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Synthesis, structural, electronic and linear electro-optical features of new quaternary Ag{sub 2}Ga{sub 2}SiS{sub 6} compound

For the first time phase equilibria and phase diagram of the AgGaS{sub 2}–SiS{sub 2} system were successfully explored by differential thermal and X-ray phase analysis methods. Crystal structure of low-temperature (LT) modification of Ag{sub 2}Ga{sub 2}SiS{sub 6} (LÐ Ñž- Ag{sub 2}Ga{sub 2}SiS{sub 6}) was studied by X-ray powder method and it belongs to tetragonal space group I-42d, with unit cell parameters a=5.7164(4) Å, c=9.8023(7) Å, V=320.32(7) Å{sup 3}. Additional details regarding the crystal structure exploration are available at the web page Fachinformationszentrum Karlsruhe. X-ray photoelectron core-level and valence-band spectra were measured for pristine LÐ Ñž- Ag{sub 2}Ga{sub 2}SiS{sub 6} crystal surface. In addition, the X-ray photoelectron valence-band spectrum of LÐ Ñž-Ag{sub 2}Ga{sub 2}SiS{sub 6} was matched on a common energy scale with the X-ray emission S Kβ{sub 1,3} and Ga Kβ{sub 2} bands, which give information on the energy distribution of the S 3p and Ga 4p states, respectively. The presented X-ray spectroscopy results indicate that the valence S p and Ga p atomic states contribute mainly to the upper and central parts of the valence band of LÐ Ñž-Ag{sub 2}Ga{sub 2}SiS{sub 6}, respectively, with a less significant contribution also to other valence-band regions. Band gap energy was estimated by measuring the quantum energy in the spectral range of the fundamental absorption. We have found that energy gap Eg is equal to 2.35 eV at 300 K. LT-Ag{sub 2}Ga{sub 2}SiS{sub 6} is a photosensitive material and reveals two spectral maxima on the curve of spectral photoconductivity spectra at λ{sub max1} =590 nm and λ{sub max2} =860 nm. Additionally, linear electro-optical effect of LT-Ag{sub 2}Ga{sub 2}SiS{sub 6} for the wavelengths of a cw He-Ne laser at 1150 nm was explored. - Graphical abstract: Manuscript present the technology of growth and investigation of properties a new quaternary compound Ag{sub 2}Ga{sub 2}SiS{sub 6} including the detailed study of the phase equilibria in the AgGaS{sub 2}–SiS{sub 2} system to determine the physico-chemical conditions of its formation. We examined crystal structure of the compound by X-ray powder method, its electronic structure by XPS method. Finally we have found these crystals like promising material for nonlinear optical, electrooptical and piezoelectric applications. - Highlights: • Phase diagram of the AgGaS{sub 2}–SiS{sub 2} system was successfully described at first time. • Crystal Ag{sub 2}Ga{sub 2}SiS{sub 6} was grown and its structure was determined. • Electronic structure and chemical bonding of the Ag{sub 2}Ga{sub 2}SiS{sub 6} crystal were examined by. • X-ray photoelectron spectroscopy (XPS) and X-ray emission spectroscopy (XES) methods. • Optical and photoelectrical properties were investigated.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Assessing Photovoltaic Capacity Factor Variability Using Long-Term Satellite Derived Solar Resource Data Under Brazilian Climate

Accurate estimation of photovoltaic (PV) energy yield and its variability is essential for reducing financial risk and supporting reliable system planning for rapidly expanding PV markets. In Brazil, high solar adoption and increasing levels of distributed energy resources are beginning to introduce operational challenges such as curtailment and evolving grid requirements. Understanding how natural variability in solar resource propagates into PV system performance is therefore increasingly important for both project design and grid integration. Modern PV yield assessments commonly rely on multi-year meteorological datasets and probabilistic exceedance metrics (e.g., P50/P90) to quantify energy yield uncertainty for project financing. However, the implications of long-term solar resource variability for PV system design choices and high-adoption grid conditions remain less well characterized for rapidly expanding markets such as Brazil. In particular, understanding how weather-driven variability propagates into PV production distributions and capacity factor expectations is important for evaluating curtailment exposure, deployment strategies, and storage requirements in regions experiencing rapid growth of distributed and utility-scale PV. Seasonal and interannual variability in atmospheric conditions can produce substantial fluctuations in monthly PV energy production, which propagate into uncertainty in annual energy yield and capacity factor expectations. Characterizing this variability using long-term meteorological datasets allows probabilistic estimation of PV system performance and provides improved insight into the range of expected PV energy outcomes. This study explores the use of long-term satellite-derived meteorological data from the National Solar Radiation Database (NSRDB) to evaluate the variability of photovoltaic system performance across multiple locations in Brazil. Using a 27-year dataset (1998-2024), PV system simulations are performed to characterize the distribution of annual and seasonal capacity factors and energy yield outcomes, while propagating key sources of meteorological variability and model uncertainty through the PV modeling chain. The analysis also investigates the sensitivity of PV performance outcomes to key system design assumptions within the PV modeling chain, including tracking configuration and system sizing parameters. The resulting probabilistic performance characterization provides insight into how weather-driven variability influences PV production expectations and capacity factor distributions. These results provide a foundation for evaluating how weather-driven variability interacts with high PV adoption and potential storage or curtailment mitigation strategies.

