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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

On the charge state of the anomalous oxygen component

Observations of a phase lag between the intensity variations of high-energy galactic cosmic rays and the quiet-time oxygen flux in the energy region 7.6-24 MeV/nucleon during the time period 1974-1975 are reported. Phase lag or hysteresis effects have been observed during the 11-year solar cycle for low-energy galactic cosmic rays and several authors have shown that this hysteresis effect is a function of the velocity and rigidity (and therefore of the ionic charge) of the particles. Assuming a similar rigidity dependence of the phase lag during the transient intensity decrease of both galactic cosmic rays and the anomalous oxygen component in the time period 1974-1975, and comparing the phase lag as observed for protons and helium during the same period with the oxygen measurements, an upper limit of approximately 4 is derived for the ionic charge of the anomalous oxygen component.

Klecker, B.↗
NASA NTRS1981

Direct observation of charge state abundances of energetic He, C, O, and Fe emitted in solar flares

The ionic charge states of helium, carbon, oxygen, and iron have been determined for three solar particle enhancements by an electrostatic deflection analyzer, which is combined with a thin window proportional counter dE/dX vs. E system. The observations are obtained during the periods September 23 to 29, 1978, June 6 to 8, 1979, and September 15 to 26, 1979, with an instrument onboard the ISEE-3 spacecraft. The mean ionic charge states for He, C, and oxygen exhibit a high degree of ionization with values of Q equals 2, 6, and 7.2, respectively. The charge state of iron is near 13 charge units. Variations from flare to flare and within the September 23, 1978 flare are small. The most surprising feature of the charge state measurement is the observation of a small (about 10%) but finite contribution of singly ionized helium.

Hovestadt, D.↗
NASA NTRS1980

In vitro Ca-45/++/ uptake and exchange by otoconial complexes in high and low K/+/Na/+/ fluids

Recently, data have been accumulating to indicate that saccular and utricular otoconial complexes of the gravity receptor organs are dynamic and interact constantly with their environment. This study investigates the possibility that the ionic composition of the surrounding fluid influences calcium ion binding and release, and explores the importance of the K(+)/Na(+) ratio. Two in-vitro methods were developed, the first of which employed artificial endolymph and perilymph while ionically balanced fluids in which only the K(+)/Na(+) was altered were used in the second. The ability of rat complexes to take up Ca-45(++) during incubation with these fluids was assessed using liquid scintillation spectrometry. In vitro uptake of Ca-45(++) was greater in fluids with a high K(+)/Na(+) ratio than in fluids in which the ratio was low. The ability of the complexes to take up Ca-45(++) appeared to decline with age.

Ross, M. D.↗
NASA NTRS1984

On the dissociation energy of CaOH and LiOH

A technique for computing the dissociation energy of ionic diatomics is extended to the ionic triatomics LiOH and CaOH. The calculated Do values (with the recommended experimental values in parentheses) are 4.72 plus or minus 0.06 eV (4.53 plus or minus 0.04) for LiOH and 4.13 plus or minus 0.07 (4.23 eV) for CaOH.

Bauschlicher, C. W., Jr.↗
NASA NTRS1985

Theoretical Thermodynamics of Mixtures at High Pressures

The development of an understanding of the chemistry of mixtures of metallic hydrogen and abundant, higher-z material such as oxygen, carbon, etc., is important for understanding of fundamental processes of energy release, differentiation, and development of atmospheric abundances in the Jovian planets. It provides a significant theoretical base for the interpretation of atmospheric elemental abundances to be provided by atmospheric entry probes in coming years. Significant differences are found when non-perturbative approaches such as Thomas-Fermi-Dirac (TFD) theory are used. Mapping of the phase diagrams of such binary mixtures in the pressure range from approx. 10 Mbar to approx. 1000 Mbar, using results from three-dimensional TFD calculations is undertaken. Derivation of a general and flexible thermodynamic model for such binary mixtures in the relevant pressure range was facilitated by the following breakthrough: there exists an accurate nd fairly simple thermodynamic representation of a liquid two-component plasma (TCP) in which the Helmholtz free energy is represented as a suitable linear combination of terms dependent only on density and terms which depend only on the ion coupling parameter. It is found that the crystal energies of mixtures of H-He, H-C, and H-O can be satisfactorily reproduced by the same type of model, except that an effective, density-dependent ionic charge must be used in place of the actual total ionic charge.

Hubbard, W. B.↗
NASA NTRS1984

Electrical research on solar cells and photovoltaic materials

The flat-plate solar cell array program which increases the service lifetime of the photovoltaic modules used for terrestrial energy applications is discussed. The current-voltage response characteristics of the solar cells encapsulated in the modules degrade with service time and this degradation places a limitation on the useful lifetime of the modules. The most desirable flat-plate array system involves solar cells consisting of highly polarizable materials with similar electrochemical potentials where the cells are encapsulated in polymers in which ionic concentrations and mobilities are negligibly small. Another possible mechanism limiting the service lifetime of the photovoltaic modules is the gradual loss of the electrical insulation characteristics of the polymer pottant due to water absorption or due to polymer degradation from light or heat effects. The mechanical properties of various polymer pottant materials and of electrochemical corrosion mechanisms in solar cell material are as follows: (1) electrical and ionic resistivity; (2) water absorption kinetics and water solubility limits; and (3) corrosion characterization of various metallization systems used in solar cell construction.

