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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

International assessment of priority environmental issues for land-based and offshore wind energy development

Non-technical summary A substantial increase in wind energy deployment worldwide is required to help achieve international targets for decreasing global carbon emissions and limiting the impacts of climate change. In response to global concerns regarding the environmental effects of wind energy, the International Energy Agency Wind Technical Collaborative Program initiated Task 34 – Working Together to Resolve Environmental Effects of Wind Energy or WREN. As part of WREN, this study performed an international assessment with the global wind energy and environmental community to determine priority environmental issues over the next 5‒10 years and help support collaborative interactions among researchers, developers, regulators, and stakeholders. Technical summary A systematic assessment was performed using feedback from the international community to identify priority environmental issues for land-based and offshore wind energy development. Given the global nature of wind energy development, feedback was of interest from all countries where such development is underway or planned to help meet United Nations Intergovernmental Panel on Climate Change targets. The assessment prioritized environmental issues over the next 5–10 years associated with wind energy development and received a total of 294 responses from 28 countries. For land-based wind, the highest-ranked issues included turbine collision risk for volant species (birds and bats), cumulative effects on species and ecosystems, and indirect effects such as avoidance and displacement. For offshore wind, the highest-ranked issues included cumulative effects, turbine collision risk, underwater noise (e.g. marine mammals and fish), and displacement. Emerging considerations for these priorities include potential application to future technologies (e.g. larger turbines and floating turbines), new stressors and species in frontier regions, and cumulative effects for multiple projects at a regional scale. For both land-based and offshore wind, effectiveness of minimization measures (e.g. detection and deterrence technologies) and costs for monitoring, minimization, and mitigation were identified as overarching challenges. Social media summary Turbine collisions and cumulative effects among the international environmental priorities for wind energy development.

17 WIND ENERGY↗
DOE OSTI2024

Development of Steady-State and Dynamic Mass and Energy Constrained Neural Networks for Distributed Chemical Systems Using Noisy Transient Data

The paper presents the development of algorithms for mass and energy constrained neural network models that can exactly conserve the overall mass and energy of distributed chemical process systems, even though the noisy transient data used for optimal model training violate the same. In contrast to approximately satisfying mass and energy balance constraints of a system by soft penalization of objective function, algorithms have been developed for solving equality-constrained nonlinear optimization problems, thus providing the guarantee of exactly satisfying the system mass and energy conservation laws. For developing dynamic mass-energy constrained network models for distributed systems, hybrid series and parallel dynamic-static neural networks have been leveraged. The developed algorithms for solving both the training and forward problems are validated using both steady-state and dynamic data in the presence of various noise characteristics. The developed data-driven algorithms are flexible to exactly satisfy mass and energy balance constraints for dynamic chemical processes if the system holdup information is available. The proposed network structures and algorithms are applied to the development of data-driven lumped and distributed models of an adiabatic superheater/reheater system, a nonisothermal continuous stirred tank reactor, as well as an electrically heated plug-flow reactor system where one form of energy gets transformed to another. It has been observed that the mass-energy constrained neural networks yield a root mean squared error of <1% with respect to the system truth for the case studies evaluated in this work.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Regulators of early maize leaf development inferred from transcriptomes of laser capture microdissection (LCM)-isolated embryonic leaf cells

The superior photosynthetic efficiency of C 4 leaves over C 3 leaves is owing to their unique Kranz anatomy, in which the vein is surrounded by one layer of bundle sheath (BS) cells and one layer of mesophyll (M) cells. Kranz anatomy development starts from three contiguous ground meristem (GM) cells, but its regulators and underlying molecular mechanism are largely unknown. To identify the regulators, we obtained the transcriptomes of 11 maize embryonic leaf cell types from five stages of pre-Kranz cells starting from median GM cells and six stages of pre-M cells starting from undifferentiated cells. Principal component and clustering analyses of transcriptomic data revealed rapid pre-Kranz cell differentiation in the first two stages but slow differentiation in the last three stages, suggesting early Kranz cell fate determination. In contrast, pre-M cells exhibit a more prolonged transcriptional differentiation process. Differential gene expression and coexpression analyses identified gene coexpression modules, one of which included 3 auxin transporter and 18 transcription factor (TF) genes, including known regulators of Kranz anatomy and/or vascular development. In situ hybridization of 11 TF genes validated their expression in early Kranz development. We determined the binding motifs of 15 TFs, predicted TF target gene relationships among the 18 TF and 3 auxin transporter genes, and validated 67 predictions by electrophoresis mobility shift assay. From these data, we constructed a gene regulatory network for Kranz development. Our study sheds light on the regulation of early maize leaf development and provides candidate leaf development regulators for future study.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Assessing the impact of demand response on peak demand in a developing country: The case of Ghana

