Search NASA⌕ Search

SEARCH · Search NASA

Results for “transform”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 793 records · Page 44
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Precipitation in Mg-Gd-Y-Zr Alloy: Atomic-scale insights into structures and transformations

This paper reports on a comprehensive investigation, using atomic-scaled C{sub s} corrected high angle annular dark field-scanning transmission electron microscopy (HAADF-STEM), of the precipitation in Mg-9.28Gd-2.93Y-0.35Zr, including structures of the precipitates and several structural transformation processes. The precipitation sequence is identified as: Super saturated solid solution → clusters → nucleation β{sup '} (major)/ β{sub H} (minor)→ precipitate β{sup '} (major)/ β{sub M} , β{sub T}{sup '} (minor)→β{sub 1} → β(Equilibrium). Under peak-age condition, the strengthening structure is independent defect-free β{sup '} with little interaction among each other. Under over-age condition, the β{sup '} precipitates start to interact with each other, during which coarsening and orientation transformation of β{sup '} precipitates take place. The coarsening and orientation transformation, in which some RE atoms in the precipitates need to change their positions, are achieved by β{sub M} and β{sub T}{sup '} as transitional structures. - Highlights: • The precipitation in Mg-Gd-Y-Zr is comprehensively investigated by advanced atomic-scale Cs-corrected HAADF-STEM. • Various novel precipitate structures are unraveled. • Four types of interfaces between the precipitates are fully characterized. • The structural transformation processes of the precipitates are revealed.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Thermodynamic, structural and magnetic studies of phase transformations in MnAl nanocomposite alloys

Highlights: • Small changes in MnAl stoichiometry (5 at.%) produce different phase structure. • In Mn{sub 60}Al{sub 40} as-cast alloy only hcp ε phase can be found • In Mn{sub 55}Al{sub 45} as-cast alloy, there is a mixture of γ{sub 2} (Al{sub 8}Mn{sub 5}) and ε as well as ferromagnetic MnAl τ-phase. • Energies of phase transformation of about 165 kJ/mol for Mn{sub 60}Al{sub 40} and 290 kJ/mol for Mn{sub 55}Al{sub 45} alloys are found. • hcp ε phase decomposes through the migration of interphase interfaces. - Abstract: We have undertaken a temperature-dependent, investigation of the thermodynamics, structure, morphology and magnetism of two MnAl nanocomposite alloys (Mn{sub 60}Al{sub 40} and Mn{sub 55}Al{sub 45}). Differential scanning calorimetry (DSC) studies allowed the determination of the exo-effects occurring in the structural phase transformation of MnAl, while by using temperature-dependent X-ray diffraction of synchrotron radiation we were able to monitor the phase transformation effects and the evolution with temperature of various structural phases occurring in the samples. We have shown that slight changes in stoichiometry (5 at.%) give rise to different phase structure in the as-cast state. While in Mn{sub 60}Al{sub 40} only hcp ε phase can be found, in Mn{sub 55}Al{sub 45} as-cast alloy, there is a quite complex phase structure with a mixture of γ{sub 2} (Al{sub 8}Mn{sub 5}) and ε as well as ferromagnetic MnAl τ-phase. Activation energies of about 165 kJ/mol and 290 kJ/mol have been calculated from the Ozawa-Flynn-Wall analysis of DSC experimental data. These findings are in good agreement with the results obtained from XRD. For the Mn{sub 55}Al{sub 45} as-cast alloy, we have confirmed by temperature-dependent synchrotron XRD that the hcp ε phase decomposes through the migration of interphase interfaces with the transformation rate controlled by boundary diffusion processes. High-resolution transmission electron microscopy have confirmed the phase structure obtained by XRD, while magnetic properties, obtained for the as-cast alloys are consistent with the multiphase character of the samples and in good agreement with previously reported results. The magnetization does not saturate for the maximum applied field of about 4 × 10{sup 6} A/m and a marked coercivity of about 160 kA/m is obtained for the Mn{sub 55}Al{sub 45} as-cast alloy.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2018

Effect of niobium and phase transformation temperature on the microstructure and texture of a novel 0.40% C thermomechanically processed steel