Orehotsky, J.↗
NASA NTRS1985

Development anmd testing of electrophoresis solutions. Task I.1: Development of optimal buffer system

Two buffers were explored for testing: low ionic strength electrophoresis buffer with and without density gradient material. It was found that the electrophoresis routine was better tolerated when Ficoll was present. The results of a viability study of primary human fetal kidney (HFK-1) cells at the first passage are shown. Cell strain HFK-1 was used in several experiments at the first and second passage. The HFK consisted mainly of fibroblasts, and HFK-1 has a high epithelioid cell content. The chromosomes of HFK were examined and found to be euploid. The stock medium for cell electrophoresis is described. In this solution density gradient solutes such as sucrose and Ficoll are dissolved to bring the osmolarity to 0.30. Its ionic strength is less than 0.01M, and its conductivity is usually 0.0011 mho/cm. Methods for viability determination included direct microscopic counting of the percent cells attached and spread within 24 hr of plating test cultures or electrophoretically separated fractions. The Cytograf viability assay concept was tested, and shown that blue stained cells scatter less light into the 0.8 to 3.3 deg angular interval than do unstained cells.

Source record↗
NASA NTRS1985

STS-8 atomic oxygen effects experiment

A flight experiment was performed on the eighth Space Shuttle mission to measure reaction of surfaces with atomic oxygen in the low earth orbital environment. More than 300 individual samples were exposed to ram (normal to surface) conditions for 41.75 hr leading to a total atomic oxygen fluence of 3.5 x 10 to the 20th atoms/sq cm. Reaction rates for surface recession measured primarily by mass change of several organic films were in the range of 3.0 x 10 to the -24th cu cm/atom, and less than 5 x 10 to the -26th cu cm/atom for Teflon. Effects of parameters such as temperature and solar radiation were assessed, as was the importance of atmospheric ionic species on surface recession. In an experiment performed on the fifth Space Shuttle flight, no temperature dependence of reaction rate for the organic films studied was found in the temperature range of 25 to 125 C. Preliminary findings indicate that the reactivity of organic films is not affected by temperature (in the range of 65 to 125 C), solar radiation, or ionic species. Significant surface morphology changes led to a carpet-like appearance also consistent with previous findings.

Visentine, J. T.↗
NASA NTRS1984

The dayside Venus ionosphere. II - Combined numerical model of ion and neutral composition above 120 km

The median vertical profile of ion densities for the dayside Venusian ionosphere obtained by the orbiter retarding potential analyzer (ORPA) is simulated by one-dimensional model calculations. The model includes both neutral and ionic chemistry, eddy and molecular diffusion for neutral constituents, and ion-plasma diffusion for ionic constituents. The electron and ion temperatures measured by the ORPA are used to calculate the plasma diffusion coefficients and scale heights for ions. The predicted O2(+) densities below about 200 km agree particularly well with observations by the ORPA, but the model values are significantly less than those measured by the orbiter ion mass spectrometer. The observed ion composition is interpreted in terms of densities of the neutral atmosphere and its composition.

Shimazaki, T.↗
NASA NTRS1985

Transition metal oxides - CrO, MoO, NiO, PdO, AgO

The transition-metal oxides are quite ionic; Mulliken population analyses for several oxides give a negative charge of about 0.7 electrons for oxygen. When the transition-metal d shell is only partially filled, the orbitals are involved in covalent bonds with O; both two-electron bonding (2)-antibonding (0) and one-electron bonding (2)-antibonding (1) bonds are formed. These covalent bonds occur in addition to the ionic bonding. There is d-sigma-O2 p sigma repulsion, and this repulsion is reduced when the d-sigma electron is promoted into an orbital which has dominantly 4sp-sigma character and is polarized away from O.

Bauschlicher, C. W., Jr.↗
NASA NTRS1985

Theoretical studies of dissociative recombination

The calculation of dissociative recombination rates and cross sections over a wide temperature range by theoretical quantum chemical techniques is described. Model calculations on electron capture by diatomic ions are reported which illustrate the dependence of the rates and cross sections on electron energy, electron temperature, and vibrational temperature for three model crossings of neutral and ionic potential curves. It is shown that cross sections for recombination to the lowest vibrational level of the ion can vary by several orders of magnitude depending upon the position of the neutral and ionic potential curve crossing within the turning points of the v = 1 vibrational level. A new approach for calculating electron capture widths is reported. Ab initio calculations are described for recombination of O2(+) leading to excited O atoms.

