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Quarterly Technical Progress Report Piperazine Advanced Stripper (PZAS™) Front End Engineering Design

EXECUTIVE SUMMARY This document summarizes the status of Cooperative Agreement DE-FE0031844, “Piperazine Advanced Stripper (PZAS™) Front-End Engineering Design,” during the reporting period of January 1 through March 31, 2020. The objective of this project is to develop accurate installed costs by conducting a Front-End Engineering Design (FEED) of PZAS™ at Golden Spread Electric Cooperative’s (GSEC) Mustang Station located in Denver City, TX. Complementary benefits include positioning the technology for a commercial project with the 45Q tax credits, qualifying PZAS™ for use on a Natural Gas Combined Cycle (NGCC) Cogen facility, and to provide cost detail to optimize PZAS™ and help guide R&D of second-generation solvent CO2 capture technologies. Results from the FEED will be used to evaluate the economic feasibility of the process at Mustang Station. This project is funded by the U.S. DOE National Energy Technology Laboratory under the aforementioned Cooperative Agreement. Exxon, Total, Chevron, UOP-Honeywell, and the University of Texas (UT) are project co-funders. AECOM and Trimeric are project team members; UT is the prime contractor. Summary of Progress Cooperative Agreement DE-FE0031844 was established in October 2019. The current reporting period, January 1 through March 31, 2020, is the second technical progress reporting period for the project. Several milestones were accomplished during this reporting period, including: • Kickoff Meeting with DOE on February 3, 2020. • Kickoff Meeting with GSEC on March 30, 2020. (Note: Due to Covid-19 travel restrictions and shelter-in-place guidelines, the kickoff meeting was conducted remotely via videoconferencing. See attached notes from that telecon.) • Updated Project Management Plan March 2020, submitted with this quarterly report Other activities during the quarter included progress on contracting and other legal agreements (e.g., non-disclosure agreements), internal kickoff meetings at both AECOM and Trimeric, and development of a Technical Implementation Plan (TIP). The TIP will help the team to make critical, early process decisions and, ultimately, to develop a project and process design basis. Note that all agreements between project team participants are complete as of this submittal, except the vendor agreement with Kiewit (steam cycle modeling). Plans for Next Reporting Period Activities during the next reporting period (April 1, 2020 through June 30, 2020) include: the completion of the Project Design Basis and progress towards the Process Design Basis/Process Design Package (PDP). The Project Design Basis is due as a deliverable and milestone during the next reporting period.

Rochelle, Gary T.↗

Feasibility Study for a Subcritical Assembly at the Oak Ridge National Laboratory

A conceptual design has been completed for a new subcritical assembly at Oak Ridge National Laboratory (ORNL). This subcritical assembly will support the Nuclear Criticality Safety Program (NCSP) training and education program to augment current subcritical assembly capabilities at Sandia National Laboratories (SNL) and at the National Criticality Experiments Research Center (NCERC). The proposed subcritical assembly uses legacy AGN-201M research reactor fuel plates that are available at the Y-12 National Security Complex. This subcritical assembly contains approximately 620 grams of 235 U as UO 2 particulates distributed homogeneously in radiation-stabilized polyethylene. The fuel plates will have a graphite neutron reflector to obtain a core multiplication, $M$, from 10 to 50, corresponding to a k eff of 0.9 to 0.95, respectively. The subcritical assembly will be able to support at least four experiments for the training courses: the addition of fissile material to increase neutron multiplication (mass), a core separation experiment (interaction), the effect of adding moderators to the core (moderation), and the effect of adding neutron absorbers to the core (poison/absorption). The proposed ORNL subcritical assembly will provide additional student bandwidth to support NCSP training courses and to provide for some backup capacity in the event that nuclear facility operations are disrupted at SNL or NCERC due to some unforeseen issue. The subcritical assembly will be designed to be an inherently safe subcritical assembly—subcritical under all normal and abnormal conditions—and it will provide the capability to conduct hands-on training to support NCSP and general nuclear criticality safety (NCS) staff training and qualification goals.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Subcritical Assembly for Training and Education Use at the Oak Ridge National Laboratory