Field emission scanning electron microscopy, electron backscatter diffraction (EBSD) and X-ray diffraction (XRD) have been employed to investigate the effect of niobium and phase transformation temperature on the evolution of microstructure and texture in a novel thermomechanically processed, medium‑carbon, low-alloy steel intended for slurry pipeline applications. Thermomechanical processing consisted of hot-rolling in the austenitic region with deformation both above the recrystallization limit temperature and below the recrystallization stop temperature. Immediately after rolling, specimens were directly quenched in water to two different temperatures of 560 °C and 420 °C and subsequently furnace cooled from those temperatures to simulate the cooling of coiled strip on a hot strip mill. The microstructure of samples quenched to 560 °C mostly comprised of upper bainite, whereas the samples quenched to 420 °C mainly consisted of lath-type lower bainite. The transformation texture of all samples at the mid-thickness position consisted of α, γ and ε-fibers with high intensities close to the transformed copper, transformed brass and rotated cube components. The addition of 0.013 wt% Nb refined the microstructure and sharpened the texture. The texture of the small fraction of retained austenite present in the final microstructures indicated that the main bcc texture components result from the brass and copper components in the parent austenite.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Effect of tailored martensitic transformation in a thick weld: Residual stresses mitigation, heterogeneous microstructure, and mechanical properties

The residual stresses, microstructural heterogeneities, and mechanical properties were extensively examined in a 25 mm thick weld consisting of two regions which respectively undergo phase transformation at relatively low (100 °C) temperature (LTT) and high (670 °C) temperature (HTT) during cooling. Due to the LTT martensitic transformation, which features a transformation strain of ~4000 με, large compressive residual stress (−510 MPa) was generated as confirmed by neutron diffraction and contour method. Meanwhile, significant heterogeneities were observed in terms of the chemical composition, yield strength, and microhardness across the interface between the LTT and HTT regions. The dependency of martensitic transformation starting temperature (M{sub s}) on chemical composition is empirically formulated, and it reveals that the dependency of M{sub s} on the Ni and Cr compositions becomes stronger when the temperature is lower than 200 °C. The maximum change of residual stresses (σ{sub x}{sup max}) exponentially decreases as M{sub s} decreases in the manner of σ{sub x}{sup max} = 97.5 exp(M{sub s}/227)-649. The fracture behavior was found highly dependent upon the volume fraction of retained austenite influenced by M{sub s}. While a ductile fracture mode was found in the cellular LTT region containing relatively higher amount of retained austenite (~10%), the interface shows transgranular brittle fracture features and sub-cracking due to the relatively small amount of retained austenite and the predominant martensite constituent.

36 MATERIALS SCIENCE↗
DOE OSTI2019

In-situ synchrotron high energy X-ray diffraction study of phase transformation of intermetallic Ti 3 Sn

Ti 3 Sn has received increasing attention as high damping metallic material. However, information of solid state transformation and crystal structure of Ti 3 Sn were still incomplete. Here, in-situ synchrotron high energy XRD during heating/cooling and during uniaxial compressive loading were used to study the phase transformation of Ti 3 Sn. Thermal-induced reversible phase transformation of Ti 3 Sn was demonstrated, and it was found that such transformation could also be stress (strain) induced. Crystal structure, lattice parameters and atomic Wyckoff positions of new base-centered orthorhombic phase of Ti 3 Sn were suggested based on Rietveld refinement of XRD profiles. Lastly, the phase contents of Ti 3 Sn during heating/cooling processes were also discussed

36 MATERIALS SCIENCE↗
DOE OSTI2023

Evolution of microstructure and strength of a high entropy alloy undergoing the strain-induced martensitic transformation

In a recent work, we have reported outstanding strength and work hardening exhibited by a metastable high entropy alloy (HEA), Fe 42 Mn 28 Co 10 Cr 15 Si 5 (in at. %), undergoing the strain-induced martensitic transformation from metastable gamma austenite (γ) to stable epsilon martensite (ε). However, the alloy exhibited poor ductility, which was attributed to the presence of the brittle sigma (σ) phase in its microstructure. The present work reports the evolution of microstructure, strength, and ductility of a similar HEA, Fe 38.5 Mn 20 Co 20 Cr 15 Si 5 Cu 1.5 (in at. %), designed to suppress the formation of σ phase. A cast and then rolled plate of the alloy was processed into four conditions by annealing for 10 and 30 min at 1100 °C and by friction stir processing (FSP) at tool rotation rates of 150 and 400 revolutions per minute (RPM) to facilitate detailed examinations of variable initial grain structures. Neutron diffraction and electron microscopy were employed to characterize the microstructure and texture evolution. The initial materials had variable grain size but nearly 100% γ structure. Diffusionless strain induced γ→ε phase transformation took place under compression with higher rate initially and slower rate at the later stages of deformation, independent on the initial grain size. The transformation facilitated part of plastic strain accommodation and rapid strain hardening owing to a transformation-induced dynamic Hall-Petch-type barrier effect, increase in dislocation density, and texture. Here, the peak strength of nearly 2 GPa was achieved under compression using the structure created by double pass FSP (150 RPM followed by 150 RPM). Remarkably, the tensile elongation exhibited by the alloy was nearly 20% with fracture surfaces featuring a combination of ductile dimples and cleavage.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Origin for retained activity in Pr 2 NiO 4 while undergoing substantial phase transformation in a long-term solid oxide cell operation

