Search NASA⌕ Search

SEARCH · Search NASA

Results for “Capacitance”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 811 records · Page 45

Lateral displacement and rotational displacement sensor

A position measuring sensor formed from opposing sets of capacitor plates measures both rotational displacement and lateral displacement from the changes in capacitances as overlapping areas of capacitors change. Capacitances are measured by a measuring circuit. The measured capacitances are provided to a calculating circuit that performs calculations to obtain angular and lateral displacement from the capacitances measured by the measuring circuit.

47 OTHER INSTRUMENTATION↗

Ions Beams and Ferroelectric Plasma Sources

Near-perfect space-charge neutralization is required for the transverse compression of high perveance ion beams for ion-beam-driven warm dense matter experiments, such as the Neutralized Drift Compression eXperiment (NDCX). Neutralization can be accomplished by introducing a plasma in the beam path, which provides free electrons that compensate the positive space charge of the ion beam. In this thesis, charge neutralization of a 40~keV, perveance-dominated Ar$^+$ beam by a Ferroelectric Plasma Source (FEPS) is investigated. First, the parameters of the ion beam, such as divergence due to the extraction optics, charge neutralization fraction, and emittance were measured. The ion beam was propagated through the FEPS plasma, and the effects of charge neutralization were inferred from time-resolved measurements of the transverse beam profile. In addition, the dependence of FEPS plasma parameters on the configuration of the driving pulser circuit was studied to optimize pulser design. An ion accelerator was constructed that produced a 30-50~keV Ar$^+$ beam with pulse duration $<$300~$\mu$s and dimensionless perveance $Q$ up to 8$\times$10$^{-4}$. Transverse profile measurements 33~cm downstream of the ion source showed that the dependence of beam radius on $Q$ was consistent with space charge expansion. It was concluded that the beam was perveance-dominated with a charge neutralization fraction of approximately zero in the absence of neutralizing plasma. Since beam expansion occurred primarily due to space charge, the decrease in effective perveance due to neutralization by FEPS plasma can be inferred from the reduction in beam radius. Results on propagation of the ion beam through FEPS plasma demonstrate that after the FEPS is triggered, the beam radius decreases to its neutralized value in about 5~$\mu$s. The duration of neutralization was about 10~$\mu$s at a charging voltage $V_{FEPS}$~=~5.5~kV and 35~$\mu$s at $V_{FEPS}$~=~6.5~kV. With $V_{FEPS}$~=~6.5~kV, the transverse current density profile 33~cm downstream of the source had a Gaussian shape with $x_{rms}$=5~mm, which corresponds to a half-angle divergence of 0.87$^\circ$. The measurements show that near-perfect charge neutralization with FEPS can be attained. No loss of ion beam current was detected, indicating the absence of a neutral cloud in the region of beam propagation, which would cause beam loss to charge exchange collisions. This provides evidence in favor of using FEPS in a future Heavy Ion Fusion accelerator. The FEPS discharge was investigated based on current-voltage measurements in the pulser circuit. Different values of series resistance and storage capacitance in the pulser circuit were used. The charged particle current emitted by the FEPS into vacuum was measured from the difference in forward and return currents in the driving circuit. It was found that FEPS is an emitter of negative charge, and that electron current emission begins approximately 0.5~$\mu$s after the fast-rising high voltage pulse is applied and lasts for tens of $\mu$s. The value of the series resistance in the pulser circuit was varied to change the rise time of the voltage pulse; plasma density was expected to decrease with increasing values of resistance. However, the data showed that changing the resistance had no significant effect. The average charge emitted per shot depends strongly on the value of the storage capacitance. Lowering the capacitance from 141~nF to 47~nF resulted in a near-complete shut-off of charge emission, although the amplitude of the applied voltage pulse was as high, and rise time as short, as when high-density plasma was produced. Increasing the capacitance from 141~nF to 235~nF increased the average charge emitted per shot by a factor of$~$2.

ferroelectric plasma source↗

A novel reduction synthesis of the graphene/Mn{sub 3}O{sub 4} nanocomposite for supercapacitors