14 SOLAR ENERGY↗

A Thermodynamic Paradigm for Studying Disease Vector’s Habitats & Life Cycles Using NASA’s NextGen Remote Sensing Instruments

Global public health is entering a new informational age through the use of spatial models of disease vector/host ecologies driven by the use of remotely sensed data to measure environmental and structural factors critical in determining disease vector habitats, distributions, life cycles, and host interactions. The vector habitat microclimates can be quantified in terms of the surface energy budget measured by satellites. The epidemiological equations (processes) can be adapted and modified to explicitly incorporate environmental factors and interfaces required by a specific disease and its vector/host cycle. Remote sensing can be used to measure or evaluate or estimate both environment (state functions) and interface (process functions). Remote sensing can be used to measure or evaluate or estimate both environment (state functions) and interface (process functions) defining vector habitats. The products of remote sensing can be integrated directly into the epidemiological equations to significantly enhance our understanding of disease vector’s life cycles and habitats. The next generation of NASA’s remote sensing instruments recently operational will provide a significant enhancement in our ability to study disease vector’s life cycles and habitats. Three new instruments have become operational on the International Space Station (ISS) In June 2018, ECOSTRESS (The ECOsystem Spaceborne Thermal Radiometer Experiment on Space Station), a five channel, thermal IR instrument with 70 m resolution and approximately 4-5 day repeat cycle of day/night pairs along with DESISa hyperspectral sensor system 235 channels (between 400 and 1000 nanometers), 30 m resolution, and data only being acquired on demand. In November 2018. GEDI (Global Ecosystem Dynamics Investigation). GEDI is a high-resolution laser ranging of Earth’s forests and topography. These instruments set the stage for NASA’s new global designated observables set of remote sensing measurements collecting hyperspectral and multispectral thermal data called SBG (Surface Biology Geology). The SBG is currently in the planning stage. The availability and use of level 1-4 data products generated from these ISS instruments will be discussed.

thermodynamics↗

The National Solar Radiation Database (NSRDB) Fiscal Years 2019-2021(Final Report)

The National Solar Radiation Database (NSRDB) is the leading public source of high-resolution solar resource data in the United States, with more than 166,000 users annually. This database represents the state of the art in satellite-based estimation of solar resource information and uses a unique physics-based modeling approach that enables improvements in accuracy with the deployment of the next-generation geostationary satellites. Making the highest quality, state-of-the-art, regularly updated data sets available on a timely basis for users reduces costs of solar deployment by providing accurate information for siting studies and system output prediction, and thereby reduces levelized cost of energy. Also, high-resolution information from the NSRDB enables moving beyond levelized cost of energy when valuing the impact of renewables on the grid. Additionally, the NSRDB enables the integration of large amounts of solar on the grid by providing critical information about solar availability and variability that is used to enhance grid reliability and power quality.

