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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 793 records · Page 44
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Improvement of the performance parameters of the surface plasmon resonance biosensor using Al{sub 2}O{sub 3} and WS{sub 2}

Here, proposed Kretschmann configuration based surface plasmon resonance biosensor shows immense improvement in its performance parameters. This highly sensitive biosensor provides a higher value of quality factor and detection accuracy. We presented a five-layer model of a biosensor with two dimensional transition metal di-chalcogenides Tungsten disulfide (WS2) in addition with Al2O3 layer. By using one layer of WS2 with six layers of Al2O3, the highest sensitivity (227.5 °/RIU), detection accuracy (1.1123), and quality factor (28.26 RIU{sup −1}) can be achieved. CaF2 as coupling prism has also played a remarkable role in enhancing the performance parameters for its low refractive index.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

Surface plasmons at the interface of metamaterial and topological insulator

We investigate the propagation of surface plasmon polaritons (SPPs) at the boundary of metamaterial and topological insulators. Instances of Bi{sub 2}Se{sub 3}, Bi{sub 2}Te{sub 3} and metamaterial boundaries are investigated. The topological insulators under consideration are three dimensional topological insulators of the second generation. Dispersion relations, absorption characteristics and propagation lengths of SPPs are calculated. The variation of bulk dielectric functions of topological insulators and metamaterial is considered by means of the Drude model and effective medium approximation theory. The key parameters making a dramatic impact on propagation lengths are acknowledged and mechanisms for engineering dispersion properties are suggested.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Tunable near-perfect absorption through interaction between localized surface plasmons modes in optical metamaterials

A hybrid metamaterial absorber is designed and simulated in 4.0–6.0 μm region based on temperature sensitive material vanadium dioxide (VO{sub 2}). A broad absorption band (bandwidth is 0.28 μm) is achieved based on two local surface plasmon (LSP) modes resonance at room temperature. The effective parameter calculation results indicate that near ideally impedance matching condition is achieved in the absorption band. The absorption band is expanded and shifted to longer resonance wavelength with the lattice constant reducing or the size of central metal particle increasing. Furthermore, new resonant absorption behaviors are achieved through rising the simulated temperature. A new absorption peak is obtained due to the coupled between LSP modes, which are excited on edges of VO{sub 2} particles, while the original absorption band is shifted to longer resonance wavelength.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

Design, optimization and critical analysis of graphene based surface plasmon resonance sensor for DNA hybridization

In this paper, the design, optimization and critical analysis of Surface Plasmon Resonance sensor is presented, which works on angular interrogation method. It comprises of five layers which are “Prism–Copper–Germanium–Graphene–Sensing medium”. The influence of the chemical potential (µ{sub c}) of graphene on the sensor performance has been studied in detail. Thickness of all the layers has been optimized. Remarkable results are achieved for the optimal thickness of copper and germanium layers as 50 nm and 6 nm respectively, while two layers of graphene having µ{sub c} of 0.5 eV are introduced to boost-up the performance. Best results in terms of detection accuracy, sensitivity and quality factor have been achieved that fulfill the necessary requirements for good sensing applications.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

Design and analysis of a plasmonic demultiplexer based on band-stop filters using double-nanodisk-shaped resonators

In this paper, a two-channel plasmonic wavelength demultiplexer (PWDM) based on band-stop filters (BSF) using double-nanodisk-shaped resonators is proposed. The structure is numerically simulated using finite difference time domain method. First, a BSF is considered for modeling which supports three modes. Then, the effect of various structural parameters of the proposed PWDM is studied on the transmission properties in detail. The results show that the transmission properties of our PWDM are highly dependent on geometric parameters. The proposed structure provides a single-mode spectrum on each of the output ports with a maximum quality factor as high as 105 (FWHM = 7.7 nm). To this end, we illustrate that the concerning published research in this field, the significant privilege of our proposed PWDM structure is in terms of its good transmission efficiency, lowest FWHM and highest quality factor. Hence, such an arrangement is easy to fabricate and it has the potential for use in all-optical ultra-compact circuits and devices.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2016