Pr 2 NiO 4 (PNO) is a known active oxygen electrode for solid oxide cells but undergoes phase transformation at high temperatures. An in-situ synchrotron study on PNO electrodes show that phase transformation reaches nearly 100% in a long-term operation. Such significant phase transformation is expected to play a detrimental role on the cell performance. However, PNO retains the activity in an enduring operation. The origin for this dichotomy has remained obscure. Here, the aim of this article is to investigate the origin for retained activity and performance stability in PNO electrode. High-resolution transmission electron microcopy analysis shows the presence of a large number of nanoclusters (~ 5 nm) through the entire electrode bulk, which are localized in the 20–60 nm region. In-situ synchrotron studies show that those nanoclusters are nickelates that account for the retained activity during phase transformation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Global Transformations for Legacy Parallel Applications via Structural Analysis and Rewriting

Performance and scalability optimization of large HPC applications is currently a labor-intensive, manual process with very low productivity. Major difficulties come from the disaggregated environment for HPC application development: the compiler is only involved in local decisions (core or multithreaded domain), while a library-based, communication-oriented programming model realizes whole-machine parallelism. Realizing any major global change in such a disaggregated environment is very difficult and involves changing large portions of the source code. We present semi-automated techniques, based on structural analysis and rewriting, for performing global transformations on an HPC application source code. We present two case studies using the Self-Consistent Field (SCF) standalone benchmark as well as the Coupled Cluster (CCSD) module (2.9 million lines of Fortran code), a key module of the NWChem computational chemistry application. We demonstrate how structural rewriting techniques can be used to automate transformations that affect multiple sections of the application's source code. We show that the transformations can be applied in a systematic fashion across the source code bases with minimal manual effort. These transformations improve the scalability of the SCF benchmark by more than two orders of magnitude and the performance of the full CCSD module by a factor of 4.0.

legacy parallel applications↗
DOE OSTI2023

Hybrid model to evaluate the frequency-dependent leakage inductance of partially-filled transformers

The leakage inductance of a transformer designed for a power electronic converter can drop significantly as the switching frequency is increased due to skin and proximity effects. Although the magnetic image method-based double-2-D model can predict the low-frequency leakage inductance of a partially-filled transformer with sufficient accuracy, it is inherently a frequency-independent model. While Dowell’s 1-D model uses frequency-dependent relations to account for both skin and proximity effects, its accuracy is severely affected by the assumed winding geometry. In this paper, a semianalytical hybrid model is proposed that uses superposition to combine a modified Dowell’s model with the double-2-D model to predict the true leakage inductance of partially-filled transformers at any given frequency. All three conductor types—round, foil, and litz wire—are modeled and analyzed. The quasi-2-D model is further investigated on a variable inductance transformer (VIT) whose winding geometry can be modified mechanically to vary its leakage inductance. With less than 5 % error throughout, the semi-analytically evaluated leakage inductances are in excellent agreement with the finite element method (FEM) simulated and experimentally measured leakage inductances.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2012

Suberoylanilide hydroxamic acid (SAHA) inhibits EGF-induced cell transformation via reduction of cyclin D1 mRNA stability