14 SOLAR ENERGY↗

Coordinated Ramping Product and Regulation Reserve Procurements in CAISO and MISO using Multi-Scale Probabilistic Solar Power Forecasts (Pro2R)

How can probabilistic solar forecasts lower costs and improve reliability for independent system operator (ISO) markets? We tackle this question in three steps. First, we enhance an existing solar forecasting system to provide well-calibrated hours-ahead probabilistic forecasts. We then relate the degree of uncertainty in those forecasts to error distributions for net load ramps for the California ISO (CAISO) using statistical and machine learning methods. Projected net load errors conditioned on solar uncertainty are translated into flexible ramp requirements that therefore reflect real-time meteorological and solar conditions, improving on typical ISO procedures. Finally, a multi-period look-ahead production cost model quantifies how conditional ramp requirements can a) decrease operating costs by lowering requirements compared to often conservative unconditional methods, and b) reduce generation scarcity events and consequently improve reliability by increasing flexibility requirements at times when unconditional forecast-based requirements understate actual ramp uncertainty. In addition to the products just described (quantification of solar uncertainty, its translation into requirements for ramp capability product, and quantification of the benefits of more accurate ramp requirements), this project also developed a visualization system that alerts system operators of ramp and uncertainty conditions within the network based on solar forecasts. The system is called Resource Forecast and Ramp Visualization for Situational Awareness (RaVIS). These four products represent significant advances in the state-of-the-art of probabilistic solar forecasting, development of weather-informed reserve requirements, production costing methods for estimating the benefits of more accurate reserve requirements, and visualization of system status, respectively. Yet the products are also practical and can be immediately implemented, potentially enabling system operators to save millions of dollars in ramp product procurement costs per year.

14 SOLAR ENERGY↗

Description of real-time Ada software implementation of a power system monitor for the Space Station Freedom PMAD DC testbed

The Ada language software development to perform the electrical system monitoring functions for the NASA Lewis Research Center's Power Management and Distribution (PMAD) DC testbed is described. The results of the effort to implement this monitor are presented. The PMAD DC testbed is a reduced-scale prototype of the electrical power system to be used in the Space Station Freedom. The power is controlled by smart switches known as power control components (or switchgear). The power control components are currently coordinated by five Compaq 382/20e computers connected through an 802.4 local area network. One of these computers is designated as the control node with the other four acting as subsidiary controllers. The subsidiary controllers are connected to the power control components with a Mil-Std-1553 network. An operator interface is supplied by adding a sixth computer. The power system monitor algorithm is comprised of several functions including: periodic data acquisition, data smoothing, system performance analysis, and status reporting. Data is collected from the switchgear sensors every 100 milliseconds, then passed through a 2 Hz digital filter. System performance analysis includes power interruption and overcurrent detection. The reporting mechanism notifies an operator of any abnormalities in the system. Once per second, the system monitor provides data to the control node for further processing, such as state estimation. The system monitor required a hardware time interrupt to activate the data acquisition function. The execution time of the code was optimized using an assembly language routine. The routine allows direct vectoring of the processor to Ada language procedures that perform periodic control activities. A summary of the advantages and side effects of this technique are discussed.

Ludwig, Kimberly↗

Charge Exchange of Highly Charged Ne and Mg Ions with H and He

Cross sections for single electron capture (SEC), or charge exchange (CX), in collisions of Ne{sup (8–10)+} and Mg{sup (8–12)+} with H and He, are computed using an approximate multichannel Landau–Zener (MCLZ) formalism. Final-state-resolved cross sections for the principal (n), orbital angular momentum (ℓ), and where appropriate, total spin angular momentum (S) quantum numbers are explicitly computed, except for the incident bare ions Ne{sup 10+} and Mg{sup 12+}. In the latter two cases, nℓ-resolution is obtained from analytical ℓ-distribution functions applied to n-resolved MCLZ cross sections. In all cases, the cross sections are computed over the collision energy range 1 meV/u to 50 keV/u with LZ parameters estimated from atomic energies obtained from experiment, theory, or, in the case of high-lying Rydberg levels, estimated with a quantum defect approach. Errors in the energy differences in the adiabatic potentials at the avoided crossing distances give the largest contribution to the uncertainties in the cross sections, which are expected to increase with decreasing cross section magnitude. The energy differences are deduced here with the Olson–Salop–Tauljberg radial coupling model. Proper selection of an ℓ-distribution function for bare ion collisions introduces another level of uncertainty into the results. Comparison is made to existing experimental or theoretical results when available, but such data are absent for most considered collision systems. The nℓS-resolved SEC cross sections are used in an optically thin cascade simulation to predict X-ray spectra and line ratios that will aid in modeling the X-ray emission in environments where CX is an important mechanism. Details on a MCLZ computational package, Stueckelberg, are also provided.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Impacts of Aerosol and Cloud Variability on Satellite-Derived All-skies Direct Aerosol Radiative Effects (DARE) over the North and Southeast Atlantic

