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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43

C-SAW: a framework for graph sampling and random walk on GPUs

Many applications require to learn, mine, analyze and visualize large-scale graphs. These graphs are often too large to be addressed efficiently using conventional graph processing technologies. Fortunately, recent research efforts find out graph sampling and random walk, which significantly reduce the size of original graphs, can benefit the tasks of learning, mining, analyzing and visualizing large graphs by capturing the desirable graph properties. This paper introduces C-SAW, the first framework that accelerates Sampling and Random Walk framework on GPUs. Particularly, C-SAW makes three contributions: First, our framework provides a generic API which allows users to implement a wide range of sampling and random walk algorithms with ease. Second, offloading this framework on GPU, we introduce warp-centric parallel selection, and two novel optimizations for collision migration. Third, towards supporting graphs that exceed the GPU memory capacity, we introduce efficient data transfer optimizations for out-of-memory and multi-GPU sampling, such as workload-aware scheduling and batched multi-instance sampling. Taken together, our framework constantly outperforms the state of the art projects in addition to the capability of supporting a wide range of sampling and random walk algorithms.

97 MATHEMATICS AND COMPUTING↗

Bioconversion of Thermochemical Intermediates

Thermochemical (TC) biofuels production via both pyrolysis and hydrothermal liquefaction produces aqueous waste streams, typically with organic compounds at concentrations of -50-100 g/L. These streams represent a wastewater treatment cost and carbon loss for the TC biorefinery, but the concentration range for these compounds is ideal for bioconversion. To that end, the Bioconversion of Thermochemical Intermediates (BTI) project is developing advanced analytics and engineered microbes to convert these waste streams to co-products, with the overall aim of improving the economics and carbon conversion efficiency of TC biorefining. To date, we have primarily focused on development of advanced analytical chemistry approaches to fully characterize TC aqueous streams and engineering of Pseudomonas putida for conversion of non-conventional substrates, including methylated phenolics, cyclic ketones, furans, and C1-C3 light oxygenates, into atom-efficient products. Two primary challenges are the rapid deployment of aqueous-compatible analytics to changing upstream conditions and dealing with the toxicity of the feed streams to engineered microbes. The project efforts have resulted in engineered strains of P. putida able to consume 90% of the organic compounds in aqueous waste streams from catalytic fast pyrolysis, more than 300-fold toxicity tolerance improvements in P. putida, and carbon closures exceeding 90% for TC wastewater streams across multiple processing technologies.

BASIC BIOLOGICAL SCIENCES,BIOMASS FUELS↗

Application of Machine Learning to Improve Biobased Glucaric Acid Production

Kalion, Inc. is an industrial biotechnology manufacturer of high-purity chemicals from biomass including glucaric acid to be used in the industrial, material, and pharmaceutical markets. The project goal is application of machine learning in conjunction with high-throughput cultivations and metabolomics to understand and overcome two different challenges: (i) improve glucaric acid productivity (the rate of production slows considerably after 48 hours, which limits the overall productivity that can be achieved in the process), and (ii) decrease its production costs (components from complex media are necessary to achieve robust production). Through a series of experiments, a set of metabolites contained in rich media that improved performance were identified using metabolomics, high throughput cultivations in bioreactors, and machine learning-friendly experimental designs. It was found that the substrate feeding strategy was the potential major driver to enhance bacterial performance of glucaric acid production. The major industrial impacts by this project are the improvement of the production process technology, as well as advancing infrastructures and workflows (where machine learning approaches in conjunction with high-throughput cultivation and metabolomics are used) to improve the analyses by making them more rapid and comprehensive.

BIOMASS FUELS↗

Bio-Energy with Carbon Capture and Storage (BECCS): Achieving Net Zero and Beyond

This work evaluates the life cycle environmental performance of Bioenergy with Carbon Capture and Storage (BECCS) across different biomass types, processing technologies, and capture rates. Preliminary results suggest that carbon neutrality could be achieved if 35% biomass is co-fired with 90% carbon capture and sequestration.

