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At least 793 records · Page 44

Identification of mixed sources with an organic scintillator-based radiation portal monitor

We have developed radionuclide identification algorithms for radiation portal monitor applications. One algorithm uses a spectral angle mapper to match the power spectral density of modified cumulative distribution functions of measured pulse height distributions to reference spectra, while the others rely on the decomposition of the observed spectrum as a linear mixture of known radionuclide spectra. Three algorithms were then tested for their ability to perform on-the-fly radionuclide identification on datasets acquired with a liquid organic scintillator-based pedestrian radiation portal monitor on moving special nuclear material and industrial radiological sources, as well as common medical isotopes. We quantified and compared the relative efficacies of the algorithms considered using F-score analysis. Measured radiation sources included 51 g of highly enriched uranium, 6.6 g of weapons grade plutonium, 241 Am, 133 Ba, 57 Co and 137 Cs sources with activities of several hundred kBq, as well as 260 kBq liquid solution samples of the medical isotopes 99m Tc, 111 In, 67 Ga, 123 I, 131 I, and 201 Tl. We achieved 100% positive identification, for three-second measurements of single sources moving at a source-transit speed of 1.2 m/s. For mixed sources with strongest and weakest sources having no more than a 5:1 ratio of detected counts, encouraging positive identification results were achieved with the un-mixing algorithms. Current radiation portal monitor designs suffer from a high incidence rate of nuisance radiation alarms caused in radiation portal monitor primary screenings by recent nuclear medicine patients and cargo containing large amounts of naturally occurring radioactive materials. Integrating reliable on-the-fly radionuclide identification into the radiation portal monitors could lower the number of nuisance alarms requiring time-consuming secondary inspections.

47 OTHER INSTRUMENTATION↗

PNNL Sequim Campus Radionuclide Air Emissions Report for Calendar Year 2025 : Department of Energy – Office of Science Pacific Northwest National Laboratory

The U.S. Department of Energy Office of Science’s Pacific Northwest Site Office has oversight and stewardship duties associated with the Pacific Northwest National Laboratory Sequim Campus. Facility operations include radiological operations with the potential-to-emit low levels of radioactive materials. This report is prepared to document compliance with the 40 CFR Part 61, National Emission Standards for Hazardous Air Pollutants, Subpart H, “National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities,” and Washington Administrative Code Chapter 246-247, Radiation Protection–Air Emissions. The PNNL Sequim Campus is in compliance with the federal and state 10 mrem/yr standard for 2025 operations.

40 CFR 61 Subpart H↗

Measuring Concentrations of Particulate 140 La in the Air

Air sampling systems were deployed to measure the concentration of radioactive material in the air during the Full-Scale Radiological Dispersal Device experiments. The air samplers were positioned 100-600 meters downwind of the release point. The filters were collected immediately and analyzed in the field. Quantities for total activity collected on the air filters are reported along with additional information to compute the average or integrated air concentrations.

61 RADIATION PROTECTION AND DOSIMETRY↗

Annual Site Environmental Report (2019)

Los Alamos National Laboratory’s (the Laboratory’s) annual site environmental reports are prepared by the Laboratory’s environmental organizations, as required by U.S. Department of Energy Order 231.1B, Administrative Change 1, Environment, Safety, and Health Reporting, and Order 458.1, Administrative Change 3, Radiation Protection of the Public and the Environment. The following chapters in this report discuss our success in complying with environmental laws, regulations, and orders (Chapter 2, Compliance Summary); how we manage the Laboratory’s environmental performance (Chapter 3, Environmental Programs); how we monitor for air emissions of radioactive materials and climate conditions (Chapter 4, Air Quality); how we monitor for effects of Laboratory operations on groundwater quality (Chapter 5, Groundwater Protection); how we monitor the movement of chemicals and radionuclides by storm water runoff and the levels of chemicals and radionuclides in deposited sediment (Chapter 6, Watershed Quality); how we monitor for the presence, levels, and effects of chemicals and radionuclides in plants, animals, and soil (Chapter 7, Ecosystem Health); and finally, what radionuclide dose or risk from chemical exposure members of the public may experience as a result of Laboratory operations (Chapter 8, Public Dose and Risk Assessment).

