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Stratospheric aerosol samples were collected using a wire impactor during the year following the eruption of Mt. St. Helens. Analysis of samples shows that aerosol volume increased for 6 months due to gas-to-particle conversion and then decreased to background levels in the following 6 months.
Gas in spiral galaxies cycles between the diffuse and dense phases as clouds collapse, form stars and are dispersed back into the ISM. Far infrared observations of continuum emission from interstellar dust and line emission from interstellar gas have revealed a wealth of information on the state of the ISM in galaxies of different morphological types. The analysis of these observations gives us information about the processes of star formation and about the evolution of the ISM. Star formation rates vary widely from galaxy to galaxy, with the rates in starburst galaxies being 10 - 100 times those in quiescent spiral galaxies. Far infrared spectroscopy of star-forming galaxies shows that the interstellar pressure increases with star formation rate. The structure of the interstellar medium in starburst galaxies is quite different from that of quiescent galaxies - much of the mass and volume are in HII regions and photodissociation regions. The size distribution of dust grains seems to depend on environment; small grains are abundant in the diffuse interstellar medium but not in dense molecular star forming regions. Quiescent spiral and elliptical galaxies contain a significant population of small grains, but starburst galaxies do not. Dwarf irregular galaxies also seem to contain few small grains; this may be the result of the higher UV flux in these galaxies. The star forming regions in dwarf irregulars also have a higher ratio of atomic to molecular gas than do those in the Galaxy. These results show that the ISM in galaxies of different morphological types reaches different equilibria, resulting in different modes of star formation and global galaxy evolution.
The properties of the pion-pion collision in the GeV region are examined in order to provide insights into the behavior of matter at densities greater than 100 Teragrams per cu cm. The predictions based on the Landau model are used to decide upon the value for the speed of sound in the expression pressure equals c(s) squared times the energy density, where c(s) is the speed of sound expressed in units of c. Several pion-pion Lagrangians are analyzed for their predictions on the value of c(s) squared. The fundamental assumption of the Landau model, namely, the laminar nature of the flow, is investigated. It is found that the hadronic matter can become turbulent in the later stages of evolution when Reynolds number of about 4,000 is reached, which gives rise to the possibility of identifying the observed tendency of the pion gas to cluster with the eddies that characterize any turbulent flow.
The current status of extreme ultraviolet (EUV) astrophysics is reviewed. Seven compact emitters of EUV radiation have been identified in the less than or equal to 5% of the sky surveyed randomly so far and the existence of a diffuse EUV background firmly established. The discussion will focus on the quality of astronomical information that can be gleaned from a combined X-ray, EUV, far UV and optical study of these objects and on the impact EUV observations of the sun and a large number of classes of compact objects will have on understanding the structure and evolution of evolved stars. The diffuse EUV background may be of even greater interest as it probably reveals the distribution of the hot coronal gas responsible for the interstellar OVI absorption and the source of heating and ionization of the interstellar medium.
With regard to the galactodynamics of the cloudy interstellar medium, the paper considers the response of such a gas to a forcing potential in the tight-winding density wave theory. The cloud fluid is treated in the hydrodynamic limit with an equation of state which softens at high densities. It is shown that in the inner regions of the galaxy, cooling of the cloud fluid in the arms can result in gravitational instability and the formation of large bound complexes of clouds which are identified with the giant molecular clouds (GMCs). Masses, dimensions, distributions, and scale heights of the GMCs are predicted by the theory. It is suggested that the interstellar gas density in the disk is regulated by the gravitational instability mechanism in the arms which siphons material into star formation. Implications for the evolution of individual GMCs and for galactic morphology are discussed.
Several authors have shown that massive stars exploding at a rate of about three per century can account for a large portion, if not all, of the observed interstellar Al-26. In a separate argument using models of Galactic chemical evolution, Clayton (1984) showed that the Al-26/Al-27 production ratio was not large enough to maintain enough Al-26 in the Galactic disk gas of about 10 exp 10 solar masses having solar composition. We present a resolution of those conflicting arguments. A past history of Galactic infall growing the Galactic disk so dilutes the stable Al-27 concentration that the two approaches can be brought into near agreement. If massive stars dominate the production of Al-26, we suggest that the apparent shortfall of their Al-26/Al-27 yield ratio is to be interpreted as evidence for significant growth of the Galactic disk. We also discuss the implications of these arguments for other extinct radioactivities in meteorites, using I-129 and Sm-146 as examples.
