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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 793 records · Page 44

Nanoscale temperature mapping in operating microelectronic devices

We report that modern microelectronic devices have nanoscale features that dissipate power nonuniformly, but fundamental physical limits frustrate efforts to detect the resulting temperature gradients. Contact thermometers disturb the temperature of a small system, while radiation thermometers struggle to beat the diffraction limit. Exploiting the same physics as Fahrenheit’s glass-bulb thermometer, we mapped the thermal expansion of Joule-heated, 80-nanometer-thick aluminum wires by precisely measuring changes in density. With a scanning transmission electron microscope (STEM) and electron energy loss spectroscopy (EELS), we quantified the local density via the energy of aluminum’s bulk plasmon. Rescaling density to temperature yields maps with a statistical precision of 3 kelvin/hertz ₋1/2 , an accuracy of 10%, and nanometer-scale resolution. Lastly, many common metals and semiconductors have sufficiently sharp plasmon resonances to serve as their own thermometers.

47 OTHER INSTRUMENTATION↗

Flight 1 technical report for experiment 74-36: Thermal migration of bubbles and their interaction with solidification interfaces

Specimens of gas saturated carbon tetrabromide were directionally solidified in a transparent furnace using a gradient freeze technique. The original temperature gradient was 5 C/cm and the cooling rate was 40 C/h. Progress of the experiment was monitored photographically. Gas bubbles were generated at the advancing solidification front in each of the three specimens. The gas bubbles were observed to increase in size, coalesce, and eventually be grown into the solid specimen under low gravity conditions. No bubble detachment from the interface was observed. Identical specimens processed in the laboratory showed bubble nucleation, bubble growth, and eventual bubble detachment due to buoyancy forces. Examination of the specimens showed a significantly greater void content in the low gravity processed samples. The grain size was observed to be finer in the low gravity processed samples.

Papazian, J. M.↗

Solar activity observed in X-rays and the EUV from OSO 7

Spectroheliograms obtained with the EUV spectroheliograph aboard OSO 7 between 1.7 and 400 A with a spatial resolution of at least 20 x 20 arc seconds are described, and results of an initial analysis of the Goddard X-ray polarimeter measurements are given and discussed in the light of current flare theories. The EUV observations are consistent with a picture in which coronal enhancement overlying an active region is made up of a nested set of arches or loops, with foot-points in regions of opposite magnetic polarity. The outermost arches are coolest, while those nearer the center are hotter. Along a given field line there is a temperature gradient such that the highest temperature occurs at the highest point of the magnetic arch. Polarimeter data provide evidence for polarization of about 20% in a number of X-ray bursts.

Thomas, R. J.↗

Critical transport parameters for porous media subjected to counterflow

Experimental and theoretical studies have been conducted to determine critical parameters at the onset of nonlinear counterflow in He II below the lambda point of He-4. Critical temperature differences have been measured in porous media for zero net mass flow and for Darcy permeabilities in the order of magnitude range from 10 to the -10th to 10 to the -8th sq cm. The normalized critical temperature gradients, which covered the liquid temperature range of 1.5 K to the lambda temperature, are found to vary with T proportional to the ratio of the superfluid density to the normal fluid density. This liquid temperature dependence appears to be consistent with duct data which are limited at low temperature by a Reynolds number criterion.

Frederking, T. H. K.↗

Effects of g-jitter and cross-diffusion on the onset of convection in doubly diffusive systems

The effects of a modulated gravity field in doubly diffusive layers with and without cross-diffusion are studied. Attention is focused on the determination of linear stability criteria for such systems. Floquet theory is used to establish the stability criteria by a systematic analysis of the topology of the neutral curves from which stability boundaries can be constructed. Convective stability boundaries for gravity-modulated doubly cross-diffusive systems are presented for the cases of dynamically free and rigid boundaries. Two physically different forms of layer stratification are considered: (1) imposed independent gradients of two components and (2) a solute gradient induced by a fixed temperature gradient.

Terrones, Guillermo↗

Elevated Temperature Crack Propagation

This paper is a summary of two NASA contracts on high temperature fatigue crack propagation in metals. The first evaluated the ability of fairly simple nonlinear fracture parameters to correlate crack propagation. Hastelloy-X specimens were tested under isothermal and thermomechanical cycling at temperatures up to 980 degrees C (1800 degrees F). The most successful correlating parameter was the crack tip opening displacement derived from the J-integral. The second evaluated the ability of several path-independent integrals to correlate crack propagation behavior. Inconel 718 specimens were tested under isothermal, thermomechanical, temperature gradient, and creep conditions at temperatures up to 650 degrees C (1200 degrees F). The integrals formulated by Blackburn and by Kishimoto correlated the data reasonably well under all test conditions.

