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Electronic Tongue for Quantitation of Contaminants in Water

An assembly of sensors, denoted an electronic tongue, is undergoing development as a prototype of compact devices for use in measuring concentrations of contaminants in water. Thus far, the electronic tongue has been tested on ions of Cu, Zn, Pb, and Fe and shown to respond to concentrations as low as about 10 parts per million. This electronic tongue is expected to be capable of measuring concentrations of other metal ions and organic compounds. Potential uses for electronic tongues include monitoring the chemical quality of water in a variety of natural, industrial, and laboratory settings; detecting micro-organisms indirectly by measuring microbially influenced corrosion; and characterizing compounds of interest to the pharmaceutical and food industries. This version of the electronic tongue includes a heater, a temperature sensor, an array of ion-specific electrodes, an oxidation/ reduction sensor pair, an electrical-conductivity sensor, and an array of galvanic cells, all on one compact ceramic substrate. Special-purpose electronic excitation and readout circuitry for the sensors has also been constructed. The main advantage of the electronic tongue, relative to electrodes of this type used traditionally to assess water quality, is extreme ruggedness. The types of measurements that can be performed by use of the sensors on the electronic tongue are quite varied. The best combination of types of measurements for a given application depends on the specific contaminants that one seeks to detect. Experimental studies to identify such combinations were in progress at the time of reporting the information for this article.

Buehler, Marlin↗

Evolution of the JPSS Ground Project Calibration and Validation System

The Joint Polar Satellite System (JPSS) is the National Oceanic and Atmospheric Administrations (NOAA) next-generation operational Earth observation Program that acquires and distributes global environmental data from multiple polar-orbiting satellites. The JPSS Program plays a critical role to NOAAs mission to understand and predict changes in weather, climate, oceans, coasts, and space environments, which supports the Nation’s economy and protection of lives and property. The National Aerospace and Atmospheric Administration (NASA) is acquiring and implementing the JPSS, comprised of flight and ground systems on behalf of NOAA. The JPSS satellites are planned to fly in the afternoon orbit and will provide operational continuity of satellite-based observations and products for NOAA Polar-orbiting Operational Environmental Satellites (POES) and the Suomi National Polar-orbiting Partnership (SNPP) satellite. To support the JPSS Calibration and Validation (CalVal) node Government Resource for Algorithm Verification, Independent Test, and Evaluation (GRAVITE) services facilitate: Algorithm Integration and Checkout, Algorithm and Product Operational Tuning, Instrument Calibration, Product Validation, Algorithm Investigation, and Data Quality Support and Monitoring. GRAVITE is a mature, deployed system that currently supports the SNPP Mission and has been in operations since SNPP launch. This paper discusses the major re-architecture for Block 2.0 that incorporates SNPP lessons learned, architecture of the system, and demonstrates how GRAVITE has evolved as a system with increased performance. It is now a robust, stable, reliable, maintainable, scalable, and secure system that supports development, test, and production strings, replaces proprietary and custom software, uses open source software, and is compliant with NASA and NOAA standards.

Data Processing↗

Evolution of the JPSS Ground Project Calibration and Validation System

The Joint Polar Satellite System (JPSS) is the National Oceanic and Atmospheric Administration's (NOAA) next-generation operational Earth observation Program that acquires and distributes global environmental data from multiple polar-orbiting satellites. The JPSS Program plays a critical role to NOAA's mission to understand and predict changes in weather, climate, oceans, coasts, and space environments, which supports the Nation's economy and protection of lives and property. The National Aeronautics and Space Administration (NASA) is acquiring and implementing the JPSS, comprised of flight and ground systems, on behalf of NOAA. The JPSS satellites are planned to fly in the afternoon orbit and will provide operational continuity of satellite-based observations and products for NOAA Polar-orbiting Operational Environmental Satellites (POES) and the Suomi National Polar-orbiting Partnership (SNPP) satellite. To support the JPSS Calibration and Validation (CalVal) node Government Resource for Algorithm Verification, Independent Test, and Evaluation (GRAVITE) services facilitate: Algorithm Integration and Checkout, Algorithm and Product Operational Tuning, Instrument Calibration, Product Validation, Algorithm Investigation, and Data Quality Support and Monitoring. GRAVITE is a mature, deployed system that currently supports the SNPP Mission and has been in operations since SNPP launch. This paper discusses the major re-architecture for Block 2.0 that incorporates SNPP lessons learned, architecture of the system, and demonstrates how GRAVITE has evolved as a system with increased performance. It is now a robust, stable, reliable, maintainable, scalable, and secure system that supports development, test, and production strings, replaces proprietary and custom software, uses open source software, and is compliant with NASA and NOAA standards.