The goal of these ROSAT PSPC pointed observations was to understand the nature of X-ray emission associated clusters that contain luminous wide-angle tailed (WAT) radio sources identified with the centrally dominant cluster galaxies. These 500 kpc diameter radio sources are strongly affected by confinement and interaction with the intracluster medium. So, a complete picture of the origin and evolution of these radio sources is not possible without detailed X-ray observations which sample the distribution and temperature of the surrounding hot gas. Two WAT clusters have been observed with the ROSAT PSPC to date. The first is Abell 2634 which contains the WAT 3C 465 and was approved for observations in AO-1. Unfortunately, these observations were broken into two widely separated pieces in time. The first data set containing about 9000 sec of integration arrived in mid-March, 1992. The second data set containing about 10,500 sec arrived just recently in early April (after a first tape was destroyed in the mail). The second cluster is 1919+479 which was approved for observations in AO-2. These ROSAT data arrived in October 1992.
The implications of recent near-infrared imaging and spectroscopy of the Galactic center stellar cluster are discussed. The central parsec appears to be powered by a cluster of hot, massive stars of which the IRS 16 complex is the central core. In the 1 to 2 micrometer band, the brightest members of this cluster are 10 to 15 HeI/HI emission line stars that can be characterized as approximately 20000 K, helium rich, very luminous supergiants. The He-I/H-I stars can account for a major fraction of the total and Lyman continuum luminosity of the central parsec, but hotter, earlier type stars are probably required in addition to account for the He-continuum. The brightest cool stars in the central parsec are red supergiants, and asymptotic giant branch stars. Two scenarios for the evolution of the central stellar core are presented: one involves a small star formation burst years ago that was the result of substantial prior gas influx into the core. In this scenario the Galactic center is presently in a short-lived, post-main sequence 'wind phase'. The second scenario involves the buildup of massive stars by sequential merging of lower mass stars. The intense mass loss from the hot stars probably affects strongly the gas dynamics in the central 0.1 pc and may prevent gas to accelerate onto the possible central hole.
A two-part symposium was held concerning topics in Solar System chemistry. The first part covered the organic chemistry ofsmall bodies of the interplanetray medium. It produced papers on the evolution, spectral properties and composition of organic matter in comets, interplanetary dust and asteroids. The second part covered cryochemistry and exobiology in planetary atmospheres (gas giant planets and their satellites) and in various astronomical ices.
CaAl rich refractory mineral inclusions (CAIs) found at 1 - 10% mass fraction in primitive chondrites appear to be several million years older than the dominant (chondrule) components in the same parent bodies. A prevalent concern is that it is difficult to retain CAIs for this long against gas-drag-induced radial drift into the sun. We assess a hot inner (turbulent) nebula context for CAI formation, using analytical models of nebula evolution and particle diffusion. We show that outward radial diffusion in a weakly turbulent nebula can prevent significant numbers of CAI-size particles from being lost into the sun for times of 1 - 3 x 10(exp 6) years. To match the CAI abundances quantitatively, we advocate an enhancement of the inner hot nebula in silicate-forming material, due to rapid inward migration of very primitive, silicate and carbon rich, meter-sized objects. 'Combustion' of the carbon into CO would make the CAI formation environment more reduced than solar, as certain observations imply. Abundant CO might also play a role in mass-independent chemical fractionation of oxygen isotopes as seen in CAIs and associated primitive, high-temperature condensates.
Porous materials are ubiquitous in the universe and weathering of porous surfaces plays an important role in the evolution of planetary and interstellar materials. Sputtering of porous solids in particular can influence atmosphere formation, surface reflectivity, and the production of the ambient gas around materials in space, Several previous studies and models have shown a large reduction in the sputtering of a porous solid compared to the sputtering of the non-porous solid. Using molecular dynamics simulations we study the sputtering of a nanoporous solid with 55% of the solid density. We calculate the electronic sputtering induced by a fast, penetrating ion, using a thermal spike representation of the deposited energy. We find that sputtering for this porous solid is, surprisingly, the same as that for a full-density solid, even though the sticking coefficient is high.
