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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 793 records · Page 44

An experimental investigation with artificial sunlight of a solar hot-water heater

Thermal performance measurements were made of a commercial solar hot water heater in a solar simulator to determine basic performance characteristics of a traditional type of flat plate collector, with and without side reflectors (to increase the solar flux). Information on each of the following was obtained; (1) the effect of flow and incidence angle on the efficiency of a flat plate collector (but only without side reflectors); (2) transient performance under flow and nonflow conditions; (3) the effectiveness of reflectors to increase collector efficiency for a zero radiation angle at fluid temperatures required for solar air conditioning; and (4) the limits of applicability of a collector efficiency correlation based on the Hottel Whillier equation.

Simon, F. F.↗

A numerical study of general viscous flows around multi-element airfoils

An efficient numerical procedure based on a velocity integral representation and Fourier series expansion is developed to compute the unsteady viscous flows around multielement airfoils. Flow developments initiated from an impulsively started motion of a Boeing VR7 airfoil with or without a leading-edge slat are studied in both laminar and turbulent flow conditions. The effect of the presence of the slat to the surface pressure distribution of the airfoil is assessed.

Wang, C. M.↗

Compliant and stretchable thermoelectric coils for energy harvesting in miniature flexible devices

With accelerating trends in miniaturization of semiconductor devices, techniques for energy harvesting become increasingly important, especially in wearable technologies and sensors for the internet of things. Although thermoelectric systems have many attractive attributes in this context, maintaining large temperature differences across the device terminals and achieving low–thermal impedance interfaces to the surrounding environment become increasingly difficult to achieve as the characteristic dimensions decrease. Here, we propose and demonstrate an architectural solution to this problem, where thin-film active materials integrate into compliant, open three-dimensional (3D) forms. This approach not only enables efficient thermal impedance matching but also multiplies the heat flow through the harvester, thereby increasing the efficiencies for power conversion. Interconnected arrays of 3D thermoelectric coils built using microscale ribbons of monocrystalline silicon as the active material demonstrate these concepts. Quantitative measurements and simulations establish the basic operating principles and the key design features. The results suggest a scalable strategy for deploying hard thermoelectric thin-film materials in harvesters that can integrate effectively with soft materials systems, including those of the human body.

42 ENGINEERING↗

Performance Demonstration of an Occupancy Sensor-enabled Integrated Solution for Commercial Buildings

Traditionally, a single-loop fixed-gain controller is applied to supply fan (SF) and cooling coil (CC) valve controls while a fixed-damper position control is applied to outdoor air (OA) damper control at air handling units (AHUs) in commercial buildings. With the increasing application of occupancy sensors, the information generated by occupancy sensors is applied to not only reduce the electricity loads from lighting and controllable plug loads, but also reset OA intake and minimum supply airflow setpoints. Meanwhile, these intermittent operation actions greatly elevate the dynamics of AHU systems, which may introduce unstable SF and CC valve operations and inaccurate OA flow control at AHUs and consequently degrade maximum energy efficiency gains. With virtual fan and valve flow meter technologies, two advanced controls, including cascade control and gain scheduling control, can be implemented on both the SF and CC valve, and an advanced control using a virtual OA flow meter can be implemented on OA damper integrated with occupancy sensors. The goal of this project is to demonstrate the savings, cost, and performance of an integrated solution that integrates the three advanced HVAC controls with occupancy sensors to allow accurate and stable AHU operations in real buildings. The project objectives are to: 1) develop and validate an advance SF control algorithm; 2) develop and validate an advanced CC valve control algorithm; 3) validate an algorithm to implement a virtual OA flow meter; and 4) demonstrate the savings, cost, and performance of the integrated solution in real buildings. The technical approaches are to: 1) select a test system at the University of Oklahoma; 2) develop and implement the algorithms of advanced SF and CC valve controls and validate the performance; 3) develop and implement the advanced OA control using a virtual OA flow meter and validate the performance; 4) demonstrate the savings, cost, and performance of the proposed integrated solution with and without three advanced HVAC controls; and 5) disseminate the project results through publications and presentations. For the SF control, both the gain scheduling and cascade controls can improve the fan energy performance by reducing the fan power during the transient period and the fan control performance at lower speeds by reducing fan speed variation. Moreover, the gain scheduling control provides a simple and low-cost solution and is recommended. The fan power savings can reach 30% in a transient period. For the CC valve control, the gain scheduling control can considerably reduce the supply air temperature oscillation range and frequency under both higher and lower load conditions and the control valve response is much more stable. As a result, the gain scheduling control is recommended. The projected pump energy consumption can be reduced by 68.5%. With the developed virtual OA flow meter, the OA can be accurately controlled at its setpoint, which is determined based on the actual number of occupants in the building provided by occupancy sensors. The RMSE of the proposed OA control is 15.9 L/s. The energy data shows that the fan power and CC cooling energy were significantly reduced. On the other hand, the energy savings majorly results from the occupancy sensors and the energy savings by the advanced HVAC controls is minimal because that the controllers in the test AHU were tuned with very slow response. An annual technical savings potential is estimated as 0.5 quads in the commercial sector.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Single stage experimental evaluation of tandem-airfoil rotor and stator blading for compressors. Part 4: Data and performance for stage B

