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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Experimental study of the spray characteristics of a research airblast atomizer

Airblast atomization was studied using a especially designed atomizer in which the liquid first impinges on a splash plate, then is directed radically outward and is atomized by the air passing through two concentric, vaned swirlers that swirl the air in opposite directions. The effect of flow conditions, air mass velocity (mass flow rate per unit area) and liquid to air ratio on the mean drop size was studied. Seven different ethanol solutions were used to simulate changes in fuel physical properties. The range of atomizing air velocities was from 30 to 80 m/s. The mean drop diameter was measured at ambient temperature (295 K) and atmospheric pressure.

Acosta, W. A.↗
NASA NTRS1991

Characterization of a 5-eV neutral atomic oxygen beam facility

An experimental effort to characterize an existing 5-eV neutral atomic oxygen beam facility being developed at Princeton Plasma Physics Laboratory is described. This characterization effort includes atomic oxygen flux and flux distribution measurements using a catalytic probe, energy determination using a commercially designed quadrupole mass spectrometer (QMS), and the exposure of oxygen-sensitive materials in this beam facility. Also, comparisons were drawn between the reaction efficiencies of materials exposed in plasma ashers, and the reaction efficiencies previously estimated from space flight experiments. The results of this study show that the beam facility is capable of producing a directional beam of neutral atomic oxygen atoms with the needed flux and energy to simulate low Earth orbit (LEO) conditions for real time accelerated testing. The flux distribution in this facility is uniform to +/- 6 percent of the peak flux over a beam diameter of 6 cm.

Vaughn, J. A.↗
DOE OSTI2023

Suppression of Midinfrared Plasma Resonance Due to Quantum Confinement in δ-Doped Silicon

The classical Drude model provides an accurate description of the plasma resonance of three-dimensional materials, but only partially explains two-dimensional systems where quantum mechanical effects dominate such as P:δ layers—atomically thin sheets of phosphorus dopants in silicon that induce electronic properties beyond traditional doping. Previously it was shown that P:δ layers produce a distinct Drude tail feature in ellipsometry measurements. However, the ellipsometric spectra could not be properly fit by modeling the δ layer as a discrete layer of classical Drude metal. In particular, even for large broadening corresponding to extremely short relaxation times, a plasma resonance feature was anticipated but not evident in the experimental data. In this work, we develop a physically accurate description of this system, which reveals a general approach to designing thin films with intentionally suppressed plasma resonances. Our model takes into account the strong charge-density confinement and resulting quantum mechanical description of a P:δ layer. Here, we show that the absence of a plasma resonance feature results from a combination of two factors: (i) the sharply varying charge-density profile due to strong confinement in the direction of growth; and (ii) the effective mass and relaxation time anisotropy due to valley degeneracy. The plasma resonance reappears when the atoms composing the δ layer are allowed to diffuse out from the plane of the layer, destroying its well-confined two-dimensional character that is critical to its distinctive electronic properties.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Size-Selective Nanoporous Atomically Thin Graphene Separators for Lithium–Sulfur Batteries

Lithium–sulfur batteries (LSBs) are extensively researched for their high energy densities but are hindered by the lithium polysulfide (LiPS) shuttling effect, which results in poor cyclability. A popular mitigation strategy is separator modification, where a LiPS trapping material is slurry-coated onto a conventional microporous polypropylene (PP) separator. This additional mass and volume unfortunately compromise the overall energy density of the LSB. This study aims to take a separator modification approach that avoids this issue. Nanoporous atomically thin membranes (NATMs) made of graphene are gaining attention for their scalable synthesis, tunable pore size, and negligible pore length. Herein, we apply a well-characterized graphene NATM for reasons similar to those of a size-selective interlayer in LSBs. The tailored pore size of ∼0.7–1.0 nm and atomic thinness facilitate the passage of Li + (solvated ionic diameters ∼0.54–1.26 nm) and blockage of larger LiPS (solvated ionic diameters ∼0.81–1.69 nm) without adding significant impedances or mass. The sulfur confinement is confirmed through scanning electron microscopy and energy-dispersive X-ray spectroscopy elemental analysis of the Li anode. An LSB with a NATM@PP separator shows virtually no capacity loss over 150 cycles, demonstrating efficacy of size-selective molecular sieving using NATMs in LSBs.