The Sample Analysis at Mars (SAM) and Chemistry and Mineralogy (CheMin) instruments on the Mars Science Laboratory (MSL) analysed several subsamples of <150 μm fines from five sites at Gale Crater. Three were in Yellowknife Bay: the Rocknest aeolian bedform ("RN") and drilled Sheepbed mudstone from sites John Klein ("JK") and Cumberland ("CB"). One was drilled from the Windjana ("WJ") site on a sandstone of the Kimberly formation investigated on route to Mount Sharp. Another was drilled from the Confidence Hills ("CH") site on a sandstone of the Murray Formation at the base of Mt. Sharp (Pahrump Hills). Outcrops are sedimentary rocks that are largely of fluvial or lacustrine origin, with minor aeolian deposits.. SAM's evolved gas analysis (EGA) mass spectrometry detected H2O, CO2, O2, H2, SO2, H2S, HCl, NO, and other trace gases, including organic fragments. The identity and evolution temperature (T) of evolved gases can support CheMin mineral detection and place constraints on trace volatile-bearing phases or phases difficult to characterize with XRD (e.g., X-ray amorphous phases). They can also give constraints on sample organic chemistry. Here, we discuss trends in major evolved volatiles from SAM EGA analyses to date.
Excitation of iron pentacarbonyl [Fe(CO) 5 ], a prototypical photocatalyst, at 266 nm causes the sequential loss of two CO ligands in the gas phase, creating catalytically active, unsaturated iron carbonyls. Despite numerous studies, major aspects of its ultrafast photochemistry remain unresolved because the early excited-state dynamics have so far eluded spectroscopic observation. This has led to the long-held assumption that ultrafast dissociation of gas-phase Fe(CO) 5 proceeds exclusively on the singlet manifold. Herein, we present a combined experimental–theoretical study employing ultrafast extreme ultraviolet transient absorption spectroscopy near the Fe M 2,3 -edge, which features spectral evolution on 100 fs and 3 ps time scales, alongside high-level electronic structure theory, which enables characterization of the molecular geometries and electronic states involved in the ultrafast photodissociation of Fe(CO) 5 . We assign the 100 fs evolution to spectroscopic signatures associated with intertwined structural and electronic dynamics on the singlet metal-centered states during the first CO loss and the 3 ps evolution to the competing dissociation of Fe(CO) 4 along the lowest singlet and triplet surfaces to form Fe(CO) 3 . Calculations of transient spectra in both singlet and triplet states as well as spin–orbit coupling constants along key structural pathways provide evidence for intersystem crossing to the triplet ground state of Fe(CO) 4 . Finally, our work presents the first spectroscopic detection of transient excited states during ultrafast photodissociation of gas-phase Fe(CO) 5 and challenges the long-standing assumption that triplet states do not play a role in the ultrafast dynamics.
Rocket plume-surface interaction is a multi-phase, complex discipline characterized by plume flow physics, erosion physics, and ejecta dynamics. To provide critical data for the validation of predictive modeling capabilities, an inert-gas, subscale ground test has been designed, with one test phase focused on cratering and ejecta and another test phase focused on plume structure and behavior. Using a supersonic, heated N2 jet impinging onto six different mechanical regolith simulants, visual data on the temporal evolution of cratering and ejecta are collected in a vacuum chamber at ambient pressures ranging from 600 Pa down to approximately 7 Pa. Using the same N2 jet impinging onto an instrumented plate, NO planar laser-induced fluorescence data are obtained at lower ambient pressures for the validation of both continuum and rarefied gas-phase physics. This paper discusses the design of this test and data products, with emphasis on the cratering and ejecta experiments, along with the physical scaling, challenges, and relevance of these data to the maturation of the plume-surface interaction discipline.
Radiochemical neutron concentration analysis was used to determine Ag, Au, Bi, Cd, Co, Cs, Ga, In, Rb, Sb, Se, Te, Tl, and Zn contents in consortium samples of solar gas and track-rich dark matrix. Data obtained confirmed that the matrix is chemically homogeneous. Most dark clasts had similar mean trace element concentrations as the matrix but were compositionally much more heterogeneous. It is concluded that material incorporated with soil and compacted to form the dark portion of Fayetteville included soil-melt, the odd C2M fragment, and dark and light clasts which escaped comminution.