Carlson, Derrick R.↗

Radiation and Thermal Stability of Solid Radwaste After Immobilization in Polymer Matrix - 13504

The paper will illustrate results of the various experiments on radiation and thermal stability of polymer matrixes after solutions solidification including aqueous and organic solutions and mixed waste. It was shown that- after irradiation the specimen and after solidification the mixture with oil and TBP hydrogen has been observed (less 1%) and some others gases have been detected. Results of the performed experiments and the radiation stability data of the polymer compositions allow the conclusion that the technological process of immobilizing the above mentioned aqueous solutions and solutions with organic products into polymers at room temperature is the explosion- and flameproof as well as the storage thereof. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Function-based Taxonomy Implementation

Function-based taxonomies are relational mapping tools used to clearly illustrate how an organization delivers Critical Functions by using various people, processes, technologies, information, and infrastructure (PPTII). Critical Functions are the actions or activities that make up the organization’s primary purpose. Enabling Functions are the combination of PPTII used by the organization to deliver their Critical Functions. A function-based taxonomy provides a framework to categorize information and related artifacts that document an organization’s unique implementation of PPTII for Critical Function delivery. The ideal state of a function-based taxonomy is to organize the existing knowledge the organization already has throughout their numerous systems, policies, people, procedures, and configurations. A well-organized taxonomy helps organizations to effectively leverage their knowledge by clearly identifying dependencies and connections. This document is the result of combined engineering and analytical experience and describes a repeatable method for producing function-based taxonomies.

42 ENGINEERING↗

Demonstration of SuperLig{sup R} 605 and SuperLig{sup R} 644 in a Regeneration Flow Sheet to Remove Radioactive Strontium and Cesium from Seawater - 16236

Remediation techniques are needed for efficient removal of radioactive strontium and cesium from seawater. Molecular Recognition Technology, using selective SuperLig{sup R} resins, demonstrates a clean chemistry approach to solving this problem. Molecular Recognition Technology offers high levels of separation of chemically pure metal contaminants, whose subsequent disposal is compatible with simple waste forms (grout and glass). SuperLig{sup R} resins can be regenerated with common reagents and used many times, limited by a dose of 1 E+9 Rad, which assures low volumes of secondary solid waste. The metal selectivity of the SuperLig{sup R} resin ensures that the solid waste is of low residual activity. These properties of sustainability are illustrated in a project that demonstrated the ability of two SuperLig{sup R} resins to selectively remove Cs and Sr from a seawater mimic representative of the contaminated seawater in Fukushima, Dai'ichi, Japan harbor. Removal of radioactive Sr-90 and Cs-134/Cs-137 from seawater using conventional ion exchange or a complexing agent is complicated by the presence of large excesses of competing ions such as Na, K, Ca, and Mg, which can be co-extracted. These competing ions, if co-extracted, reduce the capacity of a single pass resin with the consequent increase in volume of spent resin or decrease in capacity of a regenerable resin. The successful demonstration reported in this study has shown the ability of two proprietary resins, SuperLig{sup R} 605 and SuperLig{sup R} 644, to remove Sr and Cs, respectively, with high selectivity from simulated solutions containing these metal ions together with major constituents of seawater at their normal concentrations. This effort was part of a demonstration project to investigate methods for removal of Sr-90 and Cs-134/Cs-137 from 160,000 cubic meters of seawater impounded at Fukushima, Dai'ichi, Japan harbor. SuperLig{sup R} resins can be regenerated by elution with small volumes of simple acid solutions. SuperLig{sup R} resins have a high tolerance to radiation, with their performance not being degraded by doses of 1.0 E+9 Rad. Estimates, based on the results obtained, are that Cs and Sr levels in the volume of seawater in the Fukushima, Dai'ichi, Japan harbor could be reduced to desired discharge limits in 200 days with some 30 cubic meters of the two SuperLig{sup R} resins and that decontamination factors of 10 or more could be achieved. Results of the demonstration, together with advantages of the Molecular Recognition Technology process over conventional procedures for these separations are presented and discussed. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Durable Tellurite Glasses for Vitrification of Technetium Wastes - 18270

