Search NASA⌕ Search

SEARCH · Search NASA

Results for “sample environment”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 793 records · Page 44
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Studying light-harvesting models with superconducting circuits

The process of photosynthesis, the main source of energy in the living world, converts sunlight into chemical energy. The high efficiency of this process is believed to be enabled by an interplay between the quantum nature of molecular structures in photosynthetic complexes and their interaction with the environment. Investigating these effects in biological samples is challenging due to their complex and disordered structure. Here we experimentally demonstrate a technique for studying photosynthetic models based on superconducting quantum circuits, which complements existing experimental, theoretical, and computational approaches. We demonstrate a high degree of freedom in design and experimental control of our approach based on a simplified three-site model of a pigment protein complex with realistic parameters scaled down in energy by a factor of 10 5 . We show that the excitation transport between quantum-coherent sites disordered in energy can be enabled through the interaction with environmental noise. We also show that the efficiency of the process is maximized for structured noise resembling intramolecular phononic environments found in photosynthetic complexes.

42 ENGINEERING↗
NASA NTRS1999

Acceleration Measurement and Characterization in Support of the USMP-4 Payloads

One common characteristic of the USMP-4 experiments is that various effects of gravity make it difficult, if not impossible, to achieve usable results when performing the experiments on Earth's surface. Therefore, the investigators took advantage of the microgravity environment afforded by being in low-Earth orbit to perform their research. Interpretation of the experiment results both during the mission and upon post-mission analyses of data and samples required an understanding of the microgravity environment in which the experiments were conducted. To achieve that understanding, data were collected using the Orbital Acceleration Research Experiment (OARE) and two Space Acceleration Measurement Systems (SAMS). Data from those systems, combined with an assessment of mission and experiment activities, were used to characterize the microgravity environment that existed on Columbia during the mission. The text herein gives details about some characteristics of the environment that were noted during the mission and during post-mission data analysis. The disturbances studied include the Ku-band antenna 17 Hz dither; the effect of changing the Orbiter attitude deadband limits; the effects of different bicycle ergometer configurations; and the effect of IDGE (Isothermal Dendritic Growth Experiment) experiment fans and SAMS computer hard drives. Additional information about the microgravity environment is provided. Supplementary data plots representing the environment throughout the majority of the mission are available at the Uniform Resource Locator (URL). Data files for both SAMS and OARE are accessible via anonymous file transfer protocol from the file server.

Rogers, M. J. B.↗
NASA NTRS2016

Recommended Maximum Temperature For Mars Returned Samples

The Returned Sample Science Board (RSSB) was established in 2015 by NASA to provide expertise from the planetary sample community to the Mars 2020 Project. The RSSB's first task was to address the effect of heating during acquisition and storage of samples on scientific investigations that could be expected to be conducted if the samples are returned to Earth. Sample heating may cause changes that could ad-versely affect scientific investigations. Previous studies of temperature requirements for returned mar-tian samples fall within a wide range (-73 to 50 degrees Centigrade) and, for mission concepts that have a life detection component, the recommended threshold was less than or equal to -20 degrees Centigrade. The RSSB was asked by the Mars 2020 project to determine whether or not a temperature requirement was needed within the range of 30 to 70 degrees Centigrade. There are eight expected temperature regimes to which the samples could be exposed, from the moment that they are drilled until they are placed into a temperature-controlled environment on Earth. Two of those - heating during sample acquisition (drilling) and heating while cached on the Martian surface - potentially subject samples to the highest temperatures. The RSSB focused on the upper temperature limit that Mars samples should be allowed to reach. We considered 11 scientific investigations where thermal excursions may have an adverse effect on the science outcome. Those are: (T-1) organic geochemistry, (T-2) stable isotope geochemistry, (T-3) prevention of mineral hydration/dehydration and phase transformation, (T-4) retention of water, (T-5) characterization of amorphous materials, (T-6) putative Martian organisms, (T-7) oxidation/reduction reactions, (T-8) (sup 4) He thermochronometry, (T-9) radiometric dating using fission, cosmic-ray or solar-flare tracks, (T-10) analyses of trapped gasses, and (T-11) magnetic studies.