Guberman, S. L.↗
NASA NTRS1984

Density-functional calculations of the surface tension of liquid Al and Na

Calculations of the surface tensions of liquid Al and Na are described using the full ionic density functional formalism of Wood and Stroud (1983). Surface tensions are in good agreement with experiment in both cases, with results substantially better for Al than those found previously in the gradient approximation. Preliminary minimization with respect to surface profile leads to an oscillatory profile superimposed on a nearly steplike ionic density disribution; the oscillations have a wavellength of about a hardsphere diameter.

Stroud, D.↗
NASA NTRS1986

Photoelectric photometry of Comet P/Halley from Mauna Kea Observatory

A program of photoelectric photometry of comet Halley yielded 60 nights of usable photometry. The uncertainty in the photometry in all filters except OH is better than 2%. Throughout the apparition, the comet is brightest in the filters that isolated the neutral gas emission features of OH, CN, C2, and C3. The fluxes in the filters that isolated the ionic emission features of CO(+) and H2O(+) are comparable to the continuum when centered upon the optocenter, thereby making the ionic emission weak to undetectable above the continuum. The continuum colors do not appear to be a function of phase angle; therefore, the colors are probably indicative of dust grain composition and are not dominated by scattering geometry effects.

Piscitelli, J. R.↗
NASA NTRS1986

A comparison of the bonding in Cr(NO)4 and Ni(CO)4

The bonding in Cr(NO)4 is very ionic, with about 1.5 electrons donated from the Cr to the NO 2pi orbitals. There is also a NO sigma donation of about 0.5 electrons to the Cr, yielding a net charge of Cr of about 1. A large MCSCF expansion is needed to describe both the ionic and covalent contributions to the Cr 3d-NO 2pi bonding. This bonding is compared to that in the isoelectronic Ni(CO)4.

Bauschlicher, C. W., Jr.↗
NASA NTRS1986

A survey of bimolecular ion-molecule reactions for use in modeling the chemistry of planetary atmospheres, cometary comae, and interstellar clouds

All bimolecular positive ion-molecule reactions reported from 1965 to 1985 for temperatures below 1000 K are included in the present survey of those ion-molecule reactions pertinent to the chemistries of planetary atmospheres, cometary comae, and interstellar clouds. This survey is intended as an update of the first, by Huntress (1977). The tabular presentation is organized according to reactant ion, with cross-references for both the ionic and the neutral reactants as well as the ionic and neutral products.

Anicich, V. G.↗
NASA NTRS1986

Voltammetric studies of porous molybdenum electrodes for the alkali metal thermoelectric converter

Voltammetry of partially oxidized porous molybdenum alkali metal thermoelectric converter (AMTEC) electrodes from about 600 to 1000 K revealed a series of redox processes within the AMTEC operational voltage range which can be used to establish the electronic and ionic conductivities of these electrodes. Improved estimates of the free energies of formation of Na2Mo3O6, NaMoO2, and Na3MoO4 are obtained. Evidence is provided for the slow corrosive attack by Na2MoO4 on molybdenum. The ionic conductivity of Na2MoO4 is found to be sufficiently large at temperatures of greater than 700 K to explain the observed electrochemical phenomena in addition to the enhanced sodium transport in AMTEC electrodes below the freezing point of Na2MoO4.

Williams, R. M.↗
NASA NTRS1987

Soluble minerals in chemical evolution. II - Characterization of the adsorption of 5-prime-AMP and 5-prime-CMP on a variety of soluble mineral salts

The adsorption of 5-prime-AMP and 5-prime-CMP is studied in the saturated solutions of several mineral salts as a function of pH, ionic strength, and surface area of the solid salt. It is suggested that the adsorption which results from the binding between the nucleotide molecule and the salt surface is due to electrostatic forces. The adsorption is reversible in nature and decreases with increasing ionic strength.

Chan, Stephen↗
NASA NTRS1988

A study of single and binary ion plasma expansion into laboratory-generated plasma wakes

Plasma expansion into the wake of a large rectangular plate immersed in a collisionless, supersonic plasma was investigated in laboratory experiments. The experimental conditions address both single ion and binary ion plasma flows for the case of a body whose size is large in comparison with the Debye length, when the potential difference between the body and the plasma is relatively small. A new plasma source was developed to generate equi-velocity, binary ion plasma flows, which allows access to new parameter space that have previously been unavailable for laboratory studies. Specifically, the new parameters are the ionic mass ratio and the ionic component density ratio. In a series of experiments, a krypton-neon plasma is employed where the ambient density ratio of neon to krypton is varied more than an order of magnitude. The expansion in both the single ion and binary ion plasma cases is limited to early times, i.e., a few ion plasma periods, by the combination of plasma density, plasma drift speed, and vacuum chamber size, which prevented detailed comparison with self-similar theory.

Wright, Kenneth Herbert, Jr.↗