Search NASA⌕ Search

SEARCH · Search NASA

Results for “total correlation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 793 records · Page 44
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Probing planetary pollution from space

The data sets obtained from instruments that have measured carbon monoxide and tropospheric ozone from space are reviewed. These instruments include a gas cell correlation radiometer named MAPS (Measurement of Air Pollution from Satellites), the Total Ozone Mapping Spectrometer, and the Stratospheric Aerosol and Gas Experiment. Particular attention is given to differential absorption lidar technology which can determine the vertical distribution of aerosols and selected trace gases with considerably more resolution than passive remote sensing techniques. The current plans for monitoring pollution from spaceborne platforms are also discussed.

Fishman, Jack↗
NASA NTRS1992

Heat transfer from cylinders in subsonic slip flows

The heat transfer in heated wires was measured using a constant temperature anemometer over a Mach number range from 0.05 to 0.4 and pressures from 0.5 to 8.0 atmospheres. The total temperature ranged from 80 to 120 F and the wire diameters were 0.00015, 0.00032, and 0.00050 inch. The heat transfer data is presented in the form of a corrected Nusselt number. Based on suggested criteria, much of the data was obtained in the slip flow regime. Therefore, the data is compared with data having comparable flow conditions. The possible application of the heat transfer data to hot wire anemometry is discussed. To this end, the sensitivity of the wires to velocity, density, and total temperature is computed and compared using two different types of correlations.

Nagabushana, K. A.↗
NASA NTRS1993

Metallicity gradients in early-type galaxies

A study of medium-to-bright early-type galaxies in six bandpasses from 3500 A to 2.2 microns is presented in order to quantify their colors and color gradients and relate these to metallicity and properties of the underlying stellar population. The Stromgren filter system chosen makes it possible to introduce a new calibration to the Mg(2) system from the present narrow-band v - y indices. A comparison is presented of narrow-band colors centered on particular spectral features vs a color dominated by the mean temperature of the giant branch (i.e., J - K) to test the effects of light vs heavy element abundances on knowledge of the total system metallicity, Z, and the effects of reddening. A good correlation is found between v - y and Mg(2); it provides a connection between one light element metallicity indicator (v - y centers on the CN blend) and another, Mg. The color-magnitude relations for all five optical and near-IR colors are shown. The strongest correlation exists for the metallicity colors, v - y and J - K.

Schombert, James M.↗
NASA NTRS2016

Simplified ISCCP Cloud Regimes for Evaluating Cloudiness in CMIP5 Models

We take advantage of the ISCCP simulator implemented in many CMIP5 models, in order to introduce a credible method to compare model cloud output with corresponding ISCCP observations based on the cloud regime (CR) concept. A novel simplified CR derivation method is introduced that exploits the co-variations of three variables, cloud optical thickness, cloud top pressure and cloud fraction (, pc, CF). Following evaluation criteria established in a previous paper of ours, we assess model cloud simulation performance based on how well the simplified CRs are simulated in terms of similarity of centroids, global values and map correlations of relative frequency-of-occurrence (RFO), and long term total clouds amounts (as opposed to average instantaneous cloud fractions). Mirroring prior results, modeled clouds tend to be too thick optically and not as extensive as in observations. Averaging across models does not help in this or other evaluation aspects, except for cloud geographical locations. A good model for one criterion is usually found to be also a good performer for other criteria despite plenty of exceptions for the criterion of centroid similarity. On the other hand, CRs that include convectively generated high-altitude clouds are not as well simulated here compared to the previous study, but other regimes containing low clouds with high CF improve. Models that have previously performed well distinguish themselves again here, but improvements from other models are also found. The simplified cloud evaluation method thus proves to be more forgiving while still good enough to reveal model weaknesses.

