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Luna 16 - Some Li, K, Rb, Sr, Ba, rare-earth, Zr, and Hf concentrations.

Concentrations of Li, K, Rb, Sr, Na, rare-earths, Zr and Hf have been determined for some Luna 16 core materials by mass-spectrometric isotope-dilution. Two regolith fines samples from different depths in the core, and four rock-chips, including both igneous rocks and breccias, have similar trace-element concentrations. The Luna 16 materials have general lunar trace-element characteristics but differ from other returned lunar samples in a manner that suggests the presence of excess feldspar. Unless the Luna 16 igneous rocks are fused soils, they appear to represent either partial plagioclase cumulates or the least differentiated igneous material yet returned from the moon. The similarity in trace-element concentrations of the igneous rocks and the fines would then suggest largely local derivation of the Luna 16 regolith.

Philpotts, J. A.↗

Broad Genomic Sampling Reveals a Smut Pathogenic Ancestry of the Fungal Clade Ustilaginomycotina

Ustilaginomycotina is home to a broad array of fungi including important plant pathogens collectively called smut fungi. Smuts are biotrophs that produce characteristic perennating propagules called teliospores, one of which, Ustilago maydis , is a model genetic organism. Broad exploration of smut biology has been hampered by limited phylogenetic resolution of Ustilaginiomycotina as well as an overall lack of genomic data for members of this subphylum. In this study, we sequenced eight Ustilaginomycotina genomes from previously unrepresented lineages, deciphered ordinal-level phylogenetic relationships for the subphylum, and performed comparative analyses. Unlike other Basidiomycota subphyla, all sampled Ustilaginomycotina genomes are relatively small and compact. Ancestral state reconstruction analyses indicate that teliospore formation was present at the origin of the subphylum. Divergence time estimation dates the divergence of most extant smut fungi after that of grasses (Poaceae). However, we found limited conservation of well-characterized genes related to smut pathogenesis from U. maydis , indicating dissimilar pathogenic mechanisms exist across other smut lineages. The genomes of Malasseziomycetes are highly diverged from the other sampled Ustilaginomycotina, likely due to their unique history as mammal-associated lipophilic yeasts. Despite extensive genomic data, the phylogenetic placement of this class remains ambiguous. Although the sampled Ustilaginomycotina members lack many core enzymes for plant cell wall decomposition and starch catabolism, we identified several novel carbohydrate active enzymes potentially related to pectin breakdown. Finally, ~50% of Ustilaginomycotina species-specific genes are present in previously undersampled and rare lineages, highlighting the importance of exploring fungal diversity as a resource for novel gene discovery.

59 BASIC BIOLOGICAL SCIENCES↗

Uranium sorption to organic matter and long-term accumulation in a pristine alpine wetland

Understanding the controls on uranium (U) mobility in the environment is key to improve the management of sites contaminated by U mining activities. Previous research has shown that natural or engineered wetlands are particularly able to scavenge high amounts of U(VI) and U(IV) under noncrystalline forms. However, questions remain on the respective roles of sorption and reduction processes in the removal of U from running waters in wetlands, as well as on the long-term stability of U storage. Here, we performed a series of geochemical, isotopic ($δ$ 238 U, ( 234 U/ 238 U)), microscopic (SEM-EDXS, EPMA) and spectroscopic (µ-XRF, µ-XAS, XANES and EXAFS at the U L 3 and M 4 -edges and Fe K-edge) investigations to determine the modes of U accumulation and assess U mobility in a natural exceptionally U-enriched (up to 5000 µg/g) wetland on the shore of Lake Nègre (Mediterranean Alps, France). Uranium (VI) was largely dominant in the two studied soil cores, except a few samples containing as much as ~50 % U(IV). At the particle scale, U is associated to a variety of organic constituents of the soil matrix with a homogenous oxidation state. Bulk EXAFS spectroscopy at the U L 3 -edge shows that U is mostly mononuclear, with dominant monodentate binding to organic moieties (C neighbors at ~3.45 Å). An additional minor fraction of U under polymeric forms is inferred from wavelet (CCWT) analysis of the EXAFS data. These observations are reinforced by 1 M bicarbonate extractions that result in the dissolution of 82–96 % of total U, including putative polymeric species. At the wetland scale, similar or slightly fractionated isotopic ratios ($δ$ 238 U) between the wetland-feeding creek waters and the wetland soils are observed, supporting the idea that U(VI) sorption on organic matter is the primary U scavenging mechanism. Furthermore, it indicates that partial U(VI) reduction to U(IV) occurs as a second step, after sorption. Analysis of U decay chain disequilibria in the cores as a function of depth suggests that U accumulation in this wetland has lasted for several thousand years. In conclusion, we propose that the wetland acts as an active reactor where U has been massively accumulating for ~14500 years, especially as U(VI) forms associated to organic matter and is further partly exported to the lake through soil erosion.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