Stage B, composed of tandem-airfoil rotor B and stator B, was tested with uniform inlet flow and with hub radial, tip radial and 90 degree one-per-revolution circumferential distortion of the inlet flow as part of an overall program to evaluate the effectiveness of tandem airfoils for increasing the design point loading capability and stable operating range of rotor and stator blading. The results of this series of tests provide overall performance and blade element data for evaluating: (1) the potential of tandem blading for extending the loading limit and stable operating range of a stage representative of a middle stage of an advanced high pressure compressor, (2) the effect of loading split between the two airfoils in tandem on the performance of tandem blading, and (3) the effects of inlet flow distortion on the stage performance. The rotor had an inlet hub/tip ratio of 0.8 and a design tip velocity of 757 ft/sec. With uniform inlet flow, rotor B achieved a maximum adiabatic efficiency of 88.4% at design equivalent rotor speed and a pressure ratio of 1.31. The stage maximum adiabatic efficiency at design equivalent rotor speed with uniform inlet flow was 82.5% at a pressure ratio of 1.28. Tip radial and circumferential distortion of the inlet flow caused substantial reductions in surge margin.

Brent, J. A.↗

Single-stage experimental evaluation of tandem-airfoil rotor stator blading for compressors. Part 6: Data and performance for stage D

An axial flow compressor stage, having single-airfoil blading, was designed for zero rotor prewhirl, constant rotor work across the span, and axial discharge flow. The stage was designed to produce a pressure ratio of 1.265 at a rotor tip velocity of 757 ft/sec. The rotor had an inlet hub/tip ratio of 0.8. The design procedure accounted for the rotor inlet boundary layer and included the effects of axial velocity ratio and secondary flow on blade row performance. The objectives of this experimental program were: (1) to obtain performance with uniform and distorted inlet flow for comparison with the performance of a stage consisting of tandem-airfoil blading designed for the same vector diagrams; and (2) to evaluate the effectiveness of accounting for the inlet boundary layer, axial velocity ratio, and secondary flows in the stage design. With uniform inlet flow, the rotor achieved a maximum adiabatic efficiency of 90.1% at design equivalent rotor speed and a pressure ratio of 1.281. The stage maximum adiabatic efficiency at design equivalent rotor speed with uniform inlet flow was 86.1% at a pressure ratio of 1.266. Hub radial, tip radial, and circumferential distortion of the inlet flow caused reductions in surge pressure ratio of approximately 2, 10 and 5%, respectively, at design rotor speed.

Clemmons, D. R.↗

Overall and blade element performance of a 1.20-pressure-ratio fan stage with rotor blades reset -5 deg

A 51-cm-diam model of a fan stage for a short haul aircraft was tested in a single stage-compressor research facility. The rotor blades were set 5 deg toward the axial direction (opened) from design setting angle. Surveys of the air flow conditions ahead of the rotor, between the rotor and stator, and behind the stator were made over the stable operating range of the stage. At the design speed of 213.3 m/sec and a weight flow of 31.5 kg/sec, the stage pressure ratio and efficiency were 1.195 and 0.88, respectively. The design speed rotor peak efficiency of 0.91 occurred at the same flow rate.

Lewis, G. W., Jr.↗

A fast Euler solver for steady flows

A numerical technique to solve the Euler equations for steady, two-dimensional flows is presented. The technique extends to two-dimensional problems a formulation which was found to be extremely efficient for one-dimensional flows. Generalized Riemann variables are defined along two families of orthogonal coordinates, and integrated separately, sweeping back and forth alternatively along coordinate lines. The technique is second-order accurate and converges very rapidly. In addition, each step requires a minimal number of operations. Preliminary results for subsonic and transonic shockless flows are presented and discussed.