Graphene/Mn{sub 3}O{sub 4} nanocomposite is successfully synthesized from graphene oxide (GO)/MnO{sub 2} precursor using dilute hydrazine hydrate assisted hydrothermal reaction (DAH method). X-ray photoelectron spectroscopy (XPS) and Raman characterizations confirm the decrease of oxygen-containing functional groups of GO. The results indicate that GO have been reduced to graphene to a large degree to increase the electronic conductive channels. The morphology and the phase transformation of MnO{sub 2} can be ascribed to the “dissolution-recrystallization” mechanism. Such nanocomposite, as electrode material for supercapacitor, exhibits a high specific capacitance of 326.9 F g{sup −1}, almost 4 times that of GO/MnO{sub 2} precursor (81.3 F g{sup −1}). The good cycle stability of 94.6% capacitance retention after 1000 cycles, can be explained by the firm interfacial cohesion between graphene and Mn{sub 3}O{sub 4} nanoparticle. This soft chemical DAH process could be readily extended to the preparation of other classes of hybrids. - Graphical abstract: The phase transition can be explained by the “dissolution-recrystallization” model. The GO/MnO{sub 2} precursor is reduced into graphene/Mn{sub 3}O{sub 4} by the DAH process, and the electrochemical property is dramatically enhanced. - Highlights: • Graphene/Mn{sub 3}O{sub 4} nanocomposite is firstly synthesized successfully from GO/MnO{sub 2} precursor. • The phase transformation from MnO{sub 2} to Mn{sub 3}O{sub 4} has occurred. • The specific capacitance of the graphene/Mn{sub 3}O{sub 4} (326.9 F/g) is 4 times that of GO/MnO{sub 2} precursor.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Insight into synergy within multi-decorated graphene 3D networks for high performance supercapacitor

Analysis the synergy among different components within graphene based asymmetric supercapacitor could help us to establish the criterion for construction the idea supercapacitor for real applications. For this purpose, 3D Networks for Fe{sub 2}O{sub 3} and α- Ni(OH){sub 2} individually/collectively decorated S-doped graphene composites were successfully synthesized. The electrochemical performances clearly indicate the multi-decorated composite possesses the largest specific capacitance, improved cycle stability and enhanced rate capability due to its efficient additive effect among the different components of supercapacitor. The pronounced high energy density, provided by redox-active transition mental oxide/hydroxide, combined with excellent conductivity, hydrophilia and efficient charge storage, originated from S-doped graphene, result in the excellent composite for asymmetric supercapacitor. Within the voltage range from 0 to 0.44 V versus Ag/AgCl, the specific capacitance of Fe{sub 2}O{sub 3} and Ni(OH){sub 2} co-decorated S-doped graphene composite can be achieved 2386 F g{sup −1} at current density of 1 A g{sup −1}. - Graphical abstract: The electrochemical performances clearly indicate the multi-decorated composite exhibits large specific capacitance, improved rate capability and long cycle stability due to its efficient additive effect among the different components of super-capacitor.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Single step hydrothermal synthesis of carbon nanodot decorated V{sub 2}O{sub 5} nanobelts as hybrid conducting material for supercapacitor application