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PNNL-Sequim Campus Radionuclide Air Emissions Report for Calendar Year 2023

The U.S. Department of Energy Office of Science (DOE-SC) Pacific Northwest Site Office has oversight and stewardship duties associated with the Pacific Northwest National Laboratory Sequim campus. Some research projects have the potential to emit low levels of radioactive materials. This report is prepared to document compliance with the Code of Federal Regulation, Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants, Subpart H, “National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities” and Washington Administrative Code Chapter 246-247, "Radiation Protection–Air Emissions." Compliance is indicated by comparing the estimated effective dose equivalent (EDE) to the maximally exposed individual (MEI) member of the public with the 10 millirem per year (mrem/yr) U.S. Environmental Protection Agency (EPA) standard. The PNNL-Sequim campus has only fugitive emissions sources.

40 CFR 61 Subpart H↗

Testing and Deployment of Remote Systems to Remove Highly Radioactive Soil at Hanford's 324 Building - 18043

U.S. Department of Energy (DOE) contractor CH2M HILL Plateau Remediation Company (CHPRC) is in the process of procuring, testing and deploying remotely operated tools to safely remove highly contaminated soil from beneath the 324 Building on the Hanford Site in southeastern Washington State. The 324 Building operated for more than 40 years, completing a variety of high-dose engineering development and demonstration activities inside six hot cells that shielded the workers from the highly radioactive materials. Activities to decommission, decontaminate and demolish the facility began in 2008. In 2010, soil contamination was found in the soil under one of the hot cells, and building deactivation was paused to evaluate the soil contamination. Sampling efforts, using borehole technology, revealed significant under-building contamination with dose rates measuring has high as 130 Sv/hr (13,000 R/hr). The highly-contaminated soil has to be removed before traditional open air deactivation activities can continue. CHPRC completed proof of concept testing and built a full-scale test facility to demonstrate the effectiveness of three primary tools that will accomplish the floor and soil removal. The tools include a commercially available concrete saw, and a commercially available excavator arm that have been modified to operate remotely in the high-radiation environment within the hot-cell. In order to reduce the wear on the hot-cell overhead cranes, a remote operated rail and cart system has been designed to transport soil and debris out of the hot-cell to an airlock area where the waste will be separated, according to its level of radioactivity. A camera and light system has been designed to provide visual and audio coverage of the hot-cell area that will allow the operations to proceed from remote control stations. This paper will describe the primary remote operated equipment designed for the project and the challenges and processes for developing, testing and deploying the equipment necessary to excavate the soil from below the 324 Building. (authors)

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Laboratory-Scale Melter Systems for Simulated and Real AP-107 Tank Waste - 20483

The Hanford Waste Treatment and Immobilization Plant (WTP) will process and stabilize waste that is stored in underground tanks on the Hanford Site. At the WTP, the tank waste will be combined with glass-forming and modifying additives to form an aqueous and solid mixture called melter feed, which will then be vitrified in joule-heated melters. A small-scale melter system, the continuous laboratory-scale melter (CLSM), is designed to operate with a continuous feeding process while periodically pouring glass product and collecting off-gas. Two CLSMs were constructed: one in a non-radioactive environment for processing waste simulants and another in a fume hood capable of handling radioactive material for processing actual Hanford tank waste. The waste sample received for vitrification in the CLSM was from Hanford tank 241-AP-107. Approximately 12 liters of melter-feed slurry was vitrified into 7 kilograms of glass product over the course of 10 hours of charging to the CLSM. The partitioning of technetium-99 in the product streams was used to calculate the technetium-99 recovery and help determine when the vitrification process had reached a steady state. The average single-pass retention of technetium-99 in the glass product was then calculated for the processing of AP-107 waste in the CLSM system. (authors)

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H-Canyon Jumper Gasket Sealing Evaluation

H-Canyon Documented Safety Analysis approved December 2019 credits the leak integrity of HCanyon (HCA) process tanks, piping, and jumpers in preventing the release of radioactive material in a post seismic environment. Demonstration of leak tightness capability for this equipment was achieved through substantial analytical effort. However, one potential weak point that affects leak integrity exists at the gasketed joint between Hanford Connectors (HC) and nozzles. Review of the HCA Crane Log over a three-year period indicates the HCs periodically leak. Savannah River National Laboratory (SRNL) was requested to perform gasket compression tests that evaluate gasket relaxation characteristics, i.e., creep, and provide improvements to the HC installation process that can reduce or eliminate the frequency of leaks at HCs. A HC torque value of 312 ft-lbf is the target value used because it is the minimum torque value, with 95% confidence, when an unlubricated HC is impacted for standard sealing period of 9 seconds.