battery separator↗
NASA NTRS1998

Study of Atmospheric Nitric Oxide

We investigated the contribution of energetic nitrogen atoms to the production of nitric oxide in the thermosphere and their influence on the infrared emission spectrum. The nitric oxide molecules are important contributors to the cooling of the atmosphere. We first pointed out that in determining the energy distribution of the nitrogen atoms, it is important to take into account the thermal motion of the atmospheric gases. It had been ignored in all earlier studies. The source spectra are broadened considerably by the center of mass motion of the reactants. We worked out the consequences for the production of nitric oxide at night, using as sources of energetic N atoms, NO(+) + e yield N + O, N(D-2) + O yield N + O. The high energy tail is enhanced by orders of magnitude. We had earlier suggested (Sharma et al. 1993) that the reaction of energetic nitrogen atoms with O2 was responsible for the rotationally enhanced NO identified in the infrared spectrum. Our calculations provided quantitative confirmation of the suggestion. We proceeded to explore the validity of another approximation used in earlier analyses, the hard sphere approximation for the energy loss in elastic collisions. We carried out precise quantum mechanical calculations of the elastic 2 differential scattering of nitrogen atoms in collisions with oxygen atoms and showed that although the hard sphere approximation was nowhere of high precision, reasonable results could be obtained with an effective cross section of 6 x 10(exp 15)sq cm. We also initiated a program to include inelastic energy loss processes in the determination of the energy distribution function. We began a calculation of the rotation and vibrational excitation cross sections of molecular nitrogen and nitrogen atoms and developed a method for including inelastic energy loss as a function of scattering angle in the Boltzmann equation. A procedure for obtaining the solution of the Boltzman equation was worked out.

Dalgarno, A.↗
DOE OSTI2023

Revisiting the pseudo-supercritical path method: An improved formulation for the alchemical calculation of solid–liquid coexistence

Alchemical free energy calculations via molecular dynamics have been applied to obtain thermodynamic properties related to solid–liquid equilibrium conditions, such as melting points. In recent years, the pseudo-supercritical path (PSCP) method has proved to be an important approach to melting point prediction due to its flexibility and applicability. In the present work, we propose improvements to the PSCP alchemical cycle to make it more compact and efficient through a concerted evaluation of different potential energies. The multistate Bennett acceptance ratio (MBAR) estimator was applied at all stages of the new cycle to provide greater accuracy and uniformity, which is essential concerning uncertainty calculations. In particular, for the multistate expansion stage from solid to liquid, we employed the MBAR estimator with a reduced energy function that allows affine transformations of coordinates. Free energy and mean derivative profiles were calculated at different cycle stages for argon, triazole, propenal, and the ionic liquid 1-ethyl-3-methyl-imidazolium hexafluorophosphate. Comparisons showed a better performance of the proposed method than the original PSCP cycle for systems with higher complexity, especially the ionic liquid. Furthermore, a detailed study of the expansion stage revealed that remapping the centers of mass of the molecules or ions is preferable to remapping the coordinates of each atom, yielding better overlap between adjacent states and improving the accuracy of the methodology.

25 ENERGY STORAGE↗
DOE OSTI2025

Small-scale production of bespoke accelerated aging plutonium alloy

Here, this study demonstrates the 100 g scale manufacture of a plutonium alloy that ages at an accelerated rate. The resulting alloy ages six times faster than typical weapons-grade plutonium due to the addition of 238 Pu. As a major innovation, the process involved using a partial direct oxide reduction technique. This method was achieved by developing a new, complex geometry stirrer using additive manufacturing to reduce the 238Pu oxide and efficiently incorporate it into weapons-grade plutonium metal. The material was then purified by molten salt extraction and electrorefining before being alloyed with gallium. The alloy was then cold-rolled and annealed in a homogenization heat treatment. The resulting disk was characterized by metallography and differential scanning calorimetry, and the impurity content was determined using analytical chemistry techniques. The results show that a homogeneous delta phase plutonium alloy was achieved with expected microstructure and minimal impurities. This study was also successful in changing the plutonium isotopic composition by incorporating additional 238 Pu to accelerate the effects of radiation damage. This enables researchers to study long-term aging phenomena in a reduced time frame, thus avoiding the need for large-scale material production and circumventing the limitations of using naturally aged, archived plutonium.

Aging theory↗
NASA NTRS1972

A global empirical model of thermospheric composition based on OGO-6 mass spectrometer measurements

The analysis of composition measurements made with the neutral mass spectrometer aboard the OGO-6 satellite leads to the following conclusions. The measured atomic oxygen densities are generally in good agreement with those deduced from drag. The molecular nitrogen densities in the annual and semiannual variations depart significantly from those predicted by drag models and suggest similar departures for exospheric temperatures. The helium densities generally tend to vary in an inverse manner to the nitrogen densities. These composition changes are consistent with dynamical processes associated with the global circulation in the thermosphere.