Technetium-99 (Tc-99) can bring a significant environmental risk because it has a long half-life and high fission yield. The present work has developed alumino tellurite glass to immobilize Tc wastes generated by the pyrochemical processing technology. Rhenium (Re) was used as a non-radioactive surrogate for Tc. The Re{sub 2}O{sub 7} concentration in the tellurite glasses was as high as 9.11 mass% with retention of 86% on average. X-ray absorption spectroscopy analysis revealed that Re exists as Re{sup 7+} and is surrounded by 4 oxygen atoms. The 7-day PCT results were satisfied with the immobilized low-activity waste regulatory limit with Ca(ReO{sub 4}){sub 2} content less than 12 mass%. The long-term dissolution test was conducted for 256 days and a rate drop has occurred in which the rate of leaching gradually decreased. An alteration layer depleted soluble element was observed on the leached glass surface. These results suggest that tellurite glass can be a good candidate as a matrix for immobilizing Tc. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

PGSFR Core Design and Performance Characteristics

Korea Atomic Energy Research Institute (KAERI) has developed a Prototype Generation-IV Sodium-cooled Fast Reactor (PGSFR) as a representative of Gen-IV concepts. The final PGSFR core will be composed of transuranic (TRU) fuels to transmute LWR spent fuels and self-recycled its fuels, in combination with a pyro-processing facility. However, the initial POSFR core consists of low enriched uranium (LEU) fuels in order to: 1) provide an irradiation test for TRU fuels and structural materials, 2) keep pace with the development of pyro-processing technology, and 3) obtain operational experience on the reactor systems and components. During the first phase of PGSFR development plan (2012-2015), the power level was decided to be 150 MWe from many trade-off studies using different power level. The PGSFR uranium core performance characteristics at the initial, transition and equilibrium states have been carried out. In this paper, the PGSFR core design and related performance characteristics are introduced. The PGSFR uranium core design was performed at the initial/transition/equilibrium core based on the candidate fuel management scheme. It was confirmed that this design can satisfy surely all design limit and requirement. The chapter 4 of PGSFR Preliminary Safety Information Document (PSID) published in December 2015 contains the detailed information and characteristics of PGSFR core. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Design and analysis of embedded I and C for loop-scale magnetically suspended pump - 261

Improving nuclear reactor designs and fuel processing technologies for safer and more efficient operation require the development of new component designs. In particular, many of the advanced reactor design such as the molten salt reactors and high-temperature gas cooled reactors have operating environments beyond the ability of many currently commercially available components. To address this, new cross-cutting technologies need to be developed that will enable the design, fabrication, and reliable operation of new classes of reactor components. The Advanced Sensor Initiative of the Nuclear Energy Enabling Technologies initiative is investigating advanced sensor and control designs that are capable of operating in these extreme environments. Under this initiative Oak Ridge National Laboratory (ORNL) has been developing embedded instrumentation and control for extreme environments. To develop, test, and validate these new sensing and control techniques, ORNL is building a pump testbed with submerged magnetic bearings. The eventual goal is to apply these techniques to a high temperature (700 deg. C) canned rotor pump that utilizes active magnetic bearings to eliminate the need for mechanical bearings and seals. The technologies will benefit the Next Generation Power Plant, Advanced Reactor Concepts, and Small Modular Reactor programs. In this paper we will detail the design and analysis of the embedded I and C testbed with submerged magnetic bearings. Then we will analyze the fluid forces on the shaft. Finally, we will develop the radial and thrust bearing geometries needed to meet the force requirements. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Fabrication and Testing of DOE Standard Canister Closure Leak Test Assembly