Carbon nanodot (C-dot) decorated V{sub 2}O{sub 5} (C-dot@V{sub 2}O{sub 5}) nanobelts are synthesized by single step, low cost hydrothermal route at low temperature by using V{sub 2}O{sub 5} and glucose as precursors. We have not added any extra organic solvents or surfactants which are commonly used for the preparation of different nanostructures of V{sub 2}O{sub 5}. Electron microscopy analyses demonstrate that C-dot is entrapped inside V{sub 2}O{sub 5} nanobelts which in turn enhance the conductivity and ion propagation property of this composite material. The C-dot@V{sub 2}O{sub 5} nanobelts exhibit an excellent three electrode electrochemical performance in 1 M Na{sub 2}SO{sub 4} and which showed a specific capacitance of 270 F g{sup −1} at 1 A g{sup −1}, which is ~ 4.5 times higher than the pristine V{sub 2}O{sub 5} electrode. The electrochemical energy storage capacity of this hybrid is investigated towards solid state supercapacitor application also for the first time by employing electrophoretically deposited C-dot as the counter electrode and Li based gel as the electrolyte. The hybrid material delivers an energy density of 60 W h kg{sup −1} and a reasonably high power density of 4.1 kW kg{sup −1} at 5 A g{sup −1} and good cycling stability and capacitance retention of about 87% was observed even after 5000 cycles. Above mentioned results clearly show that C-dot embedded hybrid, nanostructured transition metal oxides has great potential towards fabrication of electrodes for energy storage devices. - Highlights: • Synthesis of C-dot decorated V{sub 2}O{sub 5} by single step hydrothermal reduction method. • A specific capacitance of 270 F g{sup −1} at a current density of 1 A g{sup −1} for three electrode system. • Fabrication of solid state device by using gel electrolyte. • An energy density of 60 W h kg{sup −1} at 1 A g{sup −1} high power density of 4.1 kW kg{sup −1} at 5 A g{sup −1} for C-dot@V{sub 2}O{sub 5}.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Three-dimensional hierarchical and interconnected honeycomb-like porous carbon derived from pomelo peel for high performance supercapacitors

The urgent need for sustainable development of human society has forced material scientists to explore novel materials starting from cheap natural precursors for next-generation energy storage devices by using environmentally friendly strategies. In this work, heteroatom-functionalized porous carbonaceous materials with 3D hierarchical and interconnected honeycomb-like structure have been successfully synthesized by using waste biomass pomelo peel as raw material through the combination of hydrothermal carbonization and followed KOH activation procedure. Benefiting from the unique honeycomb-like structure and high specific surface area, the as-obtained carbon material exhibits satisfactory capacitive behavior: 374 F/g at 0.1 A/g; excellent cycling stability of 92.5% capacitance retention over continuous 5000 cycles. More importantly, the as-assembled symmetric supercapacitors based on as-prepared electrode material can deliver high gravimetric and volumetric energy density of 20 W h/kg and 18.7 W h/L in 6 M KOH, respectively, as well as outstanding cycling stability. The obtained results demonstrate the possibility for taking full advantage of sustainable and large scale advanced carbon materials by choosing waste biomass, particularly the pomelo peel as a raw material. - Graphical abstract: 3D hierarchical and interconnected honeycomb-like porous carbonaceous materials (HPGC) from waste biomass (pomelo peels) were successfully prepared through the combination of hydrothermal carbonization and followed KOH activation procedure. The as-obtained carbon material exhibits satisfactory capacitive behavior. The obtained results demonstrate the possibility for taking full advantage of sustainable carbon materials by choosing biomass waste provided by nature as raw materials. Display Omitted - Highlights: • Pomelo peel was utilized to fabricate heteroatom-functionalized porous carbonaceous materials. • The as-prepared carbon materials contains 3D hierarchical and interconnected honeycomb-like structure. • The obtained carbon material and symmetric device exhibits superior electrochemical performances for supercapacitor.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Batch fabrication of mesoporous boron-doped nickel oxide nanoflowers for electrochemical capacitors

Highlights: • A new facile liquid-phase method has been employed for synthesis boron-doped NiO nanoflowers. • The specific surface area of NiO is as high as 200 m{sup 2} g{sup −1}. • NiO nanoflowers exhibit a high specific capacitance of ∼1309 F g{sup −1} at a charge and discharge current density of 3 A g{sup −1}. • NiO nanoflowers have excellent cycling ability and even after 2500 cycles there is no significant reduction in specific capacitance. - Abstract: Boron-doped nickel oxide (B-NiO) nanoflowers are prepared by simple thermal decomposition of nickel hydroxide. B-NiO is porous sphere with a diameter of about 400 nm. B-NiO nanoflowers are composed of approximately 30 nm nanoplates and the thickness of the nanosheets is approximately 3 nm. The specific surface area of the material is as high as 200 m{sup 2} g{sup −1} and the pore size distribution curves of B-NiO has three typical peaks in the range of mesoporous (5 nm, 13 nm and 18 nm). As an electrode for supercapacitors, the crystalline B-NiO nanoflowers have favorable characteristics, for instance, a specific capacitance of 1309 F g{sup −1} at a current density of 3 A g{sup −1} and no significant reduction in Coulombic efficiency after 2500 cycles at 37.5 A g{sup −1}. This remarkable electrochemical performance will make B-NiO nanoflowers a promising electrode material for high performance supercapacitors.

