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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43

Influence of skin surface roughness degree on energy characteristics of light scattered by a biological tissue

We present the results of modelling of photometric characteristics of light in soft tissues illuminated by a parallel beam along the normal to the surface, obtained with allowance for the skin roughness parameters and the angular structure of radiation approaching the surface from within the tissue. The depth structure of the fluence rate and the spectra of the diffuse reflection of light by the tissue in the interval of wavelengths 300 – 1000 nm are considered. We discuss the influence of the tilt angle variance of rough surface microelements and light refraction on the studied characteristics. It is shown that these factors lead to the reduction of the radiation flux only in the near-surface tissue layer and practically do not affect the depth of light penetration into the tissue. On the other hand, the degree of the surface roughness and the conditions of its illumination from within the tissue essentially affect the coefficient of diffuse reflection of light and lead to its considerable growth compared to the cases of a smooth interface and completely diffuse illumination, often considered to simplify the theoretical problem solution. The role of the roughness of skin surface is assessed in application to the solution of different direct and inverse problems of biomedical optics. (paper)

60 APPLIED LIFE SCIENCES↗

A laboratory investigation into microwave backscattering from sea ice

The purpose of the research reported here was to determine the sources of scattering of artificial sea ice, to compare backscatter measurements semi-quantitatively with theoretical predictions, and to develop inexpensive polarimetric radars for sea ice backscatter studies. A brief review of the dielectric properties of sea ice and of commonly used surface and volume scattering theories is presented. We provide a description of the backscatter measurements performed and experimental techniques used. The development of inexpensive short-range polarimetric radars is discussed. We discuss limitations of this system and the development of a radar that avoids the oscillator instability problems of continuously tunable oscillators by doing measurements at discrete frequencies, using a synthesized frequency source. We present results of simple test of copolar phase capability and a simple method of doing phase calibrations. We discuss ice surface characterization data and techniques. We also present a method of estimating the standard deviation of rms height and correlation length for cases of few data points.

Bredow, Jonathan W.↗

Superconducting proximity effect in a topological insulator using Fe(Te, Se)

Interest in the superconducting proximity effect has recently been reignited by theoretical predictions that it could be used to achieve topological superconductivity. Low- T c superconductors have predominantly been used in this effort, but small energy scales of ~1 meV have hindered the characterization of the emergent electronic phase, limiting it to extremely low temperatures. In this work, we use molecular beam epitaxy to grow topological insulator Bi 2 Te 3 in a range of thicknesses on top of a high- T c superconductor Fe(Te,Se). Using scanning tunneling microscopy and spectroscopy, we detect Δ ind as high as ~3.5 meV, which is the largest reported gap induced by proximity to an s -wave superconductor to date. We find that Δ ind decays with Bi 2 Te 3 thickness, but remains finite even after the topological surface states have been formed. Finally, by imaging the scattering and interference of surface state electrons, we provide a microscopic visualization of the fully gapped Bi 2 Te 3 surface state due to Cooper pairing. Lastly, our results establish Fe-based high- T c superconductors as a promising new platform for realizing high- T c topological superconductivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The Effects of Noise on Polarimetric SAR Data

Polarimetric SAR data can provide a great deal of information about the scattering behavior of the surface under observation. Polarimetric SAR systems often measure the scattering matrices of the areas under observation in linear polarizations (H and V). From the scattering matrix commonly used forms such as the covariance matrix and the Stokes matrix can be easily derived. Other measures derived from polarimetric SAR data include the standard deviation of texture, correlation coefficients between scattering matrix terms, and the mode and variance of phase differences between scattering matrix terms. The effects of additive system noise on these measurements is not often considered in the literature on this subject.

Polarimetric SAR Data analysis↗

The Effects of Noise on Polarimetric SAR Data

Polarimetric SAR data can provide a great deal of information about the scattering behavior of the surface under observation. Polarimetric SAR systems often measure the scattering matrices of the areas under observation in linear polarizations (H and V). From the scattering matrix commonly used forms such as the covariance matrix and the Stokes matrix can be easily derived. Other measures derived from polarimetric SAR data include correlation coefficients between scattering matrix terms and the mode and variance of phase differences between scattering matrix terms. The effects of additive system noise on these measurements is not often considered in the literature on this subject. In this paper, the effects of additive system noise on measurements derived from polarimetric SAR data will be examined. It will be shown how first-order noise effects can be removed and how second-order noise effects can be reduced for some measurements...

