Search NASA⌕ Search

SEARCH · Search NASA

Results for “triangularity”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 775 records · Page 43
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Estimating cross-field particle transport at the outer midplane of TCV by tracking filaments with machine learning

Abstract Cross-field transport of particles in the boundary region of magnetically confined fusion plasmas is dominated by turbulence. Blobs, intermittent turbulent structures with large amplitude and a filamentary shape appearing in the scrape-off layer (SOL), are known from theoretical and experimental studies to be the main contributor to the cross-field particle transport. The dynamics of blobs differs depending on various plasma conditions, including triangularity ( δ ). In this work, we analyze triangularity dependence of the cross-field particle transport at the outer midplane of plasmas with δ = + 0.38 , +0.15, −0.14, and −0.26 on the Tokamak à Configuration Variable, using our novel machine learning (ML) blob-tracking approach applied to gas puff imaging data. The cross-field particle flux determined in this way is of the same order as the overall transport inferred from KN1D, GBS, and SOLPS-ITER simulations, suggesting that the blobs identified by the ML blob-tracking account for most of the cross-field particle transport in the SOL. Also, the ML blob-tracking and KN1D show a decrease in the cross-field particle transport as δ becomes more negative. The blob-by-blob analysis of the result from the tracking reveals that the decrease of cross-field particle transport with decreasing δ is accompanied by a decrease in the number of blobs in a fixed time, which tend to have larger area and lower radial speed. Also, the blobs in these plasmas are in the connected sheath regime, and show a velocity scaling consistent with the two-region model.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Synthesis, disorder and Ising anisotropy in a new spin liquid candidate PrMgAl 11 O 19

Here we report the successful synthesis of large single crystals of triangular frustrated PrMgAl 11 O 19 using the optical floating zone technique. Single crystal x-ray diffraction (XRD) measurements unveiled the presence of quenched disorder within the mirror plane, specifically ~7% of Pr ions deviating from the ideal 2d site towards the 6h site. Magnetic susceptibility measurements revealed an Ising anisotropy with the c-axis being the easy axis. Despite a large spin–spin interaction that develops below ~10 K and considerable site disorder, the spins do not order or freeze down to at least 50 mK. The availability of large single crystals offers a distinct opportunity to investigate the exotic magnetic state on a triangular lattice with an easy axis out of the plane.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Quantitative investigation of the short-range magnetic correlations in the candidate quantum spin liquid NaYbO 2

Here, we present a neutron diffraction study of NaYbO 2 , a candidate quantum spin-liquid (QSL) compound hosting a geometrically frustrated triangular lattice of magnetic Yb 3+ ions. We observe diffuse magnetic scattering that persists to at least 20 K, demonstrating the presence of short-range magnetic correlations in this system up to a relatively high-energy scale. Using a reverse Monte Carlo and magnetic pair distribution function analysis, we confirm the predominant antiferromagnetic nature of these correlations and show that the diffuse scattering data can be well described by noninteracting layers of Heisenberg or XY spins on the triangular lattice. We rule out Ising spins and short-range-ordered stripe or 120° phases as candidate ground states of NaYbO 2 . These results are consistent with a possible QSL ground state in NaYbO 2 and showcase the benefit of a combined reciprocal- and real-space analysis of materials with short-range magnetic correlations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Growth of metallic delafossite PdCo O 2 by molecular beam epitaxy

The Pd- and Pt-based ABO 2 delafossites are a novel class of layered, triangular oxides with two-dimensional electronic structure and a large conductivity that rivals the noble metals. In this work, we report successful growth of the metallic delafossite PdCoO 2 by molecular beam epitaxy (MBE). The key challenge is controlling the oxidation of Pd in the MBE environment where phase segregation is driven by the reduction of PdCoO 2 to cobalt oxide and metallic palladium. This is overcome by combining low-temperature (300 °C) atomic layer-by-layer MBE growth in the presence of reactive atomic oxygen with a postgrowth high-temperature anneal. Thickness dependence (5–265 nm) reveals that in the thin regime (<75 nm), the resistivity scales inversely with thickness, likely dominated by surface scattering; for thicker films, the resistivity approaches the values reported for the best bulk crystals at room temperature, but the low-temperature resistivity is limited by structural twins. Our report shows that the combination of MBE growth and a postgrowth anneal provides a route to creating high-quality films in this interesting family of layered, triangular oxides.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Electronic and structural properties of RbCe X 2 ( X 2 : O 2 , S 2 , SeS, Se 2 , TeSe, Te 2 )