The Top-of-Atmosphere (TOA) Shortwave (SW) Direct Aerosol Radiative Effect (DARE) in all-sky conditions (i.e., aerosols in clear skies and aerosols above and below all types of clouds) is the global change in upwelling radiative flux due to aerosols. It is one of the strongest indicators of global climate change due to aerosols. SW DARE at TOA depends on the Earth’s surface albedo, cloud fraction, cloud optical properties, and aerosol optical properties, which are all challenging to accurately characterize from space. The overarching goals of our project are to provide state-of-the-art observational all-sky TOA SW DARE, along with guidance on which aerosol and/or cloud properties are the most important to measure, and at which spatio-temporal scales, for accurate DARE observations. We compute all-sky DARE based on state-of-the-art cloud and aerosol retrieval algorithms from CALIOP (Cloud–Aerosol Lidar with Orthogonal Polarization) and MODIS (Moderate Resolution Imaging spectroradiometer) satellite sensors, as well as aerosol intensive properties from MERRA-2 (Modern-Era Retrospective Analysis for Research and Applications, version 2) simulations over three specific regions of the Atlantic Ocean from 2012 to 2016. In this symposium, we present a characterization of the cloud and aerosol optical and physical properties and the observational TOA SW DARE along three individual satellite tracks in the Southeast Atlantic region -- on September 18 and 20, 2016 and August 13, 2017. We then quantify the impact of assuming homogeneous cloud or aerosol fields in space-based TOA SW DARE calculations. And, finally, the resulting space-based all-skies aerosol vertical distribution and DARE calculations are evaluated using remote sensing observations from coincident suborbital flights from the NASA ORACLES (the ObseRvations of Aerosols above CLouds and their intEractionS, ORACLES field campaign) field campaign. The NASA Atmospheric Observing System (AOS) mission addresses the NASA Aerosol, Cloud, Convection and Precipitation (ACCP) designated observables and proposes, as one of its aerosol objectives, to reduce uncertainties in estimates of global mean all-sky SW DARE at TOA. Well characterizing clouds, aerosol vertical distributions, aerosol types and associated all-skies DARE over the Atlantic Ocean will inform the AOS community on where, when, how, and how often the satellite retrievals should be performed to estimate DARE and reduce all-skies DARE uncertainties most accurately. These comprehensive characterizations will also identify the key regions and times when the AOS (or other ACCP-related) suborbital missions should be conducted to evaluate and improve the AOS space-based observations and retrievals.

aerosol↗

Toward a standardization of cryostructure and cryogenic soil structure terminology for the field description of permafrost‐affected soils

This paper establishes standardized terminology and field documentation protocols for cryostructures and cryogenic soil structures in permafrost‐affected soils and provides brief guidance on descriptions of ground ice morphology and ice volume estimates. We consolidate permafrost terminology from Russian and North American literature, clarify long‐standing ambiguities, and provide explicit guidelines that align with US Department of Agriculture‐Natural Resources Conservation Service soil description standards. Our scheme makes critical distinctions between cryostructure, the distribution of ice within soil, and cryogenic soil structure, the morphological structure of soil resulting from ice formation. The scheme organizes cryostructures into three main categories: non‐segregated ice, visible segregated ice, and ice matrices. We introduce standardized codes and parameters for field descriptions of ice and soil that enable machine‐readable data collection compatible with existing soil information systems. This standardization will significantly enhance the integration of field observations into landscape‐scale assessments of permafrost stability, infrastructure vulnerability, and ecosystem response to permafrost thaw, addressing an urgent need for quantitative data to inform modeling and decision‐making in rapidly changing Arctic and subarctic environments.

Andersen, Megan L. [University of Minnesota, Saint↗

Dust Direct Radiative Effect Including Large Particles and Component Minerals

The direct radiative effect (DRE) of dust aerosols in Earth system models (ESMs) remains highly uncertain, largely due to inadequate representations of particle size distribution (PSD) and mineral composition. Using NASA's Earth Surface Mineral Dust Source Investigation (EMIT) soil mineralogy data and observed PSD in an ESM that resolves dust mineral composition and emitted diameters from 0.1 to 70 μm, we find a near-neutral global dust net DRE (−0.057 W m −2 ), weaker than most previous estimates. Large dust (diameter >10 μm) contributes 30% of the global longwave dust optical depth, providing observational constraints on large-particle abundance, and offsets 20% of the dust shortwave cooling over major source regions. Incorporation of EMIT mineralogy reduces shortwave uncertainty by more than 50%. The remaining uncertainty mainly exists in processes controlling dust abundance, particularly the poorly understood transport of large dust, and longwave optical properties, which require additional observational constraints to more accurately quantify the dust DRE.

