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At least 793 records · Page 44

Light polarization sensitive photodetectors with m- and r-plane homoepitaxial ZnO/ZnMgO quantum wells

Homoepitaxial ZnO/(Zn,Mg)O multiple quantum wells (MQWs) grown with m- and r-plane orientations are used to demonstrate Schottky photodiodes sensitive to the polarization state of light. In both orientations, the spectral photoresponse of the MQW photodiodes shows a sharp excitonic absorption edge at 3.48 eV with a very low Urbach tail, allowing the observation of the absorption from the A, B and C excitonic transitions. The absorption edge energy is shifted by ∼30 and ∼15 meV for the m- and r-plane MQW photodiodes, respectively, in full agreement with the calculated polarization of the A, B, and C excitonic transitions. The best figures of merit are obtained for the m-plane photodiodes, which present a quantum efficiency of ∼11%, and a specific detectivity D* of ∼6.4 × 10{sup 10} cm Hz{sup 1/2}/W. In these photodiodes, the absorption polarization sensitivity contrast between the two orthogonal in-plane axes yields a maximum value of (R{sub ⊥}/R{sub ||}){sub max} ∼ 9.9 with a narrow bandwidth of ∼33 meV.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Development of Novel Functionally Graded Transition Joints for Improving the Creep Strength of Dissimilar Metal Welds in Nuclear Applications

Steam generators of the small modular Very High Temperature Reactor (VHTR) will require use of Alloy 800 and 2.25Cr-1Mo steel in different regions depending on temperature and corrosion resistance requirements. As a result, Dissimilar Metal Welds (DMWs) between these two materials are critical for design, development, and manufacturing of the VHTR. DMWs are also used in many other applications in the power generation and petrochemical industries. Experience has demonstrated that failures of such DMWs can occur prematurely well below the expected creep life of either base metal, and these failures have significant consequences in terms of plant reliability, safety, and economic impact. These DMWs failures are caused by the abrupt change in composition that occurs at the weld interface between the two alloys. In this research, the concept of developing and optimizing Graded Transition Joints (GTJ) was developed through an integrated modeling and experimental approach. With GTJs, the composition is gradually graded between the two alloys, thus eliminating the sharp change in composition that causes failure. Microstructural modeling was first conducted to identify the optimum grade length required for improved resistance to carbon diffusion that is largely responsible for premature failure. Next, GTJs were fabricated and characterized in detail to understand how the microstructure evolves during fabrication and long term aging. Finally, the creep behavior of the GTJs was investigated and compared to that of conventional DMWs to demonstrate the superior creep strength of the GTJs. The results of this research provide significant insight into design, fabrication, microstructural evolution, and resultant performance of GTJs that can be used for reducing or eliminating DMW failures in a number of high temperature applications. The results also demonstrate that the GTJs can be readily fabricated with either conventional or additive manufacturing processes, and detailed guidelines are provided on the length of grades needed for optimal performance. The results of this research benefits the general public by improving the reliability of power generation and petrochemical plants that rely on DMWs for safe and reliable operation to deliver power and other products.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Effects of Nose Bluntness on Stability of Hypersonic Boundary Layers over Blunt Cone

Receptivity and stability of hypersonic boundary layers are numerically investigated for boundary layer flows over a 5-degree straight cone at a free-stream Mach number of 6.0. To compute the shock and the interaction of shock with the instability waves, we solve the Navier-Stokes equations in axisymmetric coordinates. The governing equations are solved using the 5th-order accurate weighted essentially non-oscillatory (WENO) scheme for space discretization and using third-order total-variation-diminishing (TVD) Runge-Kutta scheme for time integration. After the mean flow field is computed, disturbances are introduced at the upstream end of the computational domain. Generation of instability waves from leading edge region and receptivity of boundary layer to slow acoustic waves are investigated. Computations are performed for a cone with nose radii of 0.001, 0.05 and 0.10 inches that give Reynolds numbers based on the nose radii ranging from 650 to 130,000. The linear stability results showed that the bluntness has a strong stabilizing effect on the stability of axisymmetric boundary layers. The transition Reynolds number for a cone with the nose Reynolds number of 65,000 is increased by a factor of 1.82 compared to that for a sharp cone. The receptivity coefficient for a sharp cone is about 4.23 and it is very small, approx.10(exp -3), for large bluntness.