We report triangular lattice delafossite compounds built from magnetic lanthanide ions are a topic of recent interest due to their frustrated magnetism and realization of quantum disordered magnetic ground states. Here we report the evolution of the structure and electronic ground states of RbCeX 2 compounds, built from a triangular lattice of Ce 3+ ions, upon varying their anion character (X 2 =O 2 , S 2 , SeS, Se 2 , TeSe, Te 2 ). This includes the discovery of a new member of this series, RbCeO 2 , that potentially realizes a quantum disordered ground state analogous to NaYbO 2 . Magnetization and susceptibility measurements reveal that all compounds manifest mean-field antiferromagnetic interactions and, with the exception of the oxide, possess signatures of magnetic correlations onset below 1 K. The crystalline electric field level scheme is explored via neutron scattering and ab initio calculations in order to model the intramultiplet splitting of the J=5/2 multiplet. In addition to the two excited doublets expected within the J=5/2 manifold, we observe one extra local mode present across the sample series. This added mode shifts downward in energy with increasing anion mass and decreasing crystal field strength, suggesting a long-lived anomalous mode endemic to anion motion about the Ce3 + sites.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

Integrated Solar-Driven Device with a Front Surface Semitransparent Catalysts for Unassisted CO 2 Reduction

Monolithic integrated photovoltaic-driven electrochemical (PV-EC) artificial photosynthesis is reported for unassisted CO 2 reduction. The PV-EC structures employ triple junction photoelectrodes with a front mounted semitransparent catalyst layer as a photocathode. The catalyst layer is comprised of an array of microscale triangular metallic prisms that redirect incoming light toward open areas of the photoelectrode to reduce shadow losses. Full wave electromagnetic simulations of the prism array (PA) structure guide optimization of geometries and length scales. An integrated device is constructed with Ag catalyst prisms covering 35% of the surface area. The experimental device has close to 80% of the transmittance with a catalytic surface area equivalent 144% of the glass substrate area. Experimentally this photocathode demonstrates a direct solar-to-CO conversion efficiency of 5.9% with 50 h stability. Selective electrodeposition of Cu catalysts onto the surface of the Ag triangular prisms allows CO2 conversion to higher value products enabling demonstration of a solar-to-C 2+ product efficiency of 3.1%. This design featuring structures that have a semitransparent catalyst layer on a PV-EC cell is a general solution to light loss by shadowing for front surface mounted metal catalysts, and opens a route for the development of artificial photosynthesis based on this scalable design approach.

14 SOLAR ENERGY↗
DOE OSTI2020

Low synchronization Gram–Schmidt and generalized minimal residual algorithms

The Gram–Schmidt process uses orthogonal projection to construct the A = QR factorization of a matrix. When Q has linearly independent columns, the operator P = I - Q(QTQ)-1QT defines an orthogonal projection onto Q⊥. In finite precision, Q loses orthogonality as the factorization progresses. A family of approximate projections is derived with the form P = I - QTQT, with correction matrix T. When T = (QTQ)-1, and T is triangular, it is postulated that the best achievable orthogonality is $\mathcal{O}(ε)\mathcal{K}(A)$. We present new variants of modified (MGS) and classical Gram–Schmidt algorithms that require one global reduction step. An interesting form of the projector leads to a compact WY representation for MGS. In particular, the inverse compact WY MGS algorithm is equivalent to a lower triangular solve. Our main contribution is to introduce a backward normalization lag into the compact WY representation, resulting in a $\mathcal{O}(ε)\mathcal{K}[r_0, AV_m])$ stable Generalized Minimal Residual Method (GMRES) algorithm that requires only one global reduce per iteration. Finally, further improvements in performance are achieved by accelerating GMRES on GPUs.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2017

Distance Determination by Gated Viewing Systems Taking into Account the Illuminating Pulse Shape

For gated viewing systems with triangular and trapezoidal illuminating pulses, we have obtained the range-intensity profiles (RIPs) of the signal as the time delay was varied between the leading edges of the gate pulse and the illuminating pulse. We have established that if the duration of the illuminating pulse Δt{sub las} is less than or equal to the duration of the gate pulse Δt{sub IC}, then the expressions for the characteristic distances are the same as for rectangular pulses and they can be used to determine the distance to objects. When Δt{sub las} > Δt{sub IC}, in the case of triangular illuminating pulses the RIP is bell-shaped. For trapezoidal pulses, the RIP is bell-shaped with or without a plateau section. We propose an empirical method for determining the characteristic distances to the RIP maximum and the boundary points for the plateau section, which we then use to calculate the distance to the object. Using calibration constants, we propose a method for determining the distance to an object and we have experimentally confirmed the feasibility of this method.