Peak demand on electricity grids is a growing problem that increases costs and risks to supply security. Residential sector loads often contribute significantly to seasonal and daily peak demand. Demand response refers to consumer actions that change the utility load profile in a way that reduces costs or improves grid security by applying price signals and automated load shedding technologies. The methodologies that are used to achieve demand response can hardly be applicable in developing countries. Peak pricing of electricity, for instance, can hardly be implemented in many developing countries as high prices would disproportionately affect the many low-income households who do not have the capacity to take action to avoid paying high peak prices. This study aims to develop demand response methodology that can be applied in developing countries to achieve residential peak demand reduction. We use a consumer preference survey to develop a methodology suitable for developing countries. The method of diversified demand is used with energy audit and monitored data to estimate the potential peak load reduction and its cost-effectiveness for Ghana. Results show that peak reduction of 15-210 MW is expected by 2040 with a positive return on investment of 2-22% for all designed scenarios.

Diawuo, FA↗
DOE OSTI2022

Long-Term and Low-Level Envelope C2V3 Stimulation by Highly Diverse Virus Isolates Leads to Frequent Development of Broad and Elite Antibody Neutralization in HIV-1-Infected Individuals

A minority of HIV-1-infected patients produce broadly neutralizing antibodies (bNAbs). Identification of viral and host correlates of bNAb production may help develop vaccines. We aimed to characterize the neutralizing response and viral and host-associated factors in Angola, which has one of the oldest, most dynamic, and most diverse HIV-1 epidemics in the world. Three hundred twenty-two HIV-1-infected adults from Angola were included in this retrospective study. Phylogenetic analysis of C2V3C3 env gene sequences was used for virus subtyping. Env-binding antibody reactivity was tested against polypeptides comprising the C2, V3, and C3 regions. Neutralizing-antibody responses were determined against a reference panel of tier 2 Env pseudoviruses in TZM-bl cells; neutralizing epitope specificities were predicted using ClustVis. All subtypes were found, along with untypeable strains and recombinant forms. Notably, 56% of the patients developed cross neutralizing, broadly neutralizing, or elite neutralizing responses. Broad and elite neutralization was associated with longer infection time, subtype C, lower CD4 + T cell counts, higher age, and higher titer of C2V3C3-specific antibodies relative to failure to develop bNAbs. Neutralizing antibodies targeted the V3-glycan supersite in most patients. V3 and C3 regions were significantly less variable in elite neutralizers than in weak neutralizers and nonneutralizers, suggesting an active role of V3C3-directed bNAbs in controlling HIV-1 replication and diversification. In conclusion, prolonged and low-level envelope V3C3 stimulation by highly diverse and ancestral HIV-1 isolates promotes the frequent elicitation of bNAbs. These results provide important clues for the development of an effective HIV-1 vaccine. Studies on neutralization by antibodies and their determinants in HIV-1-infected individuals have mostly been conducted in relatively recent epidemics caused by subtype B and C viruses. Results have suggested that elicitation of broadly neutralizing antibodies (bNAbs) is uncommon. The mechanisms underlying the elicitation of bNAbs are still largely unknown. We performed the first characterization of the plasma neutralizing response in a cohort of HIV-1-infected patients from Angola. Angola is characterized by an old and dynamic epidemic caused by highly diverse HIV-1 variants. Remarkably, more than half of the patients produced bNAbs, mostly targeting the V3-glycan supersite in HIV-1. This was associated with higher age, longer infection time, lower CD4 + T cell counts, subtype C infection, or higher titer of C2V3C3-specific antibodies relative to patients that did not develop bNAbs. These results may help develop the next generation of vaccine candidates for HIV-1.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2018

Of mosses and men: Plant succession, soil development and soil carbon accretion in the sub-Arctic volcanic landscape of Hekla, Iceland