Hedin, A. E.↗
NASA NTRS1973

An adhesion criterion in the gas solid interface

A theoretical model is developed to establish an adhesion criterion for the interaction of a gas atom or molecule with a nonmetallic surface. As a first approximation a linear lattice mass points of the solid surface is considered and the classical lattice dynamical model is used.

George, M. C.↗
NASA NTRS1972

Gravitational-wave astronomy.

Discussion of the nature and origin of gravitational waves in the light of current theories and data, stating the concept of gravitational waves as a field of relative gravitational forces that propagate with the speed of light. The topics include the generation of gravitational waves, their astrophysical sources, pulsars, supernovae, the birth of neutron stars, explosions in quasars and nuclei of galaxies, and atomic and molecular processes. Also considered are gravitational wave reception techniques, covering free-mass antennas, nonmechanical displacement sensors, almost free antennas, mechanical displacement sensors, acoustic systems, resonant antennas, Weber's detectors, and natural antennas. Future developments in gravitational wave astronomy are considered.

Press, W. H.↗
NASA NTRS1980

Ion microprobe analysis and petrogenetic interpretations of Li, Mg, Ti, K, Sr, Ba in lunar plagioclase

The ion microprobe employed in the considered investigation utilizes a focused primary ion beam to sputter a tiny volume of a sample. A small fraction of the sputtered atoms is ionized and extracted from the sample region for subsequent analysis with a mass spectrometer. A systematic study was conducted to determine which elements can be detected and analyzed in lunar Ca-rich plagioclase. Attention is given to the method of quantitative determination, the selected samples, and aspects of data presentation. A number of general conclusions are discussed. All minor elements in plagioclases from anorthosites from several lunar sites show a restricted range consistent with a common origin. The simplest interpretation is that the anorthosites developed from a moon-wide event, or at least from closely-related events. A moon-wide magma ocean would satisfy this condition.

Steele, I. M.↗
NASA NTRS1988

Ejection of sodium from sodium sulfide by the sputtering of the surface of Io

The mechanism by which Na is removed from the surface of Io prior to its injection into the plasma torus is investigated experimentally. Na2S films of thickness 3-8 microns were produced by spray coating an Ni substrate in a dry N2 atmosphere and subjected to sputtering by 34-keV Ar(+), Ne(+), Kr(+), or Xe(+) ions up to total doses of about 5 x 10 to the 18th ions/sq cm. The sputtering yields and mass spectra are found to be consistent with ejection of only small amounts of atomic Na and somewhat larger amounts of Na-containing molecules. It is concluded that the amount of Na ejected by magnetospheric-ion sputtering of Na2S would be insufficient to account for the amounts observed in the Io neutral cloud. A scenario involving sputtering of larger polysulfide molecules is considered.

Chrisey, D. B.↗
NASA NTRS1990

Disk mass densities in edge-on spiral galaxies

Very Large Array (VLA) observations of the neutral hydrogen (HI) gas in two nearby edge-on spirals (NGC 4565 and NGC 891) successfully resolve the thickness of the gas layers in both disks over a wide range in radii. The combination of B, C, and D array data produces a 4 arcsec (approx. 200 pc) beam and 21 km s(exp -1) velocity resolution, combined with sensitivity to structures as large as 18 arcmin (approx. 54 kpc). These observations directly constrain the mid-plane disk mass densities, under the assumption of an equilibrium between the thermal pressure of the gas and the gravitational attraction of the disk. The results of a preliminary analysis are given regarding the z-velocity dispersion of the gas, the mass-to-light ratio of the disk in NGC 4565, and the roles of atomic and molecular gases. The data also allow a detailed study of the HI in these galaxies; in general their brightness temperature distributions seem similar to that in the Milky Way. Both galaxies show asymmetric HI extensions beyond the optical disk. In NGC 4565 the extension is a surprisingly abrupt warp, which may bend back to parallel the galactic plane; the velocity structure implies the warp is continuous around the disk.

Rupen, Michael P.↗
NASA NTRS1971

Laboratory Methods for the Measurement of Pollutants in Water and Waste Effluents

The requirement for accurate, precise, and rapid analytical procedures for the examination of water and waste samples requires the use of a variety of instruments. The instrumentation in water laboratories includes atomic absorption, UV-visible. and infrared spectrophotometers, automatic colorimetric analyzers, gas chromatographs and mass spectrometers. Because of the emphasis on regulatory action, attention is being directed toward quality control of analytical results. Among the challenging problems are the differentiation of metallic species in water at nanogram concentrations, rapid measurement of free cyanide and free ammonia, more sensitive methods for arsenic and selenium and improved characterization of organic contaminants.