Beaty, D. W.↗
NASA NTRS2016

Evaluation of the MICAST #2-12 AI-7wt%Si Sample Directionally Solidified Aboard the International Space Station

The US team of the European led "MIcrostructure Formation in CASTing of Technical Alloys under Diffusive and Magnetically Controlled Convective Conditions" (MICAST) program recently received a third Aluminum - 7wt% silicon alloy that was processed in the microgravity environment aboard the International Space Station. The sample, designated MICAST#2-12, was directionally solidified in the Solidification with Quench Furnace (SQF) at a constant rate of 40micometers/s through an imposed temperature gradient of 31K/cm. Procedures taken to evaluate the state of the sample prior to sectioning for metallographic analysis are reviewed and rational for measuring the microstructural constituents, in particular the primary dendrite arm spacing (Lambda (sub1)), is given. The data are presented, put in context with the earlier samples, and evaluated in view of a relevant theoretical model.

Tewari, Surendra N.↗
DOE OSTI2023

SDSS-IV MaNGA: the role of the environment in AGN triggering

ABSTRACT The large- and small-scale environments around optically-selected AGN host galaxies and a control sample of non-active galaxies in the MaNGA survey have been investigated in order to evaluate the importance of the environment in AGN triggering. Using the MaNGA integral field spectroscopy, we quantify non-circular motions of the ionized gas and detect an excess of radial gas motions in AGN hosts relative to control galaxies, not associated to AGN feedback and are most likely the result of tidal interactions, possibly associated with the triggering of the AGN. We find that the large-scale environments are similar for the AGN hosts and control galaxies in our sample and are biased towards lower large-scale densities and group virial masses, suggestive that the large-scale environment properties is only relevant to the AGN phenomenon in an indirect way, in the form, e.g. of the morphology-density relation. The small-scale environment, as measured by the frequency and luminosity of close neighbours, was also found to be similar for AGN and control galaxies. However, we find a correlation between the intensity of the non-circular gas motions in AGN hosts and the strength of the tidal field, while the control sample does not present such correlation. Also, AGN hosts with the most intense radial gas motions present larger tidal fields than their control galaxies. These findings indicate that at least a fraction of the AGN hosts in our sample have been triggered by tidal interactions with nearby galaxies.

Rembold, Sandro B.↗
DOE OSTI2018

Stress Testing of Organic Light- Emitting Diode Panels and Luminaires

This report builds on previous DOE efforts with OLED technology by updating information on a previously benchmarked OLED product (the Chalina luminaire from Acuity Brands) and provides new benchmarks on the performance of Brite 2 and Brite Amber OLED panels from OLEDWorks. During the tests described here, samples of these devices were subjected to continuous operation in stress tests at elevated ambient temperature environments of 35°C or 45°C. In addition, samples were also operated continuously at room temperature in a room temperature operational life test (RTOL). One goal of this study was to investigate whether these test conditions can accelerate failure of OLED panels, either through panel shorting or an open circuit in the panel. These stress tests are shown to provide meaningful acceleration of OLED failure modes, and an acceleration factor of 2.6 was calculated at 45°C for some test conditions. In addition, changes in the photometric properties of the emitted light (e.g., luminous flux and chromaticity maintenance) was also evaluated for insights into the long-term stability of these products compared to earlier generations. Because OLEDs are a lighting system, electrical testing was also performed on the panel-driver pairs to provide insights into the impact of the driver on long-term panel performance.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
NASA NTRS2018

Field Exploration and Life Detection Sampling for Planetary Analogue Research (FELDSPAR): Variability and Correlation in Biomarker and Mineralogy Measurements from Icelandic Mars Analogues

In situ exploration of planetary environments allows biochemical analysis of sub-centimeter-scale samples; however, landing sites are selected a priori based on measurable meter- to kilometer-scale geological features. Optimizing life detection mission science return requires both understanding the expected biomarker distributions across sample sites at different scales and efficiently using first-stage in situ geochemical instruments to justify later-stage biological or chemical analysis. Icelandic volcanic regions have an extensive history as Mars analogue sites due to desiccation, low nutrient availability, and temperature extremes, in addition to the advantages of geological youth and isolation from anthropogenic contamination. Many Icelandic analogue sites are also rugged and remote enough to create the same type of instrumentation and sampling constraints typically faced by robotic exploration.