Kara, K.↗

Phase change alloy viscosities down to T{sub g} using Adam-Gibbs-equation fittings to excess entropy data: A fragile-to-strong transition

A striking anomaly in the viscosity of Te{sub 85}Ge{sub 15} alloys noted by Greer and coworkers from the work of Neumann et al. is reminiscent of the equally striking comparison of liquid tellurium and water anomalies documented long ago by Kanno et al. In view of the power laws that are used to fit the data on water, we analyze the data on Te{sub 85}Ge{sub 15} using the Speedy-Angell power-law form, and find a good account with a singularity T{sub s} only 25 K below the eutectic temperature. However, the heat capacity data in this case are not diverging, but instead exhibit a sharp maximum like that observed in fast cooling in the Molinero-Moore model of water. Applying the Adam-Gibbs viscosity equation to these calorimetric data, we find that there must be a fragile-to-strong liquid transition at the heat capacity peak temperature, and then predict the 'strong' liquid course of the viscosity down to T{sub g} at 406 K (403.6 K at 20 K min{sup −1} in this study). Since crystallization can be avoided by moderately fast cooling in this case, we can check the validity of the extrapolation by making a direct measurement of fragility at T{sub g}, using differential scanning calorimetric techniques, and then comparing with the value from the extrapolated viscosity at T{sub g}. The agreement is encouraging, and prompts discussion of relations between water and phase change alloy anomalies.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Bulk viscosity from Urca processes: npeμ matter in the neutrino-trapped regime

In this work, we extend our previous study of the bulk viscosity of hot and dense npe matter induced by the Urca process in the neutrino trapped regime to npeμ matter by adding the muonic Urca processes as well as the purely leptonic electroweak processes involving electron-muon transition. Here, the nuclear matter is modeled in a relativistic density functional approach with two different parametrizations which predict neutrino dominated matter (DDME2 model) and anti-neutrino dominated matter (NL3 model) at temperatures for which neutrinos/anti-neutrinos are trapped. In the case of neutrino-dominated matter, the main equilibration mechanism is lepton capture, whereas in the case of antineutrino-dominated matter this is due to neutron decay. We find that the equilibration rates of Urca processes are higher than that of the pure leptonic processes, which implies that the Urca bulk viscosity can be computed with the leptonic reactions assumed to be frozen. We find that the bulk viscosity decreases with temperature as ζ~T –2 at moderate temperatures. At high temperatures this scaling breaks down by sharp drops of the bulk viscosity close to the temperature where the proton fraction is density-independent and the matter becomes scale-invariant. This occurs also when the matter undergoes a transition from the antineutrino-dominated regime to the neutrino-dominated regime where the bulk viscosity attains a local maximum. We also estimate the bulk viscous dissipation timescales and find that these are in the range ≳ 1 s for temperatures above the neutrino trapping temperature. These timescales would be relevant only for long-lived objects formed in binary neutron star mergers and hot proto-neutron stars formed in core-collapse supernovas.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Half-Integer Conductance Plateau at the ν = 2 / 3 Fractional Quantum Hall State in a Quantum Point Contact