Li, Longlei [Cornell Univ., Ithaca, NY (United Sta↗

Automated reaction kinetics and network exploration (Arkane): A statistical mechanics, thermodynamics, transition state theory, and master equation software

The open-source statistical mechanics software described here, Arkane–Automated Reaction Kinetics and Network Exploration–facilitates computations of thermodynamic properties of chemical species, high-pressure limit reaction rate coefficients, and pressure-dependent rate coefficient over multi-well molecular potential energy surfaces (PES) including the effects of collisional energy transfer on phenomenological kinetics. Arkane can use estimates to fill in information for molecules or reactions where quantum chemistry information is missing. The software solves the internal energy master equation for complex unimolecular reaction systems. Inputs to the software include converged electronic structure computations performed by the user using a variety of supported software packages (Gaussian, Molpro, Orca, TeraChem, Q-Chem, Psi4). The software outputs high-pressure limit rate coefficients and pressure-dependent phenomenological rate coefficients, as well as computed thermodynamic properties (enthalpy, entropy, and constant pressure heat capacity) with added energy corrections. Some of the key features of Arkane include treatment of 1D, 2D or ND hindered internal rotation modes, treatment of free internal rotation modes, quantum tunneling effect consideration, transition state theory (TST) and Rice-Ramsperger-Kassel-Marcus (RRKM) rate coefficient computations, master equation solution with four implemented methods, inverse-Laplace transform of high-pressure limit rate coefficients into the energy domain, energy corrections based on bond-additivity or isodesmic reactions, automated and efficient PES exploration, and PES sensitivity analysis. The present work describes the design of Arkane, how it should be used, and refers to the theory that it employs. Arkane is distributed via the RMG-Py software suite (https://github.com/ReactionMechanismGenerator/RMG-Py).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Description and availability of airborne Doppler radar data

An airborne, forward-looking, pulse, Doppler radar has been developed in conjunction with the joint FAA/NASA Wind Shear Program. This radar represents a first in an emerging technology. The radar was developed to assess the applicability of an airborne radar to detect low altitude hazardous wind shears for civil aviation applications. Such a radar must be capable of looking down into the ground clutter environment and extracting wind estimates from relatively low reflectivity weather targets. These weather targets often have reflectivities several orders of magnitude lower than the surrounding ground clutter. The NASA radar design incorporates numerous technological and engineering achievements in order to accomplish this task. The basic R/T unit evolved from a standard Collins 708 weather radar, which supports specific pulse widths of 1-7 microns and Pulse Repetition Frequencies (PRF) of less than 1-10 kHz. It was modified to allow for the output of the first IF signal, which fed a NASA developed receiver/detector subsystem. The NASA receiver incorporated a distributed, high-speed digital attenuator, producing a range bin to range bin automatic gain control system with 65 dB of dynamic range. Using group speed information supplied by the aircraft's navigation system, the radar signal is frequency demodulated back to base band (zero Doppler relative to stationary ground). The In-phase & Quadrature-phase (I/Q) components of the measured voltage signal are then digitized by a 12-bit A-D converter (producing an additional 36 dB of dynamic range). The raw I/Q signal for each range bin is then recorded (along with the current radar & aircraft state parameters) by a high-speed Kodak tape recorder.