Suberoylanilide hydroxamic acid (SAHA) inhibiting cancer cell growth has been associated with its downregulation of cyclin D1 protein expression at transcription level or translation level. Here, we have demonstrated that SAHA inhibited EGF-induced Cl41 cell transformation via the decrease of cyclin D1 mRNA stability and induction of G0/G1 growth arrest. We found that SAHA treatment resulted in the dramatic inhibition of EGF-induced cell transformation, cyclin D1 protein expression and induction of G0/G1 growth arrest. Further studies showed that SAHA downregulation of cyclin D1 was only observed with endogenous cyclin D1, but not with reconstitutionally expressed cyclin D1 in the same cells, excluding the possibility of SAHA regulating cyclin D1 at level of protein degradation. Moreover, SAHA inhibited EGF-induced cyclin d1 mRNA level, whereas it did not show any inhibitory effect on cyclin D1 promoter-driven luciferase reporter activity under the same experimental conditions, suggesting that SAHA may decrease cyclin D1 mRNA stability. This notion was supported by the results that treatment of cells with SAHA decreased the half-life of cyclin D1 mRNA from 6.95 h to 2.57 h. Consistent with downregulation of cyclin D1 mRNA stability, SAHA treatment also attenuated HuR expression, which has been well-characterized as a positive regulator of cyclin D1 mRNA stability. Thus, our study identifies a novel mechanism responsible for SAHA inhibiting cell transformation via decreasing cyclin D1 mRNA stability and induction of G0/G1 growth arrest in Cl41 cells. -- Highlights: ► SAHA inhibits cell transformation in Cl41 cells. ► SAHA suppresses Cyclin D1 protein expression. ► SAHA decreases cyclin D1 mRNA stability.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2020

Stress-Induced Structural Transformations in Au Nanocrystals

Nanocrystals can exist in multiply twinned structures like icosahedron or single crystalline structures like cuboctahedron. Transformations between these structures can proceed through diffusion or displacive motion. Experimental studies on nanocrystal structural transformations have focused on high-temperature diffusion-mediated processes. Limited experimental evidence of displacive motion exists. We report structural transformation of 6 nm Au nanocrystals under nonhydrostatic pressure of 7.7 GPa in a diamond anvil cell that is driven by displacive motion. X-ray diffraction and transmission electron microscopy were used to detect the structural transformation from multiply twinned to single crystalline. Single crystalline nanocrystals were recovered after unloading, then quickly reverted to the multiply twinned state after dispersion in toluene. Furthermore, the dynamics of recovery was captured using TEM which showed surface recrystallization and rapid twin boundary motion. Molecular dynamics simulations showed that twin boundaries are unstable due to defects nucleated from the interior of the nanocrystal.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2023

White Laue and powder diffraction studies to reveal mechanisms of HCP-to-BCC phase transformation in single crystals of Mg under high pressure

Mechanisms of hexagonal close-packed (HCP) to body-centered cubic (BCC) phase transformation in Mg single crystals are observed using a combination of polychromatic beam Laue diffraction and monochromatic beam powder diffraction techniques under quasi-hydrostatic pressures of up to 58 ± 2 GPa at ambient temperature. Although experiments were performed with both He and Ne pressure media, crystals inevitably undergo plastic deformation upon loading to 40–44 GPa. The plasticity is accommodated by dislocation glide causing local misorientations of up to 1°–2°. The selected crystals are tracked by mapping Laue diffraction spots up to the onset of the HCP to BCC transformation, which is determined to be at a pressure of 56.6 ± 2 GPa. Intensity of the Laue reflections from HCP crystals rapidly decrease but no reflections from crystalline BCC phase are observed with a further increase of pressure. Nevertheless, the powder diffraction shows the formation of 110 BCC peak at 56.6 GPa. The peak intensity increases at 59.7 GPa. Upon the full transformation, a powder-like BCC aggregate is formed revealing the destructive nature of the HCP to BCC transformation in single crystals of Mg.

36 MATERIALS SCIENCE↗
DOE OSTI2011

Equivalence of domains for hyperbolic Hubbard-Stratonovich transformations

We settle a long standing issue concerning the traditional derivation of non-compact non-linear sigma models in the theory of disordered electron systems: the hyperbolic Hubbard-Stratonovich (HS) transformation of Pruisken-Schaefer type. Only recently the validity of such transformations was proved in the case of U(p, q) (non-compact unitary) and O(p, q) (non-compact orthogonal) symmetry. In this article we give a proof for general non-compact symmetry groups. Moreover, we show that the Pruisken-Schaefer type transformations are related to other variants of the HS transformation by deformation of the domain of integration. In particular we clarify the origin of surprising sign factors which were recently discovered in the case of orthogonal symmetry.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2013

Ion-beam-induced magnetic and structural phase transformation of Ni-stabilized face-centered-cubic Fe films on Cu(100)