A near-final design has been completed for a new subcritical assembly at Oak Ridge National Laboratory (ORNL). This subcritical assembly will support the Nuclear Criticality Safety Program (NCSP) training and education program to augment current subcritical assembly capabilities at Sandia National Laboratories (SNL) and at the National Criticality Experiments Research Center (NCERC). Other collaborations have been proposed with the Sunrise Consortium and others. This proposed subcritical assembly uses legacy AGN-201M research reactor fuel plates that are available from the Y-12 National Security Complex. This subcritical assembly contains approximately 620 grams of 235 U as UO 2 particulates distributed homogeneously in radiation-stabilized polyethylene. The fuel plates will have a graphite neutron reflector to obtain a core multiplication, M, from 10 to 50, corresponding to a k eff of 0.9 to 0.95, respectively. The subcritical assembly will be able to support at least four experiments for the training courses: (1) the addition of fissile material to increase neutron multiplication (mass), (2) a core separation experiment (interaction), (3) the effect of adding moderators to the core (moderation), and (4) the effect of adding neutron absorbers to the core (poison/absorption). The proposed ORNL subcritical assembly will provide additional student bandwidth to support NCSP training courses and to provide for some backup capacity if nuclear facility operations are disrupted at SNL or NCERC due to some unforeseen issue. The subcritical assembly will be designed to be an inherently safe subcritical assembly—subcritical under all normal and abnormal conditions—and it will provide the capability to conduct hands-on training to support NCSP and general nuclear criticality safety (NCS) staff training and qualification goals.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

A Subcritical Assembly for Training and Education Use at the Oak Ridge National Laboratory [Abstract]

A near-final design has been completed for a new subcritical assembly at Oak Ridge National Laboratory (ORNL). This subcritical assembly will support the Nuclear Criticality Safety Program (NCSP) training and education program to augment current subcritical assembly capabilities at Sandia National Laboratories (SNL) and at the National Criticality Experiments Research Center (NCERC). Other collaborations have been proposed with the Sunrise Consortium and others. This proposed subcritical assembly uses legacy AGN-201M research reactor fuel plates that are available from the Y-12 National Security Complex. This subcritical assembly contains approximately 620 grams of 235 U as UO 2 particulates distributed homogeneously in radiation-stabilized polyethylene. The fuel plates will have a graphite neutron reflector to obtain a core multiplication, M, from 10 to 50, corresponding to a k eff of 0.9 to 0.95, respectively. The subcritical assembly will be able to support at least four experiments for the training courses: (1) the addition of fissile material to increase neutron multiplication (mass), (2) a core separation experiment (interaction), (3) the effect of adding moderators to the core (moderation), and (4) the effect of adding neutron absorbers to the core (poison/absorption). The proposed ORNL subcritical assembly will provide additional student bandwidth to support NCSP training courses and to provide for some backup capacity if nuclear facility operations are disrupted at SNL or NCERC due to some unforeseen issue. The subcritical assembly will be designed to be an inherently safe subcritical assembly—subcritical under all normal and abnormal conditions—and it will provide the capability to conduct hands-on training to support NCSP and general nuclear criticality safety (NCS) staff training and qualification goals.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Addressing Excess Contaminated Facilities and Mercury Cleanup At the Department of Energy's Oak Ridge Reservation - 18408