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Neutron Residual Stress Mapping for Spent Nuclear Fuel Storage Canister Weldment

Many radioactive materials within the nuclear fuel cycle present a significant hazard. Such materials include spent nuclear fuel, high-level waste, legacy waste and other nuclear materials that have no current outlet than storage. These materials are often held in long-term storage as an interim stage within their lifecycle. Lifecycles can include reuse or disposal. Safety and security of spent nuclear fuel (SNF) interim storage installations are very important, due to a great concentration of fission products, actinides and activation products. Stress corrosion cracking of interim storage containers has been identified as a high priority data gap by the Department of Energy. However, little has been done with regards to the canister weld material properties and their impact on stress corrosion, until recently from Sandia National Laboratory canister mockup program. Furthermore, because no post-weld heat treatment was required, the associated high tensile residual stress within these canister welds can drive the initiation and growth of stress corrosion cracking (SCC) cracks. In this work, we carried out in-situ neutron residual stress mapping on a weld plate sectioned from Sandia mock-up canister wall. Significant residual stress profiles were identified from the received longitudinal weld sample. The details of the weldment residual stress program development at ORNL are presented in this progress report. The generated residual stress profile from neutron diffraction technique is similar to that of Sandia residual stress data obtained from the deep hole drilling approach.

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Breaking Through Historical Biases in Performance Assessments - 18056

Performance assessments (referred to as safety assessments internationally), which include mathematical modeling of natural and engineered systems for many hundreds and thousands of years, play an important role in decision-making for disposal of radioactive waste and cleanup of sites and facilities contaminated with radioactive material. These decisions can involve options costing hundreds of millions or even billions of dollars. Thus, it is critical to understand the underlying assumptions behind regulatory and technical aspects of these assessments to better understand and communicate the basis for decisions. Policy and technical biases deliberately built into early assessment approaches allowed safety margin to account for uncertainties known to be present, but not quantitatively assessed. Many of these biases (e.g., regulatory standards, human habits, effectiveness of waste forms, inadvertent intrusion assumptions, etc.) continue to exist in spite of advances in technical approaches and knowledge. These built-in biases, often not effectively communicated, can lead to misleading interpretation of results and potentially influence public confidence and costly regulatory decisions regarding the safety of a disposal facility or a closure action. (authors)

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Classification methodology for tritiated waste requiring interim storage

Fusion machines like the ITER experimental research facility will use tritium as fuel. Therefore, most of the solid radioactive waste will result not only from activation by 14 MeV neutrons, but also from contamination by tritium. As a consequence, optimizing the treatment process for waste containing tritium (tritiated waste) is a major challenge. This paper summarizes the studies conducted in France within the framework of the French national plan for the management of radioactive materials and waste. The paper recommends a reference program for managing this waste based on its sorting, treatment and packaging by the producer. It also recommends setting up a 50-year temporary storage facility to allow for tritium decay and designing future disposal facilities using tritiated radwaste characteristics as input data. This paper first describes this waste program and then details an optimized classification methodology which takes into account tritium decay over a 50-year storage period. The paper also describes a specific application for purely tritiated waste and discusses the set-up expected to be implemented for ITER decommissioning waste (current assumption). Comparison between this optimized approach and other viable detritiation techniques will be drawn. (authors)

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Viability of In-Drum Treatment for Transuranic Wastes Containing Nitrates and Organics - 20406

