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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 793 records · Page 44

Cementitious Barriers Partnership (CBP): Using the CBP Software Toolbox to Simulate Sulfate Attack and Carbonation of Concrete Structures - 13481

The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the U.S. Department of Energy Office of Tank Waste Management. The CBP project has developed a set of integrated modeling tools and leaching test methods to help improve understanding and prediction of the long-term hydraulic and chemical performance of cementitious materials used in nuclear applications. State-of-the-art modeling tools, including LeachXS{sup TM}/ORCHESTRA and STADIUM{sup R}, were selected for their demonstrated abilities to simulate reactive transport and degradation in cementitious materials. The new U.S. Environmental Protection Agency leaching test methods based on the Leaching Environmental Assessment Framework (LEAF), now adopted as part of the SW-846 RCRA methods, have been used to help make the link between modeling and experiment. Although each of the CBP tools has demonstrated utility as a standalone product, coupling the models over relevant spatial and temporal solution domains can provide more accurate predictions of cementitious materials behavior over relevant periods of performance. The LeachXS{sup TM}/ORCHESTRA and STADIUM{sup R} models were first linked to the GoldSim Monte Carlo simulator to better and more easily characterize model uncertainties and as a means to coupling the models allowing linking to broader performance assessment evaluations that use CBP results for a source term. Two important degradation scenarios were selected for initial demonstration: sulfate ingress / attack and carbonation of cementitious materials. When sufficient sulfate is present in the pore solution external to a concrete barrier, sulfate can diffuse into the concrete, react with the concrete solid phases, and cause cracking that significantly changes the transport and structural properties of the concrete. The penetration of gaseous carbon dioxide within partially saturated concrete usually initiates a series of carbonation reactions with both dissolved ions and the hydrated cement paste. The carbonation process itself does not have a negative effect, per se, on the paste physical properties and can even result in reduced porosity and can help form a protective layer at the surface of concrete. However, carbonation has been shown to increase leaching of some constituents and can potentially have a detrimental effect on reinforced concrete structures by lowering pH to ca. 9 and de-passivating embedded steel (e.g. rebar) and accelerating corrosion, which are important processes related to high-level waste tank integrity and closure evaluations. The use of the CBP Software Toolbox to simulate these important degradation phenomena for both concrete vaults and high-level waste tanks are demonstrated in this paper. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A validated methodology for the prediction of heating and cooling energy demand for buildings within the Urban Heat Island: Case-study of London

This paper describes a method for predicting air temperatures within the Urban Heat Island at discreet locations based on input data from one meteorological station for the time the prediction is required and historic measured air temperatures within the city. It uses London as a case-study to describe the method and its applications. The prediction model is based on Artificial Neural Network (ANN) modelling and it is termed the London Site Specific Air Temperature (LSSAT) predictor. The temporal and spatial validity of the model was tested using data measured 8 years later from the original dataset; it was found that site specific hourly air temperature prediction provides acceptable accuracy and improves considerably for average monthly values. It thus is a very reliable tool for use as part of the process of predicting heating and cooling loads for urban buildings. This is illustrated by the computation of Heating Degree Days (HDD) and Cooling Degree Hours (CDH) for a West-East Transect within London. The described method could be used for any city for which historic hourly air temperatures are available for a number of locations; for example air pollution measuring sites, common in many cities, typically measure air temperature on an hourly basis. (author)

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Convective Transition Statistics over Tropical Oceans for Climate Model Diagnostics: GCM Evaluation