The U.S. Department of Energy's Oak Ridge Office of Environmental Management (OREM) and its prime cleanup contractor, URS | CH2M Oak Ridge LLC (UCOR) are executing an aggressive program of cleanup and risk reduction in excess contaminated facilities on the Oak Ridge Reservation (ORR). Across the complex, DOE has designated more than 2,300 of its facilities 'excess'. Excess means 'nonoperational' and refers to a facility for which DOE no longer has a mission need. Many of these facilities pose high risk to workers and/or the environment. Delayed cleanup increases risk as well as cost. OREM and UCOR initiated a Working Group on Excess Facilities to identify and prioritize activities that are needed to enhance worker safety, minimize further degradation of the facilities, and reduce the environmental risk. Six Excess Contaminated Facilities projects on the ORR were identified as priorities. Three of the projects are located at ORNL - the Building 7500 Homogenous Reactor Experiment, the Building 3026 Radioisotope Development Laboratory and Buildings 3028/3029 Isotope Facilities. At Y-12, priority excess facilities include the Column Exchange Equipment (COLEX), the Alpha-4 Lithium Enrichment Facility and the Biology Complex Research Facilities. Work on these projects is aimed at stabilization of degraded higher risk facilities, characterization of conditions and hazards, removal of hazardous materials and placement of the facility in the lowest risk condition possible pending demolition. At the same time, DOE and UCOR are preparing to undertake a comprehensive program to remediate the presence of mercury in the water stemming from historical operations at the Y-12 National Security Complex. Over decades of operations, mercury migrated into the environment. Deteriorating conditions of large post-operation mercury-use buildings may be contributing to additional releases. Mercury cleanup is a high priority for Y-12 and the Oak Ridge Reservation. UCOR is completing the final design on a new Mercury Treatment Facility with construction expected to begin in late 2017. When constructed the treatment facility will reduce the amount of mercury in local waters, lower environmental contamination levels and serve as a guard against future releases. (author)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Exploring the Science Trade Space with the JPL Innovation Foundry A-Team

The JPL Innovation Foundry has established a new approach for exploring, developing, and evaluating early concepts with a group called the Architecture Team (A-Team). The A-Team combines innovative collaborative methods and facilitated sessions with subject matter experts and analysis tools to help mature mission concepts. Science, implementation, and programmatic elements are all considered during an ATeam study. In these studies, Concept Maturity Levels (CML) are used to group methods. These levels include idea generation and capture (CML 1), initial feasibility assessment (CML 2), and trade space exploration (CML 3). Methods used for exploring the science objectives, feasibility, and scope will be described including use of a new technique for understanding the most compelling science, called a Science Return Diagram (SRD). In the process of developing the SRD, gradients in the science trade space are uncovered along with their implications for implementation and mission architecture. Special attention is paid towards developing complete investigations, establishing a series of logical claims that lead to the natural selection of a measurement approach. Over 20 science-focused A-Team studies have used these techniques to help science teams refine their mission objectives, make implementation decisions and reveal the mission concept’s most compelling science. This paper will describe the A-Team process for exploring the mission concept's science trade space and the Science Return Diagram technique.In June of 2011 a new collaborative engineering approach forearly concept formulation began in the JPL InnovationFoundry [1], six months later becoming the “A-Team” [2].Responding to a need for exploring mission architecturelevel trades [3], the A-Team precedes Team X [4,5] in asequence of concurrent engineering teams at JPL that can beused to mature a concept from a “cocktail napkin” level ideato a complete mission point design. The A-Team efficientlyexplores the science, implementation, and programmatictrade space in early concept formulation. Small, facilitatedgroups of experts generate innovative ideas, quantitativelyassess feasibility, and discover key sensitivities in the tradespace through collaborative analysis and use of advancedmethods and tools. The A-Team process builds off theexperience within JPL and other recent approaches to earlyconcept formulation [6] including best practices of the JPLInnovation Foundry, Project Systems Engineering &Formulation Section, Team Eureka and the Rapid MissionArchitecture Team[7].The A-Team is a focal point for innovative formulationapproaches and people within JPL. It relies on a largebackground of study resources, creative thinkers and “greybeard” scrutinizers, advanced tools, and subject matterexperts with both breadth and depth in experience andexpertise that are all available at JPL. The A-Team isdesigned to be a rapid and efficient process takingapproximately 6 weeks (the entire process can be as short asjust a few days or as long as up to three months) and costingthe equivalent of a work-month of a full-time employee orless. Studies begin with detailed planning and client reviewfollowed by study sessions, analysis work, and reporting.The staffing on each study is customized to the study goalsand objectives, and it is addressed early in the A-Teamprocess. Sessions are generally half-day or whole-day eventsand conducted over a series of days with focused agendas thatare moderated by a trained facilitator. Preliminary results andknowledge capture are available within hours of each session,and a final report is generally available two weeks later.One of the biggest challenges facing early conceptdevelopment is understanding the gradient in science returnversus various available mission scenarios and payload options. Often times, major areas of scientific inquiry havealready been prioritized by science groups, including throughthe National Research Council’s Decadal Studies inAstronomy, Planetary, and Earth Science. Yet science teamscontinue to struggle, especially in competitive missionsolicitations, to capture the right amount of scope that’sachievable within the cost constraints of the opportunity.Often the desire to completely and comprehensively study ascience area in just one mission (after all, true missionopportunities are rare) drives teams to take on too much,providing requirements that are unachievable within theresources of the opportunity without inducing unacceptableimplementation risk. Alternatively, science teams can seekto reduce risk by using an established instrument, but havenot thought through the traceability and key aspects of thescience question to justify its use. Both scenarios lead to badassumptions at the beginning of the concept development thatcan then ripple through implementation option choices,potentially preventing what would have been a good scienceinvestigation from being selected.The purpose of this paper is first to provide some additionalbackground and summary of the A-Team process, tools,people, and facilities. We then focus on the A-Teammethodology for overcoming the barriers of defining thescience scope well at the early concept development stage.This includes understanding the science story andtraceability, and then examining the gradient in science returnversus key characteristics of observables, developing theright payload and mission requirement specification throughexamining the science and implementation trade space.