The v = 2/3 fractional quantum Hall state is the hole-conjugate state to the primary Laughlin v = 1/3 state. Here, we investigate transmission of edge states through quantum point contacts fabricated on a GaAs/AlGaAs heterostructure designed to have a sharp confining potential. When a small but finite bias is applied, we observe an intermediate conductance plateau with G = 0.5⁢(e 2 /ℎ). This plateau is observed in multiple QPCs, and persists over a significant range of magnetic field, gate voltage, and source-drain bias, making it a robust feature. Using a simple model that considers scattering and equilibration between counterflowing charged edge modes, we find this half-integer quantized plateau to be consistent with full reflection of an inner counterpropagating -1/3 edge mode while the outer integer mode is fully transmitted. In a QPC fabricated on a different heterostructure which has a softer confining potential, we instead observe an intermediate conductance plateau at G = (1/3)⁢(e 2 /ℎ). These results provide support for a model at v = 2/3 in which the edge transitions from a structure having an inner upstream -1/3 charge mode and outer downstream integer mode to a structure with two downstream 1/3 charge modes when the confining potential is tuned from sharp to soft and disorder prevails.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Effect of slot width on transition and noise attenuation of a flat sound shield in a Mach 6 wind tunnel

An experimental and theoretical study of a sound shield concept to attenuate the noise radiated into the test section from the turbulent boundary layer on the walls of wind tunnels was conducted. The model investigated was planar with a sharp flat plate leading edge faired into an array of rods aligned nearly parallel to the local flow. For a ratio of gap diameter to rod diameter of 0.16, the flow was laminar over the entire model at a maximum local length Reynolds number of 14 million. A 45% reduction in the tunnel free stream root mean square pressure level was measured within the shielded region for this gap width when the boundary layers on the rods were laminar. Smaller ratios of gap diameter to rod diameter resulted in substantial reductions in the transition Reynolds number, and in a 40% pressure reduction.

Stainback, P. C.↗

Convective Transition Statistics over Tropical Oceans for Climate Model Diagnostics: GCM Evaluation

To assess deep convective parameterizations in a variety of GCMs and examine the fast-time-scale convective transition, a set of statistics characterizing the pickup of precipitation as a function of column water vapor (CWV), PDFs and joint PDFs of CWV and precipitation, and the dependence of the moisture–precipitation relation on tropospheric temperature is evaluated using the hourly output of two versions of the GFDL Atmospheric Model, version 4 (AM4), NCAR CAM5 and superparameterized CAM (SPCAM). The 6-hourly output from the MJO Task Force (MJOTF)/GEWEX Atmospheric System Study (GASS) project is also analyzed. Contrasting statistics produced from individual models that primarily differ in representations of moist convection suggest that convective transition statistics can substantially distinguish differences in convective representation and its interaction with the large-scale flow, while models that differ only in spatial–temporal resolution, microphysics, or ocean–atmosphere coupling result in similar statistics. Most of the models simulate some version of the observed sharp increase in precipitation as CWV exceeds a critical value, as well as that convective onset occurs at higher CWV but at lower column RH as temperature increases. While some models quantitatively capture these observed features and associated probability distributions, considerable intermodel spread and departures from observations in various aspects of the precipitation–CWV relationship are noted. For instance, in many of the models, the transition from the low-CWV, nonprecipitating regime to the moist regime for CWV around and above critical is less abrupt than in observations. Additionally, some models overproduce drizzle at low CWV, and some require CWV higher than observed for strong precipitation. For many of the models, it is particularly challenging to simulate the probability distributions of CWV at high temperature.

54 ENVIRONMENTAL SCIENCES↗

An experimental study of the hypersonic aerodynamics of delta wings.

Results of aerodynamic balance and pressure measurements carried out in a hypersonic gun tunnel (at a free-stream Mach number of 8.2 and a Reynolds number of 800,000) on delta wings having sharp leading edges swept at 70 and 76 deg. The experimental force and pressure coefficients and shock angles are discussed in relation to simple prediction methods. Some transition data are also included.

Rao, D. M.↗

Factors Affecting Laminar Boundary Layer Measurements in a Supersonic Stream

The observed discrepancy at supersonic speeds between theoretical and apparent experimental average flat plate friction-drag coefficients calculated from boundary layer total-pressure surveys was investigated. Effects of the total-pressure probe, heat transfer through the leading edge region, change in leading-edge radius and strength of the leading-edge wave, possible early transition to turbulent flow or “bursts of turbulence,” and the slight stream-wise pressure gradient inherent in flat plate flow were investigated for plates with very sharp leading edges. Only one of these factors, the effect of the total-pressure probe, was found to be significant. Total-pressure probes of different tip heights, when placed in laminar boundary layers developing under identical conditions, were found to yield different values of friction drag coefficient. Extrapolation of these measurements indicates that a probe of vanishing size would yield the theoretical predicted values of average flat plate friction-drag coefficients. A correlation describing the relation between the friction-drag discrepancy and the probe tip height is presented.