Next-Generation↗

Atmospheric Research 2014 Technical Highlights

Atmospheric research in the Earth Sciences Division (610) consists of research and technology development programs dedicated to advancing knowledge and understanding of the atmosphere and its interaction with the climate of Earth. The Division's goals are to improve understanding of the dynamics and physical properties of precipitation, clouds, and aerosols; atmospheric chemistry, including the role of natural and anthropogenic trace species on the ozone balance in the stratosphere and the troposphere; and radiative properties of Earth's atmosphere and the influence of solar variability on the Earth's climate. Major research activities are carried out in the Mesoscale Atmospheric Processes Laboratory, the Climate and Radiation Laboratory, the Atmospheric Chemistry and Dynamics Laboratory, and the Wallops Field Support Office. The overall scope of the research covers an end-to-end process, starting with the identification of scientific problems, leading to observation requirements for remote-sensing platforms, technology and retrieval algorithm development; followed by flight projects and satellite missions; and eventually, resulting in data processing, analyses of measurements, and dissemination from flight projects and missions. Instrument scientists conceive, design, develop, and implement ultraviolet, infrared, optical, radar, laser, and lidar technology to remotely sense the atmosphere. Members of the various Laboratories conduct field measurements for satellite sensor calibration and data validation, and carry out numerous modeling activities. These modeling activities include climate model simulations, modeling the chemistry and transport of trace species on regional-to-global scales, cloud resolving models, and developing the next-generation Earth system models. Satellite missions, field campaigns, peer-reviewed publications, and successful proposals are essential at every stage of the research process to meeting our goals and maintaining leadership of the Earth Sciences Division in atmospheric science research. Figure 1.1 shows the 20-year record of peer-reviewed publications and proposals among the various Laboratories. This data shows that the scientific work being conducted in the Laboratories is competitive with the work being done elsewhere in universities and other government agencies. The office of Deputy Director for Atmospheric Research will strive to maintain this record by rigorously monitoring and promoting quality while emphasizing coordination and integration among atmospheric disciplines. Also, an appropriate balance will be maintained between the scientists' responsibility for large collaborative projects and missions and their need to carry out active science research as a principal investigator. This balance allows members of the Laboratories to improve their scientific credentials, and develop leadership potentials. Interdisciplinary research is carried out in collaboration with other laboratories and research groups within the Earth Sciences Division, across the Sciences and Exploration Directorate, and with partners in universities and other government agencies. Members of the Laboratories interact with the general public to support a wide range of interests in the atmospheric sciences. Among other activities, the Laboratories raise the public's awareness of atmospheric science by presenting public lectures and demonstrations, by making scientific data available to wide audiences, by teaching, and by mentoring students and teachers. The Atmosphere Laboratories make substantial efforts to attract and recruit new scientists to the various areas of atmospheric research. We strongly encourage the establishment of partnerships with Federal and state agencies that have operational responsibilities to promote the societal application of our science products. This report describes our role in NASA's mission, provides highlights of our research scope and activities, and summarizes our scientists' major accomplishments during calendar year 2014. The composition of the organization is shown in Figure 1.2 for each code. This report is published in a printed version with an electronic version on our atmospheres Web site, http://atmospheres.gsfc.nasa.gov/.