Ziemer, John K.↗

Energy Efficient Clothes Dryer with IR Heating and Electrostatic Precipitator

The project goal was to develop a revolutionary energy saving technology for residential clothes drying. The team developed an IR (infrared) heating system and NESP (Nebulizer and Electro-Static Precipitator) for integration into a ventless clothes dryer. The proposed technology addresses two of the major inefficiencies in current electric vented dryers by providing effective energy transfer for the removal of the water and recapture of the vapor latent heat. The IR heaters operating in the mid wave (2.5-10um) are very efficient as they target the 3-micron peak absorption of the water molecule. This allows direct energy absorption, unlike conventional element heaters where heat is transferred by convection. The low power NESP removes water vapor from the exhausted stream and recaptures the latent heat in the ESP (Electro-Static Precipitator) exchanger section. This allows the warm dry air to be recirculated back into the drum for additional efficiency savings. The remaining majority of the dryer hardware stays the same. Summing the efficiency gain from the two subcomponents we anticipated the EF (Efficiency Factor) to exceed the goal of 4.04. EF is obtained by dividing the weight (lbs) of water removed by the energy (kWhr) used, where the test load size is 8.45 lbs of bone dry clothing wetted to 57.5% or 4.8lbs of water, and dried to a remaining moisture content of 2.5-5%. Additional benefits include not having to recondition (heat or cool) the large amounts of make-up air to replace the air exhausted by a vented dryer. It was anticipated that the NESP/heat exchanger would be the most challenging and highest risk element in the program. Therefore, the team focused their efforts during Phase 1 of the program on the design, construction, testing, and optimization of the NESP/heat exchanger. At the end Phase 1, the team compared the performance of the NESP/heat exchanger with the system level requirements and made a Go/No-Go decision on proceeding with the second portion of the program. Phase 2 of the program was structured to develop the IR heating system and then integrate it and the NESP/heat exchanger into a residential clothes dryer prototype for final testing. The proposed technology utilizes heat recovery which is known to have the biggest impact on dryer efficiency. The two current mainstream recovery approaches are air to air exchangers and heat pump condenser systems. Air to air exchanges can be very efficient but require large surface areas which are prone to fouling from uncaptured lint. Dryers based on heat pump condenser recovery systems have shown efficiency improvements of 20–60% and are commercially available. The issue with a heat pump condenser approach is the added cost, as typical prices are twice that of standard vented dryers and they are only available in small to medium capacities. The energy factor (EF) for these systems is 5.50 to 6.88 pounds/kWh compared to conventional dryers at 2.75 to 3.67 pounds/kWh. The efficiency improvements for the proposed technology come from the use of IR heating and the NESP. As the concept is in its infancy, and these improvements were difficult to predict without experimental data, assumptions were made based on available literature. IR radiant drying times, when compared to convection, are typically 30% less. This is a result of the fact that radiant energy heats directly and is absorbed at and below the surface, unlike convection heating, that must conduct the heat through the boundary film of air at the clothes surface and rely on wicking of the moisture to the surface. The second area of improvement comes from the NESP. The NESP operation is as follows: 1. Highly charged, micron sized, droplets of water are injected into the dryer exhaust by the Nebulizer. 2. These charged droplets attract water molecules and continue to grow in size, until losing their charge. During this process, latent heat is rejected back into the air stream. 3. The large droplets enter the ESP, where they are recharged and drawn to the ESP wall, to be extracted at the bottom of the ESP. The warm dry air is then recirculated back into the dryer. The proposed technology, at the time of the proposal submission was estimated to have an EF of 4.79. At program completion we have designed, built, tested, integrated and optimized the proposed technologies into a prototype “high efficiency” residential clothes dryer. Testing of the integrated prototype dryer provided insight into the technical effectiveness and economic feasibility of the proposed technologies. The program has the potential of greatly impacting energy savings. The predicted EF of the proposed technology is 4.79, yielding an energy savings of 42% when compared to conventional electric vented dryers. Given there are approximately 84 million dryers in the US consuming ~64 billion kWh per year, a net savings of 27 billion kWh per year or 0.092 quads could be realized. Since the dryer is not vented, make up air from the room is not needed, adding an additional savings of ~1kWh per load, or 23.8 billion kWh per year. In addition, it is envisioned that the proposed ESP, when successful, would potentially find applications in industrial and residential dehumidification.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Opportunities for Lighter Weight and Lower Total Cost Component Manufacturing