global climate models↗
NASA NTRS2020

A Study of a Magnetic Cloud Propagating through Large-Amplitude Alfvén Waves

We discuss Wind observations of a long and slow magnetic cloud (MC) propagating through large-amplitude Alfvén waves (LAAWs). The MC axis has a strong component along GSE X, as also confirmed by a Grad-Shafranov reconstruction. It is overtaking the solar wind at a speed roughly equal to the upstream Alfvén speed, leading to a weak shock wave âLij17 hrs. ahead. We give evidence to show that the nominal sheath region is populated by LAAWs: (i) a well-defined deHoffman-Teller frame in which there is excellent correlation between the field and flow vectors, (ii) constant field and total pressure, and (iii) an Alfvén ratio (i.e. ratio of kinetic-to-magnetic energy of the fluctuations) near unity at frequencies much lower than the ion cyclotron frequency in the spacecraft frame. In the region where the LAAWs approach the MCâAZs front boundary there are field and flow discontinuities. At the first, magnetic reconnection is taking place, as deduced from a stress balance test (Walen test). This severs connection of some field lines to the Sun and the solar wind strahl disappears. There follows a aLij2-hour interval where the magnetic field strength is diminished while pressure balance is maintained. Here the bi-directionality of the suprathermal electron flows is intermittently disrupted. This interval ends with a slow expansion fan downstream of which there is a dropout of halo electrons just inside the front boundary of the MC. This study illustrates an untypical case of a slow MC interacting with LAWWs in the slow solar wind.

C. J. Farrugia↗
NASA NTRS2023

Effect of the Electrostatic Field due to the Surface Monolayer Metal Atoms on the Dissociation of Homonuclear Diatomic Gases in Gas-Metal Surface Reactions

The present paper examines the role of an electrostatic field generated by the outermost monolayer of metal ions prior to gas adsorption in aiding the dissociation of homonuclear diatomic gas molecules. The interaction of five homonuclear diatomic gases, Cl 2 , F 2 , H 2 , N 2 and O 2 , with several pure metals are examined using Coulomb’s law to calculate the attractive and repulsive forces between the electrons or ions in the gas molecule and the free surface metallic electrons or ions assuming a Bohr model. These calculations demonstrate that the total energy of the electrostatic fields from the metals can exceed the molecular binding energies of Cl 2 , F 2 , and O 2 at some distance from the metallic surface thereby suggesting that these gases interact primarily with the metallic surface in their atomic states after molecular bond dissociation prior to reaction. In contrast, H 2 and N 2 gases do not dissociate prior to reaching the metal surface due to the fact that the effective charge of the gas ions is less than the total electron charge at the outermost electronic shell. The present results correlate linearly with the electrochemical series standard reduction potential as well as with the Pauling electronegativity for several metals.

Gas-metal reactions↗
DOE OSTI2019

Speciation of Mercury and Heavy Metals in Hg-contaminated Soils from Oak Ridge TN - 19426