Ballinger, Dwight G.↗
NASA NTRS2006

MSFC Analysis of Thermal Control Materials on MISSE

Many different passive thermal control materials were flown as part of the Materials on International Space Station Experiment, including coatings, anodizes, and multi-layer insulation materials. Engineers and scientists at the Marshall Space Flight Center have analyzed a number of these materials, including: Zinc oxide/potassium silicate coating, Zinc orthotitanate/potassium silicate coating, Sulfuric acid anodized aluminum, Various coatings for part marking, automated rendezvous and capture, and astronaut visual aids, FEP Teflon with silver/Inconel backing, and Beta cloth with and without aluminization. These and other material samples were exposed to the low Earth orbital environment of atomic oxygen, ultraviolet radiation, thermal cycling, and hard vacuum, though atomic oxygen exposure was very limited for some samples. Solar absorptance, infrared emittance, and mass measurements indicate the durability of these materials to withstand the space environment. The effect of contamination from an active space station on the performance of white thermal control coatings is discussed.

Finckenor, Miria↗
NASA NTRS2007

Analysis of Thermal Control Coatings on MISSE for Aerospace Applications

Many different passive thermal control materials were flown as part of the Materials on International Space Station Experiment. Engineers and scientists at the Marshall Space Flight Center have analyzed a number of these materials, including: Zinc oxide/potassium silicate coating, Zinc oxide/potassium silicate/silicone coating, Zinc orthotitanate/potassium silicate coating, Electrically conductive thermal control coatings and Various coatings for part marking, automated rendezvous and capture, and astronaut visual aids These and other material samples were exposed to the low Earth orbital environment of atormc oxygen, ultraviolet radiation, thermal cycling, and hard vacuum, though atomic oxygen exposure was very limited for some samples. Solar absorptance, infrared emittance, and mass measurements indicate the durability of these materials to withstand the space environment. The effect of contamination from an active space station on the performance of white thermal control coatings is discussed.

Finckenor, Miria↗
NASA NTRS2014

Simulation of Energetic Neutral Atoms from Solar Energetic Particles

Energetic neutral atoms (ENAs) provide the only way to observe the acceleration site of coronal-mass-ejection-driven (CME-driven) shock-accelerated solar energetic particles (SEPs). In gradual SEP events, energetic protons can charge exchange with the ambient solar wind or interstellar neutrals to become ENAs. Assuming a CME-driven shock with a constant speed of 1800 km/s and compression ratio of 3.5, propagating from 1.5 to 40 Rs, we calculate the accelerated SEPs at 5-5000 keV and the resulting ENAs via various charge-exchange interactions. Taking into account the ENA losses in the interplanetary medium, we obtain the flux-time profiles of these solar ENAs reaching 1AU.We find that the arriving ENAs at energies above approx.100 keV show a sharply peaked flux-time profile, mainly originating from the shock source below 5 RS, whereas the ENAs below approx. 20 keV have a flat-top time profile, mostly originating from the source beyond 10 Rs. Assuming the accelerated protons are effectively trapped downstream of the shock, we can reproduce the STEREO ENA fluence observations at approx. 2-5 MeV/nucleon. We also estimate the flux of ENAs coming from the charge exchange of energetic storm protons, accelerated by the fast CME-driven shock near 1AU, with interstellar hydrogen and helium. Our results suggest that appropriate instrumentation would be able to detect ENAs from SEPs and to even make ENA images of SEPs at energies above approx.10-20 keV.

sun↗
NASA NTRS1978

Compatibility of seasonal variations in mid-latitude thermospheric models at solar maximum and low geomagnetic activity

Satellite drag data, in situ mass spectrometer data, Fabry Perot interferometer data, and incoherent scatter data were used to produce models of the concentration of atomic oxygen and molecular nitrogen in the thermosphere and of the exospheric temperature. Incoherent scatter data from two stations near 45 deg N were used. The three techniques provide similar patterns for the annual variations of the atomic oxygen concentration at 400 km, and the mean annual temperatures are within 20 K of each other for five of the six models involved. Four of the models are in good agreement concerning the annual temperature variation. There is fair agreement between incoherent scatter models and mass spectrometer models for the N2 concentrations at 400 km but disagreement between these models and the satellite drag model. It is shown that most disagreements can be resolved by changing both the vertical temperature profile and the lower-thermosphere oxygen concentration in the direction indicated by previous incoherent scatter measurements.

Alcayde, D.↗