To assess deep convective parameterizations in a variety of GCMs and examine the fast-time-scale convective transition, a set of statistics characterizing the pickup of precipitation as a function of column water vapor (CWV), PDFs and joint PDFs of CWV and precipitation, and the dependence of the moisture–precipitation relation on tropospheric temperature is evaluated using the hourly output of two versions of the GFDL Atmospheric Model, version 4 (AM4), NCAR CAM5 and superparameterized CAM (SPCAM). The 6-hourly output from the MJO Task Force (MJOTF)/GEWEX Atmospheric System Study (GASS) project is also analyzed. Contrasting statistics produced from individual models that primarily differ in representations of moist convection suggest that convective transition statistics can substantially distinguish differences in convective representation and its interaction with the large-scale flow, while models that differ only in spatial–temporal resolution, microphysics, or ocean–atmosphere coupling result in similar statistics. Most of the models simulate some version of the observed sharp increase in precipitation as CWV exceeds a critical value, as well as that convective onset occurs at higher CWV but at lower column RH as temperature increases. While some models quantitatively capture these observed features and associated probability distributions, considerable intermodel spread and departures from observations in various aspects of the precipitation–CWV relationship are noted. For instance, in many of the models, the transition from the low-CWV, nonprecipitating regime to the moist regime for CWV around and above critical is less abrupt than in observations. Additionally, some models overproduce drizzle at low CWV, and some require CWV higher than observed for strong precipitation. For many of the models, it is particularly challenging to simulate the probability distributions of CWV at high temperature.

54 ENVIRONMENTAL SCIENCES↗

Characterizing forest ecosystem dynamics through modelling and remote sensing observations

To gain a better understanding of northern/boreal forest dynamics over a range of spatial and temporal scales, an approach to integrate models of forest growth, soil processes and radiative transfer with remote sensing observations was developed. The integrated model and remote sensing can be used to examine descriptors of ecosystem dynamics. To examine the scaling of vegetation pattern from the local to the regional domain, distributions of area and perimeters of vegetation community associations were determined from satellite and aircraft images. Relationships between computed fractal dimensions (1.5 to 1.8) and succession history for managed and unmanaged areas are being explored.

Ranson, K. J.↗

Comparison and analysis of aircraft measurements and mesoscale atmospheric chemistry model simulations of tropospheric ozone

The Regional Acid Deposition Model (RADM) has been applied to several of the field experiments which were part of the Acid Models Operational and Diagnostic Evaluation Study (Acid MODES). The experiment which was of particular interest with regards to ozone photochemistry involved horizontal zig-zag flight patterns (ZIPPER) over an area from the eastern Ohio River valley to the Adirondacks of New York. Model simulations by both the standard resolution RADM (delta x = 80 km) and the nested grid RADM (delta x = 26.7 km) compare well to measurements in the low emission regions in central Pennsylvania and upstate New York, but underestimate in the high emission upper Ohio River valley. The nested simulation does considerably better, however, than the coarse grid simulation in terms of horizontal pattern and concentration magnitudes. Analysis of NO(x) and HO(x) concentrations and photochemical products rates of ozone show that the model's response to large point source emissions is very unsystematic both spatially and temporally. This is due to the models instability to realistically simulate the small scale (subgrid) gradients in precursor concentrations in and around large point source plumes.

Pleim, Jonathan E.↗

The Numerical Analysis of a Turbulent Compressible Jet

A numerical method to simulate high Reynolds number jet flows was formulated and applied to gain a better understanding of the flow physics. Large-eddy simulation was chosen as the most promising approach to model the turbulent structures due to its compromise between accuracy and computational expense. The filtered Navier-Stokes equations were developed including a total energy form of the energy equation. Subgrid scale models for the momentum and energy equations were adapted from compressible forms of Smagorinsky's original model. The effect of using disparate temporal and spatial accuracy in a numerical scheme was discovered through one-dimensional model problems and a new uniformly fourth-order accurate numerical method was developed. Results from two- and three-dimensional validation exercises show that the code accurately reproduces both viscous and inviscid flows. Numerous axisymmetric jet simulations were performed to investigate the effect of grid resolution, numerical scheme, exit boundary conditions and subgrid scale modeling on the solution and the results were used to guide the three-dimensional calculations. Three-dimensional calculations of a Mach 1.4 jet showed that this LES simulation accurately captures the physics of the turbulent flow. The agreement with experimental data was relatively good and is much better than results in the current literature. Turbulent intensities indicate that the turbulent structures at this level of modeling are not isotropic and this information could lend itself to the development of improved subgrid scale models for LES and turbulence models for RANS simulations. A two point correlation technique was used to quantify the turbulent structures. Two point space correlations were used to obtain a measure of the integral length scale, which proved to be approximately 1/2 D(sub j). Two point space-time correlations were used to obtain the convection velocity for the turbulent structures. This velocity ranged from 0.57 to 0.71 U(sub j).