Harrah, S. D.↗

The dynamical state of RXCJ1230.7+3439: A multi-substructured merging galaxy cluster

We analyse the kinematical and dynamical state of the galaxy cluster RXCJ1230.7+3439 (RXCJ1230), at $z$ = 0.332 using 93 new spectroscopic redshifts of galaxies acquired at the Telescopio Nazionale Galileo and from SDSS DR16 public data. We study the density galaxy distribution retrieved from photometric SDSS multiband data and find that RXCJ1230 appears as a clearly isolated peak in the redshift space, with a global line-of-sight (LOS) velocity dispersion of $σ$ v = 1004 -122 +147 km s -1 . Several tests applied to the spatial and velocity distributions reveal that RXCJ1230 is a complex system with the presence of three subclusters, located to the southwest, east, and south with respect to the main body of the cluster, containing several bright galaxies (BGs) in their respective cores. Our analyses confirm that the three substructures are in a pre-merger phase, where the main interaction takes place with the southwest subclump, almost in the plane of the sky. We compute a velocity dispersion of $σ$ v ~ 1000 and $σ$ v ~ 800 km s -1 for the main cluster and the southwest substructure, respectively. The central main body and southwest substructure differ by ~870 km s -1 in the LOS velocity. From these data, we estimate a dynamical mass of $M$ 200 = 9.0 ± 1.5 × 1014 $M$ ⊙ and 4.4 ± 3.3 × 1014 $M$ ⊙ for the RXCJ1230 main body and southwest clump, respectively, which reveals that the cluster will undergo a merger characterised by a 2:1 mass ratio impact. We solve a two-body problem for this interaction and find that the most likely solution suggests that the merging axis lies ~17° from the plane of the sky and the subcluster will fully interact in ~0.3 Gyr. However, a slight excess in the X-ray temperature observed in the southwest clump confirms a certain degree of interaction already. The comparison between the dynamical masses and those derived from X-ray data reveals good agreement within errors (differences ~15%), which suggests that the innermost regions (< r 500 ) of the galaxy clumps are almost in hydrostatical equilibrium. In summary, RXCJ1230 is a young but also massive cluster in a pre-merging phase accreting other galaxy systems from its environment.

79 ASTRONOMY AND ASTROPHYSICS↗

Operational Benefits of Meeting California's Energy Storage Targets

In October 2013, the California Public Utilities Commission (CPUC) finalized procurement targets and other requirements to its jurisdictional utilities for a minimum of 1,325 MW of 'viable and cost-effective' energy storage systems by 2020. The goal of this study is to explore several aspects of grid operations in California and the Western Interconnection resulting from meeting the CPUC storage targets. We perform this analysis using a set of databases and grid simulation tools developed and implemented by the CPUC, the California Independent System Operator (CAISO), and the California Energy Commission (CEC) for the CPUC's Long-term Procurement Plan (LTPP). The 2014 version of this database contains information about generators, storage, transmission, and electrical demand, for California in the year 2024 for both 33% and 40% renewable energy portfolios. We examine the value of various services provided by energy storage in these scenarios. Sensitivities were performed relating to the services energy storage can provide, the capacity and duration of storage devices, export limitations, and negative price floor variations. Results show that a storage portfolio, as outlined by the CPUC, can reduce curtailment and system-wide production costs for 33% and 40% renewable scenarios. A storage device that can participate in energy and ancillary service markets provides the grid with the greatest benefit; the mandated storage requirement of 1,325 MW was estimated to reduce the total cost of production by about 78 million per year in the 33% scenario and 144 million per year in the 40% scenario. Much of this value is derived from the avoided start and stop costs of thermal generators and provision of ancillary services. A device on the 2024 California grid and participating in only ancillary service markets can provide the system with over 90% of the value as the energy and ancillary service device. The analysis points to the challenge of new storage providing regulation reserve, as the added storage could provide about 75% of the regulation up requirement for all of California, which would likely greatly reduce regulation prices and potential revenue. The addition of storage in California decreases renewable curtailment, particularly in the 40% RPS case. Following previous analysis, storage has a mixed impact on emissions, generally reducing emissions, but also creating additional incentives for increased emissions from out-of-state coal generations. Overall, storage shows significant system cost savings, but analysis also points to additional challenges associated with full valuation of energy storage, including capturing the operational benefits calculated here, but also recovering additional benefits associated avoided generation, transmission, and distribution capacity, and avoided losses.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Valuation of Hydrogen Technology on the Electric Grid Using Production Cost Modeling: Cooperative Research and Development Final Report, CRADA Number CRD-18-00736

This research project will estimate the value to the United States electric grid of deploying hydrogen technology (such as electrolyzers and hydrogen-fueled generation) under projected conditions of high renewable penetration. The analysis will advance the state of the art in systems-level cost-benefit analysis of hydrogen technology for the electric grid by incorporating production cost modeling results in the analysis. Large-scale grid simulation tools will be used to evaluate total system production cost and grid operation when hydrogen technology is deployed for applications such as energy storage and demand response. Scenarios will include one or more future grid mixes in the Western Interconnect (WI) with a high proportion of intermittent renewables. Electric Power Research Institute (EPRI) will work with four utility companies to refine scenarios. Results of the analysis will include comparing the net cost of hydrogen to other technologies for long duration storage, and of power-to-gas (P2G) scenarios including merchant hydrogen sale and hydrogen-fueled generation.