Lava flows pose a hazard in volcanic environments and reset ecosystem development. A succession of dated lava flows provides the possibility to estimate the direction and rates of ecosystem development and can be used to predict future development. Here, we investigate plant succession, soil development and soil carbon (C) accretion on the historical (post 874 AD) lava flows formed by the Hekla volcano in south Iceland. Vegetation and soil measurements were conducted all around the volcano reflecting the diverse vegetation communities on the lavas, climatic conditions around Hekla mountain and various intensities in deposition of loose material. Multivariate analysis was used to identify groups with similar vegetation composition and patterns in the vegetation. The association of vegetation and soil parameters with lava age, mean annual temperature, mean annual precipitation and soil accumulation rate (SAR) was analysed. Soil carbon concentration increased with increasing lava age becoming comparable to concentrations found on the prehistoric lavas. The combination of a sub-Arctic climate, gradual soil thickening due to input of loose material and the specific properties of volcanic soils allow for continuing accumulation of soil carbon in the soil profile. Four successional stages were identified: initial colonization and cover coalescence (ICC) of Racomitrium lanuginosum and Stereocaulon spp. (lavas <70 years of age); secondary colonization (SC) – R. lanuginosum dominance (170–700 years); vascular plant dominance (VPD) (>600 years); and highland conditions/retrogression (H/R) by tephra deposition (70–860 years). The long time span of the SC stage indicates arrested development by the thick R. lanuginosum moss mat. The progression from SC into VPD was linked to age of the lava flows and soil depth, which was significantly deeper within the VPD stage. Birch was growing on lavas over 600 years old suggesting the development towards birch woodland, the climax ecosystem in Iceland.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Development of Cable Aging Acceptance Criteria for Nuclear Facilities

The aging of nuclear power plant electrical cables has been the subject of substantial research and development (R&D) projects in the nuclear industry, national and international laboratories, universities, and vendor organizations for several years. More specifically, these R&D efforts were conducted to develop equipment and techniques for assessing age-related degradation of in-service cables in nuclear facilities including power plants, research reactors, waste facilities and fuel fabrication plants. In recent years, cable R&D efforts in the nuclear arena have also included work to develop new cables for the next generation of reactors. Over time, exposure to harsh environmental conditions such as elevated temperatures, radiation, and humidity in nuclear installations can result in age-related degradation and failure of cables. In the current fleet of nuclear reactors, there are thousands of miles of cabling installed in each plant and many of these cables are exposed to these harsh environmental conditions. For these cables, the jacket and insulation polymers harden and become brittle over time, making them more susceptible to crack formation and growth, moisture intrusion, and other mechanisms that can lead to cable failure. Moreover, the existing U.S. fleet of 98 nuclear reactors has an average operating age of 38 years. Many of these nuclear power plants have applied for and almost all have been granted regulatory approval for license renewals to operate for 60 years, 20 years beyond their original 40-year life. Further, subsequent license renewals (SLRs) are underway with a few commercial nuclear power sites already approved to operate up to 80 years. As these reactors pursue operating life extensions, utilities must find a way to address issues associated with age-related degradation of cables. Designers of small modular reactors are also in need of technologies to evaluate the performance of cables that will be installed in harsher environments (e.g. higher temperatures, radiation doses, dose rates, etc.) than those present in current-generation reactors. Today, a variety of cable condition monitoring (CM) techniques have been developed and successfully used in nuclear facilities. These techniques are used to identify age-related degradation and assess the condition of cables to determine if their performance characteristics have changed with age. However, objective criteria must be developed for these CM tests to help quantify cable condition and thereby develop repair and replacement schedules. With operating life extending to 80 years and more SLRs on the horizon, both nuclear facilities and regulators need an objective means to determine the aged condition of cables.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Utah FORGE 1-2410: Development of a Smart Completion and Stimulation Solution - Workshop Presentation

This is a presentation on the Development of a Smart Completion & Stimulation Solution project by Welltec in collaboration with the University of Oklahoma, presented by Yosafat Esquitin, a Senior Business Development Manager at Welltec. The project's objective was to develop an annular isolation system, a stimulation isolation system, and a multi-open-close flow system for geothermal environments. These systems were developed to enable effective zonal isolation and stimulation, implement downhole Enhanced Geothermal Systems (EGS) in any location, and extend the productive life of the geothermal well. This presentation was featured in the Utah FORGE R&D Annual Workshop on September 7, 2023. The workshop provided a valuable opportunity to explore the progress made in each of the 17 Research and Development projects funded under Solicitation 2020-1 which aim to enhance our understanding of the crucial factors influencing the development EGS reservoirs and resources.