In February of 2014, a breach in a waste drum stored at the Waste Isolation Pilot Plant resulted in the release of radioactive material into the immediate surroundings and outside of the plant. The waste drum contained a mixture of an organic absorbent and nitrate salts that pressurized the drum, eventually causing the drum lid to fail, leading to the adverse event. Other waste drums with similar contents exist posing both storage and treatment risks. These drums may successfully be treated by an in-drum treatment system. This paper considers the design and operation of an in-drum treatment system and the characteristics of waste containing organics and nitrates to evaluate the viability of treatment. A description of the system, how it is operated, and a summary of previous testing performed is provided. Treatment of both liquids and absorbed liquids comprised of organics and nitrates is addressed. Viability of treatment is demonstrated by presenting operational methods and design strategies to ensure successful treatment of the waste drums. (authors)

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Scientific Investigations on the Chemical Reactivity of Los Alamos Remediated Nitrate Salt Wastes - 16540

The February 14, 2014 release of radioactivity at the Waste Isolation Pilot Plant (WIPP) was the result of runaway thermal reactions that occurred in a TRU waste drum containing nitrate salts remediated using an organic absorbent. Experimental and modeling studies performed at LANL indicate that mixtures of metal nitrate salts (oxidizer) with sWheat Scoop{sup R} organic kitty litter (fuel) create the potential for exothermic chemical reactions. The use of sWheat{sup R} absorbent in the processing of nitrate salt wastes can be pinpointed as the critical processing decision that led to the failure of the breached drum in the WIPP repository. The most plausible scenario is that a production of heat, either from low-level chemical reactions or the growth of natural microbes, in concert with mixed metal nitrate salts, bismuth lined glovebox gloves and/or lead nitrates when combined with the sWheat{sup R} organic kitty litter, generated a series of exothermic reactions that heated and pressurized the drum resulting in the venting of high-temperature gases and radioactive material into the room. Observations and modeling studies indicate that the probability of thermal runaway in another drum has decreased with time since the WIPP event. However, the complexity of the mixtures, ambiguity in procedures such as those used for neutralization, the heterogeneity of the drum contents, and the difficulty of sampling leads to an irreducible level of uncertainty that mandates the exercise of caution in managing RNS wastes. The situation also requires that this waste stream continue to be stored in a temperature-controlled environment and monitored until the waste can be remediated to remove the hazard permanently. We recommend that proposals to treat nitrate salts with organic absorbents of any kind be accompanied by experimental studies to confirm that similarly sensitive mixtures are not inadvertently created over the range of conditions (mixture quantities, moisture content, etc.) anticipated during processing and storage. (authors)

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Decommissioning Experience at Rokkasho; Standing Type Manipulator: A1000S for Dismantling Tasks - 16434

Decommissioning is a technical process which includes various steps and processes from the clean-up of radioactive materials to the progressive demolition of the plant. One of these steps is the cutting of subassemblies, like tanks, pipes or walls in small pieces suitable for the sorting and disposal. Different solutions are offered for this cutting work and can be grouped as following: - Chip forming - sawing, drilling, milling, turning etc. - Shearing - punching, stamping, scissoring. - Abrading - Grinding, lapping, polishing; water-jet. - Heat - flame cutting, plasma cutting, laser cutting. - Electro-Chemical - Etching, Electrical discharge machining (EDM). Each method has its limitations in accuracy, cost, and effect on the material. In 2013, Waelischmiller Engineering won a contract for two remote handling systems dedicated to the dismantling cell at Rokkasho Nuclear Fuel Reprocessing Facility in Japan. For this project, Inconel and other metals needed to be cut. One of the main cutting methods was decided to use of an angle grinder handled by a robotic arm. Because the use of the overhead systems (bridges and cranes) was difficult for this installation, it was determined, that the best alternative was a power manipulator A1000 installed on the floor with a pre-positioning system. The project proceeded to go forward with the adaptation of the standard A1000 with integration of a control system in a Cartesian coordinate frame; resulting in a heavy duty arm; A1000S with 6 degrees of freedom. The heavy duty power arm A1000S was developed and designed for mechanical cutting with an angle grinder, especially for thick and hard material for example stainless steel and Inconel. Cutting a thick material with an angle grinder requires repeatable precise linear motion, in order not to damage the disc. The angle grinder should be handled with a manipulator which can cut in all directions in a linear motion, since the objects which should be cut are usually very large and fixed in any direction For these requirements, the Cartesian control function was added to our standard power manipulator type A1000. In some cases, the decommissioning work includes repeated access routes or fixed access points that the manipulator arm has to pass repeatedly. For example a fixed point where the waste materials are collected, or repeated transport route that the arm has to go along for each step. For this requirement, the A1000S has been equipped with the 'Go To-Mode'. It is a 'teach and playback mode' which has been developed especially for remote operating manipulators. Quick direct teach, quick play function and an intuitive touch-panel layout are some of the features. With the Go To-Mode high working efficiency was achieved. After rigorous testing at Waelischmiller premises; the manipulator was delivered to JNFL in Rokkasho. It was found that the obtained functionality and precision can be applicable not only for the cutting with a disc grinder, but also the laser cutting method, which requires precise trajectory control. This paper will provide: - A project description, - Presentation of solution process, - Technical description of the A1000S, - Future Applications of the robotic Arm A1000S. (authors)