Planetary↗
NASA NTRS1992

Search for partial systemic Lyman edges in nearby quasars

IUE archival spectra of nearby quasars with redshifts in the range 0.4-2.3 were searched for changes in the continuum at the systemic Lyman edge positions. Thirty-nine percent of the sample do not show any discontinuities. Twenty-nine percent of the sample show complete Lyman edges at redshifts less than the quasar redshift. These objects have associated narrow absorption lines; hence the intervening gas responsible for the absorption is extrinsic to the quasar and its environment. Twenty-two percent of the sample show Lyman edges at the quasar redshift with associated narrow absorption lines. In these objects the gas is associated with the AGN or its host galaxy. Ten percent of the sample have Lyman edges with no known associated absorption lines. If Lyman edge discontinuities are due to optically thick, geometrically thin accretion disks, which are randomly oriented to the line of sight, these results indicate that the Lyman edge discontinuity, either in emission or absorption, has to be not more than 15 percent in most quasars.

Koratkar, A. P.↗
NASA NTRS2018

Radar Measurements of the LEO Orbital Debris Environment

Access to space and the preservation of the near-Earth space environment is of critical significance. Increased interest in issues surrounding space traffic management and the continued assessment and discussion of orbital debris at the United Nations Committee on the Peaceful Uses of Outer Space (COPUOS) illustrates the significance of the topic of orbital debris. There are currently over 20,000 tracked objects in the publicly available satellite catalog on Space-Track.org. The catalog is maintained by the US Air Force Space Command using a network of optical and radar ground-based sensors and is believed to be complete for a characteristic size of 10 cm or larger in low Earth orbit (LEO). Based on the work of the NASA Orbital Debris Program Office (ODPO) over approximately the past 40 years it is understood that the small debris population (< 10 cm) increases by orders of magnitude as characteristic size decreases. With population estimates ranging from 500,000 to 1,000,000 small debris objects (> 5 mm) in orbit, it is currently not practical to track and maintain precision orbits on every object. Instead the NASA ODPO uses powerful ground-based radars to sample the low Earth Orbit (LEO) environment and assign approximate orbits to each detection. This poses an interesting signal processing challenge as we are trying to detect the smallest objects possible on the edge of the radar's sensitivity. For approximately the last 30 years, NASA ODPO has partnered with the Massachusetts Institute of Technology Lincoln Laboratory (MIT/LL) to utilize the Haystack Ultra-wideband Satellite Imaging Radar (HUSIR - formerly the Long-Range Imaging Radar or simply Haystack) and the Haystack Auxiliary (HAX) radar to collect orbital debris radar data. Additionally, the ODPO collaborates with the NASA Jet Propulsion Laboratory (JPL) to use the Goldstone Solar System Radar. The orbital debris detections from these radars serve as inputs for statistical risk models used by the human spaceflight and satellite communities to assess risk to spacecraft posed by orbital debris. In this paper, we will describe the history of orbital debris radar measurements conducted by NASA, provide an overview of current radar measurements techniques and facilities, discuss the signal processing software used for orbital debris measurements and the inference of debris size and orbital parameters from these measurements, and discuss how orbital debris radar measurements are validated for use in models that are used throughout the aerospace industry.