15 GEOTHERMAL ENERGY↗
DOE OSTI2020

Developing Flexible, Networked Lighting Control Systems That Reliably Save Energy in California Buildings

An important strategy to meet California's ambitious energy efficiency goals is to use innovative wireless communications, embedded sensors, data analytics and controls to significantly reduce lighting energy use in commercial buildings. This project developed a suite of networked lighting solutions to further this goal. The technologies include a platform for low-cost sensing, distributed intelligence and communications, the “PermaMote,” which is a self-powered sensor and controller for lighting applications. The project team also developed a task ambient daylighting system that integrates sensors with data-driven daylighting control using an open communication interface, called the “Readings-At-Desk” (RAD) system. To address the problem of building occupants being confused about how to operate traditional lighting control systems, the research team created content that could be the basis for a user interface standard for lighting controls. Finally, to address the difficulty of ensuring that advanced lighting control systems actually deliver their promised energy savings, the project team developed a new method for evaluating and specifying lighting systems’ performance. The research team validated these technologies in the laboratory, showing significant lighting energy savings, up to 73% for the PermaMote sensor system from occupancy control and daylight dimming features, compared to the same light source (LED replacement lamps) operated via simple on/off scheduling. The project team also developed a proposed standard lighting data model and user interface elements, which were contributed to the ANSI Lighting Systems Committee (C137) for standardization. Existing data models are incomplete and inconsistent, whereas the lighting-specific data model developed here is clear and comprehensive, to serve as a starting point for creating common, universally agreed upon semantic definitions of key lighting parameters, to promote interoperability. For the task on verifiable performance of lighting systems, the project team developed a more effective metric for capturing the actual energy impact of a lighting system over time — the energy usage intensity (kWh/ft2/year). Three commercial lighting systems were tested in FLEXLAB® using this new metric, and the tests show a wide range in the accuracy of the self-reported energy-use metric, from 0.5% to 28% error compared to direct measurement of lighting energy using dedicated submeters. Overall, the project team estimates that these advanced technologies can reduce California office lighting energy use by 20% (above and beyond normal advanced lighting controls mandated by Title 24), resulting in about 1,600 GWh/year in savings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2018

Development of Mixed-Salt Technology for CO 2 Capture from Coal Power Plants

SRI International (SRI), in collaboration with Stanford University, OLI Systems (OLI), Politecnico de Milano (PoliMi), and Aqueous Systems Aps (ASApS) performed a 45-month effort to develop a promising Mixed-Salt Process (MSP) for carbon dioxide capture. The MSP combines existing ammonia and potassium-carbonate technologies with improved absorption steps for rate enhancement and ammonia emission reduction and a novel selective regeneration process with a high-pressure CO 2 product to introduce a new and advanced transformational solvent-based technology. The striking advantages of the SRI MSP include: low heat of reaction, high loading of CO 2 , high-pressure regeneration of > 99% pure dry CO 2 , low sensitivity to impurities, low process cost, use of a non-degradable low-cost solvent with a very low carbon footprint for its production, low emissions, and reduced water use compared to the state-of-the-art ammonia-based and amine technologies. The overall objective of the project was to develop and test a solvent-based CO 2 capture technology that can capture CO 2 from existing or new pulverized coal (PC) power plants at low cost. Our specific goal was to test SRI’s newly developed MSP at the large bench-scale level to demonstrate that the process could capture CO 2 at high efficiency (> 90%) with very high CO 2 loading (> 10 wt.%), require less than 2 GJ/tonne for solvent regeneration, and produce a CO 2 stream at high pressure with a purity > 95 vol.%. This 45-month MSP development program was designed to conduct (1) extensive test campaigns with different process flowsheet variants, and (2) detailed thermodynamic, kinetic, and process modeling. These tests and models were very important to identify any issues associated with the process in the early stages and then resolve them before moving into the next scale-up (> 1 MWe scale) testing. The technology development plan consisted of balanced experimental and process modeling activities as shown in Figure i. Such an approach reduces the risks associated with the process operability at large scales and provides capital and operating expenditure (CAPEX/OPEX) predictions with improved accuracies. Under the MSP development program at SRI, we performed an aggressive testing campaign with individual subsystems as well as integrated CO 2 capture and regeneration system to identify the best operating conditions. The project was carried out in two budget periods (BP1 & BP2).