Seasonal controls on isolated convective storm drafts, precipitation intensity, and life cycle as observed during GoAmazon2014/5

Abstract. Isolated deep convective cloud life cycle and seasonal changes in storm properties are observed for daytime events during the US Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Green Ocean Amazon Experiment (GoAmazon2014/5) campaign to understand controls on storm behavior. Storm life cycles are documented using surveillance radar from initiation through maturity and dissipation. Vertical air velocity estimates are obtained from radar wind profiler overpasses, with the storm environment informed by radiosondes. Dry-season storm conditions favored reduced morning shallow cloud coverage and larger low-level convective available potential energy (CAPE) than wet-season counterparts. The typical dry-season storm reached its peak intensity and size earlier in its life cycle compared with wet-season cells. These cells exhibited updrafts in core precipitation regions (Z>35 dBZ) to above the melting level as well as persistent downdrafts aloft within precipitation adjacent to their cores. Moreover, dry-season cells recorded more intense updrafts to earlier life cycle stages as well as a higher incidence of strong updrafts (i.e., >5 m s−1) at low levels. In contrast, wet-season storms were longer-lived and featured a higher incidence of moderate (i.e., 2–5 m s−1) updrafts aloft. These storms also favored a shift in their most intense properties to later life cycle stages. Strong downdrafts were less frequent within wet-season cells aloft, indicating a potential systematic difference in draft behaviors, as linked to graupel loading and other factors between the seasons. Results from a stochastic parcel model suggest that dry-season cells may expect stronger updrafts at low levels because of larger low-level CAPE in the dry season. Wet-season cells anticipate strong updrafts aloft because of larger free-tropospheric relative humidity and reduced entrainment-driven dilution. Enhanced dry-season downdrafts are partially attributed to increased evaporation, dry-air entrainment mixing, and negative buoyancy in regions adjacent to sampled dry-season cores.

54 ENVIRONMENTAL SCIENCES↗

Benefits of utilizing CellProfiler as a characterization tool for U–10Mo nuclear fuel

Automated image processing techniques have the potential to aid in the performance evaluation of nuclear fuels by eliminating judgment calls that may vary from person-to-person or sample-to-sample. Analysis of in-core fuel performance is required for design and safety evaluations related to almost every aspect of the nuclear fuel cycle. This study presents a methodology for assessing the quality of uranium–molybdenum fuel images and describes image analysis routines designed for the characterization of several important microstructural properties. The analyses are performed in CellProfiler, an open-source program designed to enable biologists without training in computer vision or programming to automatically extract cellular measurements from large image sets. The quality metric scores an image based on three parameters: the illumination gradient across the image, the overall focus of the image, and the fraction of the image that contains scratches. The metric presents the user with the ability to ‘pass’ or ‘fail’ an image based on a reproducible quality score. Passable images may then be characterized through a separate CellProfiler pipeline, which enlists a variety of common image analysis techniques. The results demonstrate the ability to reliably pass or fail images based on the illumination, focus, and scratch fraction of the image, followed by automatic extraction of morphological data with respect to fission gas voids, interaction layers, and grain boundaries. - Graphical abstract: Display Omitted - Highlights: • A technique is developed to score U–10Mo FIB-SEM image quality using CellProfiler. • The pass/fail metric is based on image illumination, focus, and area scratched. • Automated image analysis is performed in pipeline fashion to characterize images. • Fission gas void, interaction layer, and grain boundary coverage data is extracted. • Preliminary characterization results demonstrate consistency of the algorithm.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Optimizing accuracy of determinations of CO₂ storage capacity and permanence, and designing more efficient storage operations: An example from the Rock Springs Uplift, Wyoming