Mercury is present in various forms in the environments. Mercuric compounds, Hg(II) are found predominant species in soil and water, while elemental mercury, Hg0 is the major species in the atmosphere, and organo-mercury is present mostly in food-chain. The speciation of Hg is important to understand its mobility, bioavailability in soils, sediments and biota and potential toxicity on human and environmental health. A catastrophic Hg spill occurred at the Y-12 National Security Complex (Y-12 Plant) at the Oak Ridge Reservation of the Department of Energy (DOE) in 1960's that contaminated facilities, soil, sediment, surface water, and groundwater within the boundaries of the Y-12 Plant and the downstream environment along the East Fork Poplar Creek (EFPC) at the city of Oak Ridge. It is estimated that 350,000 kg of Hg was released to the environment. The EFPC floodplain soils were reported to contain predominantly cinnabar (HgS) form, but other inorganic and organic Hg species, including Hg0 , HgCl{sub 2}, Hg{sub 2}Cl{sub 2}, HgO and CH{sub 3}Hg{sup +} have been found within the Y-12 Facility boundaries and the 23-km long contaminated EFPC. Over the last 25 years, Hg fluxes from the Y-12 Plant have been reduced by various remediation efforts, nonetheless Hg concentration in water and fish have not declined due to the persistent leaching of Hg from contaminated floodplain soils and sediments. In this work, we performed total elemental analyses and Hg speciation in the floodplain soils and sediments collected along EFPC in Oak Ridge, TN. The objective of the study was to elucidate the distribution of Hg in floodplain soil fractions and the relation with metals including arsenic, copper, zinc and lead. Total elemental; characterization was performed by ICP-MS analysis after with HNO{sub 3} and HF dissolution. Sequential extractions were carried out to extract water-soluble (F1), cation-exchangeable (F2) fractions and those bound to carbonates (F3), reducible oxides (F4) (Mn-oxides), organic matter (F5), amorphous (F6) and crystalline iron oxides (F7) and the residual fraction (F8) containing elemental Hg, non-cinnabar Hg and humic acid-bound Hg. Preliminary studies were conducted with artificially spiked and incubated soils as well as soils contaminated with enriched {sup 200}Hg isotope. The results indicated that Hg is predominantly associated with organic matter, amorphous iron and crystalline oxides and the residual fraction. The total Hg in the first four fractions (F1, F2, F3, and F4) were about 1% of the total Hg, while Hg was found equally bound to organic matter (F5) and crystalline Fe-oxides (F7) that accounted about 20% of total Hg. The Hg associated with amorphous iron oxides (F6) accounted as much as 26% of the total Hg and non-cinnabar Hg accounted about 24% of total Hg (non-cinnabar Hg). The results also indicated positive correlation for As, Cu, Pb and Zn levels with those of Hg. Most As was associated with amorphous Fe-oxides. Cu and Pb were dominant both in organic matter and amorphous oxide fractions. Zn was mostly bound to amorphous Fe-oxide but significant amount of Zn was also found to be associated with organic matter and crystalline Fe-oxides. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Characterization of spurious-electron signals in the double-phase argon TPC of the DarkSide-50 experiment

Spurious-electron signals in dual-phase noble-liquid time projection chambers have been observed in both xenon and argon Time Projection Chambers (TPCs). This paper presents the first comprehensive study of spurious electrons in argon, using data collected by the DarkSide-50 experiment at the INFN Laboratori Nazionali del Gran Sasso (LNGS). Understanding these events is a key factor in improving the sensitivity of low-mass dark matter searches exploiting ionization signals in dual-phase noble liquid TPCs. We find that a significant fraction of spurious-electron events, ranging from 30 to 70% across the experiment's lifetime, are caused by electrons captured from impurities and later released with delays of order 5-50 ms. The rate of spurious-electron events is found to correlate with the operational condition of the purification system and the total event rate in the detector. Finally, we present evidence that multi-electron spurious electron events may originate from photo-ionization of the steel grid used to define the electric fields. These observations indicate the possibility of reduction of the background in future experiments and hint at possible spurious electron production mechanisms.

Agnes, P. [GSSI, Aquila; Gran Sasso]↗
DOE OSTI2026

Stochastic tensor contraction for quantum chemistry

Many computational methods in ab initio quantum chemistry are formulated in terms of high-order tensor contractions, whose cost determines the size of system that can be studied. We introduce stochastic tensor contraction to perform such operations with greatly reduced cost, and present its application to the gold-standard quantum chemistry method, coupled cluster theory with up to perturbative triples. For total energy errors more stringent than chemical accuracy, we reduce the computational scaling to that of mean-field theory, while starting to approach the mean-field absolute cost, thereby challenging the existing cost-to-accuracy landscape. Benchmarks against state-of-the-art local correlation approximations further show that we achieve an order-of-magnitude improvement in both total computation time and error, with significantly reduced sensitivity to system dimensionality and electron delocalization. We conclude that stochastic tensor contraction is a powerful computational primitive to accelerate a wide range of quantum chemistry.