Two-qubit correlations via a periodic plasmonic nanostructure

We theoretically investigate the generation of quantum correlations by using two distant qubits in free space or mediated by a plasmonic nanostructure. We report both entanglement of formation as well as quantum discord and classical correlations. We have found that for proper initial state of the two-qubit system and distance between the two qubits we can produce quantum correlations taking significant value for a relatively large time interval so that it can be useful in quantum information and computation processes.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2018

A unified approach to Plasmon–Polariton and Brewster mode dynamics in media with interfacial surface-admittance

In this article we develop an ab-initio formulation for the analysis of certain solutions to the macroscopic Maxwell equations in bulk homogeneous materials that are separated by a planar interface that may sustain field-dependent electric currents induced by a surface admittance tensor. Based on Clemmow’s description of complex inhomogeneous plane time-harmonic waves, a systematic procedure is given that yields particular global solutions in terms of solutions to a system of bivariate polynomial and linear eigen-value equations for a set of six complex dimensionless scalars. This algebraic system is amenable to rapid numerical analysis using Maple or Matlab on a laptop. From the resulting solutions, analytic formulae for the electromagnetic fields can be expressed in terms of values for these six scalars and the electromagnetic phenomenological properties of the bulk media and their interface. We show explicitly how general properties of Surface Plasmon–Polariton (SPP) and Brewster modes follow from this unified viewpoint without appeal to any reflections in a Fresnel formulation. In particular we emphasise that endowing the material interface with (in general) anisotropic admittance properties can lead to new global electromagnetic field characteristics offering new possibilities for the control of surface characteristics by using recent advances in the fabrication of meta-materials. We illustrate our results by showing how a mono-layer of graphene in a normal magneto-static field can be used to construct a tunable meta-surface for SPP generation and how a simple conducting Ohmic interface can be used to excite both transverse electric and transverse magnetic Brewster modes as a function of the interface admittance.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2016

Gold-plasmon enhanced photocatalytic performance of anatase titania nanotubes under visible-light irradiation

Highlights: • APTMS/(TNTs-Au) was synthesized using a deposition-precipitation process. • APTMS/(TNTs-Au) showed superior visible light activity for the degradation of methylene blue. • The electromagnetic field distribution at the interface between TNTs and Au NPs were estimated by the 3D finite-difference time domain simulation. • The working mechanism of the photocatalytic activity of APTMS/(TNTs-Au) was illustrated. - Abstract: [3-Aminopropyl]trimethoxysilane-modified titania nanotubes decorated with Au nanoparticles (APTMS/(TNTs-Au)) nanocomposites were synthesized using a deposition-precipitation process. The results showed that Au nanoparticles (NPs) in the metallic state were firmly adhered to the surface of the anatase TNTs. APTMS/(TNTs-Au) exhibited great photocatalytic activities which were evaluated from the degradation rate of methylene blue aqueous solution under visible light irradiation. 3D finite-difference time domain simulation was performed to estimate the electromagnetic field distribution at the interface between TNTs and Au NPs. The visible photocatalytic activity of APTMS/(TNTs-Au) was largely attributed to the surface plasmon absorption of metallic Au NPs, which generated and transferred hot electrons to the CB of TNTs. In addition, the hot electrons on the surface of TNTs also suppressed the radiative electron–hole recombination and consequently enhanced the photocatalytic activity.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Selective Plasmon-Induced Oxidation of 4-Aminothiophenol on Silver Nanoparticles

Selectivity in plasmonic chemistry is typically achieved using bimetallic nanostructures. Herein, we show that monometallic silver nanoparticles can also drive highly selective interfacial transformations, oxidation reactions particularly. This is illustrated through a close inspection of tip-enhanced Raman spectral images of 4-aminothiophenol (ATP)-functionalized Au vs Ag nanoparticles. Further, we find that whereas the thoroughly described dimerization reaction to form 4,4’-dimercaptoazobenzene dominates the response on Au, highly selective oxidation on Ag nanoparticles exclusively leads to 4-nitrothiophenol. We explore the origin of the distinct reaction pathways on Ag vs Au nanostructures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Electroluminescence and Plasmon-Assisted Directional Photoluminescence from 2D HgTe Nanoplatelets