This paper describes how a relatively new manufacturing technology known as additive manufacturing (AM) can enable creation of more mass efficient components when compared to those created by conventional or subtractive manufacturing (SM). An important element in the use of AM is re-thinking the design approach when completely new shape possibilities are enabled. Similarly, creative use of AM also can enable significant part count reduction. In order to make the case for the potential of AM, the more common AM processes are described and illustrated. As with any new technology, there come challenges during the reduction to practice phase of AM. Some of these challenges have been addressed and solved. Others are a work in progress and the approach to possible solutions to some of these is described.

Williams, James C.↗

Precise measurement of nuclear interaction cross sections towards neutron-skin determination with R 3 B

The R 3 B (Reactions with Relativistic Radioactive Beams) experiment as a major instrument of the NUSTAR collaboration for the research facility FAIR in Darmstadt is designed for kinematically complete studies of reactions with high-energy radioactive beams. Part of the broad physics program of R 3 B is to constrain the asymmetry term in the nuclear equation-of-state and hence improve the description of highly asymmetric nuclear matter (e.g., in neutron stars). For a precise determination of the neutron-skin thickness – an observable which is directly correlated with the symmetry energy in theoretical calculations – by measuring absolute fragmentation cross sections, it is essential to quantify the uncertainty and challenge the reaction model under stable conditions. During the successful FAIR Phase-0 campaign of R 3 B, we precisely measured the energy dependence of total interaction cross sections in 12 C + 12 C collisions, for a direct comparison with calculations based on the eikonal reaction theory.

Ponnath, L. (ORCID:0000000286742624)↗

Challenges in the post-licensing stage of U.S. hydropower development: Current status and some potential solutions

The issuance of a Federal Energy Regulatory Commission (FERC) license is an important milestone in the development process of new U.S. hydropower projects. The complexity and uncertain timeline of the licensing process have been often cited as a key deterrent to new hydropower installations in the United States. However, very little attention has been paid to post-licensing timelines and attrition rates. This article explores the challenges faced by developers in bringing their FERC-licensed hydropower projects to the construction stage. Post-licensing activities to be completed before starting construction include obtaining additional permitting from other federal or state agencies, completing the technical design, securing financing, and in most cases, negotiating a power purchase agreement. For the set of projects that obtained a FERC license between 2007 and 2018, we assembled a dataset—combining information from FERC dockets and responses from a questionnaire to developers—to calculate attrition rates and development timelines and to examine the reasons for delays and cancellations.