Orange, Thomas W.↗

Effect of poloidal asymmetries on impurity peaking in tokamaks

Poloidal impurity asymmetries are frequently observed in tokamaks. In this paper, the effect of poloidal asymmetry on electrostatic turbulent transport is studied, including the effect of the E Multiplication-Sign B drift. Collisions are modeled by a Lorentz operator, and the gyrokinetic equation is solved with a variational approach. The impurity transport is shown to be sensitive to the magnetic shear and changes sign for s Greater-Than-Or-Equivalent-To 0.5 in the presence of inboard accumulation. The zero-flux impurity density gradient (peaking factor) is shown to be rather insensitive to collisions in both ion temperature gradient and trapped electron mode driven cases. Our results suggest that the asymmetry (both the location of its maximum and its strength) and the magnetic shear are the two most important parameters that affect the impurity peaking.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Understanding the breakdown of classic two-phase theory and spray atomization at engine-relevant conditions

We present a generalized framework for multi-component liquid injections to understand and predict the breakdown of classic two-phase theory and spray atomization at engine-relevant conditions. The analysis focuses on the thermodynamic structure and the immiscibility state of representative gas-liquid interfaces. The most modern form of Helmholtz energy mixture state equation is utilized which exhibits a unique and physically-consistent behavior over the entire two-phase regime of fluid densities. It is combined with generalized models for non-linear Gradient Theory and for liquid injections to quantify multi-component two-phase interface structures in global thermal equilibrium. Then, the Helmholtz free energy is minimized which determines the interfacial species distribution as a consequence. This minimal free energy state is demonstrated to validate the underlying assumptions of classic two-phase theory and spray atomization. However, under certain engine-relevant conditions for which corroborating experimental data is presented, this requirement for interfacial thermal equilibrium becomes unsustainable. A rigorously derived probability density function quantifies the ability of the interface to develop internal spatial temperature gradients in the presence of significant temperature differences between injected liquid and ambient gas. Then, the interface can no longer be viewed as an isolated system at minimal free energy. Instead, the interfacial dynamics become intimately connected to those of the separated homogeneous phases. Hence, the interface transitions toward a state in local equilibrium whereupon it becomes a dense-fluid mixing layer. A new conceptual view of a transitional liquid injection process emerges from a transition time scale analysis. Close to the nozzle exit, the two-phase interface still remains largely intact and more classic two-phase processes prevail as a consequence. Further downstream, however, the transition to dense- fluid mixing generally occurs before the liquid length is reached. The significance of the presented modeling expressions is established by a direct comparison to a reduced model, which utilizes widely-applied approximations but fundamentally fails to capture the physical complexity discussed in this paper.

42 ENGINEERING↗

In situ investigation of explosive crystallization in a-Ge: Experimental determination of the interface response function using dynamic transmission electron microscopy

The crystallization of amorphous semiconductors is a strongly exothermic process. Once initiated the release of latent heat can be sufficient to drive a self-sustaining crystallization front through the material in a manner that has been described as explosive. Here, we perform a quantitative in situ study of explosive crystallization in amorphous germanium using dynamic transmission electron microscopy. Direct observations of the speed of the explosive crystallization front as it evolves along a laser-imprinted temperature gradient are used to experimentally determine the complete interface response function (i.e., the temperature-dependent front propagation speed) for this process, which reaches a peak of 16 m/s. Fitting to the Frenkel-Wilson kinetic law demonstrates that the diffusivity of the material locally/immediately in advance of the explosive crystallization front is inconsistent with those of a liquid phase. This result suggests a modification to the liquid-mediated mechanism commonly used to describe this process that replaces the phase change at the leading amorphous-liquid interface with a change in bonding character (from covalent to metallic) occurring in the hot amorphous material.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Electrochemical-Thermal Modeling and Microscale Phase Change for Passive Internal Thermal Management of Lithium Ion Batteries

A fully coupled electrochemical and thermal model for lithium-ion batteries is developed to investigate the impact of different thermal management strategies on battery performance. In contrast to previous modeling efforts focused either exclusively on particle electrochemistry on the one hand or overall vehicle simulations on the other, the present work predicts local electrochemical reaction rates using temperature-dependent data on commercially available batteries designed for high rates (C/LiFePO 4 ) in a computationally efficient manner. Simulation results show that conventional external cooling systems for these batteries, which have a low composite thermal conductivity (~1 W/m-K), cause either large temperature rises or internal temperature gradients. Thus, a novel, passive internal cooling system that uses heat removal through liquid-vapor phase change is developed. Although there have been prior investigations of phase change at the microscales, fluid flow at the conditions expected here is not well understood. A first-principles based cooling system performance model is developed and validated experimentally, and is integrated into the coupled electrochemical-thermal model for assessment of performance improvement relative to conventional thermal management strategies. The proposed cooling system passively removes heat almost isothermally with negligible thermal resistances between the heat source and cooling fluid. Thus, the minimization of peak temperatures and gradients within batteries allow increased power and energy densities unencumbered by thermal limitations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Estimation of surface temperature variations due to changes in sky and solar flux with elevation