DeBonis, James R.↗

The effects of spatial and temporal resolution of gridded meteorological forcing on watershed hydrological responses

Abstract. Meteorological forcing plays a critical role in accurately simulating the watershed hydrological cycle. With the advancement of high-performance computing and the development of integrated watershed models, simulating the watershed hydrological cycle at high temporal (hourly to daily) and spatial resolution (tens of meters) has become efficient and computationally affordable. These hyperresolution watershed models require high resolution of meteorological forcing as model input to ensure the fidelity and accuracy of simulated responses. In this study, we utilized the Advanced Terrestrial Simulator (ATS), an integrated watershed model, to simulate surface and subsurface flow and land surface processes using unstructured meshes at the Coal Creek Watershed near Crested Butte (Colorado). We compared simulated watershed hydrologic responses including streamflow and distributed variables such as evapotranspiration, snow water equivalent (SWE), and groundwater table driven by three publicly available, gridded meteorological forcings (GMFs) – Daily Surface Weather and Climatological Summaries (Daymet), the Parameter-elevation Regressions on Independent Slopes Model (PRISM), and the North American Land Data Assimilation System (NLDAS). By comparing various spatial resolutions (ranging from 400 m to 4 km) of PRISM, the simulated streamflow only becomes marginally worse when spatial resolution of meteorological forcing is coarsened to 4 km (or 30 % of the watershed area). However, the 4 km-resolution has much worse performance than finer resolution in spatially distributed variables such as SWE. Using the temporally disaggregated PRISM, we compared models forced by different temporal resolutions (hourly to daily), and sub-daily resolution preserves the dynamic watershed responses (e.g., diurnal fluctuation of streamflow) that are absent in results forced by daily resolution. Conversely, the simulated streamflow shows better performance using daily resolution compared to that using sub-daily resolution. Our findings suggest that the choice of GMF and its spatiotemporal resolution depends on the quantity of interest and its spatial and temporal scale, which may have important implications for model calibration and watershed management decisions.

54 ENVIRONMENTAL SCIENCES↗

Using Formal Grammars to Predict I/O Behaviors in HPC: The Omnisc'IO Approach

The increasing gap between the computation performance of post-petascale machines and the performance of their I/O subsystem has motivated many I/O optimizations including prefetching, caching, and scheduling. In order to further improve these techniques, modeling and predicting spatial and temporal I/O patterns of HPC applications as they run has become crucial. In this paper we present Omnisc'IO, an approach that builds a grammar-based model of the I/O behavior of HPC applications and uses it to predict when future I/O operations will occur, and where and how much data will be accessed. To infer grammars, Omnisc'IO is based on StarSequitur, a novel algorithm extending Nevill-Manning's Sequitur algorithm. Omnisc'IO is transparently integrated into the POSIX and MPI I/O stacks and does not require any modification in applications or higher-level I/O libraries. It works without any prior knowledge of the application and converges to accurate predictions of any N future I/O operations within a couple of iterations. Its implementation is efficient in both computation time and memory footprint.

97 MATHEMATICS AND COMPUTING↗

MODEST: A Tool for Geodesy and Astronomy

Features of the JPL VLBI modeling and estimation software "MODEST" are reviewed. Its main advantages include thoroughly documented model physics, portability, and detailed error modeling. Two unique models are included: modeling of source structure and modeling of both spatial and temporal correlations in tropospheric delay noise. History of the code parallels the development of the astrometric and geodetic VLBI technique and the software retains many of the models implemented during its advancement. The code has been traceably maintained since the early 1980s, and will continue to be updated with recent IERS standards. Scripts are being developed to facilitate user-friendly data processing in the era of e-VLBI.