DOE manages over 300 types of spent nuclear fuel (SNF), many of which are located at the Idaho National Laboratory (INL) site. Managing this large variety of SNF for storage, transportation, and disposal poses a challenge to DOE. The Idaho Cleanup Project and INL are collaborating on the DOE SNF Road-Ready Demonstration (“Road-Ready Demonstration”), which will develop and demonstrate the designs, technology, processes, and regulatory framework for packaging DOE-managed SNF for “road-ready dry storage.” Road-ready dry storage is an SNF management concept in which SNF is packaged into dry, sealed canisters that are then placed in onsite storage in anticipation of later transport and disposition. The forward-looking goal of the Road-Ready Demonstration is to establish the foundation for a large-scale road-ready dry storage program at the INL site. In support of establishing a large-scale road-ready dry storage program at the INL site, the Road-Ready Demonstration will first package Fort St. Vrain SNF currently in dry storage at INL into several DOE Standard Canisters (DOESCs). These DOESCs will in turn be loaded into another containment similar to commercial multi-purpose canisters. This multi-purpose canister will then be compatible with a transportation or storage system, such as a storage cask for interim storage or transportation package for offsite transport. These DOESCs will remain sealed over the course of their storage, transportation, and applicable disposal functions. The closure process for the DOESC will include fuel and basket loading, welding, inspection, leak testing, and, if needed, repair. As a follow-up to previous discussions on the design of the DOE Closure Leak Test Assembly (LTA), this report describes recent fabrication and testing efforts performed at INL. DOESCs are sealed by two sequential gas tungsten arc welds, both of which are performed by remotely operated and semiautomatic welding systems. The first weld is a circumferential pipe weld that completes the assembly of the canister body and lid assembly. The second and final closure weld attaches the vent plug to the vent socket via a butt joint. After the second weld is performed, the welds are helium leak tested using an evacuated envelope technique. The LTA was designed for both remote and manual operation. This report describes the fabrication and performance testing associated with the evacuated envelope technique. INL staff designed, fabricated, and tested the LTA at INL facilities. This testing included establishing technique and system sensitivities in accordance with ASME and American National Standards Institute N14.5 requirements. Forthcoming work will cover such areas as design optimization, process and personnel qualification, and implementation in Road-Ready Demonstration operations.

42 ENGINEERING↗

Drop Analysis of a Department of Energy Standard Canister Containing Fort Saint Vrain SNF– 24138

DOE manages over 300 types of SNF, many of which are located at the INL site. Managing this large variety of SNF for storage, transportation, and disposal poses a challenge to DOE. The Idaho Cleanup Project and INL are collaborating on the DOE SNF Road-Ready Demonstration (“Road-Ready Demonstration”), which will develop and demonstrate the designs, technology, processes, and regulatory framework for packaging DOE-managed SNF for “road-ready dry storage.” Road-ready dry storage (RRDS) is an SNF management concept in which SNF is packaged into dry, sealed canisters that are then placed in on-site storage in anticipation of later transport and disposition. The forward-looking goal of the Road-Ready Demonstration is to establish the foundation for a large-scale RRDS program at the INL site. One critical aspect of RRDS is the ability to certify the DOE Standard Canister and its associated transportation package in accordance with 10 CFR 71 for offsite transportation. Depending on the SNF type and transportation strategy, DOE Standard Canisters may be required to maintain structural integrity under hypothetical accident scenarios (e.g., drop events). The DOE Standard Canisters have been tested and analyzed under various SNF loading configurations and accident drop events in support of the Idaho Spent Fuel Facility and other DOE programs; however, no analysis has yet been completed in support of the recently initiated Road-Ready Demonstration. This paper presents preliminary results from a finite element analysis of the Ø45.7 cm × 4.6 m (Ø18 in. × 15 ft) DOE Standard Canister under the 9 m drop at 80 degrees off-vertical drop scenario considered in previous INL tests and analyses. It considers the Fort St. Vrain spent nuclear fuel loading configuration proposed for the Road-Ready Demonstration, uses updated material properties, and applies the strain-based acceptance criteria established in ASME Boiler and Pressure Vessel Code’s Section III, Division 3 rules for storage and transportation spent nuclear fuel containments. This updated analysis is compared to previous DOE Standard Canister drop analyses. Preliminary results from the updated analysis show that certain regions of the containment exceed the allowable limits during the accidental drop event. However, these regions are limited to components performing a non-structural function. While further work on this analysis will be pursued, this analysis serves as the foundation for formal calculations used to support applicable certification efforts of the RRDS system at INL.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Drop Analysis of Department of Energy Standard Canister with Fort Saint Vrain SNF

