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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 793 records · Page 44
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Investigating the Chemical Reactivity of Lithium Silicate Model SEI Layers

Silicon anodes suffer from an unstable solid electrolyte interphase (SEI) layer that contributes to undesirable capacity fade with cycling. A key part to addressing this unstable SEI formation is to examine how certain components of the SEI react with the electrolyte over time. One SEI component that has not been thoroughly studied in the context of the chemical reactivity against the electrolyte is lithiated silicate. Four model silicate thin films with increasing lithium content were deposited by radio frequency (RF) magnetron sputtering to study how the lithiation of the native oxide on a silicon anode affects the chemical stability of the anode surface. SiO2, Li2Si2O5, Li2SiO3, and Li3SiOx films were exposed to 1.2 M LiPF6 in the 3:7 wt% ethylene carbonate/ethyl methyl carbonate (EC/EMC) electrolyte for periods of time that are representative of the amount of time it takes to undergo cell formations. Soaked samples were rinsed, dried, and characterized by a combination of attenuated total reflectance-infrared spectroscopy (ATR-IR), focused ion beam-secondary electron microscopy (FIB-SEM), and X-ray photoelectron spectroscopy (XPS) depth profiling. It was found that the rate of the decrease in film thickness of the silicates exposed to the electrolyte over time increases as a function of the lithium content in the thin film. This reaction involves HF etching and LiPF6 salt degradation leading to silicate loss and fluorination throughout the bulk. Understanding this chemical instability is critical to determining the overall mechanism of SEI degradation over time.

ADVANCED PROPULSION SYSTEMS,ENERGY STORAGE↗
NASA NTRS1952

Experimental Determination of the Effect of Horizontal-Tail Size, Tail Length, and Vertical Location on Low-Speed Static Longitudinal Stability and Damping Pitch of a Model Having 45 Degree Sweptback Wing and Tail Surfaces

Report presents the results of an investigation conducted in the Langley stability tunnel to determine the effects of horizontal tails of various sizes and at various tail lengths (when loaded on the fuselage center line) and also the effects of vertical location of the horizontal tail relative to the wing on the low-speed static longitudinal stability and on the steady-state rotary damping in pitch for a complete-model configuration. The wing and tail surfaces had the quarter-chord lines swept back 45 degrees and had aspect ratios of 4. The results of the investigation showed that, in agreement with analytical considerations, the contribution of the horizontal tail to static longitudinal stability was related directly to the tail size and length; whereas, its contribution to damping in pitch was related directly to tail size and the square of tail length.

Lichtenstein, Jacob H↗
DOE OSTI2021

Ligand Locking on Quantum Dot Surfaces via a Mild Reactive Surface Treatment

At the outermost surface of colloidal QDs are organic surface ligands which dynamically bind and release in solution to control the growth kinetics, control the size/shape of the crystals, passivate surface states, and provide colloidal stability through favorable interactions with the solvent. However, the dynamicity comes at the expense of the stability of the QD suspension. Here, we show that ligands can be permanently locked on the QD surface by a thin layer of an inert metal oxide which forms within the ligand shell, over the headgroup. By interrogating the surface chemistry with different spectroscopic methods, we prove the ligand locking on the QD surface. As a result, an exceptional stability of the coated QD inks is achieved in a wide concentration range, even in the presence of chemically competing surface ligands in solution. We anticipate that this critical breakthrough will benefit different areas related to colloidal QDs, spanning from single-particle studies to displays and solar cells and biological applications. Furthermore, the same chemistry could be easily translated to surface treatments of bulk materials and thin films.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Experimental and Theoretical Studies of the Surface Oxidation Process of Rare–Earth Tritellurides

Recent studies have established Van der Waals (vdW) layered and 2D rare-earth tritellurides (RTe 3 ) as superconductors and near room-temperature charge density wave (CDW) materials. Their environmental stability raises natural concern owing to aging/stability effects observed in other tellurium-based layered crystals. Here, the results establish the stability and environmental aging characteristics of these RTe 3 systems involving a variety of metals such as La, Nd, Sm, Gd, Dy, and Ho. The atomic force microscopy (AFM) and scanning electron microscopy (SEM) results show that all the RTe 3 sheets oxidize to form thin TeO x layers that are primarily confined to the surface, edges, and grain boundaries. Time-resolved in situ Raman spectroscopy measurements are used to understand the kinetics of the oxidization process for different lanthanide metal cations and establish their relative stability/resilience to oxidization. Overall results indicate that the vdW layers show higher air stability as the 4f electron number decreases going from Ho to La, resulting in the most stable LaTe 3 compared to the least stable HoTe 3 . Comprehensive quantum mechanical simulations reveal that environmental degradation originates from a strong oxidizing reaction with O 2 molecules, while humidity (H 2 O) plays a negligible role unless Te vacancies are present. Moreover, the simulations explain the effects of 4f electrons on the work function and Te vacancies formation, which directly impact the aging characteristics of RTe 3 layers. Interestingly, optical and electrical measurements show that the CDW response is still observed in aged RTe 3 layers owing to the presence of underlying pristine/nonoxidized RTe 3 layers, except CDW transition temperatures increase due to the thickness effect. Overall results offer the first in-depth environmental aging studies on these materials, which can be applied to engineer and design their chemical stability, surface properties, and overall CDW characteristics.