Chemical Physics (physics.chem-ph)↗
DOE OSTI2020

Simulating the Multi-epoch Direct Detection Technique to Isolate the Thermal Emission of the Non-transiting Hot Jupiter HD187123b

We report the 6.5σ detection of water from the hot Jupiter HD187123b with a Keplerian orbital velocity K {sub p} of 53 ± 13 km s{sup −1}. This high-confidence detection is made using a multi-epoch, high-resolution, cross-correlation technique, and corresponds to a planetary mass of 1.4{sub −0.3}{sup +0.5} M {sub J} and an orbital inclination of 21° ± 5°. The technique works by treating the planet/star system as a spectroscopic binary and obtaining high signal-to-noise, high-resolution observations at multiple points across the planet’s orbit to constrain the system’s binary dynamical motion. All together, seven epochs of Keck/NIRSPEC L-band observations were obtained, with five before the instrument upgrade and two after. Using high-resolution SCARLET planetary and PHOENIX stellar spectral models, we were able to drastically increase the confidence of the detection by running simulations that could reproduce, and thus remove, the nonrandom structured noise in the final likelihood space well. The ability to predict multi-epoch results will be extremely useful for furthering the technique. Here, we use these simulations to compare three different approaches to combining the cross correlations of high-resolution spectra and find that the Zucker log(L) approach is least affected by unwanted planet/star correlation for our HD187123 data set. Furthermore, we find that the same total signal-to-noise ratio (S/N) spread across an orbit in many, lower S/N epochs rather than fewer, higher S/N epochs could provide a more efficient detection. This work provides a necessary validation of multi-epoch simulations, which can be used to guide future observations and will be key to studying the atmospheres of farther separated, non-transiting exoplanets.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1999

Is There an Arctic Ozone Hole?

Total ozone observations from the Total Ozone Mapping Spectrometer (TOMS) instruments during March 1997 revealed an extensive region of low column densities in the Arctic region centered near the north pole. Values were below 250 Dobson units for nearly a two week period during this period, and were correlated with the position of the northern lower stratospheric polar vortex. The March 1997 average total ozone column densities were more than 30% lower than the average of column densities observed during the 1979-1982 March period. Both the northern spring seasons of 1998 and 1999 have shown much higher levels of total ozone. In this presentation, we will discuss the causes of the low total ozone values in 1997 and contrast those low values with the higher 1998 and 1999 observations. The reason for my travel to the University of Valparaiso is to give this seminar and provide information to my colleagues on our work here at GSFC. The benefit to NASA is to interact with my Univ. of Valparaiso colleagues, gain their insights and input into this research, and establish collaborations with the current research efforts at the University.

Newman, Paul A.↗
NASA NTRS2000

Is There an Arctic Ozone Hole?

Total ozone observations from the Total Ozone Mapping Spectrometer (TOMS) instruments during March 1997 revealed an extensive region of low column densities in the Arctic region centered near the north pole. Values were below 250 Dobson units for nearly a two week period during this period, and were correlated with the position of the northern lower stratospheric polar vortex. The March 1997 average total ozone column densities were more than 30% lower than the average of column densities observed during the 1979-1982 March period. Both the northern spring seasons of 1998 and 1999 have shown much higher levels of total ozone. In this presentation, we will discuss the causes of the low total ozone values in 1997 and contrast those low values with the higher 1998 and 1999 observations. I will additionally discuss the just completed SOLVE campaign and the March 2000 ozone values.