Blue, Robert E↗

Boundary Layer Instabilities Generated by Freestream Laser Perturbations

A controlled, laser-generated, freestream perturbation was created in the freestream of the Boeing/AFOSR Mach-6 Quiet Tunnel (BAM6QT). The freestream perturbation convected downstream in the Mach-6 wind tunnel to interact with a flared cone model. The geometry of the flared cone is a body of revolution bounded by a circular arc with a 3-meter radius. Fourteen PCB 132A31 pressure transducers were used to measure a wave packet generated in the cone boundary layer by the freestream perturbation. This wave packet grew large and became nonlinear before experiencing natural transition in quiet flow. Breakdown of this wave packet occurred when the amplitude of the pressure fluctuations was approximately 10% of the surface pressure for a nominally sharp nosetip. The initial amplitude of the second mode instability on the blunt flared cone is estimated to be on the order of 10 −6 times the freestream static pressure. The freestream laser-generated perturbation was positioned upstream of the model in three different configurations: on the centerline, offset from the centerline by 1.5 mm, and offset from the centerline by 3.0 mm. When the perturbation was offset from the centerline of a blunt flared cone, a larger wave packet was generated on the side toward which the perturbation was offset. The offset perturbation did not show as much of an effect on the wave packet on a sharp flared cone as it did on a blunt flared cone.

Chou, Amanda↗

Mineralogy and Geochemistry of Sedimentary Rocks and Eolian Sediments in Gale Crater, Mars: A Review After Six Earth Years of Exploration with Curiosity

The Mars Science Laboratory Curiosity rover arrived at Mars in August 2012 with a primary goal of characterizing the habitability of ancient and modern environments. Curiosity was sent to Gale crater to study a sequence of ∼3.5 Ga old sedimentary rocks that, based on orbital visible and near- to short-wave infrared reflectance spectra, contain secondary minerals that suggest deposition and/or alteration in liquid water. The sedimentary sequence in the lower slopes of Mount Sharp in Gale crater preserves a dramatic shift on early Mars from a relatively warm and wet climate to a cold and dry climate, based on a transition from smectite-bearing strata to sulfate-bearing strata. The rover is equipped with instruments to examine the sedimentology and identify compositional changes in the stratigraphy. The Chemistry and Mineralogy (CheMin) instrument is one of two internal laboratories on Curiosity and includes a transmission X-ray diffractometer (XRD) and X-ray fluorescence (XRF) spectrometer. CheMin measures loose sediment samples scooped from the surface and drilled rock powders, and the XRD provides quantitative mineralogy to a detection limit of ∼1 wt.% for crystalline phases. Curiosity has traversed>20 km since landing and has primarily been exploring an ancient lake environment fed by streams and groundwater. Of the 19 drilled rock samples analyzed by CheMin as of sol 2300 (January 2019), 15 are from fluvio-lacustrine deposits that comprise the Bradbury and Murray formations. Most of these samples were drilled from units that did not have a clear mineralogical signature from orbit. Results from CheMin demonstrate an astounding diversity in the mineralogy of these rocks that signifies geochemical variations in source rocks, transportation mechanisms, and depositional and diagenetic fluids. Most detrital igneous minerals are basaltic, but the discovery in a few samples of abundant silicate minerals that usually crystallize from evolved magmas on Earth remains enigmatic. Trioctahedral smectite and magnetite at the base of the section may have formed from low-salinity pore waters with a circumneutral pH in lake sediments. A transition to dioctahedral smectite, hematite, and Ca-sulfate going up section suggests a change to more saline and oxidative aqueous conditions in the lake waters themselves and/or in diagenetic fluids. Perhaps one of the biggest mysteries revealed by CheMin is the high abundance of X-ray amorphous materials (15–73 wt.%) in all samples drilled or scooped to date. CheMin has analyzed three modern eolian sands, which have helped constrain sediment transport and mineral segregation across the active Bagnold Dune Field. Ancient eolian sandstones drilled from the Stimson formation differ from modern eolian sands in that they contain abundant magnetite but no olivine, suggesting that diagenetic processes led to the alteration of olivine to release Fe(II) and precipitate magnetite. Fracture-associated halos in the Stimson and the Murray formations are evidence for complex aqueous processes long after the streams and lakes vanished from Gale crater. The sedimentology and composition of the rocks analyzed by Curiosity demonstrate that habitable environments persisted intermittently on the surface or in the subsurface of Gale crater for perhaps more than a billion years.