Technical↗

Glyoxal Yield from Isoprene Oxidation and Relation to Formaldehyde: Chemical Mechanism, Constraints from SENEX Aircraft Observations, and Interpretation of OMI Satellite Data

Glyoxal (CHOCHO) is produced in the atmosphere by the oxidation of volatile organic compounds(VOCs). Like formaldehyde (HCHO), another VOC oxidation product, it is measurable from space by solar backscatter. Isoprene emitted by vegetation is the dominant source of CHOCHO and HCHO in most of the world. We use aircraft observations of CHOCHO and HCHO from the Southeast Nexus (SENEX) campaign over the southeast US in summer 2013 to better understand the CHOCHO time-dependent yield from isoprene oxidation, its dependence on nitrogen oxides (NO (sub x) triple bonded to NO plus NO2), the behavior of the CHOCHO-HCHO relationship, the quality of Ozone Monitoring Instrument (OMI) CHOCHO satellite observations, and the implications for using CHOCHO observations from space as constraints on isoprene emissions. We simulate the SENEX and OMI observations with the Goddard Earth Observing System chemical transport model (GEOSChem) featuring a new chemical mechanism for CHOCHO formation from isoprene. The mechanism includes prompt CHOCHO formation under low-NO (sub x) conditions following the isomerization of the isoprene peroxy radical (ISOPO2).The SENEX observations provide support for this prompt CHOCHO formation pathway, and are generally consistent with the GEOS-Chem mechanism. Boundary layer CHOCHO and HCHO are strongly correlated in the observations and the model, with some departure under low-NO (sub x) conditions due to prompt CHOCHO formation. SENEX vertical profiles indicate a free-tropospheric CHOCHO background that is absent from the model. The OMI CHOCHO data provide some support for this free-tropospheric background and show southeast US enhancements consistent with the isoprene source but a factor of 2 too low. Part of this OMI bias is due to excessive surface reflectivities assumed in the retrieval. The OMI CHOCHO and HCHO seasonal data over the southeast US are tightly correlated and provide redundant proxies of isoprene emissions. Higher temporal resolution in future geostationary satellite observations may enable detection of the prompt CHOCHO production under low-NO (sub x) conditions apparent in the SENEX data.

OMI↗

Gravitational Wave Sources as Timing References for LISA Data

In the megahertz gravitational-wave band, galactic ultra-compact binaries (UCBs) are continuous sources emitting at near-constant frequency. The signals from many of these galactic binaries will be sufficiently strong to be detectable by the Laser Interferometer Space Antenna (LISA) after approximately Omicron (1 week) of observing. In addition to their astrophysical value, these UCBs can be used to monitor the data quality of the observatory. This paper demonstrates the capabilities of galactic UCBs to be used as calibration sources for LISA by demanding signal coherence between adjacent week-long data segments separated by a gap in time of a priori unknown duration. A parameter for the gap duration is added to the UCB waveform model and used in a Markov-chain Monte Carlo algorithm simultaneously fitting for the astrophysical source parameters. Results from measurements of several UCBs are combined to produce a joint posterior on the gap duration. The measurement accuracy's dependence on how much is known about the UCBs through prior observing, and seasonal variations due to the LISA orbital motion, is quantified. The duration of data gaps in a two-week segment of data can be constrained to within approximately 0.2 s using Omicron (10) UCBs after one month of observing. The timing accuracy from UCBs improves to approximately or less than o.1 s after 1 year of mission operations. These results are robust to within a factor of approximately 2 when taking into account seasonal variations.

Gravitation Wave Sources↗

Effectiveness of Redundant Communications Systems in Maintaining Operational Control of Small Unmanned Aircraft

As a part of NASA’s Unmanned Aircraft System (UAS) Traffic Management (UTM) research, a test was performed to evaluate the effectiveness of the redundant Command and Control (C2) communications system for maintaining operational control of small UAS in the airspace over a rural area. In the test, operators set up a primary and a secondary UAS C2 communications system, sent a maneuver command to an Unmanned Aircraft (UA) with and without a functioning primary system, then verified the execution of the sent command to confirm the operator control. Operators reported that the tested redundancy configurations were effective in maintaining operational control in the test airspace over rural locations. Since the next phase of UTM research focuses on operations in an urban area where an increased level of Radio Frequency (RF) activities occur compared to a rural area, four recommendations are provided to sustain the effectiveness of redundancy in urban operations. First, the operator should not include C2 systems that use the industrial, scientific, and medical (ISM) radio bands in redundancy configurations. Second, the operator should verify the RF characteristics of the intended operation area and examine the area’s radio noise floor. Third, the operator should monitor the availability, quality, and reliability of communications services used by a redundant system. Fourth, the small UAS community should adopt a standard set of contingency steps to handle the loss of C2 communications so that such events are managed in a consistent manner across the airspace. The insights from the test will be used to accommodate the FAA’s UAS integration effort.