36 MATERIALS SCIENCE↗

Microwave-assisted rapid synthesis of birnessite-type MnO{sub 2} nanoparticles for high performance supercapacitor applications

Highlights: • Birnessite-type MnO{sub 2} nanoparticles were prepared by the microwave-assisted reflux. • The microwave reaction duration was only 5 min. • A specific capacitance of 329 F g{sup −1} was obtained for birnessite-type MnO{sub 2}. - Abstract: Birnessite-type MnO{sub 2} nanoparticles have been successfully synthesized by the microwave-assisted reflux as short as 5 min. The microstructure and morphology of the products were characterized by X-ray diffraction, N{sub 2} adsorption–desorption isotherms, scanning electron microscopy, transmission electron microscopy. The electrochemical properties of the as-prepared MnO{sub 2} as an electrode material for supercapacitor were investigated by cyclic voltammetry and galvanostatic charge-discharge measurements in 1 M Na{sub 2}SO{sub 4} electrolyte, and a high specific capacitance of 329 F g{sup −1} was achieved at a current density of 0.2 A g{sup −1}. The specific capacitance retention was 92% after 1000 cycles at 2 A g{sup −1}, suggesting that it is a promising electrode material for supercapacitors.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Advanced negative electrode of Fe{sub 2}O{sub 3}/graphene oxide paper for high energy supercapacitors

Highlights: • Novel Fe{sub 2}O{sub 3}/GP (graphene paper) negative electrode for supercapacitors was prepared. • The capacitance of Fe{sub 2}O{sub 3}/GP was ∼3.08 F cm{sup −2} at the density of 5 mA cm{sup −2}. • The Fe{sub 2}O{sub 3}/GP also showed good stability in long-term cyclic process. - Abstract: The development of Fe{sub 2}O{sub 3} with high conductivity and energy density is crucial for practical utilizations of supercapacitors. Here, we demonstrated the preparation of novel Fe{sub 2}O{sub 3}/graphene oxide paper (Fe{sub 2}O{sub 3}/GP) hybrid electrode for high density supercapacitors. Due to the characteristic features of large surface areas and fast electron transportation, the specific areal capacitance of the Fe{sub 2}O{sub 3}/GP was around 3.08 F cm{sup −2} at the charge-discharge current density of 5 mA cm{sup −2}, which is nearly 14 times of the Fe{sub 2}O{sub 3}/carbon paper (Fe{sub 2}O{sub 3}/CP, 0.22 F cm{sup −2}). More importantly, the Fe{sub 2}O{sub 3}/GP hybrid electrode also retained about 95% of the initial capacitance after long-term cyclic process. These findings would help us to develop high effective and stable materials for energy storage devices.

36 MATERIALS SCIENCE↗

Hierarchical Co{sub 3}O{sub 4}@PPy core-shell composite nanowires for supercapacitors with enhanced electrochemical performance

Highlights: • PPy were decorated on Co{sub 3}O{sub 4} nanowire surface via in-situ chemical polymerization. • Specific capacitance of 2122 F g{sup −1}at 5 mA cm{sup −2} was obtained. • The synergistic effect effectively enhanced electrochemical performance. - Abstract: Hierarchical Co{sub 3}O{sub 4}@ polypyrrole (PPy) core-shell composite nanowires (NWs) were successfully fabricated by a template-free hydrothermal route combined with in-situ chemical polymerization. Based on the composition and morphology characterization, it is found that the well-aligned Co{sub 3}O{sub 4} nanowires were uniformly coated with a thin layer of amorphous PPy. When directly used as an electrode material for supercapacitors, the Co{sub 3}O{sub 4}@PPy nanowire arrays exhibited high specific capacitance of 2122 F g{sup −1} (3.18 Fcm{sup −2}) at 5 mA cm{sup −2}, which is much higher than that of the pristine Co{sub 3}O{sub 4} nanowire arrays and improved cycling stability with 77.8% capacitance retention over 5000 cycles at 25 mA cm{sup −2}. The highly electronic conductive and electroactive PPy layer could significantly reduce charge transfer resistance and increase active sites. This synergistic strategy of the arrays structure and the PPy buffer layer can provide simple, efficient and versatile blue-prints for fabrication of Co{sub 3}O{sub 4}-based nanocomposites for extending its application for electrochemical energy storage.