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A Fast Framework for Generating Radioactive Mixture Spectra and Its Application to Remote High-Performance Mixture Identification

Remote detection of radioactive materials in mixtures using handheld or portal detectors remains a challenge because of factors such as low concentration, environmental interference, sensor noise, and other complications. This work introduces a fast framework for generating realistic mixture spectra. Moreover, we present mixture isotope identification using data generated by the fast framework. Researchers have examined a range of conventional and recent algorithms within the fields of machine learning and deep learning. An application to uranium enrichment-level prediction has been included. Extensive simulation experiments validated the efficacy of the proposed framework.

GADRAS↗

First-Principles-Based Computational Study on Nucleation and Growth Mechanisms of U on Mo(110) Surface Solvated in an Eutectic LiCl-KCl Molten Salt

In nuclear engineering and industry electrochemical methods have been intensively employed in pyro-processing technology to recycle used nuclear fuels for substantial alleviation of the concern with the safe treatment of high-level radioactive nuclear wastes. Pyro-processing is based on sequential electrochemical reactions at high temperature (typically above 700 K at ambient pressure) to enhance the efficiency for decoupling nuclear fuels from unfavorable fission fragments. Using a molten salt in electrorefining process, at which actinides can be selectively deposited in solid cathode from ionic states, gives several advantages over an aqueous solution: higher thermal conductivity (it is liquid phase at high temperature, molten salt plays a role as medium at high temperature over 773 K in electrochemical reaction, lower kinetic barrier in ionic diffusion mobility and better stability against undesired side reactions with radioactive materials. Therefore, the volume of high-level nuclear wastes to be, otherwise, disposed into secured sites is dramatically reduced. Most of all it conforms to nuclear non-proliferation treaty. Electrochemical reactions in a molten salt medium are, however, much more complicated than in aqueous solution rendering the accurate understanding of thermodynamic and kinetic properties formidably challenging. It is represented by extensive researches in experiments and computations to identify underlying mechanisms on how U and other fission fragments behave in the electrorefining system. Regardless of the researches there is a general agreement that the initial stage of the nucleation and growth process of the U deposit is critical for determining the properties of final product and the electrorefining efficiency. In spite of the focused studies it still remains unclear. Theoretical and computational researches have been often carried out with various empirical parameter for interatomic potential energy, which are unknown variables until numerical fits to experimental measurements or just assumption is made. Thus, empirical simulations sometimes predicted outcomes are inconsistent depending on materials of interest with experimental measurements. This may be largely because the accuracy of an empirical interatomic potential energy models critically depends on the input parameters and thus, can be limited in transferability of the results. Furthermore, it may be devoid of fundamental physics or chemistry. This situation requires special caution when an electrorefining system is studied to recycle spent nuclear fuels because of the extreme difficulty in reliable acquisition of thermodynamic and kinetic data from direct experimental measurements. In this presentation, we extensively utilized first principles density functional theory (DFT) calculations and ab-initio molecular dynamic (AIMD) simulations to figure out underlying mechanisms of the initial stage of nucleation and growth behaviors of U on Mo(110) surface in a eutectic LiCl-KCl molten salt at T = 773 K. To rigorously investigate the effect of the molten salt electrolyte we compared the results with those calculated under vacuum condition.