Jung, Jaewoo↗

Spatiotemporal Characteristics of the Association between AOD and PM over the California Central Valley

Many air pollution health effects studies rely on exposure estimates of particulate matter (PM) concentrations derived from remote sensing observations of aerosol optical depth (AOD). Simple but robust calibration models between AOD and PM are therefore important for generating reliable PM exposures. We conduct an in-depth examination of the spatial and temporal characteristics of the AOD-PM2.5 relationship by leveraging data from the Distributed Regional Aerosol Gridded Observation Networks (DRAGON) field campaign where eight NASA Aerosol Robotic Network (AERONET) sites were co-located with EPA Air Quality System (AQS) monitoring sites in California’s Central Valley from November 2012 to April 2013. With this spatiotemporally rich data we found that linear calibration models (R(exp 2) = 0.35, RMSE = 10.38 µg/cu.m) were significantly improved when spatial (R(exp 2) = 0.45, RMSE = 9.54 µg/cu.m), temporal (R(exp 2) = 0.62, RMSE = 8.30 µg/cu.m), and spatiotemporal (R(exp 2) = 0.65, RMSE = 7.58 µg/cu.m) functions were included. As a use-case we applied the best spatiotemporal model to convert space-borne MultiAngle Imaging Spectroradiometer (MISR) AOD observations to predict PM2.5 over the region (R(exp 2) = 0.60, RMSE = 8.42 µg/cu.m). Our results imply that simple AERONET AOD-PM2.5 calibrations are robust and can be reliably applied to space-borne AOD observations, resulting in PM2.5 prediction surfaces for use in downstream applications.

Meytar Sorek-Hamer↗

NASA’s Earth-Observing Aqua Satellite Mission

NASA’s Earth-observing Aqua satellite was launched into space on May 4, 2002; and since that time, Aqua has been collecting and transmitting data on the Earth’s atmosphere, oceans, land, and ice. These data have contributed to over 20,000 scientific publications cited over 500,000 times in the scientific literature and have been used for numerous practical applications, from weather forecasting to air quality analyses to monitoring such phenomena as forest fires, oil spills, sea ice, dust storms, and volcanic ash plumes. The speaker has been Project Scientist for the Aqua mission since April 1993, starting nine years before the satellite launched. She will give an overview of the mission, a sampling of its results, an estimate of when the mission might end (based on fuel and power limitations), and an indication of the types of tasks that take place largely behind the scenes by the Project Scientist and others to enable such missions to continue and succeed.

Claire L Parkinson↗

Concerns About Phytoplankton Bloom Trends in Global Lakes

Satellite remote sensing has been widely used to monitor the water quality of inland and coastal environments. Using satellite data from the Landsat 5 Thematic Mapper (L5TM), Ho et al.1 showed an increase in peak summertime bloom intensity in 68% of the 71 large lakes worldwide from 1982 to 2012. However, we question the veracity of their finding for at least two reasons: (1) satellite-derived reflectance in a single near-infrared (NIR) band is not a reliable proxy for bloom strength, and (2) the infrequent satellite observations from L5TM make it difficult to draw statistically meaningful conclusions.