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2018

Site Classification for Standard Modular Hydropower Development: Characterizing Stream Reaches by Module Need

The objective of site classification for Standard Modular Hydropower (SMH) development is to develop a framework for classifying potential SMH sites in terms useful for informing SMH development, such as module need and module design requirements. While the current vision for SMH has focused on applications for new stream-reach development, these site classifications are equally useful for other applications, such as modular development at non-powered dams and other hydropower co-development opportunities. We used K-means clustering to classify sites (i.e., stream reaches) into clusters (i.e., groups of sites with similar attributes) based on simultaneous consideration of physical and biological attributes of those sites. Stream reaches included were confined to those with mean annual flow > 50 cfs and < 25,000 cfs (~350,000 reaches). Site Classification was conducted separately for six modules: hydroelectric generation, water quality, sediment passage, fish passage, foundation support, and recreation. About 340,000 stream reaches across the contiguous US were classified into 10 groups for each of the 6 different module categories. For each module category, clusters are visualized on US maps and described based on the defining variables that differentiate clusters from each other.

13 HYDRO ENERGY↗
DOE OSTI2018

Advanced Gasification and Novel Transformational Coal Conversion Technologies Development: Final Technical Report

This report summarizes the work carried out in furtherance of the NETL/DOE award, OTM-Enhanced Coal Syngas for Carbon Capture Power Systems and Fuel Synthesis Applications. The overall objective of the project was to further develop Oxygen Transport Membrane (OTM) technology and assess the potential for integration in coal power generation. OTM technology has the potential to enhance the quality of syngas produced by coal gasifiers, reduce the amount of cryogenic-derived oxygen required in Integrated Gasification Combined Cycle (IGCC) power plants, and allow for coal and natural gas integration. Process simulations and techno-economic analyses were carried out to estimate the cost and performance of OTM enhanced IGCC plants, IG-NGCC plants, and OTM enhanced Fischer Tropsch (FT) Liquids from coal and natural gas plants. The OTM enhanced power plants achieved higher carbon capture rates, higher efficiencies, and lower cost of electricity compared to the base cases. The most significant benefits were achieved for cases which used low rank coal as the feed. Fischer-Tropsch coal to liquids plants with iron-based catalysts and natural gas integration utilizing OTM technology showed improved carbon conversion, improved thermal efficiency and lower cost of production. With respect to OTM core technology development, significant advances have been made in several areas. The development and implementation of a third-generation membrane materials and manufacturing process has resulted in the availability of robust and reliable, high performance membranes, that can be manufactured at high yield. Progress towards the goal of higher pressure operation has been demonstrated with the development of improved metal-ceramic seals and components of the panel array module that integrate membrane-seal assemblies with primary and secondary reforming catalysts have been further developed and demonstrated. Work concluded with the successful start-up and operation of a multi-panel pilot-scale system which is the final step in technology development ahead of demonstration.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2018

Integrated FHR technology development: Tritium management, materials testing, salt chemistry control, thermal hydraulics and neutronics, associated benchmarking and commercial basis