Blackwell, Chris↗
NASA NTRS1999

Coarsening in Solid-Liquid Mixtures Studied on the Space Shuttle

Ostwald ripening, or coarsening, is a process in which large particles in a two-phase mixture grow at the expense of small particles. It is a ubiquitous natural phenomena occurring in the late stages of virtually all phase separation processes. In addition, a large number of commercially important alloys undergo coarsening because they are composed of particles embedded in a matrix. Many of them, such as high-temperature superalloys used for turbine blade materials and low-temperature aluminum alloys, coarsen in the solid state. In addition, many alloys, such as the tungsten-heavy metal systems, coarsen in the solid-liquid state during liquid phase sintering. Numerous theories have been proposed that predict the rate at which the coarsening process occurs and the shape of the particle size distribution. Unfortunately, these theories have never been tested using a system that satisfies all the assumptions of the theory. In an effort to test these theories, NASA studied the coarsening process in a solid-liquid mixture composed of solid tin particles in a liquid lead-tin matrix. On Earth, the solid tin particles float to the surface of the sample, like ice in water. In contrast, in a microgravity environment this does not occur. The microstructures in the ground- and space-processed samples (see the photos) show clearly the effects of gravity on the coarsening process. The STS-83-processed sample (right image) shows nearly spherical uniformly dispersed solid tin particles. In contrast, the identically processed, ground-based sample (left image) shows significant density-driven, nonspherical particles, and because of the higher effective solid volume fraction, a larger particle size after the same coarsening time. The "Coarsening in Solid-Liquid Mixtures" (CSLM) experiment was conducted in the Middeck Glovebox facility (MGBX) flown aboard the shuttle in the Microgravity Science Laboratory (MSL-1/1R) on STS-83/94. The primary objective of CSLM is to measure the temporal evolution of the solid particles during coarsening.

Caruso, John J.↗
NASA NTRS2017

Validation of a Thermo-Ablative Model of Elastomeric Internal Insulation Materials

In thermo-ablative material modeling, as in many fields of analysis, the quality of the existing models significantly exceeds that of the experimental data required for their validation. In an effort to narrow this gap, a laboratory-scale internal insulation test bed was developed that exposes insulation samples to realistic solid rocket motor (SRM) internal environments while being instrumented to record real-time rates of both model inputs (i.e., chamber pressure, total surface heat flux, and radiative heat flux) as well as model outputs (i.e., material decomposition depths (MDDs) and in-depth material temperatures). In this work, the measured SRM internal environment parameters were used in conjunction with equilibrium thermochemistry codes as inputs to one-dimensional thermo-ablative models of the PBINBR and CFEPDM insulation samples used in the lab-scale test firings. The computed MDD histories were then compared with those deduced from real-time X-ray radiography of the insulation samples, and the calculated in-depth temperatures were compared with those measured by embedded thermocouples. The results of this exercise emphasize the challenges of modeling and testing elastomeric materials in SRM environments while illuminating the path forward to improved fidelity.

Martin, Heath T.↗
NASA NTRS2006

Mobile Robot for Exploring Cold Liquid/Solid Environments

The Planetary Autonomous Amphibious Robotic Vehicle (PAARV), now at the prototype stage of development, was originally intended for use in acquiring and analyzing samples of solid, liquid, and gaseous materials in cold environments on the shores and surfaces, and at shallow depths below the surfaces, of lakes and oceans on remote planets. The PAARV also could be adapted for use on Earth in similar exploration of cold environments in and near Arctic and Antarctic oceans and glacial and sub-glacial lakes.

Bergh, Charles↗
NASA NTRS1988

Moisture interaction and stability of ZOT (Zinc Orthotitanate) thermal control spacecraft coating