08 HYDROGEN↗

The Value of Increased HVDC Capacity Between Eastern and Western U.S. Grids: The Interconnections Seam Study

The Interconnections Seam Study examines the potential economic value of increasing electricity transfer between the Eastern and Western Interconnections using high-voltage direct-current (HVDC) transmission and cost-optimizing both generation and transmission resources across the United States, proposing, assessing, justifying, and illustrating a major infrastructure change involving two of the worlds largest power grids. The study conducted a multi-model analysis that used co-optimized generation and transmission expansion planning and production cost modeling. Four transmission designs under eight scenarios were developed and studied to estimate costs and potential benefits. The results show benefit-to-cost ratios that reach as high as 2.5, indicating significant value to increasing the transmission capacity between the interconnections under the cases considered, realized through sharing generation resources and flexibility across regions.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Distributed Mafic Rock Resources for Carbon Mineralization in Arizona

Ex-situ carbon mineralization is a process by which CO2 is reacted with alkaline silicate minerals and rocks to produce stable carbonate materials, which can be used for other industrial processes. Arizona, U.S.A., hosts abundant surficial mafic rocks in three young volcanic fields, Geronimo-San Bernardino, San Francisco, and Springerville, and other distributed locations throughout the state. We created a Mafic Rock Resource Inventory (MRRI) that categorizes geochemical, physical, and textural characteristics of a diverse suite of surficial mafic rock samples and provide a benchmark reaction dataset parameterizing the temperature, pressure, and pH conditions best suited ex-situ mineralization in different rock types. MRRI data is publicly available online via a map-viewer. We establish two reaction condition sets, varied in temperature, pressure, and pH, where crystal-rich and glassy rocks reach maximum reaction extent and different carbonate phases are formed. Systematic ex-situ mineralization experiments on 21 diverse rock types show trends in geochemical, mineralogical, and reactivity behavior and establish maximum effective capture capacity. From this, scoria cones in three Arizona volcanic fields have a ~62 Gt effective CO₂ storage capacity with one of the fields having a ~42 Gt storage capacity in lava flows. Reactivity results have applications to alkaline mafic rock resources exposed globally, including producing additional effective storage capacity estimates and scaled commercialization of mafic rock ex-situ mineralization, should reaction extents be improved through advances in mineralization techniques. MRRI data were used to create a Direct Air Capture to Mineralization (DACM) systems model, technoeconomic analysis, and life-cycle assessment. These documents are presented as three appendices.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Structural Weight Estimation for Launch Vehicles

This paper describes some of the work in progress to develop automated structural weight estimation procedures within the Vehicle Analysis Branch (VAB) of the NASA Langley Research Center. One task of the VAB is to perform system studies at the conceptual and early preliminary design stages on launch vehicles and in-space transportation systems. Some examples of these studies for Earth to Orbit (ETO) systems are the Future Space Transportation System [1], Orbit On Demand Vehicle [2], Venture Star [3], and the Personnel Rescue Vehicle[4]. Structural weight calculation for launch vehicle studies can exist on several levels of fidelity. Typically historically based weight equations are used in a vehicle sizing program. Many of the studies in the vehicle analysis branch have been enhanced in terms of structural weight fraction prediction by utilizing some level of off-line structural analysis to incorporate material property, load intensity, and configuration effects which may not be captured by the historical weight equations. Modification of Mass Estimating Relationships (MER's) to assess design and technology impacts on vehicle performance are necessary to prioritize design and technology development decisions. Modern CAD/CAE software, ever increasing computational power and platform independent computer programming languages such as JAVA provide new means to create greater depth of analysis tools which can be included into the conceptual design phase of launch vehicle development. Commercial framework computing environments provide easy to program techniques which coordinate and implement the flow of data in a distributed heterogeneous computing environment. It is the intent of this paper to present a process in development at NASA LaRC for enhanced structural weight estimation using this state of the art computational power.

Cerro, Jeff↗