Lian Feng↗

Polarization performance simulation for the GeoXO atmospheric composition instrument: NO2 retrieval impacts

NOAA’s Geostationary Extended Observations (GeoXO) constellation will continue and expand on the capabilities of the current generation of geostationary satellite systems to support US weather, ocean, atmosphere, and climate operations. It is planned to consist of a dedicated atmospheric composition instrument (ACX) to support air quality forecasting and monitoring by providing similar capabilities to missions such as TEMPO (Tropospheric Emission: Monitoring Pollution), currently planned to launch in 2023, and Ozone Monitoring Instrument (OMI), TROPOMI (TROPOspheric Monitoring Instrument), and GEMS (Geostationary Environment Monitoring Spectrometer) currently in operation. As the early phases of ACX development are progressing, design trade-offs are being considered to understand the relationship between instrument design choices and trace gas retrieval impacts. Some of these choices will affect the instrument polarization sensitivity (PS), which can have radiometric impacts on environmental satellite observations. We conducted a study to investigate how such radiometric impacts can affect NO2 retrievals by exploring their sensitivities to time of day, location, and scene type with an ACX instrument model that incorporates PS. The study addresses the basic steps of operational NO2 retrievals: the spectral fitting step and the conversion of slant column to vertical column via the air mass factor (AMF). The spectral fitting step was performed by generating at-sensor radiance from a clear sky scene with a known NO2 amount, the application of an instrument model including both instrument PS and noise, and a physical retrieval. The spectral fitting step was found to mitigate the impacts of instrument PS. The AMF-related step was considered for clear sky and partially cloudy scenes, where instrument PS can lead to errors in interpreting the cloud content, propagating to AMF errors and finally to NO2 retrieval errors. For this step, the NO2 retrieval impacts were small but non-negligible for high NO2 amounts; we estimated that a typical high NO2 amount can cause maximum of 0.25 x 10^15 molecules/cm^2 for a PS of 5%. These simulation capabilities were designed to aid in the development of a GeoXO atmospheric composition instrument that will improve our ability to monitor and understand the Earth’s atmosphere.

trace gases↗

Polarization Performance Simulation for the GeoXO Atmospheric Composition Instrument: NO2 Retrieval Impacts

NOAA's Geostationary Extended Observations (GeoXO) constellation will continue and expand on the capabilities of the current generation of geostationary satellite systems to support US weather, ocean, atmosphere, and climate operations. It is planned to consist of a dedicated atmospheric composition instrument (ACX) to support air quality forecasting and monitoring by providing capabilities similar to missions such as TEMPO (Tropospheric Emission: Monitoring Pollution), currently planned to launch in 2023, as well as OMI (Ozone Monitoring Instrument), TROPOMI (TROPOspheric Monitoring Instrument), and GEMS (Geostationary Environment Monitoring Spectrometer) currently in operation. As the early phases of ACX development are progressing, design trade-offs are being considered to understand the relationship between instrument design choices and trace gas retrieval impacts. Some of these choices will affect the instrument polarization sensitivity (PS), which can have radiometric impacts on environmental satellite observations. We conducted a study to investigate how such radiometric impacts can affect NO2 retrievals by exploring their sensitivities to time of day, location, and scene type with an ACX instrument model that incorporates PS. The study addresses the basic steps of operational NO2 retrievals: the spectral fitting step and the conversion of slant column to vertical column via the air mass factor (AMF). The spectral fitting step was performed by generating at-sensor radiance from a clear-sky scene with a known NO2 amount, the application of an instrument model including both instrument PS and noise, and a physical retrieval. The spectral fitting step was found to mitigate the impacts of instrument PS. The AMF-related step was considered for clear-sky and partially cloudy scenes, for which instrument PS can lead to errors in interpreting the cloud content, propagating to AMF errors and finally to NO2 retrieval errors. For this step, the NO2 retrieval impacts were small but non-negligible for high NO2 amounts; we estimated that a typical high NO2 amount can cause a maximum retrieval error of 0.25×1015 molec. cm−2 for a PS of 5 %. These simulation capabilities were designed to aid in the development of a GeoXO atmospheric composition instrument that will improve our ability to monitor and understand the Earth's atmosphere.