At a potential injection site on the Rock Springs Uplift in southwest Wyoming, an investigation of confining layers was undertaken to develop and test methodology, identify key data requirements, assess previous injection scenarios relative to detailed confining layer properties, and integrate all findings in order to reduce the uncertainty of CO₂ storage permanence. The assurance of safe and permanent storage of CO₂ at a storage site involves a detailed evaluation of the confining layers. Four suites of field data were recognized as crucial for determining storage permanence relative to the confining layers; seismic, core and petrophysical data from a wellbore, formation fluid samples, and in-situ formation tests. Core and petrophysical data were used to create a vertical heterogenic property model that defined porosity, permeability, displacement pressure, geomechanical strengths, and diagenetic history. These analyses identified four primary confining layers and multiple redundant confining layers. In-situ formation tests were used to evaluate fracture gradients, regional stress fields, baseline microseismic data, step-rate injection tests, and formation perforation responses. Seismic attributes, correlated with the vertical heterogenic property models, were calculated and used to create a 3-D volume model over the entire site. The seismic data provided the vehicle to transform the vertical heterogenic property model into a horizontal heterogenic property model, which allowed for the evaluation of confining layers across the entire study site without risking additional wellbore perforations. Lastly, formation fluids were collected and analyzed for geochemical and isotopic compositions from stacked reservoir systems. These data further tested primary confining layers, by evaluating the evidence of mixing between target reservoirs (mixing would imply an existing breach of primary confining layers). All data were propagated into a dynamic, heterogenic geologic property model used to test various injection scenarios. These tests showed that the study site could retain 25MT of injected CO₂ over an injection lifespan of 50 years. Major findings indicate that active reservoir pressure management through reservoir fluid production (minimum of three production wells) greatly reduces the risk of breaching a confining layer. To address brine production, a well completion and engineering study was incorporated to reduce the risks of scaling and erosion during injection and production. These scenarios suggest that the dolostone within the Mississippian Madison Limestone is the site’s best injection/production target by two orders of magnitude, and that commercial well equipment would meet all performance requirements. This confirms that there are multiple confining layers in southwest Wyoming that are capable of retaining commercial volumes of CO₃, making Wyoming’s Paleozoic reservoirs ideal storage targets for low-risk injection and long-term storage. This study also indicates that column height retention calculations are reduced in a CO₂-brine system relative to a hydrocarbon-brine system, which is an observation that affects all potential CCS sites. Likewise, this study identified the impacts that downhole testing imparts on reservoir fluids, and the likelihood of introducing uncertainty in baseline site assumptions and later modeling.

25 ENERGY STORAGE↗

A Joint Probability Density–Based Decomposition of Turbulence in the Atmospheric Boundary Layer

Abstract In convective flows, vertical turbulent fluxes, covariances between vertical velocity and scalar thermodynamic variables, include contributions from local mixing and large-scale coherent motions, such as updrafts and downdrafts. The relative contribution of these motions to the covariance is important in turbulence parameterizations. However, the flux partition is challenging, especially in regions without convective cloud. A method to decompose the vertical flux based on the corresponding joint probability density function (JPD) is introduced. The JPD-based method partitions the full JPD into a joint Gaussian part and the complement, which represent the local mixing and the large-scale coherent motions, respectively. The coherent part can be further divided into updraft and downdraft parts based on the sign of vertical velocity. The flow decomposition is independent of water condensate (cloud) and can be applied in cloud-free convection, the subcloud layer, and stratiform cloud regions. The method is applied to large-eddy simulation model data of three boundary layers. The results are compared with traditional cloud and cloud-core decompositions and a decaying scalar conditional sampling method. The JPD-based method includes a single free parameter and sensitivity tests show weak dependence on the parameter values. The results of the JPD-based method are somewhat similar to the cloud-core and conditional sampling methods. However, differences in the relative magnitude of the flux decomposition terms suggest that an objective definition of the flow regions is subtle and diagnosed flow properties like updraft characteristics depend on the sampling method. Moreover, the flux decomposition depends on the thermodynamic variable and convection characteristics.