36 MATERIALS SCIENCE↗
DOE OSTI2018

On Magnetic Flux Trapping by Surface Superconductivity

The magnetic flux trapping by surface superconductivity is considered. The stability of the state localized at the cylindrical sample surface upon a change in the external magnetic field is tested. It is shown that as the magnetic field decreases, the sample acquires a positive magnetic moment due to magnetic flux trapping; i.e., the magnetization curve of surface superconductivity is “paramagnetic” by nature.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2018

Corrosion Resistance and Durability of Superhydrophobic Copper Surface in Corrosive NaCl Aqueous Solution

Artificial superhydrophobic copper surfaces play an important role in modern applications such as self-cleaning and dropwise condensation; however, corrosion resistance and durability often present as major concerns in such applications. In this study, the anti-corrosion properties and mechanical durability of superhydrophobic copper surface have been investigated. The superhydrophobic copper surfaces were achieved with wet chemical etching and an immersion method to reduce the complexity of the fabrication process. The surface structures and materials were characterized using scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDX), and Fourier transform infrared spectrometer (FTIR). The corrosion resistance and mechanical properties of the superhydrophobic copper surface were characterized after immersing surfaces in a 3.5 wt % NaCl solution. The chemical stability of the superhydrophobic copper surface in the NaCl solution for a short period of time was also evaluated. An abrasion test and an ultrasound oscillation were conducted to confirm that the copper surface contained durable superhydrophobic properties. In addition, an atomic force microscope was employed to study the surface mechanical property in the corrosion conditions. The present study shows that the resulting superhydrophobic copper surface exhibit enhanced corrosion resistance and durability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Selective and Stable Non-Noble-Metal Intermetallic Compound Catalyst for the Direct Dehydrogenation of Propane to Propylene

A non-noble intermetallic compound catalyst consisting of Ni 3 Ga nanoparticles supported on Al 2 O 3 that exhibits high selectivity (~94%), comparable activity (TOF = 4.7 × 10 –2 s –1 ), good stability (~94% to 81% over the 82 h test), and regenerability in the direct dehydrogenation of propane to propylene at 600 °C has been developed. Through synthesis techniques that stabilize the Ni 3 Ga phase, the surface composition of the catalytic nanoparticles could be tuned by Ni and Ga loading such that improved selectivity toward propylene may be achieved. Comparisons with well-defined silica-supported Ni 3 Ga and NiGa catalysts and Ni 3 Ga/Al 2 O 3 with a range of Ni:Ga loading suggested that a specific surface composition range was most promising for propylene production. Furthermore the presence of Ni at the active particle surface was also found to be critical to drive dehydrogenation and enhance conversion, whereas the presence of Ga was necessary to attenuate the reactivity of the surface to improve selectivity and catalyst stability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1974

Free-flight wind tunnel investigation of a four-engine sweptwing upper-surface blown transport configuration

The dynamic stability characteristics of a four-engine turbofan transport model having an upper-surface blown-jet flap have been investigated by means of the free-flight technique in the Langley full-scale tunnel. The flight characteristics of the model were investigated through a range of lift coefficients from 3 to 8 with all four engines operating and with one outboard engine not operating. Static characteristics were investigated by conventional power-on force tests over the flight-test angle-of-attack range and through the stall.

Parlett, L. P.↗
NASA NTRS1991

Stripe stabilization in vertical Bloch line memory

Long, partial rectangular grooves have been made to reside below the stripe-confinement groove on a garnet surface, in order to stabilize minor loop stripes in a vertical Bloch-line memory. The test chip contained, in addition to either 10 or 20 minor-loop grooves, 10 read/write gate grooves and a major line groove; both 10 and 20 micron groove periods were tested. As the bias field was gradually decreased, bubbles began to stripe out. These stripes were stable at bias fields in the 70-80 Oe range. When stripes escaped from the groove, the even occurred from the end which does not face a read/write gate groove.