Sovers, Ojars J.↗

Spatially-Explicit Monitoring of Crop Photosynthetic Capacity Through the Use of Space-Based Chlorophyll Fluorescence Data

Plant functional traits such as photosynthetic capacity are critical parameters for terrestrial biosphere models. However, their spatial and temporal characteristics are still poorly represented. In this study, we used satellite observations of sun-induced fluorescence (SIF) to estimate top-of-canopy photosynthetic capacity (maximum carboxylation rate, V(sub cmax) at a reference temperature of 25 deg C) for crops, which was in turn utilized to simulate regional gross primary production (GPP). We first estimate the key parameter, V(sub cmax), in the widely-used FvCB photosynthesis model using field measurements of CO2 and water fluxes during 2007-2012 at seven crop eddy covariance flux sites over the US Corn Belt. The results showed that satellite far-red SIF retrievals have a stronger link to V(sub cmax) at the seasonal scale (R(squared)=0.70 for C4 and R(squared)=0.63 for C3 crop) as compared with widely-used vegetation indices. We calibrate an empirical model linking V(sub cmax) with SIF that was used to estimate spatially and temporally varying crop V(sub cmax) for the US Corn Belt region. The resulting V(sub cmax) maps are used together with meteorological data from MERRA reanalysis data and vegetation structural parameters derived from the satellite- based spectral reflectance data to constrain the Soil-Canopy Observation of Photosynthesis and Energy (SCOPE) balance model in order to estimate regional crop GPP. Our results show a substantial improvement in the seasonal and spatial patterns of cropland GPP when compared with crop yield inventory data. The evaluation with tall tower atmospheric CO2 measurements further supports our estimation of spatiotemporal V(sub cmax) from space-borne SIF. Considering that SIF has a direct link to photosynthetic activity, our findings highlight the potential to infer regional V(sub cmax) using remotely sensed SIF data and to use this information for a better quantification of regional cropland carbon cycles.

Drought↗

Parameter estimation with maximal updated densities

A recently developed measure-theoretic framework solves a stochastic inverse problem (SIP) for models where uncertainties in model output data are predominantly due to aleatoric (i.e., irreducible) uncertainties in model inputs (i.e., parameters). The subsequent inferential target is a distribution on parameters. Another type of inverse problem is to quantify uncertainties in estimates of “true” parameter values under the assumption that such uncertainties should be reduced as more data are incorporated into the problem, i.e., the uncertainty is considered epistemic. A major contribution of this work is the formulation and solution of such a parameter identification problem (PIP) within the measure-theoretic framework developed for the SIP. The approach is novel in that it utilizes a solution to a stochastic forward problem (SFP) to update an initial density only in the parameter directions informed by the model output data. In other words, this method performs “selective regularization” only in the parameter directions not informed by data. Further, the solution is defined by a maximal updated density (MUD) point where the updated density defines the measure-theoretic solution to the PIP. Another significant contribution of this work is the full theory of existence and uniqueness of MUD points for linear maps with Gaussian distributions. Data-constructed Quantity of Interest (QoI) maps are also presented and analyzed for solving the PIP within this measure-theoretic framework as a means of reducing uncertainties in the MUD estimate. We conclude with a demonstration of the general applicability of the method on two problems involving either spatial or temporal data for estimating uncertain model parameters. The first problem utilizes spatial data from a stationary partial differential equation to produce a MUD estimate of an uncertain boundary condition. The second problem utilizes temporal data obtained from the state-of-the-art ADvanced CIRCulation (ADCIRC) model to obtain a MUD estimate of uncertain wind drag coefficients for a simulated extreme weather event near the Shinnecock Inlet located in the Outer Barrier of Long Island, NY, USA.

42 ENGINEERING↗

Thin current sheets in the magnetotail during substorms: CDAW 6 revisited

The global magnetic field configuration during the growth phase of the Coordinated Data Analysis Workshop (CDAW) 6 substorm (March 22, 1979, 1054 UT) is modeled using data from two suitably located spacecraft and temporally evolving variations of the Tsyganenko magnetic field model. These results are compared with a local calculation of the current sheet location and thickness carried out by McPherron et al. (1987) and Sanny et al. (this issue). Both models suggest that during the growth phase the current sheet rotated away from its nominal location, and simultaneously thinned strongly. The locations and thickness obtained from the two models are in good agreement. The global model suggests that the peak current density is approximately 120 nA/sq m and that the cross-tail current almost doubled its intensity during this very strong growth phase. The global model predicts a field configuration that is sufficiently stretched to scatter thermal electrons, which may be conducive to the onset of ion tearing in the tail. The electron plasma data further support this scenario, as the anisotropy present in the low-energy electrons disappears close to the substorm onset. The electron contribution to the intensifying current in this case is of the order of 10% before the isotropization of the distribution.