This report summarizes the results of a 3-year Integrated Research Project (IRP) sponsored by the U.S. Department of Energy to address major technical challenges in the development of the Fluoride-salt-cooled High-temperature Reactor (FHR). The IRP universities included the Massachusetts Institute of Technology (MIT), the University of California at Berkeley (UCB), the University of Wisconsin (UW), and the University of New Mexico (UNM). The FHR is a new reactor concept less than 20 years old that combines (1) a clean fluoride salt coolant, (2) the graphite-matrix coated-particle fuel originally developed for High- Temperature Gas-Cooled Reactors and (3) passive decay heat removal systems from sodium fast reactors. The base-line design is a pebble-bed FHR that delivers heat between 600 to 700°C with a 7 Li 2 BeF 4 (flibe) salt coolant to the power cycle or industrial users. The Executive Summary describes what was accomplished and summarizes major conclusions. The main report contains stand-alone sections in each major area of work. Highlights are summarized below. Tritium. The coolant salt produces tritium necessitating understanding and control of tritium. Experimental work included measuring hydrogen uptake on carbon, tritium uptake during irradiation of graphite in 700°C salt and the permeability of tritium through metals with and without coatings. An FHR systems model was developed to predict tritium behavior and enable design of tritium control systems. The leading candidate for tritium removal from the flibe salt is carbon bed outside the reactor core. Thermal hydraulics and Neutronics. A 10-meter high FHR integral effects test facility, using Dowtherm A®, has been built and used to simulate the integral response of a representative FHR to improve understanding of FHR thermal hydraulics and validate thermal hydraulics codes used for the FHR. Neutronic analysis included code-to-code benchmarking, multiphysics modeling, uncertainty analysis for nuclear data uncertainties and shielding analysis. Twisted-tube heat exchangers were examined that may provide significant cost reductions because of their improved heat-transfer performance with liquid salts. The impacts on safety and design caused by uncertainties in physical properties of the salt were assessed with recommendations on where added physical property measurements are needed. Work began on understanding radiative heat transfer that becomes important in salt systems at higher temperatures. Materials. Static corrosion tests were conducted on graphite and materials in 700°C salt -- both in the UW laboratory and in the MIT reactor. In addition to static corrosion testing, a circulating salt corrosion loop was built and is operating. Methods to measure salt properties including redox were developed. The presence of carbon increases corrosion. With good redox control, the evidence indicates stainless steel can be used as a material of construction. Benchmarking. An additional series of workshops where held to enable benchmarking and comparison of results between different investigators. Commercialization. The FHR delivers higher average-temperature (~650°C) heat to the power cycle or industry than other reactors. This enables power cycles with lower-cost heat storage for variable electricity to the grid while the reactor operates at base-load -- providing a major competitive advantage by maximizing revenue from electricity sales. In October, 2016, a new startup company named Kairos Power was formed, and opened its first office in Jack London Square, Oakland, California, in January 2017. Kairos Power exists largely due to the work that was accomplished by this IRP and the previous DOE-funded FHR IRP that performed research on FHR technology from 2012 to 2015. In September, 2018, as this IRP is concluding, Kairos Power was staffed at 60 full time employees, working to develop technology derived from this IRP. Many of these employees worked with the IRP before joining Kairos Power 1 (https://kairospower.com). Other students and researchers from this IRP have joined other startup companies, including the Terrapower Molten Chloride Fast Reactor and the Terrestrial Energy development efforts.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2018

Mercury Remediation Technology Development for Lower East Fort Poplar Creek - FY2018 Update

Mercury (Hg) remediation is a high priority for the US Department of Energy (DOE) Oak Ridge Office of Environmental Management (OREM). Mercury contamination in the environment can be found at all three DOE facilities in Oak Ridge, but probably the greatest environmental risk concern relative to Hg on the Oak Ridge Reservation is associated with historical Hg losses at and near the Y-12 National Security Complex (Y-12). Water and fish from East Fork Poplar Creek (EFPC) downstream of Y-12 exceed regulatory thresholds. Because of the complexities of Hg transport and fate in the aquatic environment, conventional remedial options for EFPC are highly uncertain. DOE is using a phased, adaptive management approach to Hg remediation at Y-12, with a focus in the next few years on construction of the Mercury Treatment Facility (MTF) to treat the most contaminated Y-12 outfall entering EFPC (DOE 2017a; DOE 2017b). Once operational, the MTF will provide additional protection against inadvertent releases of Hg into the stream from decontamination and decommissioning of Y-12 Hg-use buildings. Although it is anticipated that the MTF will substantially decrease Hg water concentrations and flux in the upper part of EFPC, research and technology development is needed to develop appropriate and longer-term remedial solutions for the downstream environment. Since late 2014, OREM and UCOR/RSI (URS | CH2M Oak Ridge LLC/Restoration Services, Inc.) have supported Oak Ridge National Laboratory (ORNL) Environmental Sciences Division staff in conducting field and laboratory studies to develop Hg remedial technology solutions for lower EFPC (LEFPC). A technology development strategy for lower EFPC was developed in 2014 that was consistent with the adaptive management paradigm and DOE’s Technology Readiness Level (TRL) guidelines (Peterson et al. 2015). Initially, a thorough review of the literature and site-specific information was conducted to develop a broad number of potential technologies that might be applied in lower EFPC. An adaptive management approach was then used to focus on technologies that might have the most promise and potential remediation benefit. Field and laboratory studies conducted during 2014–2018 have (1) identified the major drivers of Hg flux and bioaccumulation in EFPC and (2) narrowed the list of highmerit technologies that might be of use in remediating the downstream environment.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Development and Comparison of Purgeable Mercury Values in SRR Samples Measured by SRNL and Eurofins FGS