Moretti, G.↗

Liquid–Liquid Microfluidic Flows for Ultrafast 5-Hydroxymethyl Furfural Extraction

We study the effects of liquid–liquid flow patterns on the extraction of 5-hydroxymethyl furfural from the aqueous phase into an organic phase (methyl isobutyl ketone, ethyl acetate, and 2-pentanol) at ultrashort residence times of 0.2–20 s in a coiled capillary microchannel. Slug, droplet, slug-droplet, dispersed, parallel, annular, and irregular two-phase flow patterns are generated. We evaluate the extraction efficiency and the volumetric mass transfer coefficient via experiments and computational fluid dynamics (CFD). The CFD predictions are in quantitative agreement with the experimental data. The convective and diffusive contributions to the mass transfer of different flow patterns are analyzed. For all solvent pairs, the extraction efficiency varies irregularly with increasing flow rate due to changes in the mass transfer mechanism caused by a transition between flow regimes. Overall, we demonstrate >90% extraction efficiencies with high volumetric mass transfer coefficients ranging from 0.006 to 2.17 s–1. Furthermore, a merit index is defined to assess the trade-off between the fast mass transfer and the pressure drop in biphasic microchannels. In general, the mass transfer rate increases significantly at high flow rates at the expense of a high-pressure drop. Furthermore, the ethyl acetate/water irregular flow pattern is optimal due to a large throughput, extraction efficiency, and mass transfer coefficient, with a minimal pressure drop.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Analysis and Optimization of the Recompression Cycle with High Temperature Recuperator Bypass for Concentrating Solar Power Applications

This work analyzes the sCO2 recompression with high temperature recuperator (HTR) bypass power cycle for use in concentrating solar power (CSP) systems. CSP operation differs from other thermal power plants in that CSP must balance between maximizing the heat transfer fluid (HTF) temperature difference and maximizing the cycle thermal efficiency, which typically are inversely related. Large HTF temperature differences reduce the size and cost of thermal energy storage (TES), improve the solar receiver efficiency, and require lower mass flow rates that reduce pumping power required to elevate the HTF to the receiver. The recompression cycle with HTR bypass potentially offers improved thermal efficiency with larger HTF temperature differences as compared to the recompression cycle, and it has fewer turbomachinery components than the partial cooling cycle. The recompression with HTR bypass cycle adds a second lower temperature primary heat exchanger which transfers heat from the HTF to the fraction of sCO2 flow that bypasses the HTR. We developed a model to compare the recompression with HTR bypass cycle to the recompression and partial cooling cycles. A sweep of design parameters including bypass fraction, recompression fraction, recuperator conductance, and pressure ratio is used to form a pareto-optimal front with the cycle thermal efficiency and HTF temperature difference as objectives. An optimization routine has also been developed to find optimal design point parameters for a target HTF temperature difference. The performance of the recompression with HTR bypass cycle is compared with recompression and partial cooling cycles.

concentrating solar power↗

Translation-vibration-dissociation coupling in nonequilibrium hypersonic flows

A new simple and computationally efficient model was developed, describing the evolution of vibrational states during relaxation and dissociation. The model is based on dividing the nitrogen molecules into two types, those in the vibrational states at a lower level, whose vibrational energy is below a cutoff energy, and those in an upper level, with vibrational energy above the cutoff. Dissociation occurs at the upper level, and recombination returns molecules to the lower level. The model was applied to two flows of engineering interest, the flow through a normal Mach 15 shock wave at 60 km, and a supersonic quasi-one-dimensional flow in a nozzle. Results are compared to those obtained by existing translation-vibration-dissociation coupling models, with results indicating significant differences between the models.

Candler, Graham↗

Elucidating Instabilities Contributing to Capacity Fade in Bipyridine‐Based Materials for Non‐aqueous Flow Batteries

Abstract Metal‐based non‐aqueous redox flow batteries have the potential for long‐term energy storage if stability requirements can be achieved. One such stability issue in metal coordination complexes arises from ligand shedding in the anolyte upon reduction. Recognizing that the free ligands are relatively more stable than the metal coordination complex under highly reducing conditions, we evaluated a family of metal‐free bipyridinium materials as flow battery anolytes with the corresponding iron coordination complex as the catholyte. Bipyridinium compounds were functionalized for increased electrochemical stability, cycled in flow cells to understand efficiencies, and analyzed for degradation products. Methylation of the bipyridine nitrogens increased electrochemical stability yet left the reduced molecule susceptible to radical‐induced bond cleavage. Subsequent functionalization of bipyridine with carbomethoxy groups resulted in good battery performance with 96 % Coulombic and 90 % voltage efficiency, and improved cycling stability over a methoxy‐substituted anolyte with 14 % vs 36 % capacity fade in the first charge‐discharge cycle.