42 ENGINEERING↗
DOE OSTI2018

Surface Effects on the Dynamic Behavior of Vortices in Type II Superconducting Strips with Periodic and Conformal Pinning Arrays

Using molecular dynamics techniques, we simulate the vortex behavior in a type II superconducting strip in the presence of triangular and two types of conformal pinning arrays, one with a pinning gradient perpendicular to the driving force (C1) and the other parallel (C2), at zero temperature. A transport force is applied in the infinite direction of the strip, and the magnetic field is increased until the rate between the density of vortices (n{sub v}) and pinning (n{sub p}) reaches n{sub v}/n{sub p} = 1.5. Our results show a monotonic increase, by steps, of the vortex density with the applied magnetic field. Besides, each pinning lattice presents a different vortex penetration delay. For the triangular pinning array, different than the case of infinite films, here the system exhibits only one pronounced depinning force peak at n{sub v}/n{sub p} = 1. However, the depinning force peak is present for only one value of field, in the range of fields where n{sub v}/n{sub p} = 1 is stable. For the case of conformal pinning arrays, in analogy to what is observed in infinite films, no commensurability depinning force peaks were found. In the present case, the C1 array is more efficient at low fields, all arrays are equivalent in the intermediate fields, and the C2 array is more efficient for high fields. We also show that for the C1 array at high fields, vortices depin following the conformal arches, from the edge to the center. For the C2 array, the depinning force is higher when compared to that of C1, because this particular conformal structure prevents the formation of easy vortex flow channels.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Supercharacters of Unipotent and Solvable Groups

The notion of the supercharacter theory was introduced by P. Diaconis and I. M. Isaaks in 2008. In this paper, we present a review of the main notions and facts of the general theory and discuss the construction of the supercharacter theory for algebra groups and the theory of basic characters for unitriangular groups over a finite field. Based on his earlier papers, the author constructs the supercharacter theory for finite groups of triangular type. The structure of the Hopf algebra of supercharacters for triangular groups over finite fields is also characterized.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2019

Effect of Yagi–Uda nano-antenna element shape on the directivity and radiation efficiency

In this paper, different optimal designs of Yagi–Uda nano-antennas (NAs) are introduced and analyzed based on different element shapes to maximize the directivity and radiation efficiency. The studied element shapes include triangular, hexagonal, cube, square, rotated square, rectangular, ellipsoid, and elliptical cylinder shapes. The NAs parameters for each design are optimized using particle swarm optimization algorithm to achieve high directivity at a wavelength of 500 nm for wireless point-to-point applications. The designs are numerically analysed using 3-D finite difference time domain method (3-D FDTD) via Lumerical software package. To illustrate the performance of the proposed antennas, different radiation parameters such as radiation pattern, directivity, and radiation efficiency have been studied. Moreover, a tolerance of ± 5% is calculated to consider the imperfections that may appear in the fabrication process at a nanoscale. The optimized rectangular prism NA achieves the highest directivity of 24.21 with an efficiency of 50.74%. However, the optimized triangular prism NA has the highest efficiency of 73% with a directivity of 20.89. This enhancement is mainly attributed to the efficient coupling between array elements along with low side lobe level. However, a trade-off between directivity and radiation efficiency is obtained by the hexagonal prism NA with directivity of 21.9 and radiation efficiency of 69.1%.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2022