Newman, Paul A.↗
NASA NTRS2004

What the Sunspot Record Tells Us About Space Climate

The records concerning the number, sizes, and positions of sunspots provide a direct means of characterizing solar activity over nearly 400 years. Sunspot numbers are strongly correlated with modem measures of solar activity including: 10.7-cm radio flux, total irradiance, x-ray flares, sunspot area, the baseline level of geomagnetic activity, and the flux of galactic cosmic rays. The Group Sunspot Number provides information on 27 sunspot cycles, far more than any of the modem measures of solar activity, and enough to provide important details about long-term variations in solar activity or Space Climate. The sunspot record shows: 1) sunspot cycles have periods of 131 plus or minus 14 months with a normal distribution; 2) sunspot cycles are asymmetric with a fast rise and slow decline; 3) the rise time from minimum to maximum decreases with cycle amplitude; 4) large amplitude cycles are preceded by short period cycles; 5 ) large amplitude cycles are preceded by high minima; 6) although the two hemispheres remain linked in phase, there are significant asymmetries in the activity in each hemisphere; 7) the rate at which the active latitudes drift toward the equator is anti-correlated with the cycle period, 8) the rate at which the active latitudes drift toward the equator is positively correlated with the amplitude of the cycle after the next; 9) there has been a significant secular increase in the amplitudes of the sunspot cycles since the end of the Maunder Minimum (1715); and 10) there is weak evidence for a quasi-periodic variation in the sunspot cycle amplitudes with a period of about 90 years. These characteristics indicate that the next solar cycle should have a maximum smoothed sunspot number of about 1.45 plus or minus 30 in 2010 while the following cycle should have a maximum of about 70 plus or minus 30 in 2023.

Hathaway, David H.↗
DOE OSTI2021

Guest-Host Interactions in Clathrate Hydrates: Benchmark MP2 and CCSD(T)/CBS Binding Energies of CH4, CO2 and H2S in (H2O)20 Cages

We present benchmark binding energies of naturally occurring gas molecules CH4, CO2, and H2S in the small cage, namely the pentagonal dodecahedron (512) (H2O)20, which is one of the constituent cages of the 3 major lattices (structures I, II and H) of clathrate hydrates. These weak interactions require higher levels of electron correlation and converge slowly with increasing basis set to the Complete Basis Set (CBS) limit, necessitating the use of large basis sets up to the augcc- pV5Z and subsequent correction for Basis Set Superposition Error (BSSE). For the host hollow (H2O)20 cages we have identified a most stable isomer with binding energy of -200.8 ± 2.1 kcal/mol at the CCSD(T)/CBS limit (-199.2 ± 0.5 kcal/mol at the MP2/CBS limit). Additionally, we report converged second order Moller-Plesset (MP2) CBS binding energies for the encapsulation of guests in the (H2O)20 cage of -4.3 ± 0.1 for CH4@(H2O)20, -6.6 ± 0.1 for CO2@(H2O)20 and -8.5 ± 0.1 kcal/mol for H2S@(H2O)20, respectively. For CH4@(H2O)20, exhibiting the weakest encapsulation affinity among the three, we report CCSD(T)/aug-cc-pVTZ binding energies and, based on them, a CCSD(T)/CBS estimate of -4.75 ± 0.1 kcal/mol. To the best of our knowledge, the CCSD(T)/aug-cc-pVTZ calculation for CH4@(H2O)20 is the largest one reported to date (168 valence electrons, 1978 basis functions and the correlation of 84 doubly occupied and 1873 virtual orbitals) and required a scalable implementation of the (T) module on 6144 nodes (350208 cores) of the “Cori” supercomputer at the National Energy Research Supercomputing Center (NERSC) for a total execution time of 195 minutes (for the (T) part). These efficient scalable implementations of highly correlated methods offer the capability to obtain long-lasting benchmarks of intermolecular interactions in complex systems. They also provide a path towards parametrizing classical potentials needed to study the dynamical and transport properties in these complex systems as well as assess the accuracy of lower scaling electronic structure methods such as Density Functional Theory (DFT) and MP2 including its spin-biased variants.