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Developments of the Versa-Pac to Expand Use for the Industry - 17475

The Versa-Pac is a certified Type AF packaging (USA NRC Certificate no. USA/9342/AF-96), designed as a replacement for USA DOT 6M drum-type transportation packaging, which was retired approximately ten years ago. The Versa-Pac can be used directly or in conjunction with pails, drums, or inserts, and a variety of smaller containers and vessels. The Versa-Pac comes in two sizes: the VP-55 (i.e. 200-liter drum version) and VP-110 (i.e. 400-liter drum version). It features a patented design that, in combination with the drum exterior, provides enhanced structural protection to payloads under Normal Conditions of Transport and Hypothetical Accident Conditions. Since its introduction in 2010, the Versa-Pac has been utilized mainly as a one-time-use package for disposing of radioactive waste. However, the Versa-Pac package, which has the familiar simplicity of a drum, is a reusable transport package with the capability of shipping a variety of radioactive materials. In the spirit of simplicity yet versatility, the capability of the package has been improved several times in collaboration with our customers. The latest design improvements include a new configuration designated the VP-55HC (high capacity), which utilizes an internal safe geometry pipe container that increases the U-235 capacity. The pipe container is similar in design to the historic USA DOT 2R vessel. Other planned and proposed improvements include provisions to transport UF{sub 6} in 1S, 2S, and 5A/5B cylinders; design changes that further increase the amount of U-235 at enrichments less than 20 wt.%; increasing the capacity of the VP-110 with a VP-110-specific analysis; developing a new, lighter 113-liter version of the package; and introducing content limits specific to uranium oxides in multiple forms. This paper traces the engineering and design efforts involved in expanding the Versa-Pac's versatility. (authors)

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Characterization and Remediation of the Hanford 618-10 Burial Ground Steel-pipe Vertical Pipe Units - 18238

The 618-10 Burial Ground is approximately 485 feet by 470 feet and consisted of 12 trenches and 94 VPUs. It is located approximately 5 miles north of Richland, Washington in the 600 Area of the Hanford Site. The 618-10 Burial Ground received low- to high-activity waste (e.g., fission products and some plutonium-contaminated waste). Most of the waste originated at the 300 Area laboratory facilities. Lower activity radioactive material and shielded drums were disposed in trenches, while laboratory wastes with higher levels of radiation were disposed in Vertical Pipe Units (VPUs). The 618-10 Burial Ground contained approximately 94 VPUs (uncertain mix of first and second generation). There are different variants of VPUs. The first generation of VPUs was simply corrugated culverts or standard pipes, 14-in diameter and 10- to 15-ft long, buried vertically. The second generation of VPUs was 22-in diameter, 15-ft long waste receptacles constructed by welding five 55-gallon bottomless drums together end-to-end and burying them vertically, separated by approximately 10 feet on center in rows approximately 25 feet apart. A subset of the first generation VPUs consisted of the steel pipe VPUs represented by carbon-steel pipes, 10 to 24 in. in diameter with various wall thicknesses. This paper will present the remediation of the steel-pipe VPUs, which were the last of the VPUs remediated in this project. The remediation process developed for steel pipe VPUs included exposing a section of the VPU within an excavated trench, placing a mix box around the VPU, filling the mix box with grout, shearing the VPU and contents, and then removing the grout waste mixture into a waste box for disposal at the Hanford Environmental Restoration Disposal Facility (ERDF). Prior the start of remedial activities extensive mock-ups were performed on surrogate steel-pipe VPUs to ensure the effectiveness of the process before introducing the hazards of radioactive VPU waste. The critical steps in the process of size reducing steel-pipe VPUs and mixing the contents with grout was successfully demonstrated. This process was completed for each steel-pipe VPU in successive lifts until the entire set of steel-pipe VPUs were mixed in grout and removed from the excavation. The remediation of the steel-pipe VPUs proved be successful in that all the VPUs were removed and transported to ERDF without a release to the local environment. (authors)

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