36 MATERIALS SCIENCE↗

Polypyrrole nanowires coated with a hollow shell for enhanced electrochemical performance

Highlights: • A hollow shell coated on polypyrrole nanowires is constructed with the assistance of atomic layer deposition (ALD). • Binder-free electrode of holloe core-shell polypyrrole-TiO{sub 2} is obtained • The hollow core-shell nanostructure shows apparent higher capacitance and better cycling stability than the bare nanowires. - Abstract: Conducting polymers are promising electrode materials for electrochemical capacitors, but are suffered from poor cycling stability and relatively low capacitance. Herein, a hollow shell coated on polypyrrole (Ppy) nanowires is designed and constructed with the assistance of atomic layer deposition (ALD). Ppy nanowires are firstly deposited on flexible carbon cloth by electrodeposition, then a thin sacrificial layer of ZnO and a thin shell of TiO{sub 2} are deposited uniformly on the surfaces of the nanowires. After removing the ZnO layer, a nanogap between the Ppy core and TiO{sub 2} shell is formed thus generate a hollow core-shell Ppy-TiO{sub 2} (noted as Ppy·TiO{sub 2}) nanoarray. When tested as supercapacitor electrodes, the hollow core-shell nanostructure shows apparent higher capacitance and better cycling stability than the bare nanowires. Such enhancement is ascribed to the rational hollow structure design that provides enlarged surface areas and enhanced structure stability. Such hollow structure can be extended to other conducting polymers and electrodes for various electrochemical applications.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Activated biomass carbon made from bamboo as electrode material for supercapacitors

Highlights: • Activated biomass carbon (ABC) produced from bamboo was prepared by carbonization and KOH activation. • The BET and morphology of the ABC have a strong dependence on the activation temperature. • High specific capacitance along with durability is achieved. • Activated biomass carbon can serve as efficient electrode material for energy storage. - Abstract: Activated biomass carbons (ABC) produced from bamboo by carbonization and activation have high specific surface areas and mesoporous structures. The specific surface area, total pore volume, and average pore size of the activated biomass carbon are controlled by adjusting the activation temperature from 700 to 1000 °C. The carbon materials activated at 900 °C have an optimal mesoporous structure with a high specific surface area (2221.1 m{sup 2} g{sup −1}), the highest capacitance (293 F g{sup −1} at 0.5 A g{sup −1} in 3 M KOH aqueous electrolyte) and excellent rate capability (193.8 F g{sup −1} at 20 A g{sup −1}). Symmetric supercapacitors made of the optimal electrodes exhibit a high energy density of 10.9 Wh kg{sup −1} (18.2 Wh L{sup −1}) at a power density of 63 W kg{sup −1} (105 W L{sup −1}) and outstanding capacitance retention of 91.8% over 10,000 cycles. The high electrochemical performance of the mesoporous ABCs show that they are highly promising for energy-storage applications with further optimization.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Size controlled synthesis of SnO2 and its electrostatic self- assembly over reduced graphene oxide for photocatalyst and supercapacitor application