In the visible range, 2D nanoplatelets (NPLs) have brought significant benefits compared to their 0D counterpart with an inherently anisotropic emission, a narrower photoluminescence (PL) signal, and new degrees of freedom to design heterostructures. Compared to the properties of cadmium chalcogenide NPLs in the visible, similar research is still mostly lacking in the infrared, in spite of existing synthetic paths to obtain narrow band gap semiconductors in 2D colloidal form. Here, in this paper, we focus on 2D HgTe NPLs and show how their PL can be stabilized through the proper choice of surface chemistry. We then demonstrate two important steps toward bright infrared light emitting diodes (LEDs) which are (i) the coupling to a plasmonic grating to control the magnitude and spatial direction of the PL signal and (ii) the observation of electroluminescence at 1300 nm, which is near telecom wavelength.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Au 329– x Ag x (SR) 84 Nanomolecules: Plasmonic Alloy Faradaurate-329

Though significant progress has been made to improve the monodispersity of larger (>10 nm) alloy metal nanoparticles, there still exists a significant variation in nanoparticle composition, ranging from ±1000s of atoms. Here in this paper, for the first time, we report the synthesis of atomically precise (±0 metal atom variation) Au 329–x Ag x (SCH 2 CH 2 Ph) 84 alloy nanomolecules. The composition was determined using high resolution electrospray ionization mass sp ectrometry. In contrast to larger (>10 nm) Au–Ag nanoparticles, the surface plasmon resonance (SPR) peak does not show a major shift, but a minor ~10 nm red-shift, upon increasing silver content. The intensity of the SPR peak also varies in an intriguing manner, where a dampening is observed with medium silver incorporation, and a significant sharpening is observed upon higher Ag content. The report outlines (a) an unprecedented advance in nanoparticle mass spectrometry of high mass at atomic precision; and (b) the unexpected optical behavior of Au–Ag alloys in the region where nascent SPR emerges; specifically, in this work, the SPR-like peak does not show a major ~100 nm blue-shift with Ag alloying of Au 329 nanomolecules, as shown to be common in larger nanoparticles.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Long-Range Dipole–Dipole Interactions in a Plasmonic Lattice

Spontaneous emission of quantum emitters can be enhanced by increasing the local density of optical states, whereas engineering dipole-dipole interactions requires modifying the two-point spectral density function. Here, we experimentally demonstrate long-range dipole-dipole interactions (DDIs) mediated by surface lattice resonances in a plasmonic nanoparticle lattice. Using angle-resolved spectral measurements and fluorescence lifetime studies, we show that unique nanophotonic modes mediate long-range DDI between donor and acceptor molecules. We observe significant and persistent DDI strengths for a range of densities that map to similar to 800 nm mean nearest-neighbor separation distance between donor and acceptor dipoles, a factor of similar to 100 larger than free space. Here, our results pave the way to engineer and control long-range DDIs between an ensemble of emitters at room temperature.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2024

Localized Plasmonic Heating for Single-Molecule DNA Rupture Measurements in Optical Tweezers

To date, studies on the thermodynamic and kinetic processes that underlie biological function and nanomachine actuation in biological- and biology-inspired molecular constructs have primarily focused on photothermal heating of ensemble systems, highlighting the need for probes that are localized within the molecular construct and capable of resolving single-molecule response. Here we present an experimental demonstration of wavelength-selective, localized heating at the single-molecule level using the surface plasmon resonance of a 15 nm gold nanoparticle (AuNP). Our approach is compatible with force-spectroscopy measurements and can be applied to studies of the single-molecule thermodynamic properties of DNA origami nanomachines as well as biomolecular complexes. We further demonstrate wavelength selectivity and establish the temperature dependence of the reaction coordinate for base-pair disruption in the shear-rupture geometry, demonstrating the utility and flexibility of this approach for both fundamental studies of local (nanometer-scale) temperature gradients and rapid and multiplexed nanomachine actuation.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2025

Exploiting Intersubband Plasmons in Vertically Aligned Carbon Nanotubes for Near-Infrared Electrochromic Windows