Savannah River Remediation (SRR) requested the development of mercury speciation capabilities at the Savannah River National Laboratory (SRNL) to support the Liquid Waste Operations at SRS. As part of that method development, SRR requested that SRNL Analytical Development (AD) compare their results with those obtained from their outside contract laboratory, Eurofins Frontier Global Sciences (FGS). This document reports on this method development work as well as the comparative analyses conducted between the two laboratories. Development, optimization, and validation were undertaken at SRNL to produce a method for the species-specific analysis of dissolved gaseous mercury (DGM) in samples from SRR. It was determined that DGM present in SRR samples represented a combination of various soluble and volatile mercury species- and is thus referred to in this document as purgeable mercury. A method has been developed and analytically validated for the analysis of purgeable mercury in caustic nuclear waste. Using multivariate optimization method, purge flow rate was determined to be highly correlated with increased response (p=0.023). Total recovery of spiked purgeable mercury from deionized water was 99.4 ±10.6% and 91.6 ±14.9% from spiked high-activity tank waste samples. Calibration, by external calibration and standard addition calibration, maintained a mean accuracy of 101 ±5% and 99.9 ±1.7%, respectively. This method represents a decrease in sample handling and processing over currently standard methods and represents a more amenable method for purgeable mercury analysis in liquid nuclear waste.1 An interlaboratory comparison was performed between SRNL and Eurofins FGS in the co-analysis of three quarterly Tank 50 samples. Two samples demonstrated no statistically significant difference (p=0.271, p=0.0811), with one sample biased 30% low to a statistically significant degree (p=0.0432). Large mean uncertainty was present in the results reported by both laboratories (±15% and 40% from SRNL and Eurofins), with no significant difference observed in uncertainty (p=0.934). Across all co-analyzed samples, no significantly difference was observed in precision (p=0.205) or reported values (p=0.352) between SRNL and Eurofins. These results indicate that SRNL-AD may provide data to the customer of statistically similar quality.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Development and Comparison of Purgeable Mercury Values in SRR Samples Measured by SRNL and Eurofins FGS

Savannah River Remediation (SRR) requested the development of mercury speciation capabilities at the Savannah River National Laboratory (SRNL) to support the Liquid Waste Operations at SRS. As part of that method development, SRR requested that SRNL Analytical Development (AD) compare their results with those obtained from their outside contract laboratory, Eurofins Frontier Global Sciences (FGS). This document reports on this method development work performed at SRNL as well as the comparative analyses conducted between the two laboratories. Development, optimization, and validation were undertaken at SRNL to produce a method for the species-specific analysis of dissolved gaseous mercury (DGM) in samples from SRR. It was determined that DGM present in SRR samples represented a combination of various soluble and volatile mercury species- and is thus referred to in this document as purgeable mercury. A method has been developed and analytically validated for the analysis of purgeable mercury in caustic nuclear waste. Using multivariate optimization, an efficient and sensitive method was produced. Total recovery of spiked purgeable mercury from deionized water was 99.4 ±10.6% and 91.6 ±14.9% from spiked high-activity tank waste samples. Calibration, by external calibration and standard addition calibration, maintained a mean accuracy of 101 ±5% and 99.9 ±1.7%, respectively. An interlaboratory comparison was performed between SRNL and Eurofins FGS in the co-analysis of three quarterly SRR Tank 50 samples. The statistical evaluations presented in this document support the following conclusions: for internal validation data, the two laboratories demonstrate biases of -4.3% for SRNL and 4.4% for Eurofins FGS, though neither are statistically significant at the 5% level. While the percent relative standard deviation for each of the laboratories is rather large (21.5% for SRNL and 18.4% for Eurofins FGS), there is no indication of a statistically significant difference between the two laboratories in the precision of these results. For the three sets of SRR quarterly Tank 50 samples, there is no indication of a statistically significant bias between the two laboratories at the 5% significance level. These results indicate that SRNL may provide data to the customer of statistically similar quality to Eurofins FGS.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Developing Efficient Perovskite/Silicon Tandem Devices