13 HYDRO ENERGY↗

Role of backbone strain in de novo design of complex α/β protein structures

Abstract We previously elucidated principles for designing ideal proteins with completely consistent local and non-local interactions which have enabled the design of a wide range of new αβ-proteins with four or fewer β-strands. The principles relate local backbone structures to supersecondary-structure packing arrangements of α-helices and β-strands. Here, we test the generality of the principles by employing them to design larger proteins with five- and six- stranded β-sheets flanked by α-helices. The initial designs were monomeric in solution with high thermal stability, and the nuclear magnetic resonance (NMR) structure of one was close to the design model, but for two others the order of strands in the β-sheet was swapped. Investigation into the origins of this strand swapping suggested that the global structures of the design models were more strained than the NMR structures. We incorporated explicit consideration of global backbone strain into the design methodology, and succeeded in designing proteins with the intended unswapped strand arrangements. These results illustrate the value of experimental structure determination in guiding improvement of de novo design, and the importance of consistency between local, supersecondary, and global tertiary interactions in determining protein topology. The augmented set of principles should inform the design of larger functional proteins.

59 BASIC BIOLOGICAL SCIENCES↗

Polymers with controlled assembly and rigidity made with click-functional peptide bundles

The engineering of biological molecules is a key concept in the design of highly functional, sophisticated soft materials. Biomolecules exhibit a wide range of functions and structures, including chemical recognition (of enzyme substrates or adhesive ligands, for example), exquisite nanostructures (composed of peptides, proteins or nucleic acids), and unusual mechanical properties (such as silk-like strength, stiffness, viscoelasticity and resiliency). Here we combine the computational design of physical (noncovalent) interactions with pathway-dependent, hierarchical ‘click’ covalent assembly to produce hybrid synthetic peptide-based polymers. The nanometre-scale monomeric units of these polymers are homotetrameric, α-helical bundles of low-molecular-weight peptides. These bundled monomers, or ‘bundlemers’, can be designed to provide complete control of the stability, size and spatial display of chemical functionalities. The protein-like structure of the bundle allows precise positioning of covalent linkages between the ends of distinct bundlemers, resulting in polymers with interesting and controllable physical characteristics, such as rigid rods, semiflexible or kinked chains, and thermally responsive hydrogel networks. Chain stiffness can be controlled by varying only the linkage. Moreover, by controlling the amino acid sequence along the bundlemer periphery, we use specific amino acid side chains, including non-natural ‘click’ chemistry functionalities, to conjugate moieties into a desired pattern, enabling the creation of a wide variety of hybrid nanomaterials.

36 MATERIALS SCIENCE↗

Full in silico DFT characterization of lanthanum and yttrium based oxynitride semiconductors for solar fuels

Finding new solar-energy absorber materials is one of the most significant challenges in artificial photosynthesis. Starting from the experimentally available LaTaON 2 and LaTiO 2 N oxynitrides, we use DFT to propose new sunlight absorbing semiconductors. The synthetically unknown YTaON 2 and YTiO 2 N are semiconductors with indirect band gaps of 2.7 eV and 2.9 eV, respectively. For the first time, we compute within Boltzmann transport theory the DOS-averaged effective mass and mobility of LaTaON 2 , LaTiO 2 N, YTaON 2 and YTiO 2 N. Our first principles calculations indicate that the Y-based materials possess advantageous dielectric (ε r ≥ 47), optical (α ≥ 10 4 cm –1 near band edge), and charge transport properties (m e,h*DOS ≈ 0.2; μ e,h ≈ 10 2 cm 2 V –1 s –1 ) for the conversion of solar energy into storable fuels. Furthermore, our work leads to the complete in silico design of semiconductors for water splitting.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Selective designer hydrolysates from Miscanthus bioenergy crop for sustainable utilization