Kolesnichenko, Claudina X.↗

Robust system size reduction of discrete fracture networks: a multi-fidelity method that preserves transport characteristics

In this paper, we propose a multi-fidelity system reduction technique that uses weighted graphs paired with three-dimensional discrete fracture network (DFN) modelling for efficient simulation of subsurface flow and transport in fractured media. DFN models are used to simulate flow and transport in subsurface fractured rock with low-permeability. One method to alleviate the heavy computational overhead associated with these simulations is to reduce the size of the DFN using a graph representation of it to identify the primary flow sub-network and only simulate flow and transport thereon. The first of these methods used unweighted graphs constructed solely on DFN topology and could be used for accurate predictions of first-passage times. However, these techniques perform poorly when predicting later stages of the mass breakthrough. We utilize a weighted-graph representation of the DFN where edge weights are based on hydrological parameters in the DFN that allows us to exploit the kinematic quantities derivable a posteriori from the flow solution obtained on the graph representation of the DFN to perform system reduction and predict the later stages of the breakthrough curve with high fidelity. We also propose and demonstrate the use of an adaptive pruning algorithm with error control that produces a pruned DFN sub-network whose predicted mass breakthrough agrees with the original DFN within a user-specified tolerance. Lastly, the method allows for the level of accuracy to be a user-controlled parameter.

58 GEOSCIENCES↗

System efficiency and power assessment of the all-aqueous copper thermally regenerative ammonia battery

Thermally regenerative ammonia batteries (TRABs) use low-temperature (T < 100 °C) heat to provide stationary energy and power with higher power densities and efficiency relative to other waste heat devices. TRABs are an active area of research in waste heat devices, but currently there is little consensus on what aspect of the system is limiting TRAB performance and what maximum efficiencies are possible. Experiments and numerical models were used here to examine the sensitivity of the battery and distillation column in a TRAB system to key operating variables, thereby establishing practical limits and identifying focus areas for improving performance. Battery power was eight times more sensitive to ohmic losses than kinetic and mass transfer losses, regardless of the operating temperature, and the peak power density was simulated to be 18.8 mW cm –2 at 75 °C. Theoretical energy efficiency limits were defined for a series of ammonia concentrations and operating pressures, ranging from 5 – 12%, which is 2–3 times higher than previous experimental estimations. Atmospheric pressure column operation used a larger amount of waste heat compared to sub-atmospheric pressure. It is estimated that the volume of the battery would take up 9.2m 3 for every 1% of the power output of a natural gas turbine, but with realistic improvements to cell conductivity, the size would reduce to 2.5 m 3 . Finally, the results presented in this work will help streamline future development by focusing on minimizing ohmic losses and provide specific data for full system evaluation of future TRABs.

25 ENERGY STORAGE↗

Tritium aspects of the fusion nuclear science facility

The Fusion Nuclear Science Facility (FNSF) is intended to bridge the technical gaps from ITER to DEMO, and provide a fully nuclear environment for the advancement of materials and blanket science, among other missions. Though smaller (~500 MW fusion power) than the envisioned DEMO, our FNSF design still seeks to test DEMO-relevant components and technologies, and to that end one of its goals is to achieve a tritium breeding ratio near one using a dual-cooled lead lithium (DCLL) blanket. We explore here the migration of bred tritium through in-vessel components and coolant loops, which is exacerbated by the relatively low solubility of tritium in PbLi and the high operating temperatures envisioned in later phases of operation. Some features inherent to the design of the DCLL help limit tritium losses, namely the relatively high PbLi flow rates; coupled with efficient tritium extraction, the DCLL potentially achieves low tritium permeation losses without the use of permeation barriers. We outline here the design of such an extraction system, and some of the materials challenges that must be met in order to realize it. The efficacy of these and other design features, such as coaxial piping, is demonstrated via a series of parameter studies. We also investigate the effect of parameter uncertainties, and find that the imprecise knowledge of the tritium solubility in PbLi in particular leads to very disparate estimates of tritium losses. Depending on the experimental value used, losses range from ~0.05 to over 6 grams of tritium per year. As a result, the former is acceptable based on estimated environmental releases and resultant dose to members of the public; the latter exceeds regulatory limits.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

3D printing synthesis of catalysts

The catalyst industry generates approximately $20 billion every year globally and plays a major role in the energy production sector. Traditional industrial catalysts (e.g., pellets) typically have mass and heat transfer limitations, and cause a pressure drop in continuous-flow reactors, lowering the efficiency of the catalytic processes. 3D printing technology has evolved rapidly over the past decade, and the 3D printing of catalysts with desired geometries can address many of the above-stated challenges with traditional catalysts. However, challenges remain to be addressed and opportunities remain to be explored before the full potential in the design and 3D printing of novel catalysts can be realized. Herein this article reviews the recent development in the 3D printing of catalysts. It summarizes the 3D printing design, dimension, property, and performance of 3D printed catalysts. The applications of 3D printed catalysts, such as reforming, wastewater treatment, and CO 2 capture and removal, are discussed, with a techno-economic analysis and life cycle analysis. Future research directions and opportunities for 3D printing of catalysts are also highlighted.

25 ENERGY STORAGE↗