This project aims at developing highly efficient perovskite/silicon tandem solar cells by developing efficient perovskite top cells, silicon bottom cells, and monolithically integrating the subcells for highly efficient tandem solar cells. The project focused on increasing the efficiency of perovskite solar cells to 20% and understanding related materials science and device physics, as well as developing a compatible bottom high-efficiency c-Si solar cell. The perovskite cells with a wide bandgap of 1.61 eV and 1.84 eV are fabricated by a low-cost, low-temperature, scalable solution process on lower bandgap silicon bottom cells. The bandgaps of perovskite top cells have been tuned between 1.61 eV and 1.84 eV by composition engineering mainly through controlling the halide mixing ratio in perovskite materials. The efficiencies of the wide bandgap perovskite solar cells have been improved to an excellent efficiency of 21.0% for perovskites with a bandgap of 1.63 eV with increased grain size, reduced energy disorder at cathode contact, and defect passivation. We invented a solvent annealing approach with solvent vapor during thermal annealing to enlarge grain size of perovskite film which reduces the charge trap density and improves the device efficiency. Moreover, we discovered that the non-wetting surface could further increase the grain size for perovskite films, because non-wetting surface could prevent the formation of too dense nuclei from heterogeneous nucleation process. We proposed to reduce the energy disorder of organic charge extraction layer to reduce the power loss in perovskite cells. We pioneered defect passivation concept and techniques to suppress the charge non-radiative recombination in perovskite solar cells to boost the efficiency. For the silicon bottom cell development, different from the conventional silicon cell work under full illumination, the light available for the silicon bottom cell in tandem structure is mainly NIR region. We developed a NIR enhanced silicon cell with efficiency of 21.2% by applying a double-layer antireflection coating at the front side and a MgF2 back reflector layer at the rear side. For the perovskite/silicon tandem device, we achieved a highest reported power conversion efficiency of 25.4% in 2018, and further increased the efficiency up to 26.0% in 2019. The research on tandem solar cells focused on reducing reflection loss to <5% at spectrum of 300-1100 nm by antireflection layer, tuning the bandgap of perovskite film for matched current density between sub-cells, and utilizing a ITO layer between perovskite top cell and silicon bottom cell as interconnect layer without Voc loss. Finally, we developed a blading technique to fabricate perovskite films which produces perovskite solar cells with comparable or even superior efficiency to those made by non-scalable spin coating method. This paves the way for scaling up perovskite/silicon tandem solar cells using solution approach.

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DOE OSTI2019

Development and Operation of a High Throughput Computer Hard Disk Drive Recycling Enterprise (CRADA NFE-16-05989)

The aim of this collaborative effort is to develop, construct and operate a high throughput computer hard disc drive (HDD) recycling system. Research conducted as part of the Critical Materials Institute (CMI), a Department of Energy (DOE) Energy Innovation Hub, has revealed the economic rationale and the necessary technology for a potentially viable HDD recycling enterprise. Moreover, the very notion of CMI is the development of replacement sources of rare earth critical materials that enable the U.S. to become less dependent on single source supplies. Focused on end-of-life (EOL) consumer products containing rare earth permanent magnets, this cooperative endeavor will develop, construct and operate a highly automated recycling process. Demonstrating economically viable recycling of high value products is largely an untapped resource in the U.S. Recycling HDDs to recover rare earth magnets and other valuable materials (e.g. aluminum, steel, printed circuit boards, copper, etc.) presents a new opportunity to satisfy U.S. demand for highly desirable commodities. The goal of this cooperative research and development agreement (CRADA) project is to create a commercial HDD recycling enterprise that changes the landscape of rare earth magnet material and magnet availability for U.S. manufacturers. Underpinning this primary goal is the development and demonstration of an economic HDD recycling process that provides a significant and alternative supply of rare earth magnets that is not dependent upon foreign sourcing. Oak Ridge National Laboratory (ORNL) has researched the technology options and down selected specific sub-process technologies based upon throughput and economic potential. The participant, however, brings significant process design, development and operational experience that may result in process improvement or optimization strategies that will be explored in collaboration with the contractor. The final outcome of this CRADA is a system/process for recycling large quantities of HDDs. The technology is available for commercial scale-up.

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