Wu, J. C.↗
DOE OSTI2024

In Situ Conversion of Artificial Proton‐Rich Shell to Inorganic Maskant Toward Stable Single‐Crystal Ni‐Rich Cathode

Single-crystal high-nickel oxide with an integral structure can prevent intergranular cracks and the associated detrimental reactions. Yet, its low surface-to-volume ratio makes surficial degradation a more critical factor in electrochemical performance. Herein, artificial proton-rich (ammonium bicarbonate) shell is successfully introduced on the nickel-rich LiNi 0.92 Co 0.06 Mn 0.02 O 2 single crystals for in situ electrochemically conversing into inorganic maskant to enhance stability of cathode. The process is that the surficial enriched proton, once released from the ammonium bicarbonate shell (proton reservoir) during 1st charge, is immediately captured by LiPF 6 , in situ electrochemically conversing to LiF and Li 3 PO 4 sub-nano particle dense maskant (sub-nano F-&P-maskant). The in situ formed compact nano F-&P-maskant significantly resists the cathode against electrolyte attack and improves the surface stability of particles during long-term cycling. Consequently, this surface modification enables 95% capacity retention after 100 cycles at a high voltage of 4.5 V in the half cell and 83% capacity retention after 800 cycles in the full cell. In conclusion, this work demonstrates a strategy for reconstructing the protective layer using the rational design of surficial enriched proton shells for advanced lithium batteries.

25 ENERGY STORAGE↗
NASA NTRS1959

The Static and Dynamic Rotary Stability Derivatives at Subsonic Speeds of an Airplane Model Having Wing and Tail Surfaces Swept Back 45 degrees

Wind-tunnel measurements were made of the static and dynamic rotary stability derivatives of an airplane model having sweptback wing and tail surfaces. The Mach number range of the tests was from 0.23 to 0.94. The components of the model were tested in various combinations so that the separate contribution to the stability derivatives of the component parts and the interference effects could be determined. Estimates of the dynamic rotary derivatives based on some of the simpler existing procedures which utilize static force data were found to be in reasonable agreement with the experimental results at low angles of attack. The results of the static and dynamic measurements were used to compute the short-period oscillatory characteristics of an airplane geometrically similar to the test model. The results of these calculations are compared with military flying qualities requirements.

Lopez, Armando E.↗
DOE OSTI2025

Advancing Sodium-Ion Battery Cathodes: A Low-Cost, Eco-Friendly Mechanofusion Route from TiO 2 Coating to Ti 4+ Doping

Layered oxide battery cathodes often require extra stabilization strategies, such as surface coating or doping, to mitigate side reactions and enhance longevity. Conventional methods such as aqueous deposition and atomic layer deposition are costly and environmentally unfriendly and even damage the original structure, especially for air-sensitive sodium-ion battery (SIB) cathodes. Herein, we introduce an all-dry mechanofusion technique that modifies hydroxide precursors with TiO 2 coating before sintering with a sodium source. Using advanced characterizations including X-ray diffraction, neutron diffraction, and solid-state nuclear magnetic resonance for structural insights, X-ray absorption spectroscopy to study metal valence states, and transmission X-ray microscopy for nanoscale visualization of nickel oxidation states, we verified that postsintering transforms TiO 2 surface coating into Ti doping, leading to improved Ni-oxidation homogeneity, modified charge compensation, and enhanced thermal stability. Electrochemical tests reveal superior performance in capacity retention, rate capability, and air stability for these modified cathodes, with pouch cells maintaining over 85% capacity after 650 cycles. This method presents a sustainable, cost-effective route for advanced SIB cathode development.

36 MATERIALS SCIENCE↗
NASA NTRS1978

Modification of the Douglas Neumann program to improve the efficiency of predicting component interference and high lift characteristics

The Douglas Neumann method for low-speed potential flow on arbitrary three-dimensional lifting bodies was modified by substituting the combined source and doublet surface paneling based on Green's identity for the original source panels. Numerical studies show improved accuracy and stability for thin lifting surfaces, permitting reduced panel number for high-lift devices and supercritical airfoil sections. The accuracy of flow in concave corners is improved. A method of airfoil section design for a given pressure distribution, based on Green's identity, was demonstrated. The program uses panels on the body surface with constant source strength and parabolic distribution of doublet strength, and a doublet sheet on the wake. The program is written for the CDC CYBER 175 computer. Results of calculations are presented for isolated bodies, wings, wing-body combinations, and internal flow.

Bristow, D. R.↗