Variable resolution Poisson-disk sampling for meshing discrete fracture networks

Here, we present the near-Maximal Algorithm for Poisson-disk Sampling (nMAPS) to generate point distributions for variable resolution Delaunay triangular and tetrahedral meshes in two and three-dimensions, respectively. nMAPS consists of two principal stages. In the first stage, an initial point distribution is produced using a cell-based rejection algorithm. In the second stage, holes in the sample are detected using an efficient background grid and filled in to obtain a near-maximal covering. Extensive testing shows that nMAPS generates a variable resolution mesh in linear run time with the number of accepted points. We demonstrate nMAPS capabilities by meshing three-dimensional discrete fracture networks (DFN) and the surrounding volume. The discretized boundaries of the fractures, which are represented as planar polygons, are used as the seed of 2D-nMAPS to produce a conforming Delaunay triangulation. The combined mesh of the DFN is used as the seed for 3D-nMAPS, which produces conforming Delaunay tetrahedra surrounding the network. Under a set of conditions that naturally arise in maximal Poisson-disk samples and are satisfied by nMAPS, the two-dimensional Delaunay triangulations are guaranteed to only have well-behaved triangular faces. While nMAPS does not provide triangulation quality bounds in more than two dimensions, we found that low-quality tetrahedra in 3D are infrequent, can be readily detected and removed, and a high-quality balanced mesh is produced.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2020

Deformation accommodating periodic computational domain for a uniform velocity gradient

Many multiscale methods for granular materials use periodic computational domains to consider particle scale interactions and then calculate the stress to drive the continuum scale calculations. For problems involving large material deformations, the computation domain often needs to be reinitialized because of the distortion, causing the loss of the history information of the system. This work introduces an algorithm to accommodate a large deformation of the material while maintaining the computational domain cuboid to avoid the domain reinitialization during the computation. The algorithm uses a rotating frame of reference, in which the velocity gradient can be represented by an upper triangular matrix. The deformation caused by the upper triangular matrix is treated by the image system implied in the periodicity to maintain the computational domain cuboid. The effect from the rotation of the reference frame is considered using the inertial forces. Finally, simulations of simple and pure shear motions are carried out to illustrate the algorithm.

42 ENGINEERING↗
DOE OSTI2018

Growth of faceted SiC nanostructures using vapor phase condensation: Microstructural analysis

Highlights: • Synthesis of nanocrystalline SiC using thermal plasma route. • XRD data indicates presence of both α- and β-SiC polytypes with β-SiC as the major content. • HRTEM and SAED analysis reveals polytypic arrangement with stacking faults SiC nanoparticles. • TEM micrograph reveals presence of faceted structures such as hexagonal, triangular, triangular pyramidal structure. - Abstract: The paper emphasizes the morphological and microstructural analysis of SiC nanostructures grown by thermal plasma assisted gas phase condensation process. High Resolution Transmission Electron Microscopic and Selected Area Electron Diffraction studies are used to analyze the growth directions and the polytypic arrangement with stacking faults in the as synthesized SiC nanoparticles. The results help in understanding the hierarchical poly-types related to the observed geometries and showed the presence of both α- and β-SiC polytypes. The microstructural study is supported by X-Ray diffraction and UV–Visible absorption spectroscopic studies.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2017

3D printed hierarchical honeycombs with shape integrity under large compressive deformations

Here, we describe the in-plane compressive performance of a new type of hierarchical cellular structure created by replacing cell walls in regular honeycombs with triangular lattice configurations. The fabrication of this relatively complex material architecture with size features spanning from micrometer to centimeter is facilitated by the availability of commercial 3D printers. We apply to these hierarchical honeycombs a thermal treatment that facilitates the shape preservation and structural integrity of the structures under large compressive loading. The proposed hierarchical honeycombs exhibit a progressive failure mode, along with improved stiffness and energy absorption under uniaxial compression. High energy dissipation and shape integrity at large imposed strains (up to 60%) have also been observed in these hierarchical honeycombs under cyclic loading. Experimental and numerical studies suggest that these anomalous mechanical behaviors are attributed to the introduction of a structural hierarchy, intrinsically controlled by the cell wall slenderness of the triangular lattice and by the shape memory effect induced by the thermal and mechanical compressive treatment.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Magnetic properties of monoclinic lanthanide orthoborates, LnBO3, Ln = Gd, Tb, Dy, Ho, Er, Yb