The magnitude of elevation effects due to changes in solar and sky fluxes, on interpretation of single thermal images and composite products such as temperature difference and thermal inertia, are examined. Simple expressions are derived for the diurnal behavior of the two parameters, by fitting field observations in one tropic (Hawaii) and two semi-arid climates (Wyoming and Colorado) (Hummer-Miller, 1981). It is shown that flux variations with elevation can cause changes in the mean diurnal temperature gradient from -4 to -14 degrees C/km, evaluated at 2000 m. Changes in the temperature-difference gradient of 1 to 2 degrees C/km are also produced which is equivalent to an effective thermal-inertia gradient of 100 W s(exp 1/2)/sq m-K-km. An example is presented showing an elevation effect of 12 degrees C on the day and night thermal scenes of a test site in Arizona.

Hummer-Miller, S.↗

Impurity transport in trapped electron mode driven turbulence

Trapped electron mode turbulence is studied by gyrokinetic simulations with the GYRO code and an analytical model including the effect of a poloidally varying electrostatic potential. Its impact on radial transport of high-Z trace impurities close to the core is thoroughly investigated, and the dependence of the zero-flux impurity density gradient (peaking factor) on local plasma parameters is presented. Parameters such as ion-to-electron temperature ratio, electron temperature gradient, and main species density gradient mainly affect the impurity peaking through their impact on mode characteristics. The poloidal asymmetry, the safety factor, and magnetic shear have the strongest effect on impurity peaking, and it is shown that under certain scenarios where trapped electron modes are dominant, core accumulation of high-Z impurities can be avoided. We demonstrate that accounting for the momentum conservation property of the impurity-impurity collision operator can be important for an accurate evaluation of the impurity peaking factor.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Application of HCMM data to regional geologic analysis for mineral and energy resource evaluation

The effects of topographic elevation and slope on thermal images were examined using representative field obstructions of the solar and sky radiation and a simple linearized thermal model. The forms are easily adapted for analysis of HCMM images using the DMA digital terrain data. From a representative set of field observations, it was found that flux variations with elevation can cause changes in the mean diurnal temperature gradient from -4 deg to -14 deg per km evaluated at 2000 m. Changes in the temperature difference gradient of 1 to 2 C per km are also produced which is equivalent to an effective thermal inertia gradient of 100 W s to the 1/2 power/sq m K/1 per km. Exposed bedrock on topographic ridges will appear to have a lower thermal inertia due to the additional effect.

Watson, K.↗

Preliminary high-fidelity simulation of duct wall deformation in sodium fast reactor subassembly

Computational Fluid Dynamics simulations of nuclear energy systems have received extensive interest and have achieved a certain level of maturity. This gives opportunities for a more realistic mechanical analysis of a sodium fast reactor subassembly that is based on more accurate estimates of pressure and temperature distributions within a subassembly. In fast reactor systems, important reactivity feedbacks can be a result of such subassembly duct wall deformation, with an impact on reactor safety considerations. The structural analysis in this work focuses on the stress-strain distributions in a fast reactor subassembly duct wall that are the result of pressure and temperature gradients across the duct. The RANS-based commercial CFD software STAR-CCM+ was used to perform the structural analysis of the duct wall in a 61-pin subassembly that was irradiated in EBR-II as a lead test subassembly. A loose coupling was performed for the thermal-hydraulics and structural mechanics to reduce the mesh cell number and computation time. It is found that the duct wall displacements are dominated by the thermal expansion, but the stress distributions are dominated by the pressure gradients between the inside and outside of the duct. However, the predicted stresses were far less than the yield stress, indicating large margin to the structural integrity of the non-irradiated duct wall. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Diversity of Eastern North American Ant Communities along Environmental Gradients

Studies of species diversity patterns across regional environmental gradients seldom consider the impact of habitat type on within-site (alpha) and between-site (beta) diversity. This study is designed to identify the influence of habitat type across geographic and environmental space, on local patterns of species richness and regional turnover patterns of ant diversity in the northeastern United States. Specifically, I aim to 1) compare local species richness in paired open and forested transects and identify the environmental variables that best correlate with richness; and 2) document patterns of beta diversity throughout the region in both open and forested habitat. I systematically sampled ants at 67 sites from May to August 2010, spanning 10 degrees of latitude, and 1000 meters of elevation. Patterns of alpha and beta diversity across the region and along environmental gradients differed between forested and open habitats. Local species richness was higher in the low elevation and warmest sites and was always higher in open habitat than in forest habitat transects. Richness decreased as temperature decreased or elevation increased. Forested transects show strong patterns of decreasing dissimilarity in species composition between sites along the temperature gradient but open habitat transects did not. Maximum temperature of the warmest month better predicted species richness than either latitude or elevation. I find that using environmental variables as key predictors of richness yields more biologically relevant results, and produces simpler macroecological models than commonly used models which use only latitude and elevation as predictors of richness and diversity patterns. This study contributes to the understanding of mechanisms that structure the communities of important terrestrial arthropods which are likely to be influenced by climatic change.