Two of the many performance requirements of the zinc orthotitanate (ZOT) ceramic thermal control paint covering parts of the Jupiter-bound Galileo spacecraft are that it be sufficiently electrically conductive so as to prevent electrostatic discharge (ESD) damage to onboard electronics and that it adhere to and protect the substrate from corrosion in terrestrial environments. The bulk electrical resistivity of ZOT on an aluminum substrate was measured over the ranges 22 C to 90 C and 0 percent RH to 100 percent RH, and also in soft (10 (minus 2) Torr) and hard (10 (minus 7) Torr) vacuums. No significant temperature dependence was evident, but measured resistivity values ranged over 9 orders of magnitude: 10 to the 5th power ohm-cm at 100 percent RH greater than 10 to the 12th power ohm-cm in a hard vacuum. The latter value violates the ESD criterion for a typical 0.019 cm thick coating. The corrosion study involved exposing typical ZOT substrate combinations to two moisture environments - 30 C/85 percent RH and 85 C/85 percent RH - for 2000 hours, during which time the samples were periodically removed for front-to-back electrical resistance and scratch/peel test measurements. It was determined that the ZOT/Al and ZOT/Mg systems are stable (no ZOT delamination), although some corrosion (oxide formation) and resistivity increases observed among the ZOT/Mg samples warrant that exposure of some parts to humid environments be minimized.

Mon, Gordon R.↗
DOE OSTI2017

Evaluation and Interpretation of Properties for Saltstone Cores Extracted from an SDU - 17344

Extraction and subsequent analysis of emplaced saltstone samples from a Savannah River Site (SRS) Saltstone Disposal Unit (SDU) were performed in order to realize the following key objectives: (1) to support the use of historical and future laboratory-derived sample data to predict the behavior of field-emplaced samples, and (2) to substantiate the saltstone properties currently assumed in Saltstone Disposal Facility (SDF) transport modeling, i.e., Performance Assessment (PA) and Special Analyses (SA) models. Multiple cores were extracted via a wet core drilling process in April-May 2015 approximately 20 months after the saltstone of interest was processed in the Saltstone Production Facility (SPF) and subsequently emplaced in SDU Cell 2A (SDU2A). The retrieved samples were stored in an inert N{sub 2} environment prior to, and during, the property testing that took place between October 2015 and March 2016. Sample analyses comprised evaluation of physical properties (density, porosity, and moisture content), saturated hydraulic conductivity (K{sub sat}), and determination of distribution coefficients and solubilities for key radionuclides. In general the SDU2A samples indicated comparative properties to laboratory-prepared samples and additionally verified many of the inputs currently assumed in the SDF PA. The principal exception was related to the leaching characteristics of I-129, which demonstrated a lower than anticipated affinity for retention within the saltstone matrix. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1995

Summary of GPC/DV results for space exposed poly(arylene ether phosphine oxide)s

Gel Permeation Chromatography (GPC) was used to analyze poly(arylene ether phosphine oxide)s whose backbones were identical except for the ketone content and placement. These samples were exposed to low Earth orbit environment (predominantly atomic oxygen) on space shuttle flights. The materials and their unexposed controls were then characterized by GPC to investigate the effect of atomic oxygen on the molecular weight distributions. Analysis of the soluble portion of the samples revealed that there was significant loss of high molecular weight species. The presence of insoluble material also suggested that crosslinking was induced by the atomic oxygen exposure and that this very likely occurred at the high molecular weight portion of the molecular weight distribution.

Siochi, Emilie↗
DOE OSTI2026

Quasi-In-Situ Analysis of Electrode Top Atomic Layers via High-Sensitivity Low-Energy Ion Scattering and Potential-Controlled Sample Transfer