Optically transparent materials with switchable near-infrared (NIR) transmissivity are of significant interest for energy-saving smart window technologies. To this end, we demonstrate that semitransparent films of vertically aligned carbon nanotubes (CNTs) incorporated into electrochemically gated devices exhibit NIR transmittance changes up to 47% and bistable optical states that are appealing for low-power, large-area operation. The tunable NIR electrochromic response is driven by a doping-induced intersubband plasmon (ISBP) absorption, an optical feature in CNTs that is selective to light polarized perpendicular to the CNT axis. Vertically aligned CNT films (as opposed to more conventional planar CNT mats) thus allow us to isolate and study the ISBP resonance changes with applied voltage, electrode material, and film thickness.

absorption↗
DOE OSTI2026

Inexpensive Hydrogen Storage: Propylene to Propane using Plasmonic Photocatalysis

Chemistry-based hydrogen storage media, such as liquid organic hydrogen carriers, offer an attractive alternative to physical hydrogen storage solutions. Here, we investigate propane as a possible hydrogen storage medium, attractive for its low cost and ease of availability. We report the ambient temperature and pressure hydrogenation of propylene using an antenna-reactor Al@TiO 2 −Pt single-atom plasmonic photocatalyst. Illumination at two distinct wavelengths, 450 and 800 nm, corresponds to high reactivity toward propane production. Theoretical insight into wavelength-dependent hot-carrier generation reveals nonequilibrium carriers with sufficient energies to activate both steps of propylene hydrogenation at either wavelength, the dissociation of H 2 and its incorporation into the propylene carbon− carbon double bond. Paired with light-driven propane dehydrogenation, this study demonstrates that photocatalytic cycling of propylene - propane for hydrogen storage and release can be performed under mild conditions.

alkyls↗
DOE OSTI2018

Strong Localization of Surface Plasmon Polaritons with Engineered Disorder

Here in this work, we experimentally demonstrate for the first time strong localization of surface plasmon polaritons (SPPs) at visible regime in metallic nanogratings with short-range correlated disorder. By increasing the degree of disorder, the confinement of SPPs is significantly enhanced, and the effective SPP propagation length dramatically shrinks. Strong localization of SPPs eventually emerges at visible regime, which is verified by the exponentially decayed fields and the vanishing autocorrelation function of the SPPs. Physically, the short-range correlated disorder induces strong interference among multiple scattered SPPs and provides an adequate fluctuation to effective permittivity, which leads to the localization effect. Finally, our study demonstrates a unique opportunity for disorder engineering to manipulate light on nanoscale and may achieve various applications in random nanolasing, solar energy, and strong light-matter interactions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2018

Nanoimprinted Chiral Plasmonic Substrates with Three-Dimensional Nanostructures

Here, we report a large-area fabrication method to prepare chiral substrates patterned with arrays of multilayer, three-dimensional nanostructures using a combination of nanoimprint lithography and glancing angle deposition. Several structures are successfully fabricated using this method, including L-shaped, twisted arc and trilayer twisted Au nanorod structures, demonstrating its generality. As one typical example, arrays of L-shaped nanostructures, consisting of two layers of orthogonally oriented Au nanorods separated by a Ge dielectric layer in the thickness direction, exhibit giant optical chirality in the infrared region with an experimentally achieved g-factor as high as 0.38. Electromagnetic simulations show that the optical chirality results from plasmon hybridization between the two orthogonal Au segments. To demonstrate scalability, a 1 cm 2 chiral substrate is fabricated with uniform chiral optical property. This method combines both high throughput and precise geometrical control and is therefore promising for applications of chiral metamaterials.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2019

Carbon Nanotube Color Centers in Plasmonic Nanocavities: A Path to Photon Indistinguishability at Telecom Bands

Indistinguishable single photon generation at telecom wavelengths from solid-state quantum emitters remains a significant challenge to scalable quantum information processing. Here we demonstrate efficient generation of 'indistinguishable' single photons directly in the telecom O-band from aryl-functionalized carbon nanotubes by overcoming the emitter quantum decoherence with plasmonic nanocavities. With an unprecedented single-photon spontaneous emission time down to 10 ps (from initially 0.7 ns) generated in the coupling scheme, we show a two-photon interference visibility at 4 K reaching up to 0.79, even without applying post selection. Cavity-enhanced quantum yields up to 74% and Purcell factors up to 415 are achieved with single-photon purities up to 99%. Here, our results establish the capability to fabricate fiber-based photonic devices for quantum information technology with coherent properties that can enable quantum logic.

36 MATERIALS SCIENCE↗