Chinita, Maria J.↗

Localized reactive flow in carbonate rocks: Core-flood experiments and network simulations

We conducted four core-flood experiments on samples of a micritic, reef limestone from Abu Dhabi under conditions of constant flow rate. The pore fluid was water in equilibrium with CO 2 , which, because of its lowered pH, is chemically reactive with the limestone. Flow rates were between 0.03 and 0.1 mL/min. The difference between up and downstream pore pressures dropped to final values <<1 MPa over periods of 3–18 h. Scanning electron microscope and microtomography imaging of the starting material showed that the limestone is mostly calcite and lacks connected macroporosity and that the prevailing pores are few microns large. During each experiment, a wormhole formed by localized dissolution, an observation consistent with the decreases in pressure head between the up and downstream reservoirs. Moreover, we numerically modeled the changes in permeability during the experiments. We devised a network approach that separated the pore space into competing subnetworks of pipes. Thus, the problem was framed as a competition of flow of the reactive fluid among the adversary subnetworks. The precondition for localization within certain time is that the leading subnetwork rapidly becomes more transmissible than its competitors. This novel model successfully simulated features of the shape of the wormhole as it grew from few to about 100 µm, matched the pressure history patterns, and yielded the correct order of magnitude of the breakthrough time. Finally, we systematically studied the impact of changing the statistical parameters of the subnetworks. Larger mean radius and spatial correlation of the leading subnetwork led to faster localization.

58 GEOSCIENCES↗

An Exceptional Synergy of High Strength, Ductility and Toughness in a Gradient-Structured Low-Carbon Steel

Generally, the improvement in the strength comes at the cost of the ductility and toughness for most metallic materials. Here, an exceptional synergy of high strength (σ{sub y} ~ 453.8 MPa), ductility (ε{sub f} ~ 24.5%) and static toughness (U{sub r} ~ 115.0 MJ/m{sup 3}) is achieved in a low-carbon steel subjected to torsion deformation and annealing treatments, compared with that (σ{sub y} ~ 282.4 MPa, ε{sub f} ~ 27.3% and U{sub r} ~ 102.9 MJ/m{sup 3}) of its coarse-grained counterpart. The enhancement of mechanical properties is attributed to the formation of a specific gradient structure with a thickness of ~ 3 mm, that is, the ferrite size increases while the volume fraction of the pearlite decreases continuously with the depth from the sample surface to the core. The strengthening and toughening mechanisms of the gradient-structured low-carbon steel are also discussed.

36 MATERIALS SCIENCE↗

Rare earth elements and radiogenic strontium isotopes in carbonate minerals reveal diagenetic influence in shales and limestones in the Appalachian Basin