E.B. Rampe↗

Properties of γ-decaying isomers in the 100 Sn region populated in fragmentation of a 124 Xe beam

A systematic study was performed of microsecond γ-decaying isomers around 100 Sn produced in a fragmentation reaction of a 124 Xe beam at 345 MeV/u at the Radioactive Ion Beam Factory of the RIKEN Nishina Center in Saitama, Japan. Half-lives of isomeric states in that region were remeasured allowing us to improve the currently available experimental information. Reduced transition probabilities were deduced and compared to shell-model calculations in various model spaces. Furthermore, the recently reported low-energy transitions in 92 Rh and 96 Ag were remeasured with improved precision. Additionally, experimental information on isomeric ratios, including five new ones, were extracted and compared to a previous experimental study and the sharp cutoff model of fragmentation reaction.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Properties of strained TaS{sub 3} samples in the state of charge density wave and in the normal state

The uniaxial strain of quasi-one-dimensional conductor whiskers of orthorhombic TaS{sub 3} at a strain higher than ε{sub c} ~ 0.8% leads to a sharp increase in the coherence of the properties of a charge density wave (CDW), which manifests itself in its motion in fields higher than threshold field E{sub t}. During uniaxial elongation, TaS{sub 3} is shown to exhibit the following unusual properties even in weak fields: Peierls transition temperature T{sub P} depends nonmonotonically on ε, one-dimensional fluctuations weaken near T{sub P}, and the coherence length of a charge density increases at T < T{sub P}. Investigations in fields higher than E{sub t} show that the ultracoherent properties of CDW exist in a wide temperature range and are retained when temperature increases up to T{sub P}. These properties of CDW make it possible to observe a sharp increase in E{sub t} near T{sub P} and an almost jumplike increase in E{sub t} at T < 90 K. The increase in E{sub t} at T{sub P} is explained by a decrease in the coherence volume of CDW because of a fluctuational suppression of the Peierls gap.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Interfacial Octahedral Manipulation Imparts Hysteresis-Free Metal to Insulator Transition in Ultrathin Nickelate Heterostructure

Much like epitaxial strain, engineering oxygen octahedral rotations (OORs) in perovskite oxide thin films can be a powerful means of manipulating their physical and chemical properties. Here, it is demonstrated that the fundamental character of the metal-insulator transition (MIT) can be sensitively controlled by the structure of the oxygen sublattice for NdNiO 3 thin films grown epitaxially on NdGaO 3 (110) substrates. The MIT is sharp and hysteretic for a Ni-O-Ni bond angle of 154.0° (6 nm thick film) like the bulk behavior, while it is diffuse and largely nonhysteretic for a bond angle of 149.5° (3 nm thick film), stemming from the smaller bond angle of the NdGaO 3 substrate. Using synchrotron X-ray diffraction to quantify the geometric framework of the oxygen sublattice, it is found that the influence of the substrate OORs propagates and decays after a few nanometers into the ultrathin film. The sublattice structure in the 6 nm thick film is similar to that for bulk NdNiO 3 , leading to the sharp and hysteretic MIT.