DOE manages over 300 types of SNF, most of which are located at the INL site. The Idaho Cleanup Project and INL are collaborating on the Road-Ready Capability Demonstration Project, which will develop and demonstrate the designs, technology, processes, and regulatory framework for packaging DOE-managed SNF at the INL site for ?road-ready dry storage?. ?Road-ready dry storage? is a SNF management concept where SNF is packaged into dry and sealed canisters, which are then placed in on-site storage in anticipation of later transportation. The forward-looking goal of the Demonstration is establishing the foundation for a large-scale road-ready dry storage program at the INL site. The Demonstration will first package Fort Saint Vrain SNF currently stored at INL into several DOE Standard Canisters. These Standard Canisters will then be loaded into another commercial transportation or storage containment system (e.g., storage cask or transportation package). The Standard Canister is a class of standardized canisters designed for containing the large variety of DOE-managed SNF during interim storage, transportation and/or disposal at a geological repository. One critical aspect of road-ready dry storage is the ability to license the DOE Standard Canisters and its associated transportation package to 10 CFR 71. Depending on the SNF and transportation strategy, the Standard Canisters may have to maintain structural integrity under normal conditions of transport and hypothetical accident scenarios (i.e., drop events). The Standard Canisters have been tested and analyzed under various SNF loading configurations and accident drop events in support of the Idaho Spent Fuel Facility and other DOE programs. However, no analysis has been completed to support the recent Demonstration. This analysis will consider the Ø0.5 m × 5.1 m Standard Canister under drop scenario(s) considered in previous INL tests and analyses, including the 9 m drop at 80 degree off vertical. However, this analysis will consider the more recent Fort Saint Vrain loading configurations proposed for the Demonstration. This analysis will performed using strain-based acceptance criteria established by the American Society of Mechanical Engineers Boiler and Pressure Vessel Code, Section III, Division 3. It will be compared to previous analyses and form the foundation of further formal calculations that will be used to support licensing efforts of the road-ready dry storage system at INL.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Fabrication and Testing of DOE Standard Canister Closure Leak Test Assembly

DOE manages over 300 types of SNF, most of which are located at the INL site. “Road-ready dry storage” is a management concept where SNF is packaged into dry, sealed canisters, which are then placed in on-site storage in anticipation of later removal. The Idaho Cleanup Project and INL are collaborating on the Road-Ready Capability Demonstration Project, which will develop and demonstrate the designs, technology, processes, and regulatory framework for packaging DOE SNF for road-ready dry storage. In support of establishing a large-scale road-ready dry storage program at the INL site, the demonstration will package a select amount of DOE-managed SNF into DOE Standard Canisters. The closure process for the DOE Standard Canisters will include fuel and basket loading, welding, inspection, leak testing, and if needed, repair. As a follow-up to previous discussion on the design of the DOE Closure Leak Test Assembly, this report describes recent fabrication and testing efforts performed at INL. DOE Standard Canisters are sealed by two sequential gas tungsten arc welds. Both are performed by remotely operated and semi-autonomous welding systems. The first weld is a circumferential pipe weld that completes assembly of the canister body and lid assembly. The second and final closure weld connects the vent plug to the vent port with an identical butt joint to the circumferential pipe weld. After the second weld is performed on the vent port, these welds are helium leak tested using an inside-out technique. In addition to the commercially available vacuum and leak detector systems, the DOE Standard Canister Closure Leak Test Assembly was designed for both remote and manual operation. This report describes fabrication and performance testing associated with the inside-out technique. INL staff designed and tested systems to accomplish these tasks. Hardware fabrication occurred at INL facilities. Forthcoming work includes design optimization, integration to existing systems, and implementation to packaging demonstration operations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Drop Analysis of a Department of Energy Standard Canister Containing Fort Saint Vrain SNF