Highlights: • The influence of pH, reaction time and temperature over the control of size of the spheres of SnO{sub 2} by hydrothermal method and further assembly over reduced graphene oxide has been carried out in this report. • The modification of SnO{sub 2} via (3- amino propyl triethoxysilane) makes the electrostatic self- assembly between the positively charged SnO{sub 2} nanostructure and the negatively charged graphene oxide (GO). • The impacts of concentration of GO added to SnO{sub 2} nanostructures and its significance on the morphology and the capacitive property of SnO{sub 2}/rGO composite are evaluated. • The functionalization of graphene enhances the capacitance as well as provides anchoring sites for the decoration by metal oxide nanostructures. - Abstract: Hydrothermally-synthesized, size and shape-controlled SnO{sub 2} nanospheres were electrostatically self-assembled over the surface of reduced graphene oxide (rGO). The control over decoration of SnO{sub 2} nanospheres on rGO was studied by microscopic analysis and the crystallographic structure of SnO{sub 2} hybrid nanocomposites (SnO{sub 2}: rGO) was determined from X-Ray diffraction analysis (XRD). Hybrid nanocomposite in 1:3 ratio exhibited (i) excellent methylene blue degradation capability within 3 min under visible light condition and (ii) high specific capacitance of 337.52 F/g at 0.5 A/g in 1 M H{sub 2}SO{sub 4} electrolyte with 89% of retention after 5000 cycles.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

All-solid-state supercapacitors on silicon using graphene from silicon carbide

Carbon-based supercapacitors are lightweight devices with high energy storage performance, allowing for faster charge-discharge rates than batteries. Here, we present an example of all-solid-state supercapacitors on silicon for on-chip applications, paving the way towards energy supply systems embedded in miniaturized electronics with fast access and high safety of operation. We present a nickel-assisted graphitization method from epitaxial silicon carbide on a silicon substrate to demonstrate graphene as a binder-free electrode material for all-solid-state supercapacitors. We obtain graphene electrodes with a strongly enhanced surface area, assisted by the irregular intrusion of nickel into the carbide layer, delivering a typical double-layer capacitance behavior with a specific area capacitance of up to 174 μF cm{sup −2} with about 88% capacitance retention over 10 000 cycles. The fabrication technique illustrated in this work provides a strategic approach to fabricate micro-scale energy storage devices compatible with silicon electronics and offering ultimate miniaturization capabilities.

36 MATERIALS SCIENCE↗

Simultaneous moisture content and mass flow measurements in wood chip flows using coupled dielectric and impact sensors

An 8-electrode capacitance tomography (ECT) sensor was built and used to measure moisture content (MC) and mass flow of pine chip flows. The device was capable of directly measuring total water quantity in a sample but was sensitive to both dry matter and moisture, and therefore required a second measurement of mass flow to calculate MC. Two means of calculating the mass flow were used: the first being an impact sensor to measure total mass flow, and the second a volumetric approach based on measuring total area occupied by wood in images generated using the capacitance sensor’s tomographic mode. Tests were made on 109 groups of wood chips ranging in moisture content from 14% to 120% (dry basis) and wet weight of 280 to 1100 g. Sixty groups were randomly selected as a calibration set, and the remaining were used for validation of the sensor’s performance. For the combined capacitance/force transducer system, root mean square errors of prediction (RMSEP) for wet mass flow and moisture content were 13.42% and 16.61%, respectively. RMSEP using the combined volumetric mass flow/capacitance sensor for dry mass flow and moisture content were 22.89% and 24.16%, respectively. Either of the approaches was concluded to be feasible for prediction of moisture content in pine chip flows, but combining the impact and capacitance sensors was easier to implement. As a result, in situations where flows could not be impeded, however, the tomographic approach would likely be more useful.

09 BIOMASS FUELS↗

Flexible Pillared Graphene-Paper Electrodes for High-Performance Electrochemical Supercapacitors

Flexible graphene paper (GP) pillared by carbon black (CB) nanoparticles using a simple vacuum filtration method is developed as a high-performance electrode material for supercapacitors. Through the introduction of CB nanoparticles as spacers, the self-restacking of graphene sheets during the filtration process is mitigated to a great extent. The pillared GP-based supercapacitors exhibit excellent electrochemical performances and cyclic stabilities compared with GP without the addition of CB nanoparticles. At a scan rate of 10 mV s -1 , the specific capacitance of the pillared GP is 138 F g -1 and 83.2 F g -1 with negligible 3.85% and 4.35% capacitance degradation after 2000 cycles in aqueous and organic electrolytes, respectively. At an extremely fast scan rate of 500 mV s -1 , the specific capacitance can reach 80 F g -1 in aqueous electrolyte. No binder is needed for assembling the supercapacitor cells and the pillared GP itself may serve as a current collector due to its intrinsic high electrical conductivity. Finally, the pillared GP has great potential in the development of promising flexible and ultralight-weight supercapacitors for electrochemical energy storage.