Pulkkinen, T. I.↗

Transport of Biomass Burning Emissions from Southern Africa

The transport of biomass burning emissions from southern Africa to the neighboring Atlantic and Indian Oceans during the dry season (May-October) of 2000 is characterized using ground, ozonesonde, and aircraft measurements of carbon monoxide (CO) and ozone (O3) in and around southern Africa, together with the GEOS-CHEM global model of tropospheric chemistry. The model shows a positive bias of approximately 20% for CO and a negative bias of approximately 10-25% for O3 at oceanic sites downwind of fire emissions. Near areas of active fire emissions the model shows a negative bias of approximately 60% and approximately 30% for CO and O3, respectively, likely due to the coarse spatial (2 deg. x 2.5 deg.) and temporal (monthly) resolution of the model compared to that of active fires. On average, from 1994 to 2000, approximately 60 Tg of carbon monoxide (CO) from biomass burning in southern Africa was transported eastward to the Indian Ocean across the latitude band 0 deg. -60 S during the 6 months of the dry season. Over the same time period, approximately 40 Tg of CO from southern African biomass burning was transported westward to the Atlantic Ocean over the latitudes 0 deg. -20 S during the 6-month dry season, but most of that amount was transported back eastward over higher latitudes to the south (21 deg. -60 S). Eastward transport of biomass burning emissions from southern Africa enhances CO concentrations by approximately 4- 13 ppbv per month over the southern subtropical Indian Ocean during the dry season, with peak enhancements in September. Carbon monoxide from southern African and South American biomass burning is seen in the model simulations as far away as Australia, contributing approximately 8 ppbv and approximately 12-15 ppbv CO, respectively, and thus explaining the approximately 20- 25 ppbv observed enhancement of CO over Melbourne in mid-September 2000.

Sinha, Parikhit↗

A validated thermal and biological model for predicting algal productivity in large scale outdoor cultivation systems

Proper assessment of the sustainability of algal products requires an understanding of algal growth rate with regional and temporal resolution. This study developed a bulk growth model that utilizes geospatial data, reactor geometry inputs, and a maximum of six strain-specific parameters to predict algal productivity with temporal and regional resolution. The model requires local weather data to calculate the time-resolved culture temperature which is combined with a biological model based on maximum theoretical carbon fixation to predict the time-resolved algal concentration. Validation of the model against experimental data illustrates an average ac- curacy of 0.27% ± 5.32% when comparing algal concentration at harvest over 45 days of cultivation data for Galdieria sulphuraria 5587.1, and Galdieria sulphuraria Soos grown in photobioreactors (PBRs) in Mesa, AZ (33.4152° N, 111.8315° W). For open raceway ponds (ORPs), an accuracy of 0.9% ± 2.35% was achieved when comparing algal concentration at harvest over 50 days of cultivation data for Chlorella vulgaris, Desmodesmus intermedius, Nannochloropsis oceanica grown in Atlanta, GA (33.7490° N, 84.3880° W) and Mesa, AZ (33.4152° N, 111.8315° W). The validation trials spanned three seasons (winter, spring, and summer) to ensure model ac- curacy throughout the year, and concentration between harvests was modeled with hourly resolution. The validated model is used to assess the productivity at several case-study locations in the United States with Chlorella vulgaris, grown in open raceway ponds and Galdieria sulphuraria grown in vertical flat panel photo- bioreactors. In conclusion, the model has been published as an open-source tool, in an effort to increase the fidelity of future studies that rely on outdoor algae cultivation for feedstock production and allow for time resolved results for future techno-economic and life cycle assessments.

59 BASIC BIOLOGICAL SCIENCES↗

Leveraging observed soil heterotrophic respiration fluxes as a novel constraint on global-scale models

Microbially-explicit models may improve understanding and projections of carbon dynamics in response to future climate change, but their fidelity in simulating global-scale soil heterotrophic respiration (RH), a stringent test for soil biogeochemical models, has never been evaluated. We used statistical global RH products, as well as 7,821 daily site-scale RH measurements, to evaluate the spatio-temporal performance of one first-order decay model (CASA-CNP) and two microbially-explicit biogeochemical models (CORPSE and MIMICS) that were forced by two different climate datasets. CORPSE and MIMICS did not provide any measurable performance improvement; instead, the models were highly sensitive to the meteorological input data used to drive them. Spatial RH variability was generally well simulated except in the northern middle latitudes (~50°N) and arid regions; models captured the seasonal variability of RH well, but showed more divergence in tropic and arctic regions. Our results demonstrate that the next generation of biogeochemical models shows promise, but also needs to be improved for realistic spatio-temporal variability of RH. Finally, we emphasize the importance of net primary production, soil moisture, and soil temperature inputs, and that jointly evaluating soil models for their spatial (global scale) and temporal (site scale) performance provides crucial benchmarks for improving biogeochemical models.