DOE manages over 300 types of SNF, many of which are located at the INL site. Managing this large variety of SNF for storage, transportation, and disposal poses a challenge to DOE. The Idaho Cleanup Project and INL are collaborating on the DOE SNF Road-Ready Demonstration (“Road-Ready Demonstration”), which will develop and demonstrate the designs, technology, processes, and regulatory framework for packaging DOE-managed SNF for “road-ready dry storage.” Road-ready dry storage (RRDS) is an SNF management concept in which SNF is packaged into dry, sealed canisters that are then placed in on-site storage in anticipation of later transport and disposition. The forward-looking goal of the Road-Ready Demonstration is to establish the foundation for a large-scale RRDS program at the INL site. One critical aspect of RRDS is the ability to certify the DOE Standard Canister and its associated transportation package in accordance with 10 CFR 71 for offsite transportation. Depending on the SNF type and transportation strategy, DOE Standard Canisters may be required to maintain structural integrity under hypothetical accident scenarios (e.g., drop events). The DOE Standard Canisters have been tested and analyzed under various SNF loading configurations and accident drop events in support of the Idaho Spent Fuel Facility and other DOE programs; however, no analysis has yet been completed in support of the recently initiated Road-Ready Demonstration. This paper presents preliminary results from a finite element analysis of the Ø45.7 cm × 4.6 m (Ø18 in. × 15 ft) DOE Standard Canister under the 9 m drop at 80 degrees off-vertical drop scenario considered in previous INL tests and analyses. It considers the Fort St. Vrain spent nuclear fuel loading configuration proposed for the Road-Ready Demonstration, uses updated material properties, and applies the strain-based acceptance criteria established in ASME Boiler and Pressure Vessel Code’s Section III, Division 3 rules for storage and transportation spent nuclear fuel containments. This updated analysis is compared to previous DOE Standard Canister drop analyses. Preliminary results from the updated analysis show that certain regions of the containment exceed the allowable limits during the accidental drop event. However, these regions are limited to components performing a non-structural function. While further work on this analysis will be pursued, this analysis serves as the foundation for formal calculations used to support applicable certification efforts of the RRDS system at INL.

42 ENGINEERING↗

Fabrication and Testing of DOE Standard Canister Closure Leak Test Assembly – 24139

DOE manages over 300 types of spent nuclear fuel (SNF), many of which are located at the Idaho National Laboratory (INL) site. Managing this large variety of SNF for storage, transportation, and disposal poses a challenge to DOE. The Idaho Cleanup Project and INL are collaborating on the DOE SNF Road-Ready Demonstration (“Road-Ready Demonstration”), which will develop and demonstrate the designs, technology, processes, and regulatory framework for packaging DOE-managed SNF for “road-ready dry storage.” Road-ready dry storage is an SNF management concept in which SNF is packaged into dry, sealed canisters that are then placed in onsite storage in anticipation of later transport and disposition. The forward-looking goal of the Road-Ready Demonstration is to establish the foundation for a large-scale road-ready dry storage program at the INL site. In support of establishing a large-scale road-ready dry storage program at the INL site, the Road-Ready Demonstration will first package Fort St. Vrain SNF currently in dry storage at INL into several DOE Standard Canisters (DOESCs). These DOESCs will in turn be loaded into another containment similar to commercial multi-purpose canisters. This multi-purpose canister will then be compatible with a transportation or storage system, such as a storage cask for interim storage or transportation package for offsite transport. These DOESCs will remain sealed over the course of their storage, transportation, and applicable disposal functions. The closure process for the DOESC will include fuel and basket loading, welding, inspection, leak testing, and, if needed, repair. As a follow-up to previous discussions on the design of the DOE Closure Leak Test Assembly (LTA), this report describes recent fabrication and testing efforts performed at INL. DOESCs are sealed by two sequential gas tungsten arc welds, both of which are performed by remotely operated and semiautomatic welding systems. The first weld is a circumferential pipe weld that completes the assembly of the canister body and lid assembly. The second and final closure weld attaches the vent plug to the vent socket via a butt joint. After the second weld is performed, the welds are helium leak tested using an evacuated envelope technique. The LTA was designed for both remote and manual operation. This report describes the fabrication and performance testing associated with the evacuated envelope technique. INL staff designed, fabricated, and tested the LTA at INL facilities. This testing included establishing technique and system sensitivities in accordance with ASME and American National Standards Institute N14.5 requirements. Forthcoming work will cover such areas as design optimization, process and personnel qualification, and implementation in Road-Ready Demonstration operations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