Metastable face-centered cubic (fcc) Fe/Cu(100) thin films are good candidates for ion-beam magnetic patterning due to their magnetic transformation upon ion-beam irradiation. However, pure fcc Fe films undergo spontaneous transformation when their thickness exceeds 10 ML. This limit can be extended to approximately 22 ML by deposition of Fe at increased CO background pressures. We show that much thicker films can be grown by alloying with Ni for stabilizing the fcc γ phase. The amount of Ni necessary to stabilize nonmagnetic, transformable fcc Fe films in dependence on the residual background pressure during the deposition is determined and a phase diagram revealing the transformable region is presented.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Spiral-like multi-beam emission via transformation electromagnetics

Transformation electromagnetics offers an unconventional approach for the design of novel radiating devices. Here, we propose an electromagnetic metamaterial able to split an isotropic radiation into multiple directive beams. By applying transformations that modify distance and angles, we show how the multiple directive beams can be steered at will. We describe transformation of the metric space and the calculation of the material parameters. Different transformations are proposed for a possible physical realization through the use of engineered artificial metamaterials. Full wave simulations are performed to validate the proposed approach. The idea paves the way to interesting applications in various domains in microwave and optical regimes.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Beam-induced graphitic carbon cage transformation from sumanene aggregates

We found that electron-beam irradiation of sumanene aggregates strongly enhanced their transformation into a graphitic carbon cage, having a diameter of about 20 nm. The threshold electron dose was about 32 mC/cm{sup 2} at 200 keV, but the transformation is still induced at 20 keV. The transformation sequence suggested that the cage was constructed accompanied by the dynamical movement of the transiently linked sumanene molecules in order to pile up inside the shell. Thus, bond excitation in the sumanene molecules rather than a knock-on of carbon atoms seems to be the main cause of the cage transformation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Measurement of the internal stress and electric field in a resonating piezoelectric transformer for high-voltage applications using the electro-optic and photoelastic effects

The high output voltages from piezoelectric transformers are currently being used to accelerate charged particle beams for x-ray and neutron production. Traditional methods of characterizing piezoelectric transformers (PTs) using electrical probes can decrease the voltage transformation ratio of the device due to the introduction of load impedances on the order of hundreds of kiloohms to hundreds of megaohms. Consequently, an optical diagnostic was developed that used the photoelastic and electro-optic effects present in piezoelectric materials that are transparent to a given optical wavelength to determine the internal stress and electric field. The combined effects of the piezoelectric, photoelastic, and electro-optic effects result in a time-dependent change the refractive indices of the material and produce an artificially induced, time-dependent birefringence in the piezoelectric material. This induced time-dependent birefringence results in a change in the relative phase difference between the ordinary and extraordinary wave components of a helium-neon laser beam. The change in phase difference between the wave components was measured using a set of linear polarizers. The measured change in phase difference was used to calculate the stress and electric field based on the nonlinear optical properties, the piezoelectric constitutive equations, and the boundary conditions of the PT. Maximum stresses of approximately 10 MPa and electric fields of as high as 6 kV/cm were measured with the optical diagnostic. Measured results were compared to results from both a simple one-dimensional (1D) model of the piezoelectric transformer and a three-dimensional (3D) finite element model. Measured stresses and electric fields along the length of an operating length-extensional PT for two different electrical loads were within at least 50 % of 3D finite element simulated results. Additionally, the 3D finite element results were more accurate than the results from the 1D model for a wider range of electrical load impedances under test.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2014

Pressure-induced transformations in amorphous silicon: A computational study

We study the transformations between amorphous phases of Si through molecular simulations using the environment dependent interatomic potential (EDIP) for Si. Our results show that upon pressure, the material undergoes a transformation from the low density amorphous (LDA) Si to the high density amorphous (HDA) Si. This transformation can be reversed by decompressing the material. This process, however, exhibits clear hysteresis, suggesting that the transformation LDA ↔ HDA is first-order like. The HDA phase is predominantly five-fold coordinated, whereas the LDA phase is the normal tetrahedrally bonded amorphous Si. The HDA phase at 400 K and 20 GPa was submitted to an isobaric annealing up to 800 K, resulting in a denser amorphous phase, which is structurally distinct from the HDA phase. Our results also show that the atomic volume and structure of this new amorphous phase are identical to those of the glass obtained by an isobaric quenching of the liquid in equilibrium at 2000 K and 20 GPa down to 400 K. The similarities between our results and those for amorphous ices suggest that this new phase is the very high density amorphous Si.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