59 BASIC BIOLOGICAL SCIENCES↗

The role of electron-scale turbulence in the JET tokamak: experiments and modelling

Dedicated electron heat transport experiments have been carried out in L- and H-mode Deuterium plasmas of the JET-ILW tokamak to identify the amount of electron heat carried by electron-scale electron temperature gradient (ETG) modes. Ion cyclotron resonance heating at different positions has been used to probe the response of the electron temperature inverse gradient length R/L Te to changes in electron heat flux qe, while different amounts of neutral beam heating allowed to scan the ratio of ion to electron temperature T e /T i , which is a key parameter for the onset of ETGs. Results indicate a steepening of the normalized qe vs R/L Te curve above R/LT e ~ 8 for T e /T i ≤ 1, suggestive of the ETG onset. Ion-scale gyro-kinetic (GK) simulations match the ion heat flux and the low-R/L Te part of the qe curve, but do not reproduce such steepening at high R/L Te . Multi-scale GK simulations covering both ion and electron scales and including one impurity bundling light and heavy species indicate an ETG contribution only for R/L Te values larger than the experimental ones. Sensitivity studies of such result are difficult to achieve due to limitation in numerical resources. The quasi-linear TGLF model has been used for sensitivity studies. With the same bundled impurity as the GK multi-scale, TGLF shows the qe steepening at much larger R/L Te values than in experiment, but when using the real mix of light impurities neglecting the heavy impurities, TGLF gets closer to the experimental results. Profile simulations with TGLF including both light and heavy impurities show over-prediction of T e profiles and in some cases also of density, but good T i predictions, confirming issues with the model electron stiffness for these plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Microstructure and functionality of a uniquely graded super duplex stainless steel designed by a novel arc heat treatment method

Highlights: • A uniquely graded duplex stainless steel microstructure was fully characterized. • Nitrogen depletion occurred by solid state diffusion next to the fusion boundary. • Phase fractions and stability were compared to thermodynamic calculations. • Orientation relationships and morphology of sigma, chi, nitrides and R were studied. • A diagram summarizing functionality of aged duplex microstructures is introduced. - Abstract: A novel arc heat treatment technique was applied to design a uniquely graded super duplex stainless steel (SDSS), by subjecting a single sample to a steady state temperature gradient for 10 h. A new experimental approach was used to map precipitation in microstructure, covering aging temperatures of up to 1430 °C. The microstructure was characterized and functionality was evaluated via hardness mapping. Nitrogen depletion adjacent to the fusion boundary depressed the upper temperature limit for austenite formation and influenced the phase balance above 980 °C. Austenite/ferrite boundaries deviating from Kurdjumov–Sachs orientation relationship (OR) were preferred locations for precipitation of σ at 630–1000 °C, χ at 560–1000 °C, Cr{sub 2}N at 600–900 °C and R between 550 °C and 700 °C. Precipitate morphology changed with decreasing temperature; from blocky to coral-shaped for σ, from discrete blocky to elongated particles for χ, and from polygonal to disc-shaped for R. Thermodynamic calculations of phase equilibria largely agreed with observations above 750 °C when considering nitrogen loss. Formation of intermetallic phases and 475 °C-embrittlement resulted in increased hardness. A schematic diagram, correlating information about phase contents, morphologies and hardness, as a function of exposure temperature, is introduced for evaluation of functionality of microstructures.

36 MATERIALS SCIENCE↗

Study of a columnar grain structure produced in a superalloy by gradient-annealing prealloyed powder extrusions

Annealing in a temperature gradient was used to produce a structure of continuous columnar grains in alloy 713 C made by extrusion of prealloyed powder. The columnar-grained specimens had tensile strengths within plus or minus 5 percent of those of the as-cast alloy at 760 C and 980 C but were significantly stronger at room temperature. Stress-rupture tests at 760 C and 980 C showed lives scattered from 17 to 376 percent of those of as-cast 713 C tested under the same conditions. X-ray diffraction studies showed the large grains formed upon annealing to have a well-defined texture, although the as-extruded material had none.

Miner, R. V., Jr.↗