Highlights: • Structural and magnetic properties of lanthanide orthoborates LnBO{sub 3}, Ln = Gd, Tb, Dy, Ho, Er, Yb. • LnBO{sub 3} forms a monoclinic structure with the magnetic Ln{sup 3+} forming eclipsed triangular layers. • With the exception of Gd{sup 3+} significant single-ion anisotropy is observed for all Ln{sup 3+}. • Ordering features for LnBO{sub 3}, Ln = Gd, Tb, Dy, Er between 0.4 and 2 K, onset of magnetic ordering for YbBO{sub 3} at 0.4 K, HoBO{sub 3} forms non-magnetic singlet ground state. • GdBO{sub 3} and DyBO{sub 3} are competitive magnetocaloric materials in the liquid helium temperature regime. - Abstract: The lanthanide orthoborates, LnBO{sub 3}, Ln = Gd, Tb, Dy, Ho, Er, Yb crystallise in a monoclinic structure with the magnetic Ln{sup 3+} forming an edge-sharing triangular lattice. The triangles are scalene, however all deviations from the ideal equilateral geometry are less than 1.5%. The bulk magnetic properties are studied using magnetic susceptibility, specific heat and isothermal magnetisation measurements. Heat capacity measurements show ordering features at T ≤ 2 K for Ln = Gd, Tb, Dy, Er. No ordering is observed for YbBO{sub 3} at T ≥ 0.4 K and HoBO{sub 3} is proposed to have a non-magnetic singlet state. Isothermal magnetisation measurements indicate isotropic Gd{sup 3+} spins and strong single-ion anisotropy for the other Ln{sup 3+}. The change in magnetic entropy has been evaluated to determine the magnetocaloric effect in these materials. GdBO{sub 3} and DyBO{sub 3} are found to be competitive magnetocaloric materials in the liquid helium temperature regime.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Structural, optical and thermal properties of glass and anti-glass phases in strontium tellurite and borotellurite systems doped with europium

Highlights: • Optical, thermal and structural properties of SrO-TeO{sub 2} and SrO-B{sub 2}O{sub 3}-TeO{sub 2} glasses containing Eu{sup 3+}. • Co-existing glass and SrTe{sub 5}O{sub 11} anti-glass inclusions in 10SrO-90TeO{sub 2} sample. • Rectangular, triangular, spherical and flower shaped inclusions in the samples. • 1-mol% Eu{sub 2}O{sub 3} modifies the shape and size of the inclusions. • B{sub 2}O{sub 3} suppresses the growth of anti-glass inclusions and enhances Eu{sup 3+} fluorescence. - Abstract: Glass sample of the composition: 10SrO-90TeO{sub 2} was prepared by melt-quenching technique and found to contain triangular, rectangular, and spherical shaped micro-inclusions of the average size ∼803 μm in the glassy matrix. The inclusions grow to an average size of ∼1347 μm and assume flower-like morphology upon adding 1 mol% Eu{sub 2}O{sub 3} in the 10SrO-90TeO{sub 2} sample. X-ray diffraction studies showed that the micro-inclusions exhibit sharp peaks, but their Raman spectra have broad phonon bands that are indistinguishable or very similar to that of the glassy matrix phase. The addition of 10 mol% B{sub 2}O{sub 3} in the samples inhibits the growth of inclusions of anti-glass phases and forms purely amorphous samples. B{sub 2}O{sub 3} significantly enhances the photoluminescence properties of Eu{sup 3+} doped samples. Furthermore, B{sub 2}O{sub 3} converts the four-fold co-ordinated Te-O structural units into three-fold co-ordinated Te-O units.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Ultracentral Collisions of Small and Deformed Systems at RHIC

We study a range of collision systems involving deformed ions and compare the elliptic and triangular flow harmonics produced in a hydrodynamics scenario versus a color glass condensate (CGC) scenario. For the hydrodynamics scenario, we generate initial conditions using TRENTO and work within a linear response approximation to obtain the final flow harmonics. For the CGC scenario, we use the explicit calculation of two-gluon correlations taken in the high-p T “(semi)dilute-(semi)dilute” regime to express the flow harmonics in terms of the density profile of the collision. Here, we consider ultracentral collisions of deformed ions as a testbed for these comparisons because the difference between tip-on-tip and side-on-side collisions modifies the multiplicity dependence in both scenarios, even at zero impact parameter. We find significant qualitative differences in the multiplicity dependence obtained in the initial conditions+hydrodynamics scenario and the CGC scenario, allowing these collisions of deformed ions to be used as a powerful discriminator between models. We also find that sub-nucleonic fluctuations have a systematic effect on the elliptic and triangular flow harmonics which are most discriminating in 0–1% ultracentral symmetric collisions of small deformed ions and in 0–10% d197Au collisions. The collision systems we consider are 238 U 238 U, d 197 Au, 9 Be 197 Au, 9 Be 9 Be, 3 He 3 He, and 3 He 197 Au.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