Freeman, A.↗

Near-Field Spectroscopy with Nanoparticles Deposited by AFM

An alternative approach to apertureless near-field optical spectroscopy involving an atomic-force microscope (AFM) entails less complexity of equipment than does a prior approach. The alternative approach has been demonstrated to be applicable to apertureless near-field optical spectroscopy of the type using an AFM and surface enhanced Raman scattering (SERS), and is expected to be equally applicable in cases in which infrared or fluorescence spectroscopy is used. Apertureless near-field optical spectroscopy is a means of performing spatially resolved analyses of chemical compositions of surface regions of nanostructured materials. In apertureless near-field spectroscopy, it is common practice to utilize nanostructured probe tips or nanoparticles (usually of gold) having shapes and dimensions chosen to exploit plasmon resonances so as to increase spectroscopic-signal strengths. To implement the particular prior approach to which the present approach is an alternative, it is necessary to integrate a Raman spectrometer with an AFM and to utilize a special SERS-active probe tip. The resulting instrumentation system is complex, and the tasks of designing and constructing the system and using the system to acquire spectro-chemical information from nanometer-scale regions on a surface are correspondingly demanding.

Anderson, Mark S.↗

SAR terrain classifier and mapper of biophysical attributes

In preparation for the launch of SIR-C/X-SAR and design studies for future orbital SAR, a program has made considerable progress in the development of an SAR terrain classifier and algorithms for quantification of biophysical attributes. The goal of this program is to produce a generalized software package for terrain classification and estimation of biophysical attributes and to make this package available to the larger scientific community. The basic elements of the SAR (Synthetic Aperture Radar) terrain classifier are outlined. An SAR image is calibrated with respect to known system and processor gains and external targets (if available). A Level 1 classifier operates on the data to differentiate: urban features, surfaces and tall and short vegetation. Level 2 classifiers further subdivide these classes on the basis of structure. Finally, biophysical and geophysical inversions are applied to each class to estimate attributes of interest. The process used to develop the classifiers and inversions is shown. Radar scattering models developed from theory and from empirical data obtained by truck-mounted polarimeters and the JPL AirSAR are validated. The validated models are used in sensitivity studies to understand the roles of various scattering sources (i.e., surface trunk, branches, etc.) in determining net backscatter. Model simulations of sigma (sup o) as functions of the wave parameters (lambda, polarization and angle of incidence) and the geophysical and biophysical attributes are used to develop robust classifiers. The classifiers are validated using available AirSAR data sets. Specific estimators are developed for each class on the basis of the scattering models and empirical data sets. The candidate algorithms are tested with the AirSAR data sets. The attributes of interest include: total above ground biomass, woody biomass, soil moisture and soil roughness.

Ulaby, Fawwaz T.↗

Enhancement of Fluorescence and Raman Scattering in Cyanine-Dye Molecules on the Surface of Silicon-Coated Silver Nanoparticles

A method of formation of a composite structure based on silver nanoparticles and a thin protective silicon film (AgNPs/Si) is developed. Enhancement of the fluorescence and Raman scattering in cyaninedye molecules deposited onto the formed nanostructure is observed. The optical properties and morphology stability of particles that are in contact with cyanine-dye solutions in organic solvents are studied. It is shown that the AgNPs/Si composite structure can be multiply used as an SERS-active surface.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Ab initio quantum scattering calculations and a new potential energy surface for the HCl( X 1Σ+)–O2(X3Σg−) system: Collision-induced line shape parameters for O2-perturbed R(0) 0–0 line in H35Cl