Aaron Pearlman↗

Dynamic Monitoring of Cleanroom Fallout Using an Air Particle Counter

The particle fallout limitations and periodic allocations for the James Webb Space Telescope are very stringent. Standard prediction methods are complicated by non-linearity and monitoring methods that are insufficiently responsive. A method for dynamically predicting the particle fallout in a cleanroom using air particle counter data was determined by numerical correlation. This method provides a simple linear correlation to both time and air quality, which can be monitored in real time. The summation of effects provides the program better understanding of the cleanliness and assists in the planning of future activities. Definition of fallout rates within a cleanroom during assembly and integration of contamination-sensitive hardware, such as the James Webb Space Telescope, is essential for budgeting purposes. Balancing the activity levels for assembly and test with the particle accumulation rate is paramount. The current approach to predicting particle fallout in a cleanroom assumes a constant air quality based on the rated class of a cleanroom, with adjustments for projected work or exposure times. Actual cleanroom class can also depend on the number of personnel present and the type of activities. A linear correlation of air quality and normalized particle fallout was determined numerically. An air particle counter (standard cleanroom equipment) can be used to monitor the air quality on a real-time basis and determine the "class" of the cleanroom (per FED-STD-209 or ISO-14644). The correlation function provides an area coverage coefficient per class-hour of exposure. The prediction of particle accumulations provides scheduling inputs for activity levels and cleanroom class requirements.

Perry, Radford↗

SeaWiFS Postlaunch Technical Report Series: The SeaBOARR-98 Field Campaign - Volume 3

This report documents the scientific activities during the first Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Bio-Optical Algorithm Round-Robin (SeaBOARR-98) experiment, which took place from 5-17 July 1998, at the Acqua Alta Oceanographic Tower (AAOT) in the northern Adriatic Sea off the coast of Italy. The ultimate objective of the SeaBOARR activity is to evaluate the effect of different measurement protocols on bio-optical algorithms using data from a variety of field campaigns. The SeaBOARR-98 field campaign was concerned with collecting a high quality data set of simultaneous in-water and above-water radiometric measurements. The deployment goals documented in this report were to: a) use four different surface glint correction methods to compute water-leaving radiances, L W (lambda), from above-water data; b) use two different in-water profiling systems and three different methods to compute L W (lambda) from in-water data (one making measurements at a fixed distance from the tower, 7.5 m, and the other at variable distances up to 29 m away); c) use instruments with a common calibration history to minimize intercalibration uncertainties; d) monitor the calibration drift of the instruments in the field with a second generation SeaWiFS Quality Monitor (SQM-II), to separate differences in methods from changes in instrument performance; and e) compare the L W (lambda) values estimated from the above-water and in-water measurements. In addition to describing the instruments deployed and the data collected, a preliminary analysis of the data is presented, and the kind of follow-on work that is needed to completely assess the estimation of L W (lambda) from above-water and in-water measurements is discussed.

Zibordi, Giuseppe↗

Salt Effects on Li-Ion Exchange Kinetics of Na 2 Mg 2 P 3 O 9 N: Systematic In Situ Synchrotron Diffraction Studies

The kinetics and thermodynamics of solid-state ion exchange of Li+ into Na2Mg2P3O9N were investigated using in situ synchrotron X-ray diffraction methods for a series of Li-containing salts, allowing systematic trends with general applicability to ion exchange reactions to be elucidated. The collection of data for a wide range of reaction conditions was enabled through the use of a novel multiwell sample environment which leverages the ability of the synchrotron beamline to rapidly (similar to 1 s) collect high-quality data suitable for monitoring reaction progress. From these data, it was possible to resolve the influence of salt choice and salt concentration on the ion exchange reaction kinetics. Furthermore, by carrying out experiments at different temperatures, initial estimates of activation energies were obtained. It was generally found that the ion exchange reaction kinetics strongly depended on the salt chosen as the ion source rather than being primarily determined by the ion mobility of the ceramic.