Heindel, Joseph↗
NASA NTRS1983

A total life prediction model for stress concentration sites

Fatigue crack growth tests were performed on center crack panels and radial crack hole samples. The data were reduced and correlated with the elastic parameter K taking into account finite width and corner crack corrections. The anomalous behavior normally associated with short cracks was not observed. Total life estimates for notches were made by coupling an initiation life estimate with a propagation life estimate.

Hartman, G. A.↗
DOE OSTI2023

Extragalactic CO emission lines in the CMB experiments: A forgotten signal and a foreground

High resolution cosmic microwave background (CMB) experiments have allowed us to precisely measure the CMB temperature power spectrum down to very small scales (multipole ℓ ~ 3000). Such measurements at multiple frequencies enable separating the power spectrum of the primary CMB anisotropies with the power spectrum of other signals like CMB lensing, thermal and kinematic Sunyaev-Zel’dovich effects (tSZ and kSZ), and cosmic infrared background (CIB). Here, in this paper, we explore another signal of interest at these frequencies that should be present in the CMB maps: extragalactic CO molecular rotational line emissions, which are the most widely used tracers of molecular gas in the line intensity mapping experiments. Using the SIDES simulations adopted for top hat bandpasses at 150 and 220 GHz, we show that the cross-correlation of the CIB with CO lines has a contribution similar to the CIB-tSZ correlation and the kSZ power, thereby contributing a non-negligible amount to the total power at these scales. This signal, therefore, may significantly impact the recently reported ≥3σ detection of the kSZ power spectrum from the South Pole Telescope collaboration, as the contribution of the CO lines is not considered in such analyses. Our results also provide a new way of measuring the CO power spectrum in cross-correlation with the CIB. Finally, these results show that the CO emissions present in the CMB maps will have to be accounted for in all the CMB auto-power spectrum and cross-correlation studies involving a large-scale structure tracer.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Femtoscopy in s NN = 5.02 TeV p+Pb collisions with ATLAS

Bose-Einstein correlations between identified charged pions are measured for p+Pb collisions at $ \sqrt{sNN}=5.02 $ TeV with the ATLAS detector using a total integrated luminosity of 28 nb -1 . Pions are identified using ionisation energy loss measured in the pixel silicon detector. Two-particle correlation functions and the extracted source radii are presented as a function of collision centrality as well as average transverse pair momentum (k T ), rapidity (y* $\pi$$\pi$ ), and azimuthal angle with respect to the second-order event plane. Pairs are selected with a rapidity -2 < y* $\pi$$\pi$ <1 and with an average transverse momentum 0.1 < k T < 0.8 GeV. The effect on the two-particle correlation function from jet fragmentation is studied, and a new method for constraining its contributions to the measured correlations is described. The measured source sizes are substantially larger in more central collisions and are observed to decrease with increasing pair k T . A correlation with the local single-particle multiplicity dN ch /dy* is demonstrated. The cross term R ol , which couples radial and longitudinal expansion, is measured as a function of rapidity, and a departure from zero is observed with 5.1σ combined significance for y* $\pi$$\pi$ > -1 in the most central events. Lastly, the azimuthal modulation of the radii in central events is observed to be consistent with that predicted by hydrodynamics and observed in A+A collisions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1977

Shuttle elevon cove aerodynamic heating by internal flow

The thermal response of the cove seal area of the Shuttle elevon wing junction is investigated in an arc heated supersonic duct. The temperature response of the seal area is measured for various seal gap widths, ambient pressures, and enthalpies to determine the dependence of internal heating on these parameters. A correlation of the results shows that the internal heating to the seal is proportional to the product of the external pressure, the gap width and the square root of the total enthalphy. Temperatures at the end of a simulated Shuttle entry compare well with predictions based on this correlation for the narrower gap widths where there is only a small pressure drop at the cove inlet. Similar predictions are made for Shuttle flight as a function of seal gap widths to determine the maximum gap width allowable, yet not exceed design temperatures on the structure.

Scott, C. D.↗