Jian, Jinshi↗

A Multivariate Space‐Time Dynamic Model for Characterizing the Atmospheric Impacts Following the Mt. Pinatubo Eruption

The June 1991 Mt. Pinatubo eruption resulted in a massive increase of sulfate aerosols in the atmosphere, absorbing radiation and leading to global changes in surface and stratospheric temperatures. A volcanic eruption of this magnitude serves as a natural analog for stratospheric aerosol injection, a proposed solar radiation modification method to combat a warming climate. The impacts of such an event are multifaceted and region-specific. Our goal is to characterize the multivariate and dynamic nature of the atmospheric impacts following the Mt. Pinatubo eruption. We developed a multivariate space-time dynamic linear model to understand the full extent of the spatially- and temporally-varying impacts. Specifically, spatial variation is modeled using a flexible set of basis functions for which the basis coefficients are allowed to vary in time through a vector autoregressive (VAR) structure. This novel model is cast in a Dynamic Linear Model (DLM) framework and estimated via a customized MCMC approach. We demonstrate how the model quantifies the relationships between key atmospheric parameters prior to and following the Mt. Pinatubo eruption with reanalysis data from MERRA-2 and highlight when such a model is advantageous over univariate models.

Dynamic Linear Model↗

Solvent and solute ingress into hydrogels resolved by a combination of imaging techniques

Using simultaneous neutron, fluorescence, and optical brightfield transmission imaging, the diffusion of solvent, fluorescent dyes, and macromolecules into a crosslinked polyacrylamide hydrogel was investigated. This novel combination of different imaging techniques enables us to distinguish the movements of the solvent and fluorescent molecules. Additionally, the swelling or deswelling of the hydrogels can be monitored. From the sequence of images, dye and solvent concentrations were extracted spatially and temporally resolved. Diffusion equations and different boundary conditions, represented by different models, were used to quantitatively analyze the temporal evolution of these concentration profiles and to determine the diffusion coefficients of solvent and solutes. Solute size and network properties were varied and their effect was investigated. Increasing the crosslinking ratio or partially drying the hydrogel was found to hinder solute diffusion due to the reduced pore size. By contrast, solvent diffusion seemed to be slightly faster if the hydrogel was only partially swollen and hence solvent uptake enhanced.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Size dependence in chord characteristics from simulated and observed continental shallow cumulus

Abstract. In this study we compare long-term Doppler and Raman lidar observations against a full month of large eddy simulations of continental shallow cumulus clouds. The goal is to evaluate if the simulations can reproduce the mean observed vertical velocity and moisture structure of cumulus clouds and their associated subcloud circulations, as well as to establish if these properties depend on the size of the cloud. We propose methods to compare continuous chords of cloud detected from Doppler and Raman lidars with equivalent chords derived from 1D and 3D model output. While the individual chords are highly variable, composites of thousands of observed and millions of simulated chords contain a clear signal. We find that the simulations underestimate cloud size and fraction but successfully reproduce the observed structure of vertical velocity and moisture perturbations. There is a clear scaling of vertical velocity and moisture anomalies below the chords with chord size, but the moisture anomalies are only 1 %–2 % higher than the horizontal mean values. The differences between the observations and simulations are smaller than the difference in sampling the modeled chords in time or space. The shape of the vertical velocity and moisture anomalies from cloud chords sampled spatially from 3D model snapshots is almost perfectly symmetric. In contrast, the chords sampled temporally from the lidar observations and 1D model output have a marked asymmetry, with stronger updrafts and higher moisture anomalies occurring earlier on.

54 ENVIRONMENTAL SCIENCES↗