Cosby, Monty R.↗

The Cloud-Aerosol Transport System (CATS): a New Lidar for Aerosol and Cloud Profiling from the International Space Station

Spaceborne lidar profiling of aerosol and cloud layers has been successfully implemented during a number of prior missions, including LITE, ICESat, and CALIPSO. Each successive mission has added increased capability and further expanded the role of these unique measurements in wide variety of applications ranging from climate, to air quality, to special event monitoring (ie, volcanic plumes). Many researchers have come to rely on the availability of profile data from CALIPSO, especially data coincident with measurements from other A-Train sensors. The CALIOP lidar on CALIPSO continues to operate well as it enters its fifth year of operations. However, active instruments have more limited lifetimes than their passive counterparts, and we are faced with a potential gap in lidar profiling from space if the CALIOP lidar fails before a new mission is operational. The ATLID lidar on EarthCARE is not expected to launch until 2015 or later, and the lidar component of NASA's proposed Aerosols, Clouds, and Ecosystems (ACE) mission would not be until after 2020. Here we present a new aerosol and cloud lidar that was recently selected to provide profiling data from the International Space Station (ISS) starting in 2013. The Cloud-Aerosol Transport System (CATS) is a three wavelength (1064, 532, 355 nm) elastic backscatter lidar with HSRL capability at 532 nm. Depolarization measurements will be made at all wavelengths. The primary objective of CATS is to continue the CALIPSO aerosol and cloud profile data record, ideally with overlap between both missions and EarthCARE. In addition, the near real time data capability of the ISS will enable CATS to support operational applications such as air quality and special event monitoring. The HSRL channel will provide a demonstration of technology and a data testbed for direct extinction retrievals in support of ACE mission development. An overview of the instrument and mission will be provided, along with a summary of the science objectives and simulated data.

Welton, Ellsworth J.↗

SU-E-T-776: Use of Quality Metrics for a New Hypo-Fractionated Pre-Surgical Mesothelioma Protocol

Purpose: The “SMART” (Surgery for Mesothelioma After Radiation Therapy) approach involves hypo-fractionated radiotherapy of the lung pleura to 25Gy over 5 days followed by surgical resection within 7. Early clinical results suggest that this approach is very promising, but also logistically challenging due to the multidisciplinary involvement. Due to the compressed schedule, high dose, and shortened planning time, the delivery of the planned doses were monitored for safety with quality metric software. Methods: Hypo-fractionated IMRT treatment plans were developed for all patients and exported to Quality Reports™ software. Plan quality metrics or PQMs™ were created to calculate an objective scoring function for each plan. This allows for an objective assessment of the quality of the plan and a benchmark for plan improvement for subsequent patients. The priorities of various components were incorporated based on similar hypo-fractionated protocols such as lung SBRT treatments. Results: Five patients have been treated at our institution using this approach. The plans were developed, QA performed, and ready within 5 days of simulation. Plan Quality metrics utilized in scoring included doses to OAR and target coverage. All patients tolerated treatment well and proceeded to surgery as scheduled. Reported toxicity included grade 1 nausea (n=1), grade 1 esophagitis (n=1), grade 2 fatigue (n=3). One patient had recurrent fluid accumulation following surgery. No patients experienced any pulmonary toxicity prior to surgery. Conclusion: An accelerated course of pre-operative high dose radiation for mesothelioma is an innovative and promising new protocol. Without historical data, one must proceed cautiously and monitor the data carefully. The development of quality metrics and scoring functions for these treatments allows us to benchmark our plans and monitor improvement. If subsequent toxicities occur, these will be easy to investigate and incorporate into the metrics. This will improve the safe delivery of large doses for these patients.

60 APPLIED LIFE SCIENCES↗

Reuse Permit I-160-02Quality Assurance Project Plan (QAPP) for Required Environmental and Process MonitoringIdaho National Laboratory Materials and Fuels Complex Industrial Waste Ditch and Pond

The purpose of this quality assurance project plan (QAPP) is to describe the technical requirements and quality assurance (QA) activities of the environmental data collection/analyses operations to be performed under Reuse Permit I-160-02, Modification 1 (hereafter ‘permit’). It describes the scope of monitoring, the organization and persons involved, the data quality objectives, the monitoring procedures, and the specific quality control (QC) measures to be employed. All QAPP activities are implemented to determine whether the results of the sampling and monitoring performed are the right type, quantity, and quality to satisfy the requirements of the permit, Section 5.

99 GENERAL AND MISCELLANEOUS↗