Rare earth element (REE) signatures are often applied to interpret paleoenvironmental conditions in sedimentary basins, however the complicated diagenetic histories in dynamic depositional environments can affect interpretation of measured REE signatures. Prior studies on REE content in shales and limestones indicated that REE in specific mineral phases may provide unique information concerning diagenetic reactions occurring in sedimentary rocks during burial and compaction. Application of sequential extraction techniques to target REE signatures in specific mineral fractions may provide greater insight into the complex processes that occurred during diagenesis and catagenesis. Thus, using this technique, this study provides a detailed account for REE, 87 Sr/ 86 Sr, and δ 13 C in the carbonate fraction of the Marcellus Shale and adjacent formations in the Appalachian Basin. A suite of 49 rock samples collected from two cores recovered from Monongalia County, West Virginia, USA was analyzed. The results showed that the carbonate concretions in calcareous shales and carbonate cements in black shales were very distinct. The REE plus yttrium (REY) were more concentrated in the carbonate concretions than in the carbonate cements. The carbonate concretions displayed REY patterns that are closely similar to modern seawater, while MREE-enrichment was observed in the carbonate cements. Likewise, the 87 Sr/ 86 Sr values in the carbonate concretions were similar to those measured for unaltered Middle Devonian carbonates, while the 87 Sr/ 86 Sr in the carbonate cements were much more radiogenic. This observation indicates that the carbonate cement could have been inherited radiogenic 87 Sr expulsed from clays during illite-smectite transition. Overall, this study demonstrated two distinct processes involved with controlling the carbonate geochemistry within Appalachian Basin shales and limestones: one fraction displaying minimal diagenetic alteration relative to depositional conditions (carbonate concretions in calcareous shales and limestone carbonate in limestones), and another fraction displaying the evidence for extensive chemical alteration during illite-smectite transition and catagenesis (carbonate cements in black shales). Here, in addition, highly variable and significant enrichments of U and Mo demonstrate that the Union Spring member and the Lower Oatka Creek member of the Marcellus Shale in the southwestern Appalachian Basin (MSEEL site) were deposited under mainly anoxic environment whereas intermitted episodes of dysoxic to perhaps oxic conditions occurred during the deposition of the Upper Oatka Creek member.

58 GEOSCIENCES↗

Effect of gamma radiation on the photocatalytic properties of Cu doped titania nanoparticles

Highlights: • Defective Cu doped TiO{sub 2} powders were prepared by sol-gel route and gamma treatment. • Nanoscale analysis show evidence of internal doping by Cu{sup 2+} in the TiO{sub 2} sublattice. • Catalyst surfaces defect sites improve significantly the photocatalytic efficiency. • (Cu{sup 2+}, V{sub O}{sup -}) cooperative effects promote the photoelectrochemical properties of TiO{sub 2}. - Abstract: The aim of this paper is to study the effect of gamma-rays on structural, physicochemical, optical and photocatalytic performance of TiO{sub 2} nanoparticles doped with different concentrations of copper ranging from 0 to 6 at.%. The powders have been prepared by sol-gel technique and annealed at 400 °C. They were irradiated by gamma-rays with doses varying from 14 to 60 KGy. These investigations confirm the formation of anatase TiO{sub 2} nanoparticles and Cu{sup 2+} ion substitution for Ti{sup 4+} sites within the TiO{sub 2} structure. This study also shows that, once the TiO{sub 2} structure is saturated with copper, a metallic copper segregation is formed at the crystallite surfaces. After gamma irradiation, samples present a crystalline core and a disordered shell structure as a result of the formation of oxygen vacancies. Such oxygen vacancies at the TiO{sub 2} nanocrystal surface lead to a remarkable enhancement of the photocatalytic activity of Cu-doped TiO{sub 2} catalysts.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

THE RADIO PROPERTIES OF RADIO-LOUD NARROW-LINE SEYFERT 1 GALAXIES ON PARSEC SCALES

We present the detection of the compact radio structures of 14 radio-loud narrow-line Seyfert 1 (NLS1) galaxies from Very Long Baseline Array (VLBA) observations at 5 GHz performed in 2013. While 50% of the sources of our sample show a compact core only, the remaining 50% exhibit a core-jet structure. The measured brightness temperatures of the cores range from 10{sup 8.4} to 10{sup 11.4} K with a median value of 10{sup 10.1} K, indicating that the radio emission is from non-thermal jets, and that, likely, most sources are not strongly beamed, thus implying a low jet speed in these radio-loud NLS1 galaxies. In combination with archival data taken at multiple frequencies, we find that seven sources show flat or even inverted radio spectra, while steep spectra are revealed in the remaining seven objects. Although all of these sources are very radio-loud with R > 100, their jet properties are diverse in terms of their milliarcsecond (mas) scale (parsec scale) morphology and their overall radio spectral shape. The evidence for slow jet speeds (i.e., less relativistic jets), in combination with the low kinetic/radio power, may offer an explanation for the compact VLBA radio structure in most sources. The mildly relativistic jets in these high accretion rate systems are consistent with a scenario where jets are accelerated from the hot corona above the disk by the magnetic field and the radiation force of the accretion disk. Alternatively, a low jet bulk velocity can be explained by low spin in the Blandford–Znajek mechanism.