36 MATERIALS SCIENCE↗

Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material

Abstract Atmospheric aerosols can assume liquid, amorphous semi-solid or glassy, and crystalline phase states. Particle phase state plays a critical role in understanding and predicting aerosol impacts on human health, visibility, cloud formation, and climate. Melting point depression increases with decreasing particle diameter and is predicted by the Gibbs–Thompson relationship. This work reviews existing data on the melting point depression to constrain a simple parameterization of the process. The parameter $$\xi $$ ξ describes the degree to which particle size lowers the melting point and is found to vary between 300 and 1800 K nm for a wide range of particle compositions. The parameterization is used together with existing frameworks for modeling the temperature and RH dependence of viscosity to predict the influence of particle size on the glass transition temperature and viscosity of secondary organic aerosol formed from the oxidation of $$\alpha $$ α -pinene. Literature data are broadly consistent with the predictions. The model predicts a sharp decrease in viscosity for particles less than 100 nm in diameter. It is computationally efficient and suitable for inclusion in models to evaluate the potential influence of the phase change on atmospheric processes. New experimental data of the size-dependence of particle viscosity for atmospheric aerosol mimics are needed to thoroughly validate the predictions.

36 MATERIALS SCIENCE↗

Frequency dispersion of nonlinear response of thin superconducting films in the Berezinskii-Kosterlitz-Thouless state

The effects of microwave radiation on transport properties of atomically thin La 2-x Sr x CuO₄ films were studied in the 0.1-20 GHz frequency range. Resistance changes induced by microwaves were investigated at different temperatures (8–15 K) near the superconducting transition. A strong decrease of the nonlinear response is observed within a few GHz of a cutoff frequency ν cut ≈ 2GHz. The expected frequency dependence vastly underestimates the sharpness of this drop. Numerical simulations that assume ac response to follow dc V-I characteristics of the films reproduce well the low frequency behavior, but fail above ν cut . Thus, high-frequency radiation is much less effective in inducing vortex-antivortex dissociation in the oscillating superconducting condensate.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The c-Abl signaling network in the radioadaptive response

The radioadaptive response, or radiation hormesis, i.e. a low dose of radiation can protect cells and organisms from the effects of a subsequent higher dose, is a widely recognized phenomenon. Mechanisms underlying such radiation hormesis, however, remain largely unclear. Preliminary studies indicate an important role of c-Abl signaling in mediating the radioadaptive response. We propose to investigate how c-Abl regulates the crosstalk between p53 and NFκB in response to low doses irradiation. We found in our recent study that low dose IR induces a reciprocal p53 suppression and NFκB activation, which induces HIF-a and subsequently a metabolic reprogramming resulting in a transition from oxidative phosphorylation to glycolysis. Of importance is that this glycolytic switch is essential for the radioadaptive response. This low-dose radiationinduced HIF1α activation was in sharp contrast with the high-dose IR-induced p53 activation and HIF1α inhibition. HIF1α and p53 seem to play distinct roles in mediating the radiation dose-dependent metabolic response. The induction of HIF1α-mediated glycolysis is restricted to a low dose range of radiation, which may have important implications in assessing the level of radiation exposure and its potential health risk. Our results support a dose-dependent metabolic response to IR. When IR doses are below the threshold of causing detectable DNA damage (<0.2Gy) and thus little p53 activation, HIF1α is induced resulting in induction of glycolysis and increased radiation resistance. When the radiation dose reaches levels eliciting DNA damage, p53 is activated and diminishes the activity of HIF1α and glycolysis, leading to the induction of cell death. Our work challenges the LNT model of radiation exposure risk and provides a metabolic mechanism of radioadaptive response. The study supports a need for determining the p53 and HIF1α activity as a potential reliable biological readout of radiation exposure in humans. The exquisite sensitivity of cellular metabolism to low doses of radiation could also serve as a valuable biomarker for estimating the health effects of low-level radiation exposure.

59 BASIC BIOLOGICAL SCIENCES↗