Designer enzymatic hydrolysates deliver targeted, optimized fermentable sugars while reducing the formation of inhibitory by-products. Herein, five distinct enzymatic hydrolysates (EH) were generated from Miscanthus biomass using alkaline-ethanol fractionation and hydrothermal-mechanical refining (HMR) pretreatment approaches. Noticeably, alkali-ethanol fractionated hemicellulose A (HMA) and hemicellulose B (HMB) hydrolysis resulted in xylose-rich enzymatic hydrolysates with 104.8 ± 5.6 g L −1 and 173.4 ± 4.6 g L −1 xylose, respectively. All five hydrolysates encompassing varied carbon to nitrogen ratios were evaluated for lipid production using an engineered oleaginous yeast, R. toruloides 880-ADS. Microbial fermentation of xylose-rich hydrolysates, viz. HMR-EH2, HMA-EH, and HMB-EH, resulted in lipid yields ranging from 0.05 to 0.12 g g −1 sugar. Compositional and 2D NMR analyses revealed that HMA-EH residues are highly lignin-enriched while preserving the non-condensed structure conducive to valorization. Overall, the findings highlighted a novel, selective trade-off approach for maximizing lipid titers from designer hydrolysates, corroborating complete resource recovery for establishing integrated biorefineries.

Singh, Shuchi [University of Illinois at Urbana-Ch↗

Plasma production and ion heating systems for the Material Plasma Exposure eXperiment

Plasma production and ion heating in the Material Plasma Exposure eXperiment (MPEX), whose design is nearing completion, is accomplished using continuous wave RF power with average power density up to 1.6 MW/m2 at the plasma interface. Plasma is produced using helicon waves coupled through a single helical antenna at 13.56 MHz with power supplied by three 100 kW fixed-frequency RF generators feeding a power combiner network followed by the matching network and launcher. The helicon source can utilize various gasses including hydrogen, deuterium, and helium, with a magnetic field strength in the source region up to 0.2 T, and maximum device |B| of 2.5 T. Power is coupled to ions via ion cyclotron heating at the fundamental resonance using a pair of phased helical antennas operating in the frequency range 4-9 MHz, that launch waves towards the resonance from the antenna region where ω > ωci. ICH power is supplied by a single 500 kW tunable RF transmitter through a 90° power splitter and matching/decoupling network. In the case of both the helicon and ICH systems the antennas are located external to the vacuum, with power transferred through novel water-cooled coaxial vacuum windows consisting of fused quartz outer cylinders and silicon nitride inner cylinders with forced convection water cooling between them. The antenna enclosures are pressurized with dry air to 3 bar absolute for voltage standoff.Several 3-D COMSOL models have been created to simulate the two systems. A model of the helicon region utilizing a cold plasma dielectric tensor with accurate magnetic field and realistic plasma density profiles has been used to calculate the plasma loading/complex antenna input impedance at the launcher feed for various ne and |B| values, for the purpose of estimating power handling. It also incorporates the geometry of all launcher structures relevant to this determination. A still more detailed model of the launcher together with a lossy dielectric plasma surrogate has been used to determine RF electric field values and power losses in the device components.Similar models have been produced to predict the performance and power handling of the ICH launcher. For this device the impedance matrix of the two-element antenna array is calculated using a warm plasma model, necessary to properly determine the wave propagation and absorption.