79 ASTRONOMY AND ASTROPHYSICS↗

Core-collapse supernovae in the Dark Energy Survey: luminosity functions and host galaxy demographics

ABSTRACT We present the luminosity functions and host galaxy properties of the Dark Energy Survey (DES) core-collapse supernova (CCSN) sample, consisting of 69 Type II and 50 Type Ibc spectroscopically and photometrically confirmed supernovae over a redshift range 0.045 < z < 0.25. We fit the observed DES griz CCSN light curves and K-correct to produce rest-frame R-band light curves. We compare the sample with lower redshift CCSN samples from Zwicky Transient Facility (ZTF) and Lick Observatory Supernova Search (LOSS). Comparing luminosity functions, the DES and ZTF samples of SNe II are brighter than that of LOSS with significances of 3.0σ and 2.5σ, respectively. While this difference could be caused by redshift evolution in the luminosity function, simpler explanations such as differing levels of host extinction remain a possibility. We find that the host galaxies of SNe II in DES are on average bluer than in ZTF, despite having consistent stellar mass distributions. We consider a number of possibilities to explain this – including galaxy evolution with redshift, selection biases in either the DES or ZTF samples, and systematic differences due to the different photometric bands available – but find that none can easily reconcile the differences in host colour between the two samples and thus its cause remains uncertain.

79 ASTRONOMY AND ASTROPHYSICS↗

A 50 kA Superconducting Transformer for the Upcoming High-Field High-Current Testing Station at the BNL

Brookhaven national laboratory is upgrading its existing user facility to support R&D for High Energy Physics (HEP) and Fusion Energy Sciences (FES). The goal of this upgrade is to host the testing of the superconducting cables, conductors, joints and insert coils under high magnetic field (10 T), with currents up to 50 kA (present limit 20 kA) and at temperatures varying from 4 K to 40 K. To provide a current up to 50 kA to the sample, a superconducting core-less transformer is under construction. The superconducting transformer would additionally reduce the heat loss at the current leads at high currents. The SC transformer consists of two coaxial coils. The primary coil is inside the secondary coil. The primary coil consists of 3048 turns of rectangular wires (1.91 mm x 1.27 mm), wound in 24 layers. The secondary coil consists of 13 turns of the secondary cable (18.35 mm x 5.96 mm), wound in one layer. The parameters of the transformer are chosen to satisfy the space restrictions while using the available conductor. Here this paper presents the design of the 50-kA transformer.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Sample-morphology effects on x-ray photoelectron peak intensities. III. Simulated spectra of model core–shell nanoparticles

The National Institute of Standards and Technology database for the simulation of electron spectra for surface analysis has been used to simulate Cu 2p photoelectron spectra for four types of spherical copper–gold nanoparticles (NPs). These simulations were made to extend the work of Tougaard [J. Vac. Sci. Technol. A 14, 1415 (1996)] and of Powell et al. [J. Vac. Sci. Technol. A 31, 021402 (2013)] who performed similar simulations for four types of planar copper–gold films. The Cu 2p spectra for the NPs were compared and contrasted with analogous results for the planar films and the effects of elastic scattering were investigated. The new simulations were made for a monolayer of three types of Cu/Au core–shell NPs on a Si substrate: (1) an Au shell of variable thickness on a Cu core with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm; (2) a Cu shell of variable thickness on an Au core with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm; and (3) an Au shell of variable thickness on a 1 nm Cu shell on an Au core with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm. For these three morphologies, the outer-shell thickness was varied until the Cu 2p{sub 3/2} peak intensity was the same (within 2%) as that found in our previous work with planar Cu/Au morphologies. The authors also performed similar simulations for a monolayer of spherical NPs consisting of a CuAu{sub x} alloy (also on a Si substrate) with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm. In the latter simulations, the relative Au concentration (x) was varied to give the same Cu 2p{sub 3/2} peak intensity (within 2%) as that found previously. For each morphology, the authors performed simulations with elastic scattering switched on and off. The authors found that elastic-scattering effects were generally strong for the Cu-core/Au-shell and weak for the Au-core/Cu-shell NPs; intermediate elastic-scattering effects were found for the Au-core/Cu-shell/Au-shell NPs. The shell thicknesses required to give the selected Cu 2p{sub 3/2} peak intensity for the three types of core–shell NPs were less than the corresponding film thicknesses of planar samples since Cu 2p photoelectrons can be detected from the sides and, for the smaller NPs, bottoms of the NPs. Elastic-scattering effects were also observed on the Au atomic fractions found for the CuAu{sub x} NP alloys with different diameters.