Electrocatalytic reactions involve interfacial interactions between the surfaces of electrodes and reactive species at an electrolyte interface. There are presently no universal or unambiguous methods to directly assay the active top atomic layer composition that influences the reactivity of these electrodes under relevant operating conditions. Low-energy ion scattering (LEIS) spectroscopy is a surface characterization technique that yields compositional analysis of the outermost atomic layer of a material, but it must be performed in ultrahigh vacuum (UHV). Application of LEIS measurements to electrochemical materials that are removed from ambient liquid-phase environments thus leaves an open question as to whether the surface that is transferred to UHV is truly the surface that manifested during the electrochemical reaction. Toward the goal of preserving the active surface state, we developed a sample transfer workflow for LEIS enabling air-free removal and drying of an electrode from an electrochemical cell while maintaining control of the potential using an auxiliary electrode. The potential-controlled emersion method was demonstrated to give distinct potential-dependent surface compositions for a Cu−Pd alloy relative to removal after uncontrolled return to open-circuit potential. A Cu-enriched surface was found at anodic potential and a Pd-enriched surface at cathodic potential, suggesting that the approach can be used to retain representative atomic configurations during transfer. Since adsorbates will often persist from the reaction environment, conventional sample pretreatment methods for removal, including atomic O and atomic H exposure, were also contrasted. Both methods were found to differ with results from incidental low-dose depth profiling by the LEIS primary ion source, which removes adventitious species and surface atoms during the course of repeated measurements. These depth profiles were found to be sensitive to sample history and thus qualitatively informative, despite the possible changes induced by ion damage. The results exhibit (i) the need for complete control over the polarization state of the sample at all times (no excursions to open circuit during transfer) and (ii) the utility of low-dose depth profiling to capture changes in the near-surface composition.

Alloys↗
DOE OSTI2022

Modeling the use of mobile modular gas samplers in near-field detection

The Wireless Independent Noble Gas Sampler (WINGS) is a mobile, modular gas sampling system designed for use in low infrastructure environments. In the case of a suspected underground nuclear explosion (UNE), WINGS units could be deployed to detect noble gases emanating from the suspected explosion site or identify gases originating from another source entering the local area from offsite. In conclusion, this work uses the atmospheric transport modeling tool inline WRF-HYSPLIT to test the effectiveness of WINGS units around a suspected UNE site as a function of sampler density and distance from the emission point of gases from a UNE.

Air sampling↗
DOE OSTI2019

Nitrate-Utilizing Microorganisms Resistant to Multiple Metals from the Heavily Contaminated Oak Ridge Reservation.

Contamination of environments with nitrate generated by industrial processes and the use of nitrogen-containing fertilizers is a growing problem worldwide. While nitrate can be removed from contaminated areas by microbial denitrification, nitrate frequently occurs with other contaminants, such as heavy metals, that have the potential to impede the process. In this work, nitrate-reducing microorganisms were enriched and isolated from both groundwater and sediments at the Oak Ridge Reservation (ORR) using concentrations of nitrate and metals (Al, Mn, Fe, Co, Ni, Cu, Cd, and U) similar to those observed in a contaminated environment at ORR. Seven new metal-resistant, nitrate-reducing strains were characterized, and their distribution across both noncontaminated and contaminated areas at ORR was examined. Additionally, while the seven strains have various pH ranges for growth, carbon source preferences, and degrees of resistance to individual and combinations of metals, all were able to reduce nitrate at similar rates both in the presence and absence of the mixture of metals found in the contaminated ORR environment. Four strains were identified in groundwater samples at different ORR locations by exact 16S RNA sequence variant analysis, and all four were found in both noncontaminated and contaminated areas. By using environmentally relevant metal concentrations, we successfully isolated multiple organisms from both ORR noncontaminated and contaminated environments that are capable of reducing nitrate in the presence of extreme mixed-metal contamination.IMPORTANCE Nitrate contamination is a global issue that affects groundwater quality. In some cases, cocontamination of groundwater with nitrate and mixtures of heavy metals could decrease microbially mediated nitrate removal, thereby increasing the duration of nitrate contamination. In this study, we used metal and nitrate concentrations that are present in a contaminated site at the Oak Ridge Reservation to isolate seven metal-resistant strains. All were able to reduce nitrate in the presence of high concentrations of a mixture of heavy metals. Four of seven strains were located in pristine as well as contaminated sites at the Oak Ridge Reservation. Further study of these nitrate-reducing strains will uncover mechanisms of resistance to multiple metals that will increase our understanding of the effect of nitrate and metal contamination on groundwater microbial communities.

59 BASIC BIOLOGICAL SCIENCES↗