adoption of M-HEV on the average fuel economy of the new vehicle fleet and on the sales share of PEVs. The study reviews recent sales trends and market forecasts, and uses published estimates of manufacturing cost and fuel economy of M-HEV with an existing discrete choice model (Market Acceptance of Advanced Automotive Technologies or MA3T) to project the market penetration and impacts of M-HEV under different scenarios of M-HEV choice positions, designed to enhance conclusion robustness. It is found that among engine-based powertrain choices, micro-HEV appears to be the most cost-effective, followed by ICEVs, mild-HEV and finally full HEVs. M-HEV technologies are likely to improve fleetwide average fuel economy without significant adverse effects on sales of plug-in electric vehicles, and are likely to remain highly competitive outside PEVs through 2050.

33 ADVANCED PROPULSION SYSTEMS↗

Emissions Overview

The Emissions Reduction Project is working in close partnership with the U.S. aircraft engine manufacturers and academia to develop technologies to reduce NO, emissions by 70 percent over the LTO cycle from 1996 ICAO standards with no increase in other emission constituents (carbon monoxide, smoke, and unburned hydrocarbons) and with comparable NO, reduction during cruise operations. These technologies cannot impact the overall combustor and fuel delivery system operability, affordability or maintainability. These new combustion concepts and technologies will include lean burning combustors with higher operating gas temperatures and pressures, fuel staging, ceramic matrix composite material liners with reduced cooling air and possibly advanced controls. Improved physics-based analysis tool will be developed and validated and some longer term technologies that are more revolutionary will be assessed. These improved computational codes will provide improved design tools to increase design confidence and cut the development time to achieve major reductions in NO, emissions. Longer term, revolutionary technologies like active combustion controls, combustion from a large array of micro-injectors, electrostatic fuel injectors, fuel additives and others will be investigated and assessed through proof-of-concept testing.

Rohde, John↗

Solvent-Based Absorption

Solvent-based CO2 absorption processes are the oldest and most mature technology, having been deployed at what would be considered full-scale for post-combustion CO2 capture. There are many commercial 1st and 2nd generation technologies such as Econamine FG+, CANSOLV, Oase Blue, KS-1, with dozens if not hundreds of 3rd generation solvents that are been studied at varying stages of testing. While there are many solvents that are under development, nearly all solvents function on the same physical and chemical principles and it is not surprising that they all have similar configurations with somewhat comparable levels of performance. The enhancements in energy efficiency for solvents have come primarily from the engineering advancements over many decades of refinement, though surprisingly little has changed with respect to the molecular structure of solvents over the same period of time. In this chapter, we explain the tenets of solvent-based processes and provide a chronological timeline of solvents throughout their nearly 90-year history with discussions of why and how advancements in solvent efficiency have been achieved and we conclude with an outlook for the future of solvents and their place in CCUS.

Heldebrant, David J.↗

Measuring Critical Fuel Properties for Simulations to Accelerate Fuel Qualification

NREL's sustainable aviation fuel (SAF) research in the area of fuel properties and end use is focused on accelerating SAF development and deployment. This will be achieved by close collaboration with BETO program researchers on fuel property measurement and development of structure-property relationships. Additionally, fuel properties measured at often extreme engine operating conditions will be measured, and will be used as inputs to exascale ready simulations of aviation combustion turbines to reveal impacts of properties on turbine operation. This research will potentially lead to a widening of the allowable fuel property range for SAF, expanding SAF production process options and production volumes.

ADVANCED PROPULSION SYSTEMS↗

Advanced Environmental Barrier Coating Development for SiC-SiC Ceramic Matrix Composite Components

This presentation reviews the NASA advanced environmental barrier coating (EBC) system development for SiC-SiC Ceramic Matrix Composite (CMC) combustors particularly under the NASA Environmentally Responsible Aviation, Fundamental Aeronautics and Transformative Aeronautics Concepts Programs. The emphases have been placed on the current design challenges of the 2700-3000F capable environmental barrier coatings for low NOX emission combustors for next generation turbine engines by using advanced plasma spray based processes, and the coating processing and integration with SiC-SiC CMCs and component systems. The developments also have included candidate coating composition system designs, degradation mechanisms, performance evaluation and down-selects; the processing optimizations using TriplexPro Air Plasma Spray Low Pressure Plasma Spray (LPPS), Plasma Spray Physical Vapor Deposition and demonstration of EBC-CMC systems. This presentation also highlights the EBC-CMC system temperature capability and durability improvements under the NASA development programs, as demonstrated in the simulated engine high heat flux, combustion environments, in conjunction with high heat flux, mechanical creep and fatigue loading testing conditions.