36 MATERIALS SCIENCE↗

Proposal and application of ROM-Lasso method for sensitivity coefficient evaluation

We propose a novel method for evaluating sensitivity coefficients of neutronics parameters to cross sections, so-called the reduced-order modeling technique ROM-Lasso. In this method, cross sections of interest are randomly sampled, and corresponding perturbed core analyses are performed. Then, the sensitivity coefficient vector of the higher-level model is expanded via the active subspace bases obtained with the lower-level model whose dimensional complexity is smaller than that of the higher-level model, and the expansion coefficients are estimated by the Lasso regression. A unique feature of the ROM-Lasso method allows the use of different bases optimized for each neutronics parameter. We conducted a verification calculation for an accelerator-driven system and demonstrated that the ROM-Lasso method can reproduce the sensitivity coefficients with a much smaller number of forward calculations than the direct method. The proposed method can be used to practically evaluate sensitivity coefficients. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Physiochemical Evidence of Faulting Processes and Modeling of Fluid in Evolving Fault Systems in Southern California

Our study targets recent (Plio-Pleistocene) faults and young (Tertiary) petroleum fields in southern California. Faults include the Refugio Fault in the Transverse Ranges, the Ellwood Fault in the Santa Barbara Channel, and most recently the Newport- Inglewood in the Los Angeles Basin. Subsurface core and tubing scale samples, outcrop samples, well logs, reservoir properties, pore pressures, fluid compositions, and published structural-seismic sections have been used to characterize the tectonic/diagenetic history of the faults. As part of the effort to understand the diagenetic processes within these fault zones, we have studied analogous processes of rapid carbonate precipitation (scaling) in petroleum reservoir tubing and manmade tunnels. From this, we have identified geochemical signatures in carbonate that characterize rapid CO 2 degassing. These data provide constraints for finite element models that predict fluid pressures, multiphase flow patterns, rates and patterns of deformation, subsurface temperatures and heat flow, and geochemistry associated with large fault systems.

01 COAL, LIGNITE, AND PEAT↗

Development of advanced strain diagnostic techniques for reactor environments

The following research is operated as a Laboratory Directed Research and Development (LDRD) initiative at Sandia National Laboratories. The long-term goals of the program include sophisticated diagnostics of advanced fuels testing for nuclear reactors for the Department of Energy (DOE) Gen IV program, with the future capability to provide real-time measurement of strain in fuel rod cladding during operation in situ at any research or power reactor in the United States. By quantifying the stress and strain in fuel rods, it is possible to significantly improve fuel rod design, and consequently, to improve the performance and lifetime of the cladding. During the past year of this program, two sets of experiments were performed: small-scale tests to ensure reliability of the gages, and reactor pulse experiments involving the most viable samples in the Annulated Core Research Reactor (ACRR), located onsite at Sandia. Strain measurement techniques that can provide useful data in the extreme environment of a nuclear reactor core are needed to characterize nuclear fuel rods. This report documents the progression of solutions to this issue that were explored for feasibility in FY12 at Sandia National Laboratories, Albuquerque, NM.

Fleming, Darryn D.↗