The remote sensing of abundance and properties of HCl—the main atmospheric reservoir of Cl atoms that directly participate in ozone depletion—is important for monitoring the partitioning of chlorine between “ozone-depleting” and “reservoir” species. Such remote studies require knowledge of the shapes of molecular resonances of HCl, which are perturbed by collisions with the molecules of the surrounding air. In this work, we report the first fully quantum calculations of collisional perturbations of the shape of a pure rotational line in H35Cl perturbed by an air-relevant molecule [as the first model system we choose the R(0) line in HCl perturbed by O2]. The calculations are performed on our new highly accurate HCl(X1Σ+)–O2(X3Σg−) potential energy surface. In addition to pressure broadening and shift, we also determine their speed dependencies and the complex Dicke parameter. This gives important input to the community discussion on the physical meaning of the complex Dicke parameter and its relevance for atmospheric spectra (previously, the complex Dicke parameter for such systems was mainly determined from phenomenological fits to experimental spectra and the physical meaning of its value in that context is questionable). We also calculate the temperature dependence of the line shape parameters and obtain agreement with the available experimental data. We estimate the total combined uncertainties of our calculations at 2% relative root-mean-square error in the simulated line shape at 296 K. This result constitutes an important step toward computational population of spectroscopic databases with accurate ab initio line shape parameters for molecular systems of terrestrial atmospheric importance.

Chemistry↗

Advanced Solid-State Array Spectroradiometer (ASAS) support of 1989 field experiments

An overview of the ASAS data acquired in support of the 1989 field experiments is presented and data quality is discussed. The precision of the ASAS data is considered through the presentation of SNRs derived from both field and laboratory data. ASAS is an airborne, off-nadir pointing, imaging spectroradiometer that acquires digital image data for 29 visible and near-infrared spectral bands (465 to 871 nm) with a spectral resolution of 15 nm. Surfaces observed for the field experiments include volcanic surfaces and a playa within a sparsely vegetated semiarid ecosystem, grass canopies within a prairie ecosystem, and tree canopies within a northern forest ecosystem. It is shown that calibrated ASAS data are sufficiently exact for investigations of the directional distribution of radiation scattered from terrestrial surfaces.

Irons, James R.↗

Analysis of volcanic surface morphology on Venus from comparison of Arecibo, Magellan, and terrestrial airborne radar data

The paper compares Arecibo Observatory and Magellan radar data for Venus to airborne radar images for potential terrestrial analog surfaces. Volcanic deposits in western Eistla Regio and northern Sedna Planitia are characterized. It is shown that the expected-sense circularly polarized echoes in the 'dark plains' and broad flow aprons of Eistla Regio decrease rapidly with incidence angle. This angular scattering behavior implies surfaces no rougher than terrestrial pahoehoe flows. Polarization ratio comparisons show that the extensive lava flows in Western Eistla Regio and Sedna Planitia are generally consistent with the properties of terrestrial pahoehoe flows, with only limited occurrences of a'a morphology. Three scenarios are suggested. Many of the large flow units in the two study regions were emplaced as complexes of low-effusion rate pahoehoe flows, rather than as higher eruption rate events which might be expected to produce a'a surface textures; the long lava flows were originally emplaced as a'a but have since weathered to a smoother texture; or a combination of atmospheric and magma compositional effects combine to inhibit a'a formation even at high volume eruption rates.

Campbell, Bruce A.↗

Local Intensity Enhancements in Spherical Microcavities: Implications for Photonic Chemical and Biological Sensors

In this report, we summarize recent findings regarding the use spherical microcavities in the amplification of light that is inelastically scattered by either fluorescent or Raman-active molecules. This discussion will focus on Raman scattering, with the understanding that analogous processes apply to fluorescence. Raman spectra can be generated through the use of a very strong light source that stimulates inelastic light scattering by molecules, with the scattering occurring at wavelengths shifted from that of the source and being most prominent at shifts associated with the molecules natural vibrational frequencies. The Raman signal can be greatly enhanced by exposing a molecule to the intense electric fields that arise near surfaces (typically of gold or silver) exhibiting nanoscale roughness. This is known as surface-enhanced Raman scattering (SERS). SERS typically produces gain factors of 103 - 106, but under special conditions, factors of 1010 - 1014 have been achieved.

Fuller, Kirk A.↗