36 MATERIALS SCIENCE↗

A Study on the Surface Composition and Migration of Materials and Their Effect on Surface Microhardness during Micro-EDM of Ti-6Al-4V

This study aims to investigate the effect of machining parameters on the surface topography and composition of Ti-6Al-4V after micro-EDM as well as the effect of elemental composition on the surface microhardness. The surface topography has been studied in terms of quality of machined surface, crater sizes, and the presence of surface defects. Statistical analysis was carried out to study the influence of micro-EDM process parameters, i.e., voltage, capacitance, discharge energy, electrode rotational speed, and the electrode coating, on the elemental composition of the machined surface. It was found that the crater size, and hence the surface finish, was dependent on the electrical parameters only, with more pronounced effect of capacitance over voltage. The 60 V and 30 pF combination resulted in crater size as small as 1 µm, whereas crater size of 12 µm was obtained using a combination of 4700 pF and 112 V. Although smaller capacitance resulted in smaller crater sizes, it also increased the chances of defects or deposition of debris on the machined surface. There was migration of material from the tool electrode, dielectric oil, and atmosphere to the workpiece surface, which influenced the surface topography, crater sizes, and surface microhardness. The effects of non-electrical parameters on the relative percentage of various elements were found to be statistically insignificant. The surface microhardness was found to increase slightly due to the surface modification after EDM. The reason for increase in surface microhardness was identified as the migration of tungsten from the tool electrode and carbon from the dielectric. The maximum surface microhardness of 455 HV was obtained at a surface composition after micro-EDM containing 7.96% C and 9.69% W, where non-machined Ti-6Al-4V surface does not have any carbon or tungsten on the surface.

36 MATERIALS SCIENCE↗

Keratin-derived functional carbon with superior charge storage and transport for high-performance supercapacitors

In this work, we report a scalable method to synthesize hierarchically porous, hetero-atom doped activated carbon nanosheet from waste biomass-human hair, and demonstrates the use of this carbon as an ultra-high performance electrode material for supercapacitor applications. Microscopic analyses reveal that sheet size ranges from 50 to 200 nm having a thickness of 15–27 nm. As-synthesized, carbon nanosheets possess a hierarchical porous structure having a specific surface area of 1548 m 2 g -1 . Heteroatom concentration (nitrogen, oxygen, and sulfur) of around 25% is confirmed from XPS analysis. Therefore, the novel interconnected hierarchical porous nanosheets structure enables fast adsorption and transportation of ions during electrochemical processes. Also, the abundant chemically available electroactive heteroatom species in the material enhance the wettability of ions and contribute to pseudocapacitance. The electrochemical analyses through cyclic voltammetry and galvanostatic charge-discharge measurements in 6 M KOH reveal the quasi-EDLC behavior of the activated carbons due to the presence of heteroatoms. A reprensentative KOH activated carbon shows an excellent specific capacitance value of 999 F g -1 at a current density of 1 A g -1 . Furthermore, the symmetrically assembled two-electrode device also delivers a maximum energy density of 32 W h Kg -1 at a power density of 325 W Kg -1 . In addition, excellent cyclic stability of 98% capacitance retention is observed after 10,000 continuous GCD cycles even at a high current density of 5 A g -1 . Symmetric flexible supercapacitor device using KOH-PVA-K3FeCN6 as redox gel polymer electrolyte shows a synergistic specific capacitance of 145 mF cm -1 at a current density of 0.8 mA cm -1 exhibiting very less deviation in bending mode. Therefore, this waste biomass derived heteroatom doped hierarchical porous carbon nanosheets can be a promising material for cost-effective high- performance supercapacitor.

42 ENGINEERING↗