Goulding, Richard↗

Cryogenics and purification systems of the ICARUS T600 detector installation at Fermilab

This paper describes the cryogenic and purification systems of the ICARUS T600 detector in its present implementation at the Fermi National Laboratory, Illinois, U.S.A. The ICARUS T600 detector is made of four large Time Projection Chambers, installed in two separate containers of about 275 m 3 each. The detector uses liquid argon both as target and as active medium. For the correct operation of the detector, the liquid argon must be kept in very stable thermal conditions and the contamination of electronegative impurities must be consistently kept at the level of small fractions of parts per billion. The detector was previously operated in Italy, at the INFN Gran Sasso Underground Laboratory (LNGS), in a three-year run on the CERN to LNGS Long Baseline Neutrino Beam. For its operation on the Booster and NuMI neutrino beams at Fermilab, for the search of sterile neutrinos and measurements of neutrino-argon cross sections, the detector was moved from Gran Sasso to CERN for the upgrades required for operation at shallow depth with high intensity neutrino beams. The liquid argon containers, the thermal insulation and all the cryogenic equipment have been completely re-designed and rebuilt, following the schemes of the previous installation in Gran Sasso. The detector and all the equipment have been transported to Fermilab, where they have been installed, tested and recently put into operation. The work described in this paper has been conducted as a joint responsibility of CERN and Fermilab with the supervision provided by the ICARUS Collaboration. Design, installation, testing, commissioning and operation are the result of a common effort of CERN, Fermilab and INFN groups.

Cryogenic detectors↗

Progress on the Development of the Nb 3 Sn 11T Dipole for the High Luminosity Upgrade of LHC

The high-luminosity large hadron collider (LHC) project at CERN entered into the production phase in October 2015 after the completion of the design study phase. In the meantime, the development of the 11 T dipole needed for the upgrade of the collimation system of the machine made significant progress with very good performance of the first two-in-one magnet model of 2-m length made at CERN. The 11 T dipole, which is more powerful than the current main dipoles of LHC, can be made shorter with an equivalent integrated field. This will allow creating space for the installation of additional collimators in specific locations of the dispersion suppressor regions. Following tests carried out during heavy ions runs of LHC in the end of 2015, and a more recent review of the project budget, the installation plan for the 11 T dipole was revised. Consequently, one 11 T dipole full assembly containing two 11 T dipoles of 5.5-m length will be installed on either side of interaction point 7. These two units shall be installed during the long shutdown 2 in years 2019-2020. After a brief reminder on the design features of the magnet, this paper describes the current status of the development activities, in particular the short model programme and the construction of the first full scale prototype at CERN. Finally, critical operations such as the reaction treatment and the coil impregnation are discussed, the quench performance tests results of the two-in-one model are reviewed and finally, the plan toward the production for the long shut down 2 is described.

43 PARTICLE ACCELERATORS↗

Design and Analysis of High Heat Flux Plasma-Facing Components for NSTX Upgrade

The National Spherical Tokamak Experiment (NSTX) upgrade (NSTX-U) requirements lead to enhanced heat loads on plasma-facing components (PFCs) especially in the divertor regions, where normal heat flux density can reach up to 8 MW/m 2 . For these high heat flux (HHF) regions, the PFCs were redesigned, to use castellations which relieved the thermal stresses associated with high incident heat flux. Another design feature of HHF PFCs is the absence of front face mounting holes which create localized areas of high temperature and thermal stress concentrations. Optimized shaping of the front face of the HHF PFCs eliminates regions where the front face is perpendicular to the heat flux direction during normal helicity operation and spreads the heat load. A unique mechanism was designed to connect PFC tiles to the NSTX-U center stack casing using locking features accessible from the low heat flux regions. Isotropic graphite was selected as the HHF PFC tile material. Initial tile design parameters were accessed using analytical expressions for pulsed heat flux loading. A working prototype of the locking mechanism was created during the initial stages of the design to prove the concept performance. This article presents an overview of the divertor HHF PFC design and the results of the thermal and structural analyses performed using ANSYS software. The results of the analyses cover normal operating conditions and disruptions which impose electromagnetic (EM) loads from eddy and halo currents. The 3-D, transient, nonlinear analyses took into account the temperature-dependent properties of the materials, friction interfaces between the parts, and variable electric properties of the parts and interfaces. The results confirm that the HHF PFC tiles remain within the allowable limits for the loads defined by the NSTX-U Recovery Project. In addition, tolerance stack up analyses were performed to ensure tile performance in the worst possible assembly configuration. Finally, the design process was completed successfully, and the NSTX HHF PFC tiles are currently in the production phase.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