Helium evolution from the transfer of helium-saturated propellant in space is quantified to assess its impacts from creating two-phase gas/liquid flow from the supply tank, gas injection into the receiving tank, and liquid discharge from the receiving tank. Propellant transfer takes place between two similar tanks whose maximum storage capacity is approximately 2.55 cubic meters each. The maximum on-orbit propellants transfer capability is 9000 lbm (fuel and oxidizer). The transfer line is approximately 1.27 cm in diameter and 6096 cm in length and comprised of the fluid interconnect system (FICS), the orbiter propellant transfer system (OPTS), and the International Space Station (ISS) propulsion module (ISSPM). The propellant transfer rate begins at approximately 11 liter per minute (lpm) and subsequently drops to approximately 0.5 lpm. The tank nominal operating pressure is approximately 1827 kPa (absolute). The line pressure drops for Monomethy1hydrazine (MMH) and Nitrogen tetroxide (NTO) at 11.3 lpm are approximately 202 kPa and 302 kPa, respectively. The pressure-drop results are based on a single-phase flow. The receiving tank is required to vent from approximately 1827 kPa to a lower pressure to affect propellant transfer. These pressure-drop scenarios cause the helium-saturated propellants to release excess helium. For tank ullage venting, the maximum volumes of helium evolved at tank pressure are approximately 0.5 ft3 for MMH and 2 ft3 for NTO. In microgravity environment, due to lack of body force, the helium evolution from a liquid body acts to propel it, which influences its fluid dynamics. For propellant transfer, the volume fractions of helium evolved at line pressure are 0.1% by volume for MMH and 0.6 % by volume for NTO at 11.3 lpm. The void fraction of helium evolved varies as an approximate second order power function of flow rate.
Recently developed solutions of problems are discussed that were traditionally considered fundamental in classical solar system cosmogony: determination of planetary orbit distribution patterns, values for mean eccentricity and orbital inclinations of the planets, and rotation periods and rotation axis inclinations of the planets. Two important cosmochemical aspects of accumulation are examined: the time scale for gas loss from the terrestrial planet zone, and the composition of the planets in terms of isotope data. It was concluded that the early beginning of planet differentiation is a function of the heating of protoplanets during collisions with large (thousands of kilometers) bodies. Energetics, heat mass transfer processes, and characteristic time scales of these processes at the early stages of planet evolution are considered.
Context . The 1.8 MeV γ -rays corresponding to the decay of the radioactive isotope 26 Al (with a half-life of 0.72 Myr ) have been observed by the SPI detector on the INTEGRAL spacecraft and extensively used as a tracer of star formation and current nucleosynthetic activity in the Milky Way Galaxy. Further information is encoded in the observation related to the higher 26 Al content found in regions of the Galaxy with the highest line-of-sight (LoS) velocity relative to an observer located in the Solar System. However, this feature remains unexplained. Aims . We ran a cosmological “zoom-in” chemodynamical simulation of a Milky Way-type galaxy, including the production and decays of radioactive nuclei in a fully self-consistent way. We then analyzed the results to follow the evolution of 26 Al throughout the lifetime of the simulated galaxy to provide a new method for interpreting the 26 Al observations. Methods . We included the massive star sources of 26 Al in the Galaxy and its radioactive decay into a state-of-the-art galactic chemical evolution model, coupled with cosmological growth and hydrodynamics. This approach allowed us to follow the spatial and temporal evolution of the 26 Al content in the simulated galaxy. Results . Our results are in agreement with the observations with respect to the fact that gas particles in the simulation with relatively higher 26 Al content also have the highest LoS velocities. On the other hand, gas particles with relatively lower 26 Al content (i.e., not bright enough to be observed) generally display the lowest LoS velocities. However, this result is not conclusive because the overall rotational velocity of our simulated galaxy is higher than that observed for cold CO gas in the Milky Way Galaxy. Furthermore, we found no significant correlation between gas temperature, rotational velocity, and 26 Al content at any given radius. We also found the presence of transient 26 Al-rich spots at low LoS velocities and we show that one such spot had been captured by the INTEGRAL/SPI data. Based on our model, we present a prediction for the detection of 1.8 MeV γ -rays by the future COSI mission. We find that according to our model, the new instrument will be able to observe similar 26 Al-emission patterns to those seen by INTEGRAL/SPI.