CMAS↗

An experimental and kinetic modeling study of the pyrolysis of isoprene, a significant biogenic hydrocarbon in naturally occurring vegetation fires

Isoprene dominates the carbon flux emitted by vegetation and constitutes 40% of non-methane biogenic emissions worldwide. Despite pyrolysis experiments at temperatures above 1000 K showing a link between isoprene combustion and aromatic species formation, comprehensive mechanistic research on isoprene is scarce in the literature. Here, in this work, we carry out an experimental and theoretical study to build, for the first time, a chemical kinetic model describing isoprene pyrolysis. The formation of polycyclic aromatic hydrocarbon (PAH) precursor species, often observed in vegetation fire plumes, is partially explained by isoprene pyrolysis experiments and theoretical modeling. Molecular dynamics (MD) simulations unveil reaction pathways from allylic isoprenyl radicals to allene and cyclopentadiene (CPD) intermediates, two relevant species detected in the experiments. Rate constants for these identified pathways are calculated using variational transition state theory to update the kinetic model, which is validated against single-pulse shock tube (SPST), and jet-stirred reactor (JSR) experimental data in the temperature range of 850–1690 K. The kinetic model presents satisfactory agreement with the SPST experimental data, and a reaction pathway analysis shows that association of propargyl radicals results in benzene formation. The JSR pathway analysis also identifies the prominent reactions for CPD, benzene, styrene, and toluene formation. Our model does not reproduce the CPD experimental profiles, indicating that additional studies are necessary. Overall, our findings advance the understanding of isoprene pyrolysis and its related atmospheric pollutants in naturally occurring vegetation fires where smoldering and oxygen-deficient combustion processes are present.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Combustion Feature Characterization using Computer Vision Diagnostics within Rotating Detonation Combustors

Rotating detonation engines (RDEs) theoretically achieve pressure gain by continuously propagating detonation waves in a cylindrical annulus. Research aims to implement them in gas turbines for improved propulsion and power generation efficiency. Current diagnostic methods, such as point measurements and optical diagnostics, face limitations due to high data acquisition rates required to analyze rapid detonation interactions. In contrast, image classification and time series classification achieve real-time capabilities with rates of 4 and 5 Hz, respectively. Object detection offers the highest time-step resolution at 20 μsec, while real-time methods require longer resolutions of 80 msec, highlighting the advancements in diagnostic capabilities for RDEs.

May, Kristyn Johnson↗

Influence of Natural Gas Addition on Combustion Instabilities on a Lean-Premixed Hydrogen Flame

The influence of fuel composition on combustion instabilities in a high-pressure combustor operated with hydrogen and natural gas fuels is characterized. A micromix multi-stage injector with 19 elements is used to introduce hydrogen and natural gas premixed with heated air into an optically accessible combustor. As the equivalence ratio and flame temperature is varied along with change in hydrogen fraction in the fuel, self-excited longitudinal instabilities are observed in the combustor. The instability amplitude reduces considerably as hydrogen fraction is increased. This sensitivity differs at higher flame temperature, with large amplitude instabilities attenuating at lower hydrogen fractions for flames with more thermal power. Increasing hydrogen concentration is shown, through kinetic modeling, to decrease the bulk reaction timescale linearly with observed instability amplitude. Spatial distribution of heat release in the combustor evaluated from OH* chemiluminescence imaging reveals excitation of primarily the 2L mode in the combustion chamber at ~1100 Hz, at all equivalence ratios and fuel compositions. Increasing equivalence ratio and hydrogen addition decreases the length of the positively correlated region, which leads to instability dampening.

08 HYDROGEN↗

Combustion research for gas turbine engines

Research on combustion is being conducted at Lewis Research Center to provide improved analytical models of the complex flow and chemical reaction processes which occur in the combustor of gas turbine engines and other aeropropulsion systems. The objective of the research is to obtain a better understanding of the various physical processes that occur in the gas turbine combustor in order to develop models and numerical codes which can accurately describe these processes. Activities include in-house research projects, university grants, and industry contracts and are classified under the subject areas of advanced numerics, fuel sprays, fluid mixing, and radiation-chemistry. Results are high-lighted from several projects.

Mularz, E. J.↗

Combustion research for gas turbine engines

Research on combustion is being conducted at Lewis Research Center to provide improved analytical models of the complex flow and chemical reaction processes which occur in the combustor of gas turbine engines and other aeropropulsion systems. The objective of the research is to obtain a better understanding of the various physical processes that occur in the gas turbine combustor in order to develop models and numerical codes which can accurately describe these processes. Activities include in-house research projects, university grants, and industry contracts and are classified under the subject areas of advanced numerics, fuel sprays, fluid mixing, and radiation-chemistry. Results are high-lighted from